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International Journal of Hydrogen Energy 30 (2005) 359 – 371

www.elsevier.com/locate/ijhydene

Review of bipolar plates in PEM fuel cells: Flow-field designs


Xianguo Li∗ , Imran Sabir
Department of Mechanical Engineering, University of Waterloo, 200 University Avenue West, Waterloo, Ontario, Canada, N2L 3G1

Received 7 April 2004; received in revised form 11 August 2004; accepted 2 September 2004
Available online 23 November 2004

Abstract
The polymer electrolyte membrane (PEM) fuel cell is a promising candidate as zero-emission power source for transport
and stationary cogeneration applications due to its high efficiency, low-temperature operation, high power density, fast start-
up, and system robustness. Bipolar plate is a vital component of PEM fuel cells, which supplies fuel and oxidant to reactive
sites, removes reaction products, collects produced current and provides mechanical support for the cells in the stack. Bipolar
plates constitute more than 60% of the weight and 30% of the total cost in a fuel cell stack. For this reason, the weight,
volume and cost of the fuel cell stack can be reduced significantly by improving layout configuration of flow field and use of
lightweight materials. Different combinations of materials, flow-field layouts and fabrication techniques have been developed
for these plates to achieve aforementioned functions efficiently, with the aim of obtaining high performance and economic
advantages. The present paper presents a comprehensive review of the flow-field layouts developed by different companies
and research groups and the pros and cons associated with these designs.
䉷 2004 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
Keywords: PEM fuel cell; Bipolar plate; Flow field; Flow channels

1. Introduction
During the past two decades, the research and develop-
The polymer electrolyte membrane fuel cell (PEMFC) ment of the PEMFC with a Nafion䉸 membrane as elec-
is one of the most widely researched fuel cell technolo- trolyte have received much attention. Much research has
gies because it offers several advantages for transport and focussed on single cells of PEMFC or their components,
a number of other applications. Its low-temperature oper- such as novel membrane electrolytes, catalysts and structure,
ation, high power density, fast start-up, system robustness, electrochemical reaction mechanisms and kinetics, as well
and low emissions have ensured that the majority of motor as electrode materials and preparation. This has resulted in
manufacturers are actively pursuing PEMFC research and a number of alternatives to Nafion䉸 membrane technology
development. Already in Europe with demonstration buses with low load, high utilization catalyst yielding significantly
and passenger vehicles in California, for example, a first higher power density than was available few years back. Im-
market introduction of fuel cell vehicles will be seen in the provements in cell design and manufacturing have further
near future. However, there are still technical barriers to be increased power, while reducing manufacturing costs, which
overcome before fuel cell vehicles reach a significant mar- is essential if the fuel cell is to compete with the internal
ket penetration [1–3]. combustion engine.
For a given membrane/electrode assembly (MEA), the
power density of a fuel cell stack can be significantly in-
∗ Corresponding author. Tel.: +1 519 888 4567/X 6843; creased by reducing the profile of the bipolar plates. A key
fax: +1 519 888 6197. prerequisite for many power applications is the production
E-mail address: x6li@uwaterloo.ca (X. Li). of compact and lightweight PEMFC stacks, which may be

0360-3199/$30.00 䉷 2004 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
doi:10.1016/j.ijhydene.2004.09.019
360 X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371

achieved with appropriate selection of materials. Bipolar


plate design as a whole, and flow channel layout configura-
tion, in particular, are potential areas of research for making
this alternative clean power source compatible to its coun-
terparts [4–6]. Challenges remain, however, that include re-
ducing the weight, volume and cost of the fuel cell stack
with the present goal being to develop a 50 kW stack system
weighing less than 133 l and a cost of $35/kW (DOE). The
dominance of the bipolar plates (BPPs) in a PEMFC stacks
is illustrated in Fig. 1. The objective of this review article is
to present a comprehensive overview of the state-of-the-art
technology for the BPPs in PEMFCs and the current and
future direction of the R&D activities that aim at the reduc-
tion in the weight, volume and cost of BPPs with improved
performance and lifetime.

2. Biopolar plates

As discussed earlier, BPPs account for the bulk of the


stack, hence it is desirable to produce plates with the small-
est possible dimensions permissible (<3 mm in thickness)
[US Department of Energy (DOE), 8]. With the bipolar plate
arrangement for current collection each of the MEAs (mem-
brane electrode assembly) is interspersed between two fluid-
impermeable, electrically conductive plates, commonly re-
ferred to as the anode and the cathode plates, respectively.
When the reactant flow channels are formed on the anode
and cathode plates, the plates are normally referred to as
fluid flow-field plates. When the flow channels are formed
on both side of the same plate, one side serves as the an-
ode plate and the other side as the cathode plate to the ad-
jacent cell, and the plate is called bipolar (separator) plate,
as shown in Fig. 2. In this stack design, cooling is accom-
plished with accommodating separate cooling plates after a
few cells in series. It is more often that one of the reactants
flows on one side of such a plate, while a cooling fluid flows
on the other side of the same plate in order to remove the
waste heat generated in the cell, and these plates collectively
have to keep the fuel, oxidant and cooling fluid apart, pre-
venting them from mixing with each other, otherwise safety
concerns and hazardous situations may arise.

2.1. Functions

BPPs being one of the most important components in Fig. 1. Mass distribution in a 33 kW PEMFC stacks [7].
PEMFC stacks must perform a number of functions well
simultaneously in order to achieve good stack performance
and lifetime. BPPs supply the reactant gases through the
flow channels to the electrodes and serve the purpose of
electronically connecting one cell to another in the elec- facilitate these functions. Topologies can include straight,
trochemical cell stack. These plates also provide structural serpentine, or interdigitated flow fields, internal manifold-
support for the thin and mechanically weak MEAs and ing, internal humidification, and integrated cooling. There-
means to facilitate water management within the cell. In fore, optimal design must be sought for the BPPs because
the absence of dedicated cooling plates, the BPPs also fa- the above functions have conflicting requirements on the
cilitate heat management. Plate topologies and materials BPP design.
X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371 361

Fig. 2. Stack components of fuel cell [9].

2.2. Requirements

The essential requirements for BPPs, in respect to physic-


ochemical characteristics, are uniform distribution of the
reactant gases over the respective active electrode surface
to minimize the concentration overpotential; high values of
electronic conductivity for current collection; high mechan-
ical strength for stack integrity; impermeability to reactant
gases for safe operation; resistance to corrosion in severe Fig. 3. Pin-type flow-field [16,17].
cell environment for long lifetime; cheap materials, easy and
automated fabrication for low cost.
impact on PEMFC performance (i.e., energy efficiency and
2.3. Channel cross-section power density) [12]. As much as 50% increase in the output
power density has been reported [13,14] just by appropri-
The fluid flow channels are typically rectangular in cross- ate distribution of gas flow fields alone. In spite of all the
section, even though other configurations such as trape- industrial R&D efforts, the time-effective design and opti-
zoidal, triangular, semi-circular, etc. have been explored mization of the gas flow fields and BPPs remain one of the
[10]. The flow channel dimensions range from a fraction of important issues for the cost reduction and performance im-
1 about 2 mm in width and depth as a low limit for a rea- provement of PEM fuel cells.
sonable fluid pressure loss due to friction losses. The most As to the geometrical configurations of the gas flow fields,
common methods of fabricating fluid flow channels on the a variety of different designs are known and the conventional
BPPs require the engraving or milling of flow channels into designs typically comprise either pin, straight or serpentine
the surface of the BPPs. After molding the plates at high designs of flow-field channels, as summarized in [15]. Fuel
temperature and pressure, the gas distribution channels are cell developers have used alternative designs, such as
machined, generally in a parallel flow configuration.
Simulation results for values of channel depth, width and 1. pin-type flow field,
land width have also been reported close to 1.5, 1.5, and 2. series-parallel flow field,
0.5 mm, respectively. Decreasing land width will increase 3. serpentine flow field,
hydrogen concentration at the anode, and triangular and 4. integrated flow fields,
hemispherical cross-sections have land width close to zero 5. interdigitated flow field,
[11]. In practice these design suggestions have limitations 6. flow-field designs made from metal sheets.
too, for example triangular or near zero land width design
might crush the MEA at high pressure contact areas that
hampers the current collection. 3.1. Pin-type flow field

Examples of the pin-type flow fields are illustrated by


3. Flow-field layout design Reiser and Sawyer [16] and Reiser [17] , and an example is
shown in Fig. 3. The flow-field network is formed by many
One of the main obstacles to large-scale commercializa- pins arranged in a regular pattern, and these pins can be in
tion of fuel cells is the gas flow fields and BPPs, includ- any shape, although cubical and circular pins are most often
ing the development of low-cost lightweight construction used in practice. Normally, both the cathode and the anode
materials, optimal design and fabrication methods and their flow-field plates have an array of regularly spaced cubical
362 X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371

Inlet

Flow-
Channel

Outlet

Rib or Channel Support

Flow Channel

Fig. 5. Variation of configuration in straight or parallel flow field


Fig. 4. Straight and parallel flow field and flow channel
design [19].
cross-section [18].

or circular pins protruding from the plates, and the reactant periods of operation, because of cathode gas flow distribu-
gases flow across the plates through the intervening grooves tion and cell water management. As the fuel cell operated
formed by the pins. The actual fluid flow thus goes through continuously, the water formed at the cathode accumulates
a network of series and parallel flow paths. As a result, pin- in the flow channels adjacent to the cathode, the channels
design flow fields result in low reactant pressure drop. How- become wet, and the water thus tends to cling to the bot-
ever, reactants flowing through such flow fields tend to fol- tom and the sides of the channels. The water droplets also
low the path of least resistance across the flow field, which tend to coalesce and form larger droplets. A force, which in-
may lead to channelling and the formation of stagnant areas, creases with the size and number of the droplets, is required
thus uneven reactant distribution, inadequate product water to move the droplets through the channel and out of the
removal and poor fuel cell performance. Further, relative cell. Since the number and size of the water droplets in the
stable recirculation zones may arise behind each pin since parallel channels are likely different, the reactant gas then
the reactant flow is very slow in such a small flow chan- flows preferentially through the least obstructed channels.
nels, and the Reynolds number for the reactant flow remains Water thus tends to collect in the channels in which little or
small, particularly for the fuel stream Reynolds numbers no gas is passing. Accordingly, stagnant areas tend to form
may range from a few tens to low hundreds. Reactant con- at various areas throughout the plate. Hence, the poor cell
centration may be depleted in the stable recirculation zones performance arises from the inadequate water drainage and
as well, decreasing the cell and stack performance. These poor gas flow distribution on the cathode side. This problem
issues may become particularly problematic with flow fields is similar to the one that occurs in the pin-type flow field, as
having certain geometric shapes. discussed earlier. Few more examples of straight or parallel
flow-field design are shown in Figs. 5–7.
3.2. Straight flow field Another problem associated with this design is that the
straight and parallel channels in the BPPs tend to be rel-
Pollegri and Spaziante [18] showed a straight flow-field atively short and have no directional changes. As a con-
design, which is further exemplified by General Electric and sequence, the reactant gas has a very small pressure drop
Hamilton Standard LANL No. 9-X53-D6272-1 (1980). In along these channels, and the pressure drop in the stack dis-
this design, the gas flow-field plate includes a number of tribution manifold and piping system, which is normal to
separate parallel flow channels connected to the gas inlet and the BPPs, tends to be large in comparison. This inadequate
exhaust headers, which are parallel to the edges of the plate. pressure loss distribution results in non-uniform flow distri-
An example is shown in Fig. 4 with the flow channel cross- bution of reactant gases among various active cells in the
sectional shape. When air is used as the oxidant, it is found stack, usually the first few cells near the manifold inlet have
that low and unstable cell voltages occur after extended more flow than those towards the end portion of the inlet
X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371 363

aligned in parallel to allow for the concurrent and counter-


current flow arrangements for the fuel and oxidant stream.
The contact area, as defined by the overlap of the ribs on the
anode and the cathode plates, depends on the manufacturing
tolerances affecting the width of the ribs, the smoothness of
the rib surface, the exact location of the ribs, rib-edge ma-
chining and assembly alignments (plate to plate), etc. The
variation in the contact areas of the ribs results in variation
in the local stress and the associated cell strain. A minimum
local stress is necessary to maintain minimum electrical (as
well as thermal) contact resistance, whereas a significantly
high local stress may lead to the damage and premature
failure of cell components. To ensure uniform compression
load across the cell, it is necessary to have even distribution
of both parallel and perpendicular contact areas (i.e., cross
flow and co-flow arrangements).

3.2.1. Modified versions


Johnson et al. [20] proposed a design with pressure gra-
dients within the channels, such that the resistance to reac-
tant flow differs along the length of the adjacent channels
Fig. 6. Straight or parallel flow field [19].
as shown in Figs. 8 and 9. Prior to flow field designs with
linear, parallel, uniform channels, there may be no signifi-
cant local pressure differential between adjacent channels.
However, by appropriately varying flow resistance in the
channels, pressure differentials may desirably be increased
in such flow fields. This improved version of straight or par-
allel flow channels performs better than the one mentioned
before, even though the pressure drop may not be as much
as that achieved by serpentine layout.
The flow-field layout by Yang et al. [21] introduced re-
strictions between the inlet of the manifold and inlet of the
straight channels which in turn contribute towards pressure
differential without using long, tortuous channels as shown
in Fig. 10. Essentially the flow restriction is accomplished
through the use of fuel inlet tubes, which pass through the
frame member and connect the fuel inlet manifold to the
fuel channel inlets and similarly on the oxidant side. The
cross-sectional or flow areas of inlet tubes are such that they
create a flow restriction and, therefore, a pressure differen-
tial required to drive reaction products out of the reactive
area.

3.3. Serpentine flow field


Fig. 7. Example of straight or parallel flow field design [19].
In an attempt to tackle the problems with straight chan-
nels, Spurrier et al. [22] and Granata and Woodle [23] de-
manifold. One possible solution is to artificially place some scribed a modified serpentine gas flow field across the plate
restrictions at the inlet and the exit of these parallel flow surface, as shown schematically in Fig. 11. The channels
channels to increase the pressure drop in the channels and are generally linear and arranged parallel to one another, but
hence improve the flow distribution among the active cells. skewed to the edge of the plate, while the spaced slots allow
However, this complicates the design and fabrication, thus cross-channel flow of the reactant gas in a staggered man-
the cost. A further problem with this design is the possi- ner, which creates a multiple of mini-serpentine flow paths
ble and often-arisen non-uniform distribution of a compres- transverse to the longitudinal gas flow along the channels.
sive load carried across the fuel cells within the stack when Thus, adjacent pairs of the channels are interconnected by
the flow channels on the anode and the cathode plates are the spaced slots. The flow channels on the anode and cathode
364 X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371

Fig. 10. Straight channels flow field with restrictions [21].

Fig. 8. Modified straight flow channels design [20].

Fig. 11. Serpentine flow field by Spurrier et al. [22].

plates are skewed in opposite directions in such a manner


that exact co-flow arrangement is avoided, and some cross
flow and some nearly co-flow configuration are achieved.
So, it is claimed that this design can improve reactant flow
distribution across the electrode surface of the fuel cells,
and produce a uniform distribution of stack compression
Fig. 9. Straight flow channel design for pressure variation along loading on each fuel cell within the stack. In reality, this
the length [20]. design may incur high reactant pressure loss with potential
X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371 365

Fig. 13. Multiple serpentine flow channels [25].

Fig. 12. Single serpentine flow channel design [24].


Although reactant pressure losses through the flow dis-
tribution fields increase the parasitic load and the degree of
difficulty for hydrogen recirculation, they are actually help-
formation of stagnant areas due to the cross channel flow
ful for the removal of product water in vapour form. Assum-
by the spaced slots as shown in Fig. 11b.
ing ideal gas behaviour, the total reactant gas pressure PT
To resolve the problem of water flooding resulting from
= Pvap + Pgas , where Pvap and Pgas are the partial pres-
the inadequate water removal from the cells, Watkins et al.
sure of the water vapour and reactant gas in the reactant gas
[14] proposed using a continuous fluid-flow channel that
stream, respectively. Then the molar flow rate of the water
had an inlet at one end and an outlet at the other, and typ-
vapour and the reactant (either hydrogen or oxygen) is re-
ically followed a serpentine path. A schematic diagram is
lated as follows:
shown in Fig. 12. Such a single serpentine flow field forces
the reactant flow to traverse the entire active area of the Ṅvap Pvap Pvap
corresponding electrode thereby eliminating areas of stag- = = . (1)
Ṅgas Pgas PT − Pvap
nant flow. However, this channel layout results in a rela-
tively long reactant flow path, hence a substantial pressure Hence, the total pressure loss along a flow channel will
drop and significant concentration gradients from the flow increase the amount of water vapour that can be carried and
inlet to outlet. In addition, the use of a single channel to taken away by a given amount of the reactant gas flow if
collect all the liquid water produced from the electrode re- the relative humidity is maintained. This approach can be
action may promote flooding of the single serpentine, es- used to enhance water removal by both oxidant and fuel
pecially at high current densities. Hence, for higher current streams. In fact, a sufficient pressure loss in the anode flow
density operation, especially when air is used as the oxidant channels can even draw water through the membrane from
or with very large gas flow field plates, Watkins et al. [13] the cathode side, and remove the excess water by the anode
pointed out that several continuous separate flow channels stream, so that the fuel cell performance at high current
might be used in order to limit the pressure drop and thus operations can be improved significantly, as demonstrated
minimize the parasitic power required to pressurize the air, by Voss and Chow [19].
which can be as much as over 30% of the stack power out- Eq. (1) also indicates that an increase in the water vapour
put. This design, shown schematically in Fig. 13, ensures partial pressure can enhance the ability of the reactant gas
adequate water removal by the gas flow through the chan- stream to remove water, and the water vapour pressure is
nel, and no stagnant area formation at the cathode surface limited by the saturation pressure determined by the gas
due to water accumulation. Watkins et al. [13] reported that stream temperature. Hence, liquid water can flood the ser-
under the same experimental conditions, the output power pentine channels and the electrodes after the cathode gas
from the cell could be increased by almost 50% with this stream has been saturated. However, if the reactant gas tem-
new type of flow-field plates. Although multiple serpentine perature is increased along the flow direction from the inlet
flow-field designs of this type reduce the reactant pressure to the outlet of the fuel cell, the capacity of the gas stream
drop relative to single serpentine designs, the reactant pres- to absorb water also increases. Fletcher et al. [26] described
sure drop through each of the serpentines remains relatively a stack arrangement where the coolant flow is substantially
high due to the relatively long flow path of each serpen- parallel to the reactant flow, such that the coolest region
tine channel, thus the reactant concentration changes signif- of each cooling layer coincides with the inlet region of the
icantly from the flow inlet region to the exit region for each adjacent reactant layer where the gas stream has the low-
active cell. est temperature and water content, and the warmest region
366 X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371

Fig. 14. Flow-field design by Cavalca et al., [27].

Fig. 15. Serially linked serpentine flow field [28].

of each cooling layer coincides with the outlet region of


the adjacent reactant layer where the reactant gas stream
has the highest temperature and water content. Thus, the
temperature increase along the cooling path is also used nel via the diffusion layer so as to expose the MEA con-
to increase the cathode stream temperature, enhancing the fronting the land of consecutive legs of channel. In this re-
cathode stream’s capability of absorbing and removing the gard, gas can flow from an upstream (high pressure) leg
reaction product water in the vapour form. However, this of the channel to a downstream leg of the same channel
creates an undesirable non-uniform temperature distribution (low pressure) through the diffusion layer under the land.
throughout the cell. Due to the small pressure drop between However, in long channel legs excessive pressure drop can
the inlet and outlet ports, there are no water droplet block- occur between adjacent legs or between the ends of the
ages in the bipolar plates with the serpentine flow geometry, legs. Such excessive pressure drop can in turn result in the
as used in Ballard PEM Fuel Cells. gaseous reactant, short circuiting excessively between adja-
Another design by Cavalca et al. [27] exhibits distri- cent legs, rather than flowing through the full length of the
bution of reactants more uniformly with higher average channel.
reactant concentrations and also pressure drop is low and The layout design suggested by Rock [28] takes care of
prevents formation of stagnant flow areas. This type is the above problem by subdividing the channels into a plu-
shown in Fig. 14. Here, flow field is divided in several rality of serially arranged segments or stages as shown in
sections with separate inlet and outlet. Each flow sector has Fig. 15. Each of these segments has its own serpentine con-
parallel flow channels, which are further sub-divided into figuration whose legs are relatively short; as a result, very
few sets of channels connected in series. This design gives little pressure drop exists between adjacent legs and between
combined advantages from pin, straight and serpentine the ends of the legs. Another noticeable point here is that
design. the end of the medial leg closest to the inlet leg of the one
segment (high pressure) is spaced farther from the bridging
3.3.1. Modified versions section than the end of the medial leg closest to the exit leg
Serpentine channels are designed to allow some limited of the same segment to reduce gas bypass into the bridging
gas movement between adjacent legs of the same chan- section from the one segment.
X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371 367

Fig. 17. Example of integrated flow-field design [31].

Fig. 16. Reactant gas flow field and cooling fluid flow field built
on the same plate surface [29,30].

3.4. Integrated flow field

Chow et al. [29,30] released a BPP design, which pos-


sesses both reactant gas flow field and cooling flow field on
the same plate surfaces, as shown in Fig. 16. The gas flow
field directly faces the electrochemically active area of the
adjacent MEA, while the cooling flow field surrounds the
gas flow field. This integrated reactant and coolant flow-field
plate design eliminates the need for a separate cooling layer
in a stack, thus significantly improves the stack power den-
sity [29,30]. In the same spirit, Ernst and Mittleman [31]
described a fluid flow-field plate assembly, which is divided
into a multiple of fluid flow sub-plates, as illustrated in Fig.
17. Each sub-plate is electrically insulated from all other
sub-plates of the same plate assembly, and has its own reac-
tant flow field adjacent to the electrochemically active area
of the nearby MEA. A cooling flow field may be positioned
in-between and around each of the gas flow sub-plates [31].
However, these designs cannot maintain a uniform temper-
ature distribution over the entire fuel cell surface.

3.5. Interdigitated flow field

For all the above designs of flow fields, the flow channels Fig. 18. Conventional flow-field design mechanism [32].
are fabricated on the flow distribution plates (or BPPs), or
to the lesser degree, on the porous electrode backing layers,
and they provide continuous flow passages, from the stack for electrochemical reaction and electric power generation,
inlet manifold to the exit manifold, while traversing through is predominantly by molecular diffusion through the elec-
the electrode surface of the active areas of the cell. In this trode backing layer. Not only molecular diffusion is a slow
configuration, as schematically shown in Fig. 18, the domi- process, easily leading to the occurrence of large concen-
nant reactant flow is in the direction parallel to the electrode tration gradients across the backing layer and mass transfer
surface, and the reactant flow to the catalyst layer, required limitation phenomenon for the cell operation, but it is also
368 X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371

Fig. 19. Interdigitated flow-field design [32].

difficult to remove liquid water which exists in the porous


region of the backing layer. This difficulty is compounded
by the fact that typical flow in the flow channels is laminar
due to the small gas velocity and the small flow channel
dimensions. Therefore, interdigitated flow fields have been
explored to provide convection velocity normal to the elec- Fig. 20. Improved mass transfer channels (Variable channel cross
trode surface for better mass transfer, and convection flow in section and/or Interdigitated concept) [35].
the porous backing layer for enhanced water removal capa-
bility [33]. An interdigitated flow field, as shown in Fig. 19,
consists of dead-ended flow channels built on the flow dis- tending the linear region of the cell potential versus current
tribution plates. The flow channels are not continuous from density plot. When a fuel cell accumulates too much water
the stack inlet manifold to the exit manifold, as the reactant at high current density, about one-third of the electrode sur-
flow is forced under pressure to go through the porous elec- face area is not utilized [34]. To overcome mass transport
trode backing layer to reach the flow channels connected to limitations in porous electrodes, the diffusive mass transfer
the stack exit manifold, thus developing the convection ve- mechanism is changed into a forced convective mass transfer
locity towards the catalyst layer and convection flow in the which causes limiting current density and maximum power
backing layer itself. Such flow-field design can remove wa- density to increase significantly. This design outperforms
ter effectively from the electrode structure, preventing water conventional flow-field design, especially on cathode side at
flooding phenomenon and providing enhanced performance high current densities.
at high current density operation. However, a large pressure
loss occurs for the reactant gas flow, especially the oxidant 3.5.1. Modified versions
air stream. The parasitic power required for air compression As gases flow in the channels, the reactants are trans-
may limit the application of this flow-field design to smaller ferred into the gas diffusion layer, and thus the concentra-
stack sizes. tion of reactant in the flow channels is reduced along the
The interdigitated flow field is attractive since the reactant flow direction. This reduction in concentration can result in
gases are forced to flow into the active layer of the elec- non-uniform reaction across the fuel cell active area. Gurau
trodes, where the forced convection (instead of diffusion) et al. [35] proposed a design for improved mass transfer us-
avoids flooding and gas diffusion limitations, thereby ex- ing interdigitated flow-field design concept (Fig. 20). In this
X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371 369

Fig. 23. Configurations for flow fields made by metal sheets [38] .

Fig. 21. Gas block mechanism for water removal in interdigitated


flow field [36].

Fig. 22. Biomimetic flow-field concept for bipolar plates [37].

layout the outlet channel volume is less than the inlet chan-
Fig. 24. Bipolar plate flow-field design from metal sheets [38,39].
nel volume, whereby the rate at which the fluids flow to the
outlet channel is increased causing improved fluid removal.
Different approaches have been mentioned to achieve such
a phenomenon, such as outlet channel depth can be less than reduced land width permits greater mass flow rates as the
that of the inlet channel or may vary the width, etc. The concentration of the reactants is decreased. This advantage
channel width may also be varied so that the land width re- can be coupled with improved water removal by decreasing
duce along the channel from the inlet to the dead end, e.g. the outlet channel volume as well as by reducing the depth
the inlet channel can increase in width towards its terminus of it relative to inlet channel or reducing the outlet channel
and outlet channel can increase in width away from its ter- length relative to the inlet channel.
minus. This will result in a closer positioning of the inlet and For improved water removal, Issacci and Rehg [36] con-
the outlet channel in the direction of flow of the fluids. This sidered the gas block mechanism for cathode and anode
370 X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371

Fig. 25. Stamped flow-field design on sheet metal [40].

sides in a fuel cell. In this design, they used one or more sistance to corrosion) to improve gas distribution on the cell
porous gas block media at points adjacent to the flow field, plane. Proposals have been made to fabricate BPPs from
as illustrated in Fig. 21, that have pore size such that water metals such as titanium, chromium, stainless steel, niobium,
is sipped off to the outside of the flow field by capillary flow etc. [38–41]. Figs. 23 and 24 illustrate possible configura-
and the cathode gas is blocked from flowing through the tions for the reactant and cooling flow fields. The plates com-
medium. On the other surface of the plate is channel in fluid prise corrosion-resistant thin metal sheets brazed together to
communication with each porous gas block medium [36]. provide a cooling flow field between the sheets and reactant
The patented ‘Biomimetic’ BPP technology developed by gas flow fields on the two outside surfaces of the sheets.
MFC (Morgan fuel cell) drew its inspiration from the natural Such a BPP design eliminates the need for a separate cool-
world [37]. It mimics the structure as seen in animal lungs ing plate, decreases material usage for stack construction
and plant tissues to allow the gases to flow through the plate and reduces the weight and volume of the stack.
in a far more efficient way than has never been achieved Rock [40] proposed a stamped BPP for PEM fuel cells
before. The Biomimetic plates also have the added advan- from a single metallic sheet. The plate has a serpentine
tage of being produced using MFC’s patented ElectroEtch flow field formed on one side and an interdigitated flow
system, which allows them to be manufactured at a fraction field formed on the opposite side such that a single plate
of the time and cost of conventional methods. Looking at member is usable as an anode and cathode side flow fields
how animal lungs and plant leaves ‘breathe’, a structure con- for adjacent fuel cells (Fig. 25).
sisting of large distribution channels feeding progressively
to smaller capillaries is the most efficient way to distribute
reactants, as shown in Fig. 22. This structure reduces the 4. Conclusions
pressure drop found in the industry-standard serpentine de-
sign of flow field and ensures a more even delivery of gas Bipolar plate is one of the key components in PEM fuel
across the BPP, so that more power can be extracted from cell stacks, and it performs a number of essential func-
the fuel cell. Initial results are very promising, with tests tions in stack operation, such as reactants supply to the cell
already confirming a 16% increase in peak power [37]. active area, current collection, mechanical support to the
MEA, water management, heat management and maintain-
3.6. Flow channels from metal sheets ing the reactants separate. In practice, PEM fuel cell stack
design often boils down to bipolar plate design, which in
Flow through porous carbon has also been proposed for turn is basically the design of flow channels formed on the
improved water management; a better method may be the two surfaces of the bipolar plates, because the requirements
use of flow through porous metallic meshes (with high re- on carrying out the bipolar plate functions optimally are
X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371 371

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