Vidyamandir Classes

Solutions to JEE Advanced-4 | JEE-2018

CHEMISTRY PAPER-1

MULTIPLE CORRECT ANSWERS TYPE

1.(ACD) ∆G ° = − nFE cell = Maximum work done by cell

0.0591 [Cu 2+ ]
E cell = E cell − log
n [Ag + ]2

2.(ACD) ∆Vmixing > 0 ⇒ positive deviation from ideal behavior

3.(ABD)

ℓn2 ℓn2
(t1/2 )i = , (t1/2 )ii =
k1 k2
Since k1 : k 2 = 1: 2 ⇒ (t1/2 )i > (t1/2 )ii
(C B ) t k1 1
= =
(CC ) t k 2 2
At t = 20 min :→ (C A ) t = (CC ) t
k2  x k 
⇒ (CA )0 − x = x 2 ⇒ (CA )0 − x = x sin ce 1 = 1 
k1 + k 2  x2 k2 
k1 + k 2
⇒ x = (CA )0 ×
(k1 + 2k 2 )
k2 k2 2
(CB ) t = x= (C A )0 = (C A )0 ⇒ (A), (B) & (D) are incorrect.
(k1 + k 2 ) (k1 + 2k 2 ) 5

4.(ABC)

Upon adding a strong base or weak base to a mixture of strong acid and a weak acid (eg. HCl and
CH3COOH), the conductance falls until the strong acid is neutralised, then rises as the weak acid is
converted into its salts, and finally rises more steeply as excess strong alkali is introduced. There is no
change in conductance with excess of weak base(region IV).
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5.(C)

Carbanion is more stabilized by attack on carbon 4 than 1 & 2.

6.(D)

A, B & C are correct options.

7.(BCD)

B, C & D are incorrect options.

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MATRIX MATCHING TYPE

8-10. 8.(D) 9.(B) 10.(D)
Based upon theory

11.(B) Oakwood degradation reaction

12.(B) SN 2Ar mechanism by Carbanion intermediate

13.(A)

(I)

(II)

(III)

(IV)

SINGLE INTEGER VALUE CORRECT TYPE

3a 3 × 2 2R 2
1.(7) Distance between successive planes = = =2 R
3 3 3
2
⇒ Number of planes between 13 R =7
3

∧m k × 1000
2.(3) α= , ∧m = ⇒ α = 0.1
∧om C

⇒ [OH − ] = Cα = 10−3 M ⇒ pOH = 3

o o
p 2 ∆H vap  1 1  500 ∆H vap  1 1  0.7 × R × 250 × 350
3.(8) ln =  −  ⇒ ln =  −  ⇒ ∆H vap =
p1 R  T1 T2  250 R  250 350  100

RTbo2 × M 0
Kb = &i=2 ⇒ ∆Tb = i × k b × m = 8
∆H ovap

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4.(5)

5.(4)
Reaction Mechanism
1 E1
2 SN 1
3 Electrophilic addition
4 NGP with rearrangement
5 SE reaction
6 E1cB
7 Free radical substitution
8 Activated SN 2 or SN 2Ar
9 Electrophilic addition
Reactions 1, 2, 3 and 5 proceed by carbocationic intermediate.

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Solutions to JEE Advanced-4 | JEE-2018

PHYSICS PAPER-1

MULTIPLE CORRECT ANSWERS TYPE

1.(AC) At equilibrium
2 ( kx0 cos θ ) cos θ = mg
mg
x0 =
2k cos 2 θ
mg
Elongation in spring = x0 cos θ =
2k cos θ
FR = −2 ( kx cos θ ) cos θ = ma
 2k cos 2 θ 
a = − x
 m 
 
m
T = 2π
2k cos 2 θ
∴ The correct option is (AC).

2.(ABC) Number of pulse encountered by the moving plane per unit time is given by
distance travelled C +V
C V   V
v' = = =
1 +  = v  1 + 
wave length λ λ C  C
Frequency received by an observer on ground
2
11 C  C +V 
1
v = v = 
C −V  C −V 
C C  C −V 
Reflected wavelength = 11
=  
v v  C +V 
 C +V  2vV
Beats = v" − v = v  −v =
 C −V  C −V
∴ The correct option is (ABC).

3.(AC) If a uniform charge density is given at surface of cylinder, the OO’ is shifted (i.e. zero charge surface
density) to some where on cylinder. i.e. Electric field same at all axial point.
Using line integral on path
PQRS
i.e., ∫ E. d ℓ = 0
∴ E ' = E0
i.e., Electric field inside cylinder is uniform.
∴ The correct option is (AC).

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4.(ABC) Polarisation of charge takes places

(
Wext + Wcell = V f − Vi ) [ As H = 0]
1 1 1
( )
Wext + V C f V − CiV = C f V 2 − CiV 2 = k f − Ci V 2
2 2 2
( )
1
(
Wext = − C f − Ci V 2
2
)
1
Welectric = −Wext = C f − Ci V 2
2
( )
( )
Wcell = C f − Ci V 2 = 2 V f − Vi ( )
∴ The correct option is (ABC).

5.(BD) FBA = mg + FBC

∴ FBA > FBC
⇒ Charge on capacitor C BA > charge on capacitor CBC
⇒ QBA > QBC
∴ The correct option is (BD).

6.(BC) Potential increases opposite to electric field.

∴ The correct option is (BC).

i
7.(ABCD) As j = = σ E = neVd
A
 dx 
dH = i 2 Rdt = i 2  δ  dt
 A
dH i 2δ
⇒ =
dx
dt A
∴ The correct option is (ABCD).

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MATRIX MATCHING TYPE

8.(D) 9.(B) 10.(B) 11.(C) 12.(D) 13.(A)

SINGLE INTEGER VALUE CORRECT TYPE

1.(2) a = 50 sin st
Aω 2 = 50
⇒ A ( 5 ) = 50
2

A = 2m

1 A2
2.(1) As I = A2ω 2δ v ⇒ I ∝ A2ω 2 ∝
2 T2
IA  2 × 152   1 2
= × =1
I B  1 × 152   2 


1 T J 64
3.(3) f = = = 400 Hz
2L µ 2 × 0.10 1 × 10−2
−1
 300  399  vs 
v' =  v⇒ = 1 +
 300 + v  400  300 

 s 

1 vs
⇒ 1− =1−
400 300
3
∴ vs = = 0.75 = 0.25 × 3 ∴ −3
4
i
4.(2) Re q = Equivalent resistance between terminal points iReq = R
2

R R  Rx  2 2
Req =   ⇒ =   ⇒ R + Rx = 2 Rx ⇒ R = Rx ⇒ R = x
2 2  R+x
x = Resistance net after removal of 'R'.
x and R are parallel to each other.

 L 
5.(1) Air thrust =  δ 2 R  v 2 = δ LRv 2
 2 
Taking torque about 0

( NIπ R ) B = δ LRV
2 2 3L
×
4
3δ Lv L 2
I= = 1mA
4 Nπ R

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Solutions to JEE Advanced-4 | JEE-2018

MATHEMATICS PAPER-1
MULTIPLE CORRECT ANSWERS TYPE
2π cot 2 cot1 2π
1.(ACD) ∫ [cot −1 x ]dx = 2 ∫ dx + 1 ∫ dx + 0 ∫ dx
−π / 2 −π / 2 cot 2 cot1

 π
= 2 cot 2 +  + [cot1− cot 2] = π + cot1 + cot 2
 2
(since cot 3 < − 1.5 ≈ − π / 2) and cot −1 x∈ (0, π )

2.(ABC) 3x 2 + 2 y 2 + 6 x − 8 y + 5 = 0
⇒ 3( x 2 + 2 x ) + 2( y 2 − 4 y ) + 5 = 0
⇒ 3( x 2 + 2 x +1) + 2( y 2 − 4 y + 4) + 5 = 0 + 3 + 8
( x + 1)2 ( y − 2)2
⇒ 3( x +1)2 + 2( y − 2)2 = 6 ⇒ + =1 ( b > a )
2 3
b2 − a2 1
So, e = =
b 3
Centre = (−1, 2)
Focus lies on major axis i.e. x + 1 = 0
At distance be from centre Let foci ≡ ( −1, α )
 1 
⇒  | 2 − α | = 3. = 1 ⇒ 2 −α = ± 1
 3 
α = 2 + 1, 2 −1 = 3, 1
So, foci are (−1, 1) and (−1, 3)
And directrices are parallel to minor axis to y = λ passing through point (−1, 2 ± 3)
⇒ y = 5 and y = − 1

3.(ABC) The locus of point through which perpendicular tangents can be drawn is known as director
circle.
x2 y2
Equation of director circle to − = 1 is
a2 b2
x 2 + y 2 = a 2 − b2 . . . .(i)
2
a2 + b
Now e2 =
a2
If n = 1 ⇒ a 2 − b 2 = 0 so, e = 2 (rectangular hyperbola)
If n > 1 ⇒ a 2 − b 2 > 0 ⇒ a 2 > b2
a 2 + b2 2a 2
⇒ e2 = 2
<
a a2

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⇒ e2 < 2
If n = 0 ⇒ a2 − b2 < 0
⇒ a 2 < b2
⇒ e2 > 2 ⇒ e > 2
4.(AC)

If the radius of the bigger circle is R.

Then
( R − r ) is the length of the side OB and OA

Also, AB = 2r
By sine rule
R −r 2r 2r sin 30°
= ⇒ R −r =
sin 30° sin 60° sin 60°

⇒ R −r =
2r
3
⇒ (
R = 2 3 +3 )r
3
Also, the radius of smaller circle touching three circles externally is
r r
R − 2r = (2 3 + 3) − 2r = (2 − 3)
3 3

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5.(ABC) Equation of tangent to the hyperbolas x 2 − 3 y 2 = 3 at ( 3, 0)

is x = 3 . . . . (i)
Equations of asymptotes are
x
y =± . . . .(ii)
3
⇒ Angle between asymptotes is 60°
Also, OA = OB
So ∆OAB is an equilateral triangle with side 2 unit
⇒ Area = 3sq unit.

6.(ABC) f ( x) = x1/ 3 ( x −1)

1 1
⇒ f ′( x) = 4 / 3 x1/ 3 − 2/3
=
(4 x −1)
3x3x2 / 3
1 1
So, function is increasing for x > and decreasing for x <
4 4
as x 2 / 3 is always +ve.
4 1
Now, f ′( x) = x1/ 3 − x −2 / 3 (Non existent at x = 0 vertical tangent)
3 3
Now,
4 1 2 1 2
f ′′( x) = + = (2 x + 1)
9 x 2 / 3 9 x5 / 3 9 x 5 / 3
So, f ′′( x) = 0 at x = − 1/ 2 (inflection pt.)

7.(ABC) f ( x) = ln(1 − ln x ) domain (0, e)

1 1
f ′( x ) = − . <0 ⇒ Decreasing ∀ x in its Domain
(1 − ln x ) x
f ′(1) = − 1 also f (1) = 0
lim f ( x) 
→ ∞, lim f ( x) 
→∞
x →e−1 x → 0+

− ln x
f ′′( x ) =
x (1 − ln x)2
2

f ′′(1) = 0 which is a pt. of in flection

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MATRIX MATCHING TYPE

8.(A) (A) (1) (A) (i)

gof (x) = x ⇒ g(f (x) = x
⇒ g ′( f ( x) × f ′( x) =1
1 1
⇒ g ′( f ( x) = =
f ′( x ) 1 + cos x
π 1  1 2
g ′ +  = g ′( f (π / 4)) = = = 2( 2 −1) = 2 − 2
4 2 1+
1 2+1
2
(B) (1) (B) (i)
f ′( x) = 1 + cos x ≠ 2 − 2
1
1
9.(B) (A) (1) (C) (iii) ⇒ ∫ ( x + sin x)dx ≠ 2
0
1
dx
(B) (4) (C) (iv) ⇒ ∫ x+3x
Let x = t6 ⇒ dx = 6t 5 dt
0
1 1 3 1
6t 5 dt t dt (t 3 + 1) −1
⇒ I= ∫ t3 + t 2 =6 ∫ t +1
=6 ∫
(t + 1)
dt
0 0 0
1
 t3 t 2 
= 6  − + t  − 6ln(1 + t )]10
 3 2  0
 1 1
= 6 1 + −  − 6ln 2
 3 2
= 6 + 2 – 3 – 6 ln2 = 5 – 6 ln 2
(C) (2) (C) (iv)
x + 2 2 x − 4 = ( x − 2) + 2 2 x − 2 + 2 = | x − 2 + 2 |
1
⇒ ∫| x − 2 + 2 | + | x − 2 − 2 | dx ≠ 5 − 6 ℓn 2
6
10.(A) (A) (3) (D) (iii)
x2
x 1+x + + ...... − 1 − x
e −1 − x 2 1
lim = lim =
x →0 sin x 2 x →0 sin x 2 2
2
× x2
x
(B) (1) (D) (ii)
1
lim ( x + sin x ) = 0 ≠
x →0 10
(C) (4) (B) (iii)
 
d  1  1
 1  ≠
dx  1  2
x +x
2 3


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11-13. Let the point P be (α , β )

1
So, equation of tangent is ( y − β ) = f ′( x) ( x − α ) and equation of normal is ( y − β ) = − (x − α )
′
f ( x)
 β 
T ≡ α − , 0, S = (0, β + α f ′( x))
 f ′( x) 
 α 
N = (α + β f ′( x ), 0) M =  0, β + 
 f ′( x ) 

11.(A) (A) (1) (A) (iv)

12-13. 12.(B) 13.(C)
β2
TP = PS ⇒ + β 2 = α 2 + α 2 ( f ′( x ))2
( f ′( x))2
β dy y
⇒ f ′( x) = ± ⇒ =± ⇒ Curve is
α dx x
(1) (C) (iv) either straight line or hyperbola
(B) TP = OP
β2 dy y
+ β 2 =α 2 + β 2 ⇒ =±
( f ′( x)) 2 dx x
⇒ Curve is this straight line or hyperbola
(2) (B) (iii)
(C) NM = NP
2
 α 
⇒ (α + β f ′( x ))2 +  β +  = ( β f ′( x)) + β
2 2

 f ′( x ) 
dy x x2
⇒ =− ⇒ y2 + = constant ⇒ Curve is an ellipse
dx 2y 2

SINGLE INTEGER VALUE CORRECT TYPE

1.(1) Let as discuss in small interval around x = 0

lim f ( x) = 0 ⇒ p > 0 and q > −1
x →0
x≠0
1
| h | p sin
+ h | tan h |q
f ′(0) = lim h
h →0 h
For f to be differentiable at x = 0
p > 1 and q > 0
So, [p + q] = 1

(1 + 2 x)1/ 4 x − e (1 + 2 x)1/ 2 x − e 2
2.(0) f ( x) = = ×
x 2x (1 + 2 x) 4 x + e
1/

Since lim (1 + 2 x )1/ 4 x = e

x →0

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(1 + 2 x )1/ 2 x − e 2
So, lim f ( x) = lim ×
x →0 x →0 2x (1 + 2 x) 4 x + e
1/

 
 e1/ 2 x ln(1 + 2 x ) −1 − 1 ln(1 + 2 x ) − 2 x  2
= lim e  × ×
x →0
 ln(1 + 2 x ) 4x 2
 (1 + 2 x)
1/ 4 x
+ e
−1
 2x 
e 2 e
=− × =−
2 2 e 2
e
So, f (0) = − ⇒ [| f (0) |] = 0
2
x2 y2
3.(1) Since angle between asymptotes of a hyperbola − =1 is
a2 b2
b θ b
θ = 2 tan − ⇒ tan =
a 2 a
θ a a 2 + b2 θ a 1
So, cos = , where e= ⇒ cos = = ⇒ k =1
2 2
a +b 2 a 2 ae e

4.(5) Let ∆1 and ∆ 2 be areas of S1, S2 respectively

d∆1 d∆ 2
So ∆1 = l12 and ∆ 2 = ℓ 22 ⇒ = 2l1 and = 2l2
dl1 dl2
d∆ 2 l2 dl2 l2 1 1 1
⇒ = = = = =
d∆1 l1 dl1 l1 (1 + 3l22 ) 8(1 + 3) 32 25
(since l1 = l2 + l23 + 6) ⇒ λ =5
3
5.(1) f ( x) = max{1t −1 | + | t +1| − | t |}, − ≤ t≤x
2
Let g ( x ) = | t −1| + | t + 1| − | t |
 −t + 1 − t −1 + t , t <− 1

 −t + 1 + t + 1 + t , −1 ≤ t < 0
=
 −t + 1 + t + 1 − t , 0 ≤ t <1
 t − 1 + t + 1 − t , t ≥1
 −t , t < −1
 t +2 , −1 ≤ t < 0

=
 −t + 2 , 0 ≤ t <1
 t , 1≤ t
2
∴ ∫ f ( x) dx = Area bounded by the curve y = f ( x) & x-axis from x = − 3/ 2 to x = 2
−3 / 2

3  1 51
= Area of ABCDEF =   + × (3/ 2 + 2) × 1/ 2 + 2 * 2 =
2  2 8
8 51
∴ × =1
51 8

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