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LABORATORY REPORT
PHYSICAL CHEMISTRY
(CHM 431)
No. Experiment 8
OBJECTIVES
1. To study the adsorption isotherm of acetic acid by activated carbon
APPARATUS
1. 250cm3 conical flask
2. 20cm3 beaker
3. Burette
4. 25cm3 pipette
5. 100cm3 measuring cylinder
6. Filter funnel
7. Retort stand
8. Parafilm
CHEMICALS
1. Activated charcoal (carbon)
2. 0.4M acetic acid, CH2COOH
3. 0.1M sodium hydroxide, NaOH
4. Phenolphthalein indicator
PROCEDURE
About 1.5 g of activated charcoal was weighed into each or the six dry glass – stoppered
flasks. A series of acetic acid of various concentration was prepared according to the Table 8.
1. A 100cm measuring cylinder was used to measure the required amount of 0.4M acetic acid
and then was diluted with distilled water to exactly the 100cm3 mark. Next, the prepared acetic
acid solution (100cm3) was poured into each of the glass – stoppered conical flask containing
charcoal. The flask was then vigorously swirled and let them stand for a week before the
solution is being filtered.
RESULTS
Sample 1 2 3 4 5 6
Mass of activated 1.5047 1.5070 1.5127 1.5016 1.5030 1.5021
carbon (g)
Titration: Volume of NaOH (cm3)
Trial 1 37.1 25.5 17.1 18.6 6.4 4.0
Trial 2 33.4 26.0 17.1 19.1 6.6 3.5
Trial 3 34.8 27.3 17.0 18.7 5.9
Average volume 35.1 26.3 17.0 18.8 6.3 3.78
of NaOH (cm3)
Calculation:
Sample 1 2 3 4 5 6
Initial
concentration of 0.4 0.3 0.2 0.1 0.04 0.02
diluted acetic
acid (mol dm-3)
(c)
Final
concentration of 0.351 0.263 0.17 0.0752 0.0252 9.3x10-3
diluted acetic
acid (mol dm-3)
Concentration of
acetic acid
(adsorbed) in 0.049 0.037 0.03 0.025 0.015 0.0107
equilibrium with
the adsorbent
(mol dm-3)
Amount in mole
of adsorbed 0.033 0.0017 0.00096 0.00041 0.00010 0.0000035
acetic acid per g mol/g mol/g g/mol mol/g g/mol g/mol
charcoal (y)
Log c -0.40 -0.52 -0.70 -1 -1.40 -1.70
Log y -2.68 -2.77 -3.07 -3.37 -4.0 -4.46
c/y 121.12 176.47 208.33 243.90 400 571.43
The Freudlich Isotherm Graph
REFERENCES
1. http://www.uobabylon.edu.iq/eprints/publication_1_14313_250.pdf
2. https://www.fpharm.uniba.sk/fileadmin/faf/Pracoviska-
subory/KFCHL/ENG/lectures/Physical_Chemistry/Exercise_5__Determination_of_ad
sorption_isotherm_of_acetic_acid_on_activated_charcoal.pdf