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I. Aim (s)
The aims of this experiment are as the following; to understand the principle of
photocatalysis degradation using a semiconductor material; to compare the effectiveness of
dye degradation of dye photocatalysts using metal oxides; and to understand the awareness of
environmental and alternative waste treatment that is environmentally friendly and
inexpensive.
II. Theoretical background
Metal oxides are of great technological importance in environmental remediation
and electronics because of their capability to generate charge carriers when simulated
with required amount of energy. Metal oxides such as oxides of vanadium, chromium,
titanium, zinc, tin, and cerium having these caracteristics follow similar primary
photocatalytic processes such as light absorption, which induces a charge separation
process with the formation of positive holes that are able to oxidize organic substrates
(Khan, et al., 2015).
The TiO2, a wide band-gap semiconductor oxide, is an exceptional material that
is widely applied in photocatalysis, electrochromic devices, and dye-sensitized solar cells
(Wang, et al., 2006). TiO2 powders have been commonly used as white pigments from
ancient times. They are inexpensive, chemically stable and harmless, and have no
absorption in the visible region. Therefore, they have a white color. However, the
chemical stability of TiO2 holds only in the dark, Instead, it is active under UV light
irradiation, inducing some chemical reactions. Such activity under sunlight was known
from the flaking of paints and the degradation of fabrics incorporating TiO2 (Hashimoto,
K, et al., 2005).
Photocatalysis is a science of employing catalyst that is utilized for speeding up
chemical reactions that requires or engages light. A photocatalyst is defined as a material
that is capable of absorbing light, producing electron-hole pairs that enable chemical
transformations of the reaction partic ipants and regenerate its chemical composition after
each cycle of such interactions. There are two types of photocatalytic reactions;
homogeneous photocatalysis and heterogeneous photocatalysis. The significant features
of the photocatalytic systems are the desired band gap, suitable morphology, high surgace
area, stability and reusability (Khan, et al., 2015). The photocatalytic properties of certain
materials have been used to convert solar energy into chemical energy to oxidize or
reduce materials to obtain useful materials including hydrogen and hydrocarbons, and to
remove pollutants and bacteria on wall surfaces in air and water (Hakata, et al.,2012).
TiO2 photocatalysis is widely used in a variety of applications and products in
the environmental and energy fields, including self-cleaning surfaces, air and water
purification systems, sterilization, hydrogen evolution, and photochemical conversion.
The photocatalytic properties of TiO2 are derived from the formation of photogenerated
charge carriers (hole and electro) which occurs upon the absorption of ultraviolet (UV)
light corresponding to the band gap. The photogenerated holes in the valence band
diffuse to the TiO2 surgace and react with adsorbed water molecules, forming hydroxyl
radicals ([dot]OH)(Nakata, et al., 2012).
Methylene blue or now called, methylthionium chloride is use
III. Experimental method
a. Materials
The materials used in this experiment were as the following; TiO2 or ZnO, source of UV,
and pigment.
b. Equipment
The equipment used in this experiment were as the following; UV-VIS
Spectrophotometer,
c. Procedure
IV. Result and discussion
a. Experimental Result
b. Discussion
Each dye solution will be degraded using a TiO2 photocatalyst. The process of
photocatalysis is done by using a room that irradiated UV lamps within a certain period
of time. Ultraviolet radiation which is often abbreviated as UV is electromagnetic
radiation to the shorter wavelength of the area with visible light.
Absorption of UV rays by TiO2 will form electrons (e) in the conduction band
and hole (h +) in the valence band. The electrons react with oxygen in the sample to form
anions (O2-), while the holes react with hydroxyl ions to form hydroxyl radicals (OH).
This OH (OH) radical strikes the dye molecule, creating intermediate molecules so that it
can be degraded into a CO2 and H2O molecule for some time. The degradation rate is
related to the formation of OH radicals (OH) which is the most important species in the
degradation process. The reaction of OH radical formation (OH) and dye degradation is
expressed in the following equation.
V. Conclusion
VI. References
Khan, M. M., Adil, S. F., Al-Mayouf, A. 2015. Metal oxides as photocatalysts. Journal of
Saudi Chemical Society, 19 (5), 462-464, pp.
Hashimoto, K., Irie, H., Fujishima, A. 2005. TiO2 Photocatalysis: A Historical Overview and
Future Prospects. Japanese Journal of Applied Physics, 44(12), 8269-8285 [Part 1], pp.
Nakata, K., Fujishima, A. 2012. TiO2 photocatalysis: Design and applications. Journal of
Photochemistry and Photobiology C: Photochemistry Reviews, 13, 169-189, pp.
Wang, N,. Lin, H., Li, J., Zhang, L., Lin, C., Li, X. 2006. Crystalline Transition from
H2Ti3O7 Nanotubes to Anatase Nanocrystallines Under Low-Temperature Hydrothermal
Conditions, J. Am. Ceram. Soc., 89 (11), 3564-3566, pp.