1 2 3 4 5

P-101 B17 V-101 E-101 -101

P-101 B17 V-101 E-101
LIQUID LIQUID LIQUID LIQUID VAPOR
Substream: MIXED
Mole Flow kmol/hr
METHANOL 273.8218 273.8218 273.8218 340.9191 340.9191
WATER 4.19115 4.19115 4.19115 5.610935 5.610935
DIMET-01 0.55882 0.55882 0.55882 0.5588662 0.5588662
ACETIC ACID 0.27941 0.27941 0.27941 0.2794105 0.2794105
ACETONE 0.27941 0.27941 0.27941 0.9758502 0.9758502
ACETA-01 0.27941 0.27941 0.27941 0.2794378 0.2794378
Total Flow kmol/hr 279.41 279.41 279.41 348.6236 348.6236
Total Flow kg/hr 8920.407 8920.407 8920.407 11136.38 11136.38
Total Flow l/min 187.2328 187.6284 187.6284 237.1701 14654.18
Temperature C 25 26.40682 26.40688 34.63738 218.6236
Pressure bar 1.01325 16.8 16.8 16.8 16.212
Vapor Frac 0 0 0 0 1
Liquid Frac 1 1 1 1 0
Solid Frac 0 0 0 0 0

Enthalpy cal/mol -57183.7 -57149.11 -57149.11 -56956.12 -45819.78

Enthalpy cal/gm -1791.14 -1790.056 -1790.056 -1783.007 -1434.385
Enthalpy cal/sec -4438300 -4435600 -4435600 -5515600 -4437200
Entropy cal/mol-K -57.0973 -56.98572 -56.98571 -56.32307 -29.91867
Entropy cal/gm-K -1.78843 -1.784939 -1.784938 -1.76319 -0.9366019
Density mol/cc 0.024872 0.0248194 0.0248194 0.0244988 0.0003965
Density gm/cc 0.794057 0.7923824 0.7923824 0.7825873 0.0126657
Average MW 31.92587 31.92587 31.92587 31.94385 31.94385
Liq Vol 60F l/min 186.8649 186.8649 186.8649 233.2567 233.2567
 6 7 8 9 10 11 12 13 14
E-102 B4 T-101 P-103 T-102 B9 T-103
-101 E-102 B4 T-101 T-101 P-103 T-102 T-102 B9
VAPOR MIXED MIXED LIQUID LIQUID MIXED LIQUID LIQUID MIXED

68.18382 68.18382 68.18382 0.3409191 67.8429 67.8429 0.0678429 67.77506 67.77506

141.9786 141.9786 141.9786 0 141.9786 141.9786 0.0001179 141.9785 141.9785
136.9265 136.9265 136.9265 136.2419 0.6846325 0.6846325 0.6845864 4.611E-05 4.611E-05
0.2794105 0.2794105 0.2794105 0 0.2794105 0.2794105 2.316E-07 0.2794103 0.2794103
0.9758502 0.9758502 0.9758502 0.0492088 0.9266413 0.9266413 0.2302304 0.6964109 0.6964109
0.2794378 0.2794378 0.2794378 0.2515833 0.0278545 0.0278545 0.0278267 2.785E-05 2.785E-05
348.6236 348.6236 348.6236 136.8836 211.74 211.74 1.010605 210.7294 210.7294
11136.38 11136.38 11136.38 6301.397 4834.983 4834.983 48.31186 4786.671 4786.671
19015.99 2408.205 2408.217 144.2231 110.0951 875.4647 1.071461 108.916 19884.55
365 115 115.0001 -24.98512 149.7694 136.7325 -16.50873 150.921 79.6851
16.212 16.212 16.212 1 10 6.991425 1 10 1.01325
1 0.1903125 0.1903135 0 0 0.0450227 0 0 0.1948373
0 0.8096875 0.8096865 1 1 0.9549773 1 1 0.8051627
0 0 0 0 0 0 0 0 0

-45513.66 -54954.69 -54954.69 -49839.69 -61861.52 -61861.52 -52480.34 -61910.48 -61910.48

-1424.802 -1720.353 -1720.353 -1082.654 -2709.122 -2709.122 -1097.802 -2725.56 -2725.56
-4407500 -5321800 -5321800 -1895100 -3638500 -3638500 -14732.47 -3624000 -3624000
-25.6243 -46.34298 -46.34296 -80.23237 -36.88855 -36.81452 -75.5977 -36.7736 -36.05986
-0.802167 -1.450764 -1.450763 -1.742867 -1.615472 -1.61223 -1.58138 -1.618928 -1.587507
0.0003056 0.0024128 0.0024127 0.0158185 0.0320541 0.004031 0.01572 0.0322464 0.0001766
0.0097605 0.0770724 0.0770721 0.7282001 0.7319406 0.092046 0.7514951 0.7324713 0.0040121
31.94385 31.94385 31.94385 46.03472 22.83453 22.83453 47.80491 22.71477 22.71477
250.5577 250.5577 250.5577 160.0002 90.55751 90.55751 1.157006 89.4005 89.4005
 15 16 17 18
E-103 P-102 V-101
T-103 T-103 P-102 E-103
LIQUID LIQUID LIQUID LIQUID

0.6777506 67.09731 67.09731 0.6777506

140.5587 1.419785 1.419785 140.5587
1.08E-15 4.61093E-05 4.611E-05 1.08E-15
0.2794098 5.38355E-07 5.384E-07 0.2794098
1.873E-05 0.6963921 0.6963921 1.873E-05
2.631E-12 2.78546E-05 2.785E-05 2.631E-12
141.5159 69.21356 69.21356 141.5159
2570.701 2215.97 2215.97 2570.701
51.8814 49.49718 49.67209 43.20804
178.7028 64.13908 66.17495 24.70275
10 1 17.0226 1.01325
0 0 0 0
1 1 1 1
0 0 0 0

-65233.05 -56230.81 -56175.27 -68267.72

-3591.048 -1756.312 -1754.577 -3758.105
-2564300 -1081100 -1080000 -2683600
-31.01533 -54.01251 -53.85739 -38.92314
-1.707379 -1.687025 -1.68218 -2.1427
0.0454613 0.0233055 0.0232234 0.054587
0.8258261 0.7461604 0.743533 0.9915982
18.16546 32.01642 32.01642 18.16546
43.00874 46.39176 46.39176 43.00874
 p(kg/m3) liquid
ρacetone 784 0 Volume and diameter of the flash
ρdme 2.11 0
ρwater 997 0.01 Ʈ(min) 5
ρacetaldehyde 788 0 Fl(kg/min) 185.6
ρacetic acid 1049 0
ρmethanol 792 0.99 V=(Fl/pl*Ʈ)*2 2.035869

pl(liquid density) 911.65 D=(V/pi)^1/3= 0.216122

 CSTR=Stoich_Reactor
ppartial methanol(Kpa)= 1585.534

ko(kmol/
m3
. h. kPa) 1210000

Ea(J/mol)= 80480

T(K)= 491.95

R(j/mol.K)= 8.314

(-r)(kmol/m3.h)= 5.462428

V= Fmethanol(in)-Fmethanol(out)
(-r)
V(m3)= 12.48236
HEAT EXCHANGERS

Cooling stream(⁰C)
U= 35
T1= 35
T2= 37

Boiling Steam= Cooling to Extreamly low temp(⁰C)

U= 1140 U= 35
T1= 225 T1= -37
T2= 222 T2= -35

Molar Flowrate of the streams(mol/s)

n_101 96.8

n_102 96.8

n_103 58.8

n_104 36

n_105 58.6

n_106 0.28

n_107 39.31

n_108 19.23
Parallel Flow
VARIABLES E-101(Heater) E-102(Cooler) E-103(reboiler) E-104(condensor)

t1(⁰C) 218.8 365 115 115

t2(⁰C) 34.8 115 150 -24

U(W/m2⁰C) 1140 35 1140 35

∆T1 190.2 328 75 150

∆T2 3.2 80 107 13

∆Tlm 45.60976 0 175.8865 0 90.14085 55.91837

Q(J/mol) 46588.6 -39457.2 28868.3 21401.16

Q(W) 4509776 -3819460 1697456 770441.8
A(m2) 86.73461 620.4422 16.51856 393.6564
 Counter Flow
E-104(condensor) E-105(reboiler) E-106(condensor) E-107(reboiler) E-108(condensor)

137 136.7 80 80

151 -17 179 64

1140 35 1140 35

74 171.7 46 115
85 20 142 101

79.13669 70.55814 85.1819 107.8582

-202.724 9381.2 -13901.6 2679.7

-11879.6 2626.736 -546470 51530.63
0.13168 1.063656 5.627482 13.65036
 Column 1(T-101) Column 2(T-102)
MW(Average molecular weight) 36.92 22.88

W(Mass flow of bottom product_in Kg/s) 1.34 1.32

P*MW=p*R*T
pv(Vapour density_kg/m3)= 1.16 0.68

pl(Liquid density_Kg/m3)= 722.28 902.70

Uv=(-0.7171lt^2+0.27*lt-0.047)*(pl-pv/pv)^1/2 1.13 1.65

Dc=sqrt((4*W/(pi*pv*Uv)) 1.14 1.22

H=lt*(N+1)= 6.05 6.05

Densities
ρacetone 784
ρdme 2.11
ρwater 997
ρacetaldehyde 788
ρacetic acid 1049
ρmethanol 792
Column 2(T-102) Column 3(T-103)
22.30

0.71

0.77

902.70

1.55

0.87

6.05
 VOLUMETRIC FLOWRATE(litre/day) STORAGE VOLUME(changed daily)

CRUDE METHANOL 269615.2 269615.2

DME 207058.3 207058.3

STREAM 12 WASTE 1440 1440

STREAM 15 WASTE 74707 74707

changed daily)