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Appendix A

Binary Diffusion Coefficients


Table A.l Mass Diffi Livities in Gases
System T, K DABP,m*-Pds System T, K DABP,m2-Pds
Air Carbon dioxide
Ammonia 273 2.006 Ethanol 273 0.702
Aniline 298 0.735 Ethyl ether 273 0.548
Benzene 298 0.974 Hydrogen 273 5.572
Bromine 293 0.923 Methane 273 1.550
Carbon dioxide 273 1.378 Methanol 298.6 1.064
Carbon disulfide 273 0.894 Nitrogen 298 1.672
Chlorine 273 1.256 Nitrous oxide 298 1.185
Diphen yl 49 1 1.621 Propane 298 0.874
Ethyl acetate 273 0.7 18 Water 298 1.661
Ethanol 298 1.337 Hydrogen
Ethyl ether 293 0.908 Ammonia 293 8.600
Iodine 298 0.845 Argon 293 7.800
Methanol 298 1.641 Benzene 273 3.211
Mercury 614 4.79 1 Ethane 273 4.447
Naphthalene 303 0.870 Methane 273 6.331
Nitrobenzene 298 0.879 Oxygen 273 7.061
n-Octane 298 0.610 Pyridine 318 4.427
Oxygen 273 1.773 Nitrogen
Propyl acetate 315 0.932 Ammonia 293 2.441
Sulfur dioxide 273 1.236 Ethylene 298 1.651
Toluene 298 0.855 Hydrogen 288 7.527
Water 298 2.634 Iodine 273 0.709
Ammonia Oxygen 273 1.834
Ethylene 293 1.793 Oxygen
Carbon dioxide Ammonia 293 2.563
Benzene 318 0.724 Benzene 296 0.95 1
Carbon disulfide 318 0.724 Ethylene 293 1.844
Ethyl acetate 319 0.675 Water 308.1 2.857
Source: Welty, J. R., C. E. Wicks, and R. E. Wilson, Fundamentals of Momentum, Heat,
and Mass Transfer, 3rd ed., Wiley, New York (1984).

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564 Appendix A Binary Diffusion Coefficients

Table A.2 Mass Diffusivities in Liauids at Infinite Dilution


System T, K D>x lo5,cm2/s System T, K D0mx lo5,cm2/s
Chloroform (solvent B) Ethyl acetate (solvent B)
Acetone 298 2.35 Acetic acid 293 2.18
Benzene 288 2.5 1 Acetone 293 3.18
Ethanol 288 2.20 Ethyl benzoate 293 1.85
Ethyl ether 298 2.13 MEK 303 2.93
Ethyl acetate 298 2.02 Nitrobenzene 293 2.25
MEK 298 2.13 Water 298 3.20
Benzene (solvent B) Water (solvent B)
Acetic acid 298 2.09 Methane 298 1.49
Aniline 298 1.96 Air 298 2.00
Benzoic acid 298 I .38 Carbon dioxide 298 1.92
Bromobenzene 28 1 1.45 Chlorine 298 1.25
Cyclohexane 298 2.09 Argon 298 2.00
Ethanol 288 2.25 Benzene 298 1.02
Formic acid 298 2.28 Ethanol 288 1.oo
n-Heptane 353 4.25 Ethane 298 1.20
MEK 303 2.09 Oxygen 298 2.10
Naphthalene 28 1 1.19 Pyridine 288 0.58
Toluene 298 1.85 Aniline 293 0.92
Vinyl chloride 28 1 1.77 Ammonia 298 1.64
Acetone (solvent B) Ethylene 298 1.87
Acetic acid 288 2.92 Ally1 alcohol 288 0.90
Acetic acid 313 4.04 Acetic acid 293 1.19
Benzoic acid 298 2.62 Benzoic acid 298 1.oo
Formic acid 298 3.77 Propionic acid 298 1.06
Water 298 4.56 Vinyl chloride 298 1.34
Ethanol (solvent B) Ethylbenzene 293 0.81
Benzene 298 1.81 Sulfuric acid 298 1.73
Water 298 1.24 Nitric acid 298 2.60
Sources: Reid, R. C., J. M. Prausnitz, and B. E. ding, The Properties of Gases and
Liquids, 4th ed., McGraw-Hill, New York (1987); Cussler, E. L., Diffusion, Mass
Transfer in Fluid Systems, 2nd ed., Cambridge University Press, Cambridge, UK (1997).
Appendix A Binary Diffusion Coefficients 565

Table A.3 Mass Diffusivities in the Solid State


System T, K Diffusivity, cm2/s
Hydrogen in iron 283 1.66 x 10-9
323 11.4~10-9
373 124 x 10-9
Hydrogen in nickel 358 11.6 ~ 1 0 - 9
438 10.5 x 10-8
Carbon monoxide in nickel 1223 4.00 x 10-8
1323 14.0 x 10-8
Aluminum in copper 1123 2.20 x 10-9
293 1.30 x 10-30
Uranium in tungsten 2000 1.30 x 10-11
Cerium in tungsten 2000 95.0 x 10-11
Yttrium in tungsten 2000 1820 x 10-11
Tin in lead 558 1.60 x 10-10
Gold in lead 558 4.60 x 10-10
Gold in silver 1033 3.60 x 10-10
Antimony in silver 293 3.60 x 10-10
Zinc in aluminum 773 2.00 x 10-9
Silver in aluminum 323 1.20 x 10-9
Bismuth in lead 293 1.10 x 10-16
Cadmium in copper 293 2.70 x 10-15
Carbon in iron 1073 1.50 x 10-8
1373 45.0 x 10-8
Helium in silica 293 4.00 x 10-10
773 7.80 x 10-8
Hydrogen in silica 473 6.50 x 10-10
773 1.30 x 10-8
Helium in Pyrex 293 4.50 x 10-11
773 2.00 x 10-8
Sources: Barrer, R. M., Diffusion in and Through Solids, Macmillan, New York (1941);
American Society for Metals, Diffusion, ASM (1973); Cussler, E. L., Diffusion,Muss
Transfer in Fluid Systems, 2nd ed., Cambridge University Press, Cambridge, UK (1997).
Appendix B
Lennard-Jones Constants
Determined from Viscosity Data
Compound 0 9 8 , Elk, K

Ar Argon 3.542 93.3


He Helium 2.55 1 10.22
Kr Krypton 3.655 178.9
Ne Neon 2.820 32.8
Xe Xenon 4.047 23 1.O
Air Air 3.620 97.0
ASH^ Arsine 4.145 259.8
BCl3 Boron chloride 5.127 337.7
BF3 Boron fluoride 4.198 186.3
B(OCH3)3 Methyl borate 5.503 396.7
Br2 Bromine 4.296 507.9
CC4 Carbon tetrachloride 5.947 322.7
CF4 Carbon tetrafluoride 4.662 134.0
CHC13 Chloroform 5.389 340.2
CH2C12 Methylene chloride 4.898 356.3
CH3Br Methyl bromide 4.1 18 449.2
CH3Cl Methyl chloride 4.182 350.0
CH30H Methanol 3.626 481.8
CH4 Methane 3.758 148.6
co Carbon monoxide 3.690 91.7
cos Carbonyl sulfide 4.130 336.0
co2 Carbon dioxide 3.941 195.2
cs2 Carbon disulfide 4.483 467.0
C2H2 Acetylene 4.033 23 1.8
C2H4 Ethylene 4.163 224.7
C2H6 Ethane 4.443 215.7
C2H5Cl Ethyl chloride 4.898 300.0
C2H50H Ethanol 4.530 362.6
C2N2 Cyanogen 4.361 348.6
CH30CH3 Methyl ether 4.307 395.0
CH2CHCH3 Propylene 4.678 298.9

566
Appendix B Lennard-Jones Constants 567

Lennard-Jones Constants Determined from Viscosity Data


Compound 0 9 8 , elk, K

Methylacetylene 4.761 251.8


Cyclopropane 4.807 248.9
Propane 5.118 237.1
n-Propyl alcohol 4.549 576.7
Acetone 4.600 560.2
Methyl acetate 4.936 469.8
n-Butane 4.687 531.4
Isobutane 5.278 330.1
Ethyl ether 5.678 313.8
Ethyl acetate 5.205 521.3
n-Pentane 5.784 341.1
2,2-Dimethylpropanone 6.464 193.4
Benzene 5.349 412.3
Cyclohexane 6.182 297.1
n-Hexane 5.949 399.3
Chlorine 4.217 316.0
Fluorine 3.357 112.6
Hydrogen bromide 3.353 449.0
Hydrogen cyanide 3.630 569.1
Hydrogen chloride 3.339 344.7
Hydrogen fluoride 3.148 330.0
Hydrogen iodide 4.211 288.7
Hydrogen 2.827 59.7
Water 2.641 809.1
Hydrogen peroxide 4.196 289.3
Hydrogen sulfide 3.623 301.1
Mercury 2.969 750.0
Mercuric bromide 5.080 686.2
Mercuric chloride 4.550 750.0
Mercuric iodide 5.625 695.6
Iodine 5.160 474.2
Ammonia 2.900 558.3
Nitric oxide 3.492 116.7
Nitrogen 3.798 71.4
Nitrous oxide 3.828 232.4
Oxygen 3.467 106.7
Sulfur hexafluoride 5.128 222.1
Sulfur dioxide 4.112 335.4
uF6 Uranium hexafluoride 5.967 236.8
Source: Reid, R. C., J. M. Praunitz, and B. E. Poling, The Properties of Gases and
Liquids, 4th ed., McGraw-Hill, New York (1987).

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