Ejercicio 1

El fluido del yacimiento proveniente de un yacimiento que esta a 4

condiciones de tanque son: 14.7 lpca y 120 °F. D

CONSTANTES FISICAS
Temperatura inicial 180 °F
Presión inical 4000 lpca
Cte. GASES: 8.31451 m3.kPa/(°K.kmol)
Conversión: 4.1855 kJ/kcal(180 F) [s/IRAM 23]
Volumen Molar: 23.645 m3/kmol

Comp. % mol Fracción mol

C1 44.04 0.44040
C2 4.32 0.04320
C3 4.05 0.04050
C4 2.84 0.02840
C5 1.74 0.01740
C6 2.90 0.02900
C7+ 40.11 0.40110
100.00 1.00000
yacimiento que esta a 4000 lpca y a 180 °F. Las condiciones de los separadores son: 500 lpca y 1
on: 14.7 lpca y 120 °F. Determine la composición del liquido y del gas en cada una de las etapas e

Peso molecular Densidad Liquido

Peso Mol. (kg/kmol) Densidad Relativa
aparente (kg/m3)
16.0428 7.0652 0.30000 0.24388
30.0696 1.2990 0.35619 0.04484
44.0965 1.7859 0.50699 0.06165
58.1234 1.6507 0.57344 0.05698
72.1503 1.2554 0.62791 0.04334
86.1772 2.4991 0.66383 0.08627
287.0000 115.1157 0.90710 3.97362
es son: 500 lpca y 120 °F y 65 lpca y 120 °F respectivamente y las
una de las etapas en el proceso de separación

Zci Tc (ºK) Pc (kPa) Factor Acént. Cp kcal/kgC

0.99800 190.56 4598.8 0.0115 526.58

0.99150 305.83 4880.0 0.0908 407.43
0.98210 369.82 4250.0 0.1454 388.05
0.96800 408.13 3648.0 0.1756 386.19
0.93700 469.69 3364.0 0.2510 387.84
0.91300 506.40 3030.0 0.2957 385.88
0.86600 539.20 2740.0 0.3506 384.04
 PROPIEDADES
OPERACIÓN
Temperatura
Presión
Cte de gases

Vol. Espec. (m3/kg) Comp.

0.00617 C1
0.00489 C2
0.00454 C3
0.00446 C4
0.00434 C5
0.00429 C6
0.00426 C7+

Cálculo de pTr y pPr

Tr
Pr

Densidad Masa
d
 322 K 120 F
3447 kPa 500 lpca
8.31451 m3.kPa/(°K.kmol)

yiMi (kg/kmol) Fracción molar Zi Tci (K) Pci (kPa)

7.0652 0.44040 83.9204 2025.3115

1.2990 0.04320 13.2119 210.8160
1.7859 0.04050 14.9777 172.1250
1.6507 0.02840 11.5909 103.6032
1.2554 0.01740 8.1726 58.5336
2.4991 0.02900 14.6856 87.8700
115.1157 0.40110 216.2731 1099.0140
130.6711 1.00000 362.8322 3757.2733

0.888 K Z
0.918 kPa

Densidad Relativa
Mezcla
205.17 kg/m3 G
 49 C

G (mezcla) Constante "K"

0.1074 6.50000
0.0019 1.55000
0.0025 0.60000
0.0016 0.85000
0.0008 0.11000
0.0025 0.03750
1.5938 0.01500
1.7105

0.82

1.711
 PROPIEDADES OPERACIÓN
T 322 K 120
P 3447 kPa 500
R 8.31451 m .kPa/(°K.kmol)
3

Comp. yiMi (kg/kmol) Fracción molar Zi Constante "K"

C1 7.0652 0.44040 8.23000
C2 1.2990 0.04320 1.55000
C3 1.7859 0.04050 0.60000
C4 1.6507 0.02840 0.85000
C5 1.2554 0.01740 0.11000
C6 2.4991 0.02900 0.03750
C7+ 115.1157 0.40110 0.01500
130.6711 1.0000

Asumir 0.5655
Zi*(1-1/Ki)/(1-
L(1-(1/Ki)) 1-L(1-(1/Ki))
L(1-1/Ki))
0.4968 0.5032 0.7689
0.2007 0.7993 0.0192
-0.3770 1.3770 -0.0196
-0.0998 1.0998 -0.0046
-4.5756 5.5756 -0.0252
-14.5151 15.5151 -0.0480
-37.1360 38.1360 -0.6907
0.0000

Vl = YiMi/d Vmi = Mi/d Vi = Vmi*Xi

23.5508 53.4760 0.0321
3.6469 84.4201 0.2533
3.5226 86.9771 1.5569
2.8786 101.3592 3.3550
1.9994 114.9055 3.4242
3.7647 129.8182 7.4516
126.9052 316.3929 271.5284
166.2682 287.6014
 F 49 C 540 R
lpca

Zi/Ki Zi*Ki 1/Ki 1-1/Ki Zi*(1-(1/Ki))

0.0535 3.6245 0.1215 0.8785 0.3869
0.0279 0.0670 0.6452 0.3548 0.0153
0.0675 0.0243 1.6667 -0.6667 -0.0270
0.0334 0.0241 1.1765 -0.1765 -0.0050
0.1582 0.0019 9.0909 -8.0909 -0.1408
0.7733 0.0011 26.6667 -25.6667 -0.7443
26.7400 0.0060 66.6667 -65.6667 -26.3389
27.8538 3.7489

Asumir 0.5655
[1-L(1- Zi*(1-1/Ki)/[1- Zi*(1-1/Ki)/(1-L(1-
L(1-(1/Ki)) 1-L(1-(1/Ki))
1/Ki)]^2 L(1-1/Ki)]^2 1/Ki))
0.2532 1.3423 0.4968 0.5032 0.7689
0.6389 0.0085 0.2007 0.7993 0.0192
1.8962 0.0095 -0.3770 1.3770 -0.0196
1.2096 0.0007 -0.0998 1.0998 -0.0046
31.0873 0.0366 -4.5756 5.5756 -0.0252
240.7180 0.0794 -14.5151 15.5151 -0.0480
1454.3551 1.1892 -37.1360 38.1360 -0.6907
2.6663 0.0000

Mai = Mi*Xi xi (tanque) Ml Mg

0.0096 0.0006 1.7061 14.0409
0.0902 0.0030 1.0485 1.6251
0.7893 0.0179 2.1616 1.2969
1.9239 0.0331 1.7658 1.5009
2.1501 0.0298 2.0469 0.2252
4.9466 0.0574 4.2954 0.1611
246.3034 0.8582 201.2371 3.0186
256.2131 214.2613 21.8686
 V 1000000 ft3/d
Vem 379.6354 ft3/Lbmol
Asumir 0.5600

Zi*(1-(1/Ki)^2) L(1-(1/Ki)) 1-L(1-(1/Ki)) Zi*(1-1/Ki)/(1-L(1-1/Ki))

0.3399 0.4920 0.5080 0.7615
0.0054 0.1987 0.8013 0.0191
0.0180 -0.3733 1.3733 -0.0197
0.0009 -0.0988 1.0988 -0.0046
1.1391 -4.5309 5.5309 -0.0255
19.1046 -14.3733 15.3733 -0.0484
1729.5878 -36.7733 37.7733 -0.6973
-0.0147

0.5655 0.4345
Zi*(1-1/Ki)/[1-
[1-L(1-1/Ki)]^2 Xi Yi
L(1-1/Ki)]^2
0.2532 1.3423 0.1063 0.8752
0.6389 0.0085 0.0349 0.0540
1.8962 0.0095 0.0490 0.0294
1.2096 0.0007 0.0304 0.0258
31.0873 0.0366 0.0284 0.0031
240.7180 0.0794 0.0498 0.0019
1454.3551 1.1892 0.7012 0.0105
2.6663 1.0000 1.0000
Valores X1 Y1
0.5655 0.4345
C1 0.1063 0.8752
C2 0.0349 0.0540
C3 0.0490 0.0294
C4 0.0304 0.0258
C5 0.0284 0.0031
C6 0.0498 0.0019
C7 0.7012 0.0105
1.0000 1.0000
 d 62.4 Agua
d 28.9625 Aire
Asumir

[1-L(1-1/Ki)]^2 Zi*(1-1/Ki)/[1-L(1-1/Ki)]^2 L(1-(1/Ki)) 1-L(1-(1/Ki))

0.2581 1.3168 0.49681 0.5032
0.6421 0.0085 0.20067 0.7993
1.8860 0.0095 -0.37702 1.3770
1.2074 0.0007 -0.09980 1.0998
30.5910 0.0372 -4.57560 5.5756
236.3394 0.0808 -14.51510 15.5151
1426.8247 1.2122 -37.13603 38.1360
2.6658
 0.5655
Zi*(1-1/Ki)/(1- Zi*(1-1/Ki)/[1-
[1-L(1-1/Ki)]^2
L(1-1/Ki)) L(1-1/Ki)]^2
0.7689 0.2532 1.3423
0.0192 0.6389 0.0085
-0.0196 1.8962 0.0095
-0.0046 1.2096 0.0007
-0.0252 31.0873 0.0366
-0.0480 240.7182 0.0794
-0.6907 1454.3565 1.1892
0.0000 2.6663
 PROPIEDADES OPERACIÓN
T 322 K 120 F 49 C
P 448 kPa 65 lpca
R 8.31451 m .kPa/(°K.kmol)
3

yiMi Fracción molar Constante

Comp. Zi Zi/Ki Zi*Ki 1/Ki
(kg/kmol) "K"
C1 1.7061 0.10634 48.50000 0.0022 5.1577 0.0206
C2 1.0485 0.03487 10.30000 0.0034 0.3591 0.0971
C3 2.1616 0.04902 3.40000 0.0144 0.1667 0.2941
C4 1.7658 0.03038 0.95000 0.0320 0.0289 1.0526
C5 2.0469 0.02837 0.35000 0.0811 0.0099 2.8571
C6 4.2954 0.04984 0.11000 0.4531 0.0055 9.0909
C7+ 201.2371 0.70117 0.12000 5.8431 0.0841 8.3333
214.2613 1.0000 6.4293 5.8119

Asumir 0.8377 Asumir

Zi*(1-
Zi*(1-1/Ki)/ [1-L(1- 1/Ki)/[1-
L(1-(1/Ki)) 1-L(1-(1/Ki)) L(1-(1/Ki))
(1-L(1-1/Ki)) 1/Ki)]^2 L(1-
1/Ki)]^2
0.8204 0.1796 0.5800 0.0322 3.1630 0.8204
0.7564 0.2436 0.1292 0.0594 0.4789 0.7564
0.5913 0.4087 0.0847 0.1670 0.1462 0.5913
-0.0441 1.0441 -0.0015 1.0901 0.0001 -0.0441
-1.5557 2.5557 -0.0206 6.5317 0.0150 -1.5557
-6.7777 7.7777 -0.0519 60.4924 0.0539 -6.7777
-6.1431 7.1431 -0.7199 51.0235 0.7390 -6.1431
0.0000 4.5961

0.8377 0.1623
Vmi = Vi = Mai =
Xi Yi Vl = YiMi/d
Mi/d Vmi*Xi Mi*Xi
0.0122 0.5922 5.6869 5.6869 0.0034 0.0096
0.0139 0.1431 2.9436 2.9436 0.0088 0.0902
0.0353 0.1199 4.2635 4.2635 0.0763 0.7893
0.0306 0.0291 3.0793 3.0793 0.1019 1.9239
0.0317 0.0111 3.2599 3.2599 0.0971 2.1501
0.0583 0.0064 6.4707 6.4707 0.3714 4.9466
0.8180 0.0982 221.8467 221.8467 190.3888 246.3034
1.0000 1.0000 247.5505 191.0478 256.2131
 540 R V 560398.75 ft3/d
Vem 379.6354 ft3/Lbmol
Asumir 0.8500
Zi*(1- Zi*(1- Zi*(1-1/Ki)/(1-
1-1/Ki L(1-(1/Ki)) 1-L(1-(1/Ki))
(1/Ki)) (1/Ki)^2) L(1-1/Ki))
0.9794 0.1042 0.1020 0.8325 0.1675 0.6217
0.9029 0.0315 0.0284 0.7675 0.2325 0.1354
0.7059 0.0346 0.0244 0.6000 0.4000 0.0865
-0.0526 -0.0016 0.0001 -0.0447 1.0447 -0.0015
-1.8571 -0.0527 0.0978 -1.5786 2.5786 -0.0204
-8.0909 -0.4033 3.2629 -6.8773 7.8773 -0.0512
-7.3333 -5.1419 37.7076 -6.2333 7.2333 -0.7109
0.0596

Asumir 0.8377
Zi*(1-
Zi*(1-
1-L(1- [1-L(1- 1/Ki)/[1-
1/Ki)/(1-
(1/Ki)) 1/Ki)]^2 L(1-
L(1-1/Ki))
1/Ki)]^2
0.1796 0.5800 0.0322 3.1630
0.2436 0.1292 0.0594 0.4789
0.4087 0.0847 0.1670 0.1462
1.0441 -0.0015 1.0901 0.0001
2.5557 -0.0206 6.5317 0.0150
7.7777 -0.0519 60.4922 0.0539
7.1431 -0.7199 51.0233 0.7390
0.0000 4.5961

xi
Ml Mg
(tanque)
0.0006 0.1959 9.5002 C1
0.0030 0.4178 4.3033 C2
0.0179 1.5556 5.2890 C3
0.0331 1.7802 1.6912 C4
0.0298 2.2884 0.8009 C5
0.0574 5.0207 0.5523 C6
0.8582 234.7699 28.1724 C7
246.0285 50.3094
 r 62.4 Agua
r 28.9625 Aire
Asumir 0.8383
Zi*(1-1/Ki)/
Zi*(1-1/Ki)/(1-
[1-L(1-1/Ki)]^2 [1-L(1- L(1-(1/Ki)) 1-L(1-(1/Ki))
L(1-1/Ki))
1/Ki)]^2
0.0281 3.6346 0.82104 0.1790 0.5820
0.0541 0.5258 0.75693 0.2431 0.1295
0.1600 0.1527 0.59176 0.4082 0.0848
1.0915 0.0001 -0.04412 1.0441 -0.0015
6.6490 0.0147 -1.55688 2.5569 -0.0206
62.0514 0.0526 -6.78278 7.7828 -0.0518
52.3211 0.7207 -6.14769 7.1477 -0.7194
5.1011 0.0029

X1 Y1
0.0122 0.5922
0.0139 0.1431
0.0353 0.1199
0.0306 0.0291
0.0317 0.0111
0.0583 0.0064
0.8180 0.0982
1.0000 1.0000
 Zi*(1-1/Ki)/[1-
[1-L(1-1/Ki)]^2
L(1-1/Ki)]^2
0.0320 3.1848
0.0591 0.4811
0.1667 0.1466
1.0902 0.0001
6.5376 0.0150
60.5716 0.0539
51.0894 0.7381
4.6195
 PROPIEDADES OPERACIÓN
T 322 K
P 101 kPa
R 8.31451 m3.kPa/(°K.kmol)
Comp. yiMi (kg/kmol) Fracción molar Zi
C1 0.1959 0.01221
C2 0.4178 0.01389
C3 1.5556 0.03528
C4 1.7802 0.03063
C5 2.2884 0.03172
C6 5.0207 0.05826
C7+ 234.7699 0.81801
246.0285 1.0000

Asumir
L(1-(1/Ki)) 1-L(1-(1/Ki))
0.9238 0.0762
0.9089 0.0911
0.8695 0.1305
0.7098 0.2902
0.2662 0.7338
-1.1386 2.1386
-2.3955 3.3955

0.9316 0.0684
Xi Yi
0.0013 0.1603
0.0037 0.1525
0.0180 0.2703
0.0251 0.1055
0.0309 0.0432
0.0605 0.0272
0.8604 0.2409
1.0000 1.0000
 120 F 49
14.7 lpca

Constante "K" Zi/Ki Zi*Ki

120.00000 0.0001 1.4652
41.00000 0.0003 0.5697
15.00000 0.0024 0.5292
4.20000 0.0073 0.1286
1.40000 0.0227 0.0444
0.45000 0.1295 0.0262
0.28000 2.9215 0.2290
3.0837 2.9923

0.9316
Zi*(1-1/Ki)/[1-L(1-
Zi*(1-1/Ki)/(1-L(1-1/Ki)) [1-L(1-1/Ki)]^2
1/Ki)]^2
0.1590 0.0058 2.0700
0.1488 0.0083 1.5928
0.2523 0.0170 1.8043
0.0804 0.0842 0.2111
0.0123 0.5385 0.0048
-0.0333 4.5737 0.0190
-0.6195 11.5297 0.4691
0.0000 6.1712

Vl = YiMi/d Vmi = Mi/d Vi = Vmi*Xi

0.6529 53.4760 0.0321
1.1730 84.4201 0.2533
3.0683 86.9771 1.5569
3.1045 101.3592 3.3550
3.6444 114.9055 3.4242
7.5632 129.8182 7.4516
258.8137 316.3929 271.5284
278.0200 287.6014
 C 540 R

1/Ki 1-1/Ki Zi*(1-(1/Ki))

0.0083 0.9917 0.0121
0.0244 0.9756 0.0136
0.0667 0.9333 0.0329
0.2381 0.7619 0.0233
0.7143 0.2857 0.0091
2.2222 -1.2222 -0.0712
3.5714 -2.5714 -2.1035

Asumir 0.9316
L(1-(1/Ki)) 1-L(1-(1/Ki)) Zi*(1-1/Ki)/(1-L(1-1/Ki))
0.9238 0.0762 0.1590
0.9089 0.0911 0.1488
0.8695 0.1305 0.2523
0.7098 0.2902 0.0804
0.2662 0.7338 0.0123
-1.1386 2.1386 -0.0333
-2.3955 3.3955 -0.6195
0.0000

Mai = Mi*Xi xi (tanque) Ml

0.0096 0.0006 0.0214
0.0902 0.0030 0.1118
0.7893 0.0179 0.7946
1.9239 0.0331 1.4605
2.1501 0.0298 2.2274
4.9466 0.0574 5.2169
246.3034 0.8582 246.9311
256.2131 256.7639
 X1
C1 0.0013
C2 0.0037
C3 0.0180
C4 0.0251
C5 0.0309
C6 0.0605
C7 0.8604
1.0000
 V 476676.812083206
Vem 379.6354
Asumir
Zi*(1-(1/Ki)^2) L(1-(1/Ki))
0.0120 0.9322
0.0132 0.9171
0.0307 0.8773
0.0178 0.7162
0.0026 0.2686
0.0870 -1.1489
5.4089 -2.4171

[1-L(1-1/Ki)]^2 Zi*(1-1/Ki)/[1-L(1-1/Ki)]^2
0.0058 2.0698
0.0083 1.5927
0.0170 1.8042
0.0842 0.2111
0.5385 0.0048
4.5737 0.0190
11.5297 0.4691
6.1708

Mg
2.5718
4.5850
11.9195
6.1343
3.1184
2.3476
69.1407
99.8172
 Y1
0.1603
0.1525
0.2703
0.1055
0.0432
0.0272
0.2409
1.0000
 ft3/d d
ft3/Lbmol d
Asumir 0.9400
1-L(1-(1/Ki)) Zi*(1-1/Ki)/(1-L(1-1/Ki)) [1-L(1-1/Ki)]^2
0.0678 0.1785 0.0046
0.0829 0.1635 0.0069
0.1227 0.2684 0.0150
0.2838 0.0822 0.0805
0.7314 0.0124 0.5350
2.1489 -0.0331 4.6177
3.4171 -0.6156 11.6769
0.0563
 62.4 Agua
28.9625 Aire
Asumir
Zi*(1-1/Ki)/[1-L(1-
L(1-(1/Ki)) 1-L(1-(1/Ki))
1/Ki)]^2
2.6095 0.92450 0.0755
1.9231 0.90953 0.0905
2.0423 0.87012 0.1299
0.2207 0.71030 0.2897
0.0048 0.26636 0.7336
0.0188 -1.13944 2.1394
0.4632 -2.39727 3.3973
7.2825
 0.9323
Zi*(1-1/Ki)/[1-L(1-
Zi*(1-1/Ki)/(1-L(1-1/Ki)) [1-L(1-1/Ki)]^2
1/Ki)]^2
0.1604 0.0057 2.1065
0.1498 0.0082 1.6159
0.2535 0.0169 1.8217
0.0806 0.0839 0.2119
0.0124 0.5382 0.0048
-0.0333 4.5772 0.0190
-0.6192 11.5414 0.4687
0.0042 6.2484