Page 1/6

Safety Data Sheet

according to 1907/2006/EC, Article 31
Printing date 05.07.2007 Revision: 05.07.2007

* 1 Identification of the substance/preparation and of the company/undertaking

· Product details
· Trade name: DINITROL 25B
· Application of the substance / the preparation Anticorrosion additive
· Manufacturer/Supplier:
EFTEC Ltd. Rhigos, Aberdare, Mid-Glamorgan CF44 9UE, United Kingdom
EFTEC Aftermarket GmbH Pyrmonterstr. 76 D-32676 Lügde
· Further information obtainable from: +44(0)16 85 81 54 00 Q&E Plastisols
· Information in case of emergency: +44(0)16 85 81 54 00

* 2 Hazards identification
· Hazard description:
Xn Harmful
· Information concerning particular hazards for human and environment:
Th e prod uct h as to b e lab elled due t o the calcu lat ion procedure o f the " Gen eral C lassifi cati on
guideline for preparations of the EU" in the latest valid version.
At lo ng or rep eated conta ct with skin it ma y cause d erma titis d ue to the d egrea sing effect o f the
solvent.
R 65 Harmful: may cause lung damage if swallowed.
R 66 Repeated exposure may cause skin dryness or cracking.
· Classification system:
The classification is according to th e latest edit ions of the EU-lists, and extended by company and
literature data.
· Additional information:
The petrol eum n aphtha / petroleum dist illate / lu bricati ng oil meet the requirements for not b eing
classified as carcinogenic (<0,1% benzene alt<3% (w/w) DMSO extract (IP 346)).

* 3 Composition/information on ingredients
· Chemical characterization
· Description: Hydrocarbon solvent based corrosion rust preventive.
· Dangerous components:
EINECS: 265-150-3 Naphtha (petroleum), hydrotreated heavy 50-100%
cas nr 64742-48-9
Xn; R 65-66
CAS: 64742-52-5 Distillates (petroleum), hydrotreated heavy naphthenic 10-25%
EINECS: 265-155-0
CAS: 68608-26-4 Sodium petroleum sulfonate 5-10%
EINECS: 271-781-5 Xi; R 36
CAS: 111-76-2 2-butoxyethanol 1-5%
EINECS: 203-905-0 Xn, Xi; R 20/21/22-36/38
· Additional information: For the wording of the listed risk phrases refer to section 16.
GB

(Contd. on page 2)

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 Page 2/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 05.07.2007 Revision: 05.07.2007

Trade name: DINITROL 25B

(Contd. of page 1)

* 4 First-aid measures
· After inhalation: Supply fresh air.
· After skin contact: Remove contaminated clothing. Wash skin with soap and water.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: Seek medical treatment.

* 5 Fire-fighting measures
· Suitable extinguishing agents:
Fire-extinguishing powder
Foam
Carbon dioxide
· Protective equipment: Wear self-contained respiratory protective device.
· Additional information Cool endangered receptacles with water spray.

* 6 Accidental release measures

· Person-related safety precautions:
Ensure adequate ventilation
Keep away from ignition sources.
Avoid contact with skin, eyes and clothes.
· Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
· Measures for cleaning/collecting:
Dispose of the material collected according to regulations.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.

* 7 Handling and storage

· Handling:
· Information for safe handling:
No special measures required.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection: No special measures required.
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions:
Store receptacle in a well ventilated area.
Protect from heat and direct sunlight.

* 8 Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· Ingredients with limit values that require monitoring at the workplace:
Naphtha (petroleum), hydrotreated heavy
cas nr 64742-48-9
OEL Long-term value: 1000 mg/m³
(Contd. on page 3)
GB

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 Page 3/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 05.07.2007 Revision: 05.07.2007

Trade name: DINITROL 25B

(Contd. of page 2)
64742-52-5 Distillates (petroleum), hydrotreated heavy naphthenic
OEL Short-term value: 10 mg/m³
Long-term value: 5 mg/m³
Mineral Oil mist
111-76-2 2-butoxyethanol
WEL Short-term value: 50 ppm
Long-term value: 25 ppm
Sk
· Additional information: The lists valid during the making were used as basis.
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
· Respiratory protection:
In case of brief exposure or lo w pollution u se respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
· Protection of hands:

Protective gloves

· Material of gloves
Neoprene gloves
Nitrile rubber, NBR
The sel ection of th e suitable gl oves does not only depend on the mat erial, but al so on further marks
of qu ality and varies from manufact urer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has t herefore
to be checked prior to the application.
· Penetration time of glove material
The exact break trough time ha s to be found out by the manu facturer of the pro tective gl oves and
has to be observed.
· Eye protection: Goggles recommended during refilling
· Body protection: Protective work clothing

* 9 Physical and chemical properties

· General Information
Form: Liquid
Colour: Transparent
Odour: Solvent-like
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
· Flash point: > 62°C (ISO 2719)
· Ignition temperature: 200.0°C
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product does not present an explosion hazard.
(Contd. on page 4)
GB

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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 05.07.2007 Revision: 05.07.2007

Trade name: DINITROL 25B

(Contd. of page 3)

· Explosion limits:
Lower: 0.6 Vol %
Upper: 7.0 Vol %
· Vapour pressure at 20°C: 0.5 hPa
· Density at 20°C: 0.82000 g/cm³
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· pH-value at 20°C: 8.3
· Solvent content:
Organic solvents: 74.9 %
· Solids content: 25.1 %

10 Stability and reactivity

· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Dangerous reactions No dangerous reactions known.
· Dangerous decomposition products: No dangerous decomposition products known.

* 11 Toxicological information
· Acute toxicity:
· LD/LC50 values relevant for classification:
Naphtha (petroleum), hydrotreated heavy
cas nr 64742-48-9
Oral LD50 >2000 mg/kg (rat)
Dermal LD50 >2000 mg/kg (rabbit)
Inhalative LC50/4h >5000 ppm (rat)
· Primary irritant effect:
· on the skin:
Degreases th e skin which with lo ng or often repeated contact may ca use red dening a nd sometimes
eczema. In combi nation with bad personal hygiene, it may cause dermatit is, oi l acne or other skin
changes.
· on the eye: Irritation to eyes possible after a long exposure time.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The pro duct shows the fol lowing dang ers accord ing to t he calcul ation meth od o f th e General EU
Classification Guidelines for Preparations as issued in the latest version:
· Inhalation:
May cause hea dache, dizziness, tiredness and indispositio n. At hig h co ncentra tions react ion time
and memory may deteriora te and u nconsciousness may o ccur. Long or often repeated inhalatio n of
high concentrations may cause permanent damage to the nervous system.
· Ingestion:
May cause similar symptoms as for inhalation.
Risk of chemical pneumonia if the product reaches the lungs at vomiting or similar.
GB

(Contd. on page 5)

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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 05.07.2007 Revision: 05.07.2007

Trade name: DINITROL 25B

(Contd. of page 4)

* 12 Ecological information
· Information about elimination (persistence and degradability):
Naphtha (petroleum), hydrotreated heavy
cas nr 64742-48-9
BOD28/COD 61 % (-)
· Ecotoxical effects:
· Acquatic toxicity:
Naphtha (petroleum), hydrotreated heavy
cas nr 64742-48-9
EC50 c 100 mg/l (daphnia)
IC50 c 100 mg/l (alga)
LC50 12-159 mg/l (-)
c 100 mg/l (fish)
· Remark: The solvent can be bioaccumulated.
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do no t a llow un dilu ted pro duct or la rge qua ntit ies of it to reach gro und wat er, wat er course or
sewage system.

* 13 Disposal considerations
· Product:
· Recommendation
Mu st not be disposed tog eth er wit h hou seho ld ga rba ge. Do not al low p rodu ct to reach sewa ge
system.
· European waste catalogue
08 00 00 WASTES FROM THE MAN UFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF
COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS
AND PRINTING INKS
08 01 00 wastes from MFSU and removal of paint and varnish
08 01 11 waste paint and varnish containing organic solvents or other dangerous substances

· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

* 14 Transport information
· Land transport ADR/RID (cross-border)
· ADR/RID class: -
· Maritime transport IMDG:
· IMDG Class: -
· Marine pollutant: No
· Air transport ICAO-TI and IATA-DGR:
· ICAO/IATA Class: -

· Transport/Additional information: Not dangerous according to the above specifications.

GB

(Contd. on page 6)

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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 05.07.2007 Revision: 05.07.2007

Trade name: DINITROL 25B

(Contd. of page 5)

* 15 Regulatory information
· Labelling according to EU guidelines:
Th e pro duct ha s been cl assi fied an d marked in accordan ce wi th EU Direct ives / Ordin ance on
Hazardous Materials.
· Code letter and hazard designation of product:

Xn Harmful

· Hazard-determining components of labelling:

Naphtha (petroleum), hydrotreated heavy
cas nr 64742-48-9
· Risk phrases:
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
· Safety phrases:
2 Keep out of the reach of children.
13 Keep away from food, drink and animal feedingstuffs.
23 Do no t b rea t h e ga s/fu mes/ vap o u r/ sp ra y ( a pp rop ri at e w o rd i n g to b e speci fi ed b y th e
manufacturer).
46 If swallowed, seek medical advice immediately and show this container or label.
51 Use only in well-ventilated areas.
56 Dispose of this material and its container to hazardous or special waste collection point.
· National regulations:
The pro duct is subject t o b e la beled according wit h th e p revail ing versi on o f th e regulat ions on
hazardous substances.

· Technical instructions (air):

Class Share in %
NK 50-100

· Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
· EU-VOC: 74.95 %

* 16 Other information
The information is based on our current level of knowledge and relates to the product in the state in
wh ich it i s deli vered . It i s in tend ed to d escrib e ou r produ ct fro m th e po in t o f vi ew o f sa fety
requirements and is not intended to guarantee any particular property.
· Relevant R-phrases
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
36 Irritating to eyes.
36/38 Irritating to eyes and skin.
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
· Department issuing MSDS: Q&E Department
· Contact:
J. Maxwell
john.maxwell@eftecltd.co.uk
· * Data compared to the previous version altered.
GB

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