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SCH3U1 Grade 11 Chemistry Unit 3 Solutions and Solubility Unit Test Study Notes
Solubility of Solid
– trend: solubility of solids increase as temperature increases
– energy is required to break apart bonds of solids when dissolved in water
– as temperature increases, there is more energy to break these bonds
S = soluble
SS = slightly soluble
I = insoluble
Solubility of Gases
– trend: solubility of gases decrease as temperature increases
– with more energy, the gas particles escape the solution
Solubility of Liquids
– trend: solubility of liquids is not affected by the temperature
– solute: liquid with less amount
– solvent: liquid with greater amount
Water
– universal solvent
– small size, highly polar nature, and the capacity to form hydrogen bonds makes water very successful
at dissolving solutes
– water has a permanent dipole
– the negative end is attracted to the positive end, causing a special type of attraction called hydrogen
bonding
Hydrogen Bonding
– any substance containing hydrogen and oxygen/fluorine/nitrogen
– doesn’t create an actual bond, uses strong intermolecular forces to create a force of attraction
– hydrogen bonded compounds are likely to dissolve in water
Properties
– water is held together by covalent bonds which re stronger than hydrogen bonds
– however, the hydrogen bond is stronger than regular dipole-dipole attractions
– this results in higher boiling points because more energy is required to break apart these bonds
– hydrogen bonds also result in higher surface tension
Molarity
– molar [ ]
– moles of solute/1L of solution
Dilutions
– reducing concentration of a solute by adding additional solution to the mixture
– standard/stock solution: one where the [ ] is known
– c1V1 = c2V2
– c1 is the initial [ ]
– c2 is the final [ ]
– V1 is the initial volume
– V2 is the final volume
Acids
– sour taste
– no texture
– conducts electricity in an aqueous solution
– pH less than 7
– turns litmus paper red
– phenolphthalein is colourless
– Acid + Metal H2(g)
– Acid + Carbonate CO2(g) + H2O(l)
Bases
– bitter taste
– slippery texture
– conducts electricity in an aqueous solution
– pH greater than 7
– turns litmus paper blue
– turns phenolphthalein pink
Arrhenius Theory
– an acid is any substance that will ionize in water to produce H ions
– a base is a substance that will dissociate in water to produce OH ions
– H ions cannot exist alone, and thus exist attached to H2O, creating hydronium: H3O
– Only valid for reactions in water
Bronsted-Lowry Theory
– acids are substances that have an H ion removed
– conjugate base is paired with the acid, and becomes the new base
– bases are substances that have an H ion added
– conjugate acid is paired with the base and becomes the new acid
Strong Acids
– will completely dissociate
Weak Acids
– will only have some of the solution dissociated
– indicated in a chemical equation by a double arrow
Monoprotic Acid
– can only give up 1 H ion
Diprotic Acid
– can give up 2 H ions (H2SO4, H2CO3)
Triprotic Acid
– can give up 3 H ions (H3PO4)
pH and pOH
– pH = -log[H or H3O]
– [H or H3O] = 10-pH
– pOH = -log[OH]
– [OH] = 10-pOH
– pH + pOH = 14
Neutralization
– Acid + Base Salt + Water
– Titrations are done to determine the number of moles when the number of moles of H and OH are
equal
– Equivalence point: the point when titration is complete (H = OH)
– End point: a sudden change occurs during a titration
– Equivalence is theoretical and determined by calculations
– End is experimental and determined by indicators
RELATED NOTES:
SCH3U Grade 11 Chemistry Quantities and Stoichiometry Test Notes
Isotope: element variations with different atomic mass but same atomic number
If given percentages, you can find average atomic mass by adding each
portion
Calculate:
10.01x+(1-x)11.01=10.81
10.01x+11.01-11.01x=10.81
-1.00x=0.2
X=0.2
Molar Mass: how much grams per mol of an element = atomic mass
Percentage Composition
Empirical Formula
1) Find the number of moles for each element (assume % is per 100g for simplicity)
2) Divide all the moles by the smallest number mole to reduce the decimals
3) If not whole numbers yet, multiply by some special factors to reduce decimals
Molecular Formula
A chemical formula that expresses the exact ratio of atoms (whole numbers) for
a compound
NO REDUCTION REQUIRED, and not suitable for ionic bonds (metal + non metal)
Limiting/excess reactants
Regardless of how much excess remains, the reaction will stop once the limiting is used
When 2 or more reactants seem limiting, one must pick the reactant that is limiting all the
others
Process:
1) Balance equation
Finding Hydrate
Process
4) based on ratio, find out how many mols of water should exist
Percentage Yield
How much percent of the actual product will
happen over the theoretical amount
Factors:
Competing Reaction
Other reactions will happen at the same time, limiting the reactant produced
Reaction Rate
Purity of reactant
Laboratory Techniques
Nuclear reactions
Nuclear Fission
Occurs when an unstable isotope splits into smaller fragments. Multiple neutrons
released along with high energy (radiation)
Nuclear Fusion
Topics:
1. Significant Digits
2. Trends of the Periodic Table
3. Types of Bonds
4. Properties of Ionic and Covalent Compounds
5. Lewis Structures
6. Nomenclature/Balancing Equations
7. Types of Reactions
Significant Digits
Rules:
1. all non-zero digits are significant
2. all leading and following zeros are not significant
3. all zeros between two other digits are significant
4. any zero that follows a digit and is to the right of the decimal point is significant
When performing multiplication or division, the value with the fewest number of significant digits is the
number of significant digits used in the final answer
When performing addition or subtraction, the value with the fewest number of digits after the decimal
place represents the number of decimal places in the final answer
Scientific Notation: used for numbers greater than 1000 or less than 0.001
To use, move the decimal to be placed after the first non-zero digit
Count the number of decimal places moved
If the decimal has moved to the left, the exponent is positive
If the decimal has moved to the right, the exponent is negative
Key Terms:
Shielding Effect: the effect of filled inner electron orbitals on the attractiveness of valence electrons to
the nucleus
Effective Nuclear Charge: the apparent nuclear charge experienced by valence electrons, result of the
shielding effect
Trend 2 Ionization Energy:
Trend 4 Electronegativity:
Types of Bonds
Ionic:
Polar Covalent:
Covalent:
Ionic:
Covalent
– low melting point
– does not conduct electricity as a solid or in a solution
– not soluble in water
– non-polar compounds soluble in non-polar compounds
– polar compounds soluble in polar compounds
– can be solid, liquid, or gas
– soft, flexible, waxy consistency as a solid
Lewis Structures
Nomenclature/Balancing Equations
– will not be a major part of the test, so does not need to be reviewed too much
Types of Reactions
Synthesis:
Decomposition:
Combustion
– chemical reaction of a substance with oxygen producing one or more oxides, heat, and light
– inorganic combustion general formula: X + O2 XO
– organic combustion only occurs with hydrocarbons which are compounds composed of only hydrogen
and carbon
– complete combustion of a hydrocarbon general formula: CxHy + O2 CO2 + H2O
– incomplete combustion of a hydrocarbon general formula: CxHy + O2 C(s) + CO + CO2 + H2O
Single Displacement
Double Displacement
– chemical reaction in which positive ions of two ionic compounds exchange places, creating 2 new ionic
compounds
– neutralization reaction: acid + base water + “Salt” (ionic compound)
– e.g. H2SO4(aq) + Ca(OH)2(aq) H2O + NaCl
– precipitation reaction: reaction with two ionic solutions that creates a precipitate
– e.g. 2LiCl(aq) + Pb(NO3)2 2LiNO3 + PbCl2