Encapsulation of Silver Nanoparticles into Polystyrene Microspheres - Chemistry of Materials (ACS... https://pubs.acs.org/doi/abs/10.

1021/cm900436n

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Encapsulation of Silver Nanoparticles into Polystyrene Microspheres

Amar S. Kumbhar†‡ and George Chumanov*†
† Department of Chemistry, Clemson University, Clemson, South Carolina 29634-0919.
‡ Current Address: CHANL Instrumentation Facility, Institute for Advanced Materials, NanoScience and Technology,

Chapel Hill, North Carolina 27599-3216.

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Chem. Mater., 2009, 21 (13), pp 2835–2839 Cite this: Chem. Mater. 21, 13, 2835-2839
DOI: 10.1021/cm900436n PDF (2016 KB) Abstract
Publication Date (Web): May 13, 2009
Copyright © 2009 American Chemical Society
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*Corresponding author. E-mail: gchumak@clemson.edu.

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Acetone treatment performed on silver nanoparticles obtained by hydrogen reduction of aqueous silver(I) oxide solution in
the presence of polystyrene (PS) microspheres resulted in the formation of Ag−PS core−shell structures. Email a Colleague
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Hydrogen reduction of a saturated silver(I) oxide solution at elevated temperatures in the presence
of ∼200 nm polystyrene (PS) microspheres followed by acetone treatment lead to the
encapsulation of the resulting silver nanoparticles (Ag NPs) into the PS microspheres. Extinction
Article Views: 2,593 Times
spectra reveal an expected red-shift of the characteristic plasmon resonance frequency of Ag−PS
core−shell particles due to the increase in the surrounding dielectric constant. The Ag−PS Received 15 February 2009
core−shell particles maintain their stability when redispersed back into water. Published online 13 May 2009
Published in print 14 July 2009

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