TOPIC WISE TEST

CHAPTER – ATOMIC STRUCTURE

Question 1

The students of a class were divided into two groups : Group B (of boys) and Group G (of girls). Both
the groups were asked to perform one experiment each. Group B observed a photon of wave number
8 ´ 107 m–1, while group G observed photon of energy 1.8 ´ 10–17 joule. Both the groups claimed that
their photon has greater momentum. What do you say : Use h = 6.625 ´ 10–34
Js.

Options:

A : Photon of group B has greater momentum.

B : Photon of group G has greater momentum

C : Photons of both groups have same momentum

D : Nothing can be said with certainty.

Question 2

Options:

A : 13.6 V

B : 10.2 V

C : 1.51 V

D : 1.89 V
Question 3

Light of wavelength l strikes a metal surface with intensity X and the metal emits Y electrons per
second, of average kinetic energy Z. What will happen to Y and Z, if X is doubled keeping l constant
:

Options:

A : Y will decrease ; Z will decrease

B : Y will increase ; Z will remain same

C : Y will remain same ; Z will increase

D : Y will increase ; Z will increase

Question 4

Which of the following statements is correct :

Options:

A : In Li2+ ion, the ratio of series limit wavelength of Humphry series and wavelength of 2nd line of
Paschen series is 3136 : 325 respectively.

B : The dxy orbital has two nodal planes, xz and yz planes, and two additional angular nodes.

C : The ratio of time period of revolution of electron in 1st orbit of He+ ion and 2nd orbit of Be3+ ion is
1 : 2 respectively.

D : Canal rays is the other name for anode rays and the positively charge particles travelling in it are
one of the fundamental particles of an atom - protons.
Question 5

Options:

A:

B:

C:

D:

Question 6

Options:

A : i, ii & iv ; Hund's rule of maximum multiplicity.

B : iii & v ; Hund's rule of maximum multiplicity.

C : i, ii & iv ; Pauli exclusion principle.

D : iii & v ; Pauli exclusion principle.

Question 7

Which of the following statements is/are Incorrect :

Options:

A : A H-atom sample having electrons in 5th orbit can emit 3 photons in infrared region upon back-
transition.

B : We cannot use two photons successively of 1240 Å and 2000 Å wavelength in order to ionise a H
atom from ground state.

C : According to Bohr model, binding energy of nth orbit is always less than excitation energy of nth
orbit for all H-like species.

D : A single isolated H-atom having its electron in 4th orbit can emit 2 photons in visible region upon
back-transition.

Question 8

Options:

A : 17

B:8

C : 11

D : 14
Question 9

Options:

A : Minimum possible atomic number of element containing atleast one electron in orbital represented
by ψ411 is
31.

B : Majority of the lines of Balmer series in Hydrogen spectrum lie in ultraviolet

region.

C : Zeeman effect and Stark effect (splitting of spectral lines into finer lines on applying electric and
magnetic field respectively) are failures of Bohr
model.

D : The number of neutrons in the daughter nuclei left after emission of 1 a-particle from 92U238 is

144.

Question 10

A sample of hydrogen atoms absorbs radiations of wavelength lo and consequently emits radiations of
maximum ten different wavelengths upon back-transition, of which only five wavelengths are longer
than lo. Choose the incorrect alternative :

Options:

A : The highest orbit occupied by the electron is the 5th orbit.

B : The initial orbit number of the electrons is 2.

C : Among the emitted radiations, four wavelengths are shorter than λo.

D : Among the emitted radiations, one wavelength belongs to Pfund series.

Question 11

Which of the following statements is INCORRECT :

Options:

A : de Broglie wave length of electron in the 1st orbit of He+ ion is equal to that in 2nd orbit of Be 3+ion.

B:

C : Maximum number of isoelectronic species among the following is six.

N2, CN–, Si, NO–, CO, O22+, C22–, C2H4, CH3+

D : Fourth line of Brakett series in He+ spectrum lies in infrared region.

Question 12

A proton and an a-particle, both initially at rest, are supplied with same potential difference and are
projected from infinity towards a thin gold foil. What can be said about their closest distance of
approach from the gold nucleus
:

Options:

A : a-particle will reach closer to the gold nucleus than

proton.

B : Proton will reach closer to the gold nucleus than α-

particle.

C : Both proton and a-particle will have same value of closest distance of approach from the gold

nucleus

D : Nothing can be said with certainty.

Question 13

Options:

A : 16

B:8

C : 32

D : 24

Question 14

Electrons in a Be3+ sample make transition from n = 7 upto I excited state producing photons with all
possible wavelengths. From these, the photons of second maximum wave number are incident upon a
He+ ion sample, in which the electrons jump from n1 orbit to n2 orbit as a result of it. Find the value of
n1 & n2
:

Options:

A : 1, 2

B : 1, 3

C : 1, ∞

D : No electron jump in He+ ion takes place

Question 15

According to Heisenberg's uncertainty principle, on decreasing the wavelength of light used to locate a
microscopic particle, uncertainty in measurement of momentum of particle
:
Options:

A : Increases

B : Decreases

C : Remains unchanged

D : Cannot be predicted

Question 16

Question 17
Question 18

Question 19

Question 20
Question 21

Question 22

Question 23

For a hypothetical H like species which follows Bohr's model, some spectral lines were observed as
shown in figure. If it is known that line 'E' belongs to the visible region, then the line(s) possibly
belonging to infrared region will be : [Given : n1, n2, n3 and n4 are consecutive orbits & n1 = 3]

Options:

A:D B:C

C:B D:A
Question 24

In which of the following conditions, the de Broglie wavelength of a charged particle A will be less than
that of another charged particle B ? Given that particle A is heavier than particle B :

Options:

A : Linear momentum of these particles is same.

B : Both particles move with same speed.

C : Both particles have same kinetic energy.

D : Same potential difference has been applied across both the particles from rest.

Question 25

Select the correct statement(s) :

Options:

A : n/p ratio increases during a-emission.

B : In b-emission from a nucleus, the atomic number of the daughter element decreases by one.

C : Correct order of ionisation power is a > b > g.

D : Lesser the value of binding energy per nucleon for a nucleus, greater is the stability of nucleus.
Question 26

Options:

A : Orbital corresponding to (I) diagram has non-zero value of orbital angular momentum

B : Orbital corresponding to (II) diagram has no spherical node.

C : Orbital corresponding to (II) diagram has one nodal plane.

D : Orbital corresponding to (I) diagram is 3s orbital.

Question 27

Options:

A : Orbital corresponding to (I) graph may be 2px orbital.

B : Orbital corresponding to (II) graph may be 3pz orbital.

C : Orbital corresponding to (II) graph may be 2s orbital.

D : Orbital corresponding to (I) graph may be 1s orbital.

Question 28

The famous alien Jadu on his visit to our planet earth brought a sample containing 100 identical H-like
atoms (hypothetical atoms, Z can be fractional) from his planet. He gave these atoms to Rohit (Hritik
Roshan) asking him to analyze them. He further gave Rohit the following informations :

1. Out of the given atoms, some are in ground state and some others are in a higher energy level (n =
x) and the potential energy of electron in the ground state of given atom is –192 eV.
2. When the sample is exposed to radiations of wavelength 155 nm, the electrons jump to another
higher energy level (n = x + 3). Upon back-transition upto ground state, a maximum of 10 different
spectral lines are produced.
Now answer the following two questions that Jadu asked Rohit : (Take hc = 12400 eV Å.)

What is the final state in which the electrons move, after absorbing photons of wavelength 155 nm ?

Options:

A:6

B:5

C:7

D:8

Question 29

The famous alien Jadu on his visit to our planet earth brought a sample containing 100 identical H-like
atoms (hypothetical atoms, Z can be fractional) from his planet. He gave these atoms to Rohit (Hritik
Roshan) asking him to analyze them. He further gave Rohit the following informations :

1. Out of the given atoms, some are in ground state and some others are in a higher energy level (n =
x) and the potential energy of electron in the ground state of given atom is –192 eV.
2. When the sample is exposed to radiations of wavelength 155 nm, the electrons jump to another
higher energy level (n = x + 3). Upon back-transition upto ground state, a maximum of 10 different
spectral lines are produced.
Now answer the following two questions that Jadu asked Rohit : (Take hc = 12400 eV Å.)

Options:

A : 93

B : 94

C : 95

D : 96

30) Match the Coloumn

A Co3+ P

B Cu+ Q

C Ti2+ R Total number of fully filled orbitals is 10 or more.

D Sc3+ S Number of electrons with (ml = 0) may be 11.

(T) Value of total spin is zero.