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2-hexanamine
N-methyl-1-propanamine
N,N-dimethylcyclohexanamine
N-ethyl-N-methylethanamine
1,2-propanediamine
• Have fishy smell.
• BP & MP higher than alkane but lower
than alcohol.
methanal methanamine
1 amine
N-methylmethanamine
2 amine
N,N-dimethylmethanamine
3 amine
1. LiAlH4
butanamide 2. H2O 1-butanamine
1. Fe, HCl
2. NaOH
or H2, Ni
methanol
nitrobenzene aniline
Reaction of amines
react with acid chloride to form amide
O O
R’NH2 RCCl R C NHR' HCl
acid
amide
chloride
example
O O
CH3NH2 CH3CCl CH3 C NHCH3 HCl
methanamine methanoyl N-methylethanamide
chloride
Amides
General formula
O
R C NH2
Derivatives of carboxylic acids where an
amino (-NH2) group replaces the –OH group.
O O
CH3 — C—OH CH3 — C—NH2
carboxylic acid amide
ethanoic acid ethanamide
Examples
O
HC–NH2 methanamide
O
CH3C–NHCH3 N-methylethanamide
O
CH3CH2C–N(CH3)2 N,N-dimethylpropanamide
O
C NH CH 3
N - me th y lb e n z a mid e
Properties of amides
O CH3
CH3 N
N
O N N
CH3
Caffe in e , co ffe e b e an s an d te a