1992 organo-arsenic compounds, nonmetal heterocycles

organo-arsenic compounds, nonmetal heterocycles

S 0117 Benzothiarsolium Cations: Evidence for pπ-Bonding Between Ar-
45 - 224 senic and Sulfur in the First Structurally Characterized Arsenium
System. — Tetrachloroaluminate salts of benzothiazarsolium (II) and
benzodithiarsolium (III) are conveniently prepared by usual halide ion ab-
straction from the corresponding chloroarsoles. Spectroscopic data including
X-ray data (space group: P21/c with Z = 4 for both the new thiaza deriva-
tives) indicate that the cations represent the first examples of stable systems
containing As–S p-π-bonding. — (BURFORD, N.; PARKS, T. M.; ROYAN,
B. W.; RICHARDSON, J. F.; WHITE, P. S.; Can. J. Chem. 70 (1992) 3,
703-709; Dep. Chem., Dalhousie Univ., Halifax, Nova Scotia B3H 4J3, Can.; EN)