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Chemistry
(Advanced Level)
39
9729 H2 CHEMISTRY (2017)
40
9729 H2 CHEMISTRY (2017)
1
rest mass of proton, 1H mp = 1.67 × 10–27 kg
1
rest mass of neutron, 0 n mn = 1.67 × 10–27 kg
0
rest mass of electron, −1 e me = 9.11 × 10–31 kg
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9729 H2 CHEMISTRY (2017)
2 Ionisation energies (1st, 2nd, 3rd and 4th) of selected elements, in kJ mol–1
H 1 1310 – – –
He 2 2370 5250 – –
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9729 H2 CHEMISTRY (2017)
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9729 H2 CHEMISTRY (2017)
3 Bond energies
Homonuclear Heteronuclear
Cl―Cl 244
Br―Br 193
I―I 151
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9729 H2 CHEMISTRY (2017)
Homonuclear Heteronuclear
N―H 390
N―Cl 310
O―H 460
Si―Cl 359
Si―H 320
P―H 320
P―Cl 330
P―O 340
P=O 540
S―H 347
S―Cl 250
S―O 360
S=O 500
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9729 H2 CHEMISTRY (2017)
Electrode reaction E! / V
Ag+ + e– ! Ag +0.80
Al 3+ + 3e– ! Al –1.66
Cu+ + e– ! Cu +0.52
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9729 H2 CHEMISTRY (2017)
Electrode reaction E! / V
K+ + e – ! K –2.92
Li+ + e– ! Li –3.04
Na+ + e– ! Na –2.71
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9729 H2 CHEMISTRY (2017)
Electrode reaction E! / V
All ionic states refer to aqueous ions but other state symbols have been omitted.
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9729 H2 CHEMISTRY (2017)
Electrode reaction E! / V
Ag+ + e– ! Ag +0.80
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9729 H2 CHEMISTRY (2017)
Electrode reaction E! / V
K+ + e – ! K –2.92
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9729 H2 CHEMISTRY (2017)
(b) Period 2
F 0.072 F– 0.136
(c) Period 3
Cl 0.099 Cl – 0.181
(d) Group 2
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9729 H2 CHEMISTRY (2017)
(f) Group 17
Cl 0.099 Cl – 0.181
At 0.140
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9729 H2 CHEMISTRY (2017)
aldehyde 9.3–10.5
amide 5.0–12.0
Note: δ values for "O"H and "N"H protons can vary depending on solvent and concentration.
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9729 H2 CHEMISTRY (2017)
Appearance of peak
Functional groups containing Absorption range (in
Bond (s = strong,
the bond wavenumbers) / cm–1
w = weak)
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9729 H2 CHEMISTRY (2017)
The position of the incoming group, E, is determined by the nature of the group, G, already bonded to the
ring, and not by the nature of the incoming group E.
Reactivity of ring
(compared to Activated Deactivated Deactivated
benzene)
Position of E
(relative to position 2- and/or 4- 2- and/or 4- 3-
of G)
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9729 H2 CHEMISTRY (2017)
reaction with
cation
NaOH(aq) NH3(aq)
ammonium,
ammonia produced on heating –
NH4+ (aq)
barium, no ppt.
no ppt.
Ba2+(aq) (if reagents are pure)
grey-green ppt.
chromium(III), grey-green ppt.
soluble in excess
Cr3+(aq) insoluble in excess
giving dark green solution
blue ppt.
copper(II), pale blue ppt.
soluble in excess
Cu2+(aq), insoluble in excess
giving dark blue solution
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9729 H2 CHEMISTRY (2017)
anion reaction
carbonate,
CO2 liberated by dilute acids
CO32–
chloride,
gives white ppt. with Ag+(aq) (soluble in NH3(aq))
Cl –(aq)
bromide,
gives pale cream ppt. with Ag+(aq) (partially soluble in NH3(aq))
Br–(aq)
iodide,
gives yellow ppt. with Ag+(aq) (insoluble in NH3(aq))
I–(aq)
nitrate,
NH3 liberated on heating with OH–(aq) and Al foil
NO3– (aq)
sulfate,
gives white ppt. with Ba2+(aq) (insoluble in excess dilute strong acids)
SO42– (aq)
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10 The Periodic Table of Elements
Group
1 2 13 14 15 16 17 18
Key 1 2
H He
hydrogen helium
1.0 4.0
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
6.9 9.0 relative atomic mass 10.8 12.0 14.0 16.0 19.0 20.2
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23.0 24.3 3 4 5 6 7 8 9 10 11 12 27.0 28.1 31.0 32.1 35.5 39.9
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39.1 40.1 45.0 47.9 50.9 52.0 54.9 55.8 58.9 58.7 63.5 65.4 69.7 72.6 74.9 79.0 79.9 83.8
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85.5 87.6 88.9 91.2 92.9 95.9 – 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba lanthanoids Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
132.9 137.3 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
Fr Ra actinoids Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
138.9 140.1 140.9 144.2 – 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.1 175.0
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232.0 231.0 238.0 – – – – – – – – – – –