ATTACHMENT OF CALCULATION

1. Determining mmolHClinitial
mmol = N HCl x V HCl = 0.02 x 10 ml = 0.2 mmol

2. Determining mmolNaOHinitial
mmol = N NaOH x V NaOH = 0.02 x 2.22 ml= 0.0444 mmol

3. Determining mmol NaOHtitration

mmol = N x VNaOH titration
t = 3 mmol = 0.02 x 5.1 ml = 0.102
t = 8 mmol = 0.02 x 5.8 ml = 0.116
t = 15mmol = 0.02 x 6.2 ml = 0.124
t = 25mmol = 0.02 x 6.5 ml = 0.13
t = 40mmol = 0.02 x 6.7 ml = 0.134
t = 65mmol = 0.02 x 6.8 ml = 0.136
t = 2880mmol = 0.02 x 7.1 ml = 0.142

Based on the reactiobelow, the mmol of NaOH titration = the mmol of NaOH residue. Or we can
say that NaOH titration is (b-x)

CH3COOC2H5 + NaOH = CH3COONa + C2H5OH + NaOH residue

x mmol
NaOH residue + HCl = NaCl + H2O + HCl residue
x mmol x mmol

HCl residue + NaOH titration = NaCl + H2O

x mmol x mmol

So (b-x) = x mmol

1. First titration
V NaOH = 5.1 ml t = 3 menit 20detik = 200s

CH3COOC2H5 + NaOH = CH3COONa + C2H5OH

0.0556 mmol 0.0444 mmol
X mmol x mmol +
(0.0556 – x)mmol 0.102 mmol

0.102 mmol (b-x)

0.0444 mmol – x = 0.102 mmol

X = (0.0444 – 0.102) mmol
X = - 0.0576 mmol
 0.0556 mmol – x = (a-x)
0.0556 mmol – (-0.0576) mmol = (a-x)
0.0556 + 0.0576 = (a-x)
0.1132 mmol = (a-x)

ln(𝑎−𝑥) ln 𝑎
(𝑏−𝑥)
−
𝑏
𝐾1 = 𝑡
(𝑏(𝑎−𝑥)−𝑎(𝑏−𝑥))

𝑙𝑛 (0.1132) ln 0.0556
(0.102)
− 0.0444
𝐾1 =
200 (0.0444(0.1132) − 0.0556(0.102))

2. Second titration

V NaOH = 5.8 ml t = 8 menit 40detik = 520s

CH3COOC2H5 + NaOH = CH3COONa + C2H5OH

0.0556 mmol 0.0444 mmol
X mmol x mmol +
(0.0556 – x)mmol 0.116 mmol

0.116 mmol (b-x)

0.0444 mmol – x = 0.116 mmol

X = (0.0444 – 0.116) mmol
X = - 0.0716 mmol

0.0556 mmol – x = (a-x)

0.0556 mmol – (-0.0716) mmol = (a-x)
0.0556 + 0.0716 = (a-x)
0.1272 mmol = (a-x)

ln(𝑎−𝑥) ln 𝑎
(𝑏−𝑥)
−
𝑏
𝐾2 = 𝑡
(𝑏(𝑎−𝑥)−𝑎(𝑏−𝑥))

𝑙𝑛 (0.1272) ln 0.0556
(0.116)
− 0.0444
𝐾2 =
520 (0.0444(0.1272) − 0.0556(0.116))

3. Third titration
V NaOH = 6.2 ml t = 15 menit 25detik = 925s

CH3COOC2H5 + NaOH = CH3COONa + C2H5OH

0.0556 mmol 0.0444 mmol
X mmol x mmol +
(0.0556 – x)mmol 0.124 mmol

0.124 mmol (b-x)

 0.0444 mmol – x = 0.124 mmol
X = (0.0444 – 0.124) mmol
X = - 0.0796 mmol

0.0556 mmol – x = (a-x)

0.0556 mmol – (-0.0796) mmol = (a-x)
0.0556 + 0.0716 = (a-x)
0.1352 mmol = (a-x)

ln(𝑎−𝑥) ln 𝑎
(𝑏−𝑥)
−
𝑏
𝐾3 = 𝑡
(𝑏(𝑎−𝑥)−𝑎(𝑏−𝑥))

𝑙𝑛 (0.1352) ln 0.0556
(0.124)
− 0.0444
𝐾3 =
925 (0.0444(0.1352) − 0.0556(0.124))

4. Fourth titration
V NaOH = 6.5 ml t = 25 menit 55detik = 1555s

CH3COOC2H5 + NaOH = CH3COONa + C2H5OH

0.0556 mmol 0.0444 mmol
X mmol x mmol +
(0.0556 – x)mmol 0.13 mmol

0.124 mmol (b-x)

0.0444 mmol – x = 0.13 mmol

X = (0.0444 – 0.13) mmol
X = - 0.0856 mmol

0.0556 mmol – x = (a-x)

0.0556 mmol – (-0.0796) mmol = (a-x)
0.0556 + 0.0856 = (a-x)
0.1412 mmol = (a-x)

ln(𝑎−𝑥) ln 𝑎
(𝑏−𝑥)
−
𝑏
𝐾4 = 𝑡
(𝑏(𝑎−𝑥)−𝑎(𝑏−𝑥))

𝑙𝑛 (0.1412) ln 0.0556
−
(0.13) 0.0444
𝐾4 =
1555 (0.0444(0.1412) − 0.0556(0.13))

5. Fifth titration
V NaOH = 6.2 ml t = 15 menit 25detik = 925s

CH3COOC2H5 + NaOH = CH3COONa + C2H5OH

0.0556 mmol 0.0444 mmol
X mmol x mmol +
 (0.0556 – x)mmol 0.124 mmol

0.124 mmol (b-x)

0.0444 mmol – x = 0.124 mmol

X = (0.0444 – 0.124) mmol
X = - 0.0796 mmol

0.0556 mmol – x = (a-x)

0.0556 mmol – (-0.0796) mmol = (a-x)
0.0556 + 0.0716 = (a-x)
0.1352 mmol = (a-x)

ln(𝑎−𝑥) ln 𝑎
(𝑏−𝑥)
−
𝑏
𝐾3 = 𝑡
(𝑏(𝑎−𝑥)−𝑎(𝑏−𝑥))

𝑙𝑛 (0.1352) ln 0.0556
(0.124)
− 0.0444
𝐾3 =
925 (0.0444(0.1352) − 0.0556(0.124))

6.

4. Determining mmolHClreact =mmolNaOHrest

mmol = mmolHClinitial - mmolHClrest
t = 3 mmol = 0.2 – 0.102 = 0.098
t = 8mmol = 0.2 – 0.116 = 0.084
t = 15mmol = 0.2 – 0.124 = 0.076
t = 25mmol = 0.2 – 0.13 = 0.07
t = 40mmol = 0.2 – 0.134 = 0.066
t = 65mmol = 0.2 – 0.136 = 0.064
t = 2880mmol = 0.2 – 0.142 = 0.058