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Received 7 April 2004; received in revised form 11 August 2004; accepted 2 September 2004
Available online 23 November 2004
Abstract
The polymer electrolyte membrane (PEM) fuel cell is a promising candidate as zero-emission power source for transport
and stationary cogeneration applications due to its high efficiency, low-temperature operation, high power density, fast start-
up, and system robustness. Bipolar plate is a vital component of PEM fuel cells, which supplies fuel and oxidant to reactive
sites, removes reaction products, collects produced current and provides mechanical support for the cells in the stack. Bipolar
plates constitute more than 60% of the weight and 30% of the total cost in a fuel cell stack. For this reason, the weight,
volume and cost of the fuel cell stack can be reduced significantly by improving layout configuration of flow field and use of
lightweight materials. Different combinations of materials, flow-field layouts and fabrication techniques have been developed
for these plates to achieve aforementioned functions efficiently, with the aim of obtaining high performance and economic
advantages. The present paper presents a comprehensive review of the flow-field layouts developed by different companies
and research groups and the pros and cons associated with these designs.
䉷 2004 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
Keywords: PEM fuel cell; Bipolar plate; Flow field; Flow channels
1. Introduction
During the past two decades, the research and develop-
The polymer electrolyte membrane fuel cell (PEMFC) ment of the PEMFC with a Nafion䉸 membrane as elec-
is one of the most widely researched fuel cell technolo- trolyte have received much attention. Much research has
gies because it offers several advantages for transport and focussed on single cells of PEMFC or their components,
a number of other applications. Its low-temperature oper- such as novel membrane electrolytes, catalysts and structure,
ation, high power density, fast start-up, system robustness, electrochemical reaction mechanisms and kinetics, as well
and low emissions have ensured that the majority of motor as electrode materials and preparation. This has resulted in
manufacturers are actively pursuing PEMFC research and a number of alternatives to Nafion䉸 membrane technology
development. Already in Europe with demonstration buses with low load, high utilization catalyst yielding significantly
and passenger vehicles in California, for example, a first higher power density than was available few years back. Im-
market introduction of fuel cell vehicles will be seen in the provements in cell design and manufacturing have further
near future. However, there are still technical barriers to be increased power, while reducing manufacturing costs, which
overcome before fuel cell vehicles reach a significant mar- is essential if the fuel cell is to compete with the internal
ket penetration [1–3]. combustion engine.
For a given membrane/electrode assembly (MEA), the
power density of a fuel cell stack can be significantly in-
∗ Corresponding author. Tel.: +1 519 888 4567/X 6843; creased by reducing the profile of the bipolar plates. A key
fax: +1 519 888 6197. prerequisite for many power applications is the production
E-mail address: x6li@uwaterloo.ca (X. Li). of compact and lightweight PEMFC stacks, which may be
0360-3199/$30.00 䉷 2004 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
doi:10.1016/j.ijhydene.2004.09.019
360 X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371
2. Biopolar plates
2.1. Functions
BPPs being one of the most important components in Fig. 1. Mass distribution in a 33 kW PEMFC stacks [7].
PEMFC stacks must perform a number of functions well
simultaneously in order to achieve good stack performance
and lifetime. BPPs supply the reactant gases through the
flow channels to the electrodes and serve the purpose of
electronically connecting one cell to another in the elec- facilitate these functions. Topologies can include straight,
trochemical cell stack. These plates also provide structural serpentine, or interdigitated flow fields, internal manifold-
support for the thin and mechanically weak MEAs and ing, internal humidification, and integrated cooling. There-
means to facilitate water management within the cell. In fore, optimal design must be sought for the BPPs because
the absence of dedicated cooling plates, the BPPs also fa- the above functions have conflicting requirements on the
cilitate heat management. Plate topologies and materials BPP design.
X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371 361
2.2. Requirements
Inlet
Flow-
Channel
Outlet
Flow Channel
or circular pins protruding from the plates, and the reactant periods of operation, because of cathode gas flow distribu-
gases flow across the plates through the intervening grooves tion and cell water management. As the fuel cell operated
formed by the pins. The actual fluid flow thus goes through continuously, the water formed at the cathode accumulates
a network of series and parallel flow paths. As a result, pin- in the flow channels adjacent to the cathode, the channels
design flow fields result in low reactant pressure drop. How- become wet, and the water thus tends to cling to the bot-
ever, reactants flowing through such flow fields tend to fol- tom and the sides of the channels. The water droplets also
low the path of least resistance across the flow field, which tend to coalesce and form larger droplets. A force, which in-
may lead to channelling and the formation of stagnant areas, creases with the size and number of the droplets, is required
thus uneven reactant distribution, inadequate product water to move the droplets through the channel and out of the
removal and poor fuel cell performance. Further, relative cell. Since the number and size of the water droplets in the
stable recirculation zones may arise behind each pin since parallel channels are likely different, the reactant gas then
the reactant flow is very slow in such a small flow chan- flows preferentially through the least obstructed channels.
nels, and the Reynolds number for the reactant flow remains Water thus tends to collect in the channels in which little or
small, particularly for the fuel stream Reynolds numbers no gas is passing. Accordingly, stagnant areas tend to form
may range from a few tens to low hundreds. Reactant con- at various areas throughout the plate. Hence, the poor cell
centration may be depleted in the stable recirculation zones performance arises from the inadequate water drainage and
as well, decreasing the cell and stack performance. These poor gas flow distribution on the cathode side. This problem
issues may become particularly problematic with flow fields is similar to the one that occurs in the pin-type flow field, as
having certain geometric shapes. discussed earlier. Few more examples of straight or parallel
flow-field design are shown in Figs. 5–7.
3.2. Straight flow field Another problem associated with this design is that the
straight and parallel channels in the BPPs tend to be rel-
Pollegri and Spaziante [18] showed a straight flow-field atively short and have no directional changes. As a con-
design, which is further exemplified by General Electric and sequence, the reactant gas has a very small pressure drop
Hamilton Standard LANL No. 9-X53-D6272-1 (1980). In along these channels, and the pressure drop in the stack dis-
this design, the gas flow-field plate includes a number of tribution manifold and piping system, which is normal to
separate parallel flow channels connected to the gas inlet and the BPPs, tends to be large in comparison. This inadequate
exhaust headers, which are parallel to the edges of the plate. pressure loss distribution results in non-uniform flow distri-
An example is shown in Fig. 4 with the flow channel cross- bution of reactant gases among various active cells in the
sectional shape. When air is used as the oxidant, it is found stack, usually the first few cells near the manifold inlet have
that low and unstable cell voltages occur after extended more flow than those towards the end portion of the inlet
X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371 363
Fig. 16. Reactant gas flow field and cooling fluid flow field built
on the same plate surface [29,30].
For all the above designs of flow fields, the flow channels Fig. 18. Conventional flow-field design mechanism [32].
are fabricated on the flow distribution plates (or BPPs), or
to the lesser degree, on the porous electrode backing layers,
and they provide continuous flow passages, from the stack for electrochemical reaction and electric power generation,
inlet manifold to the exit manifold, while traversing through is predominantly by molecular diffusion through the elec-
the electrode surface of the active areas of the cell. In this trode backing layer. Not only molecular diffusion is a slow
configuration, as schematically shown in Fig. 18, the domi- process, easily leading to the occurrence of large concen-
nant reactant flow is in the direction parallel to the electrode tration gradients across the backing layer and mass transfer
surface, and the reactant flow to the catalyst layer, required limitation phenomenon for the cell operation, but it is also
368 X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371
Fig. 23. Configurations for flow fields made by metal sheets [38] .
layout the outlet channel volume is less than the inlet chan-
Fig. 24. Bipolar plate flow-field design from metal sheets [38,39].
nel volume, whereby the rate at which the fluids flow to the
outlet channel is increased causing improved fluid removal.
Different approaches have been mentioned to achieve such
a phenomenon, such as outlet channel depth can be less than reduced land width permits greater mass flow rates as the
that of the inlet channel or may vary the width, etc. The concentration of the reactants is decreased. This advantage
channel width may also be varied so that the land width re- can be coupled with improved water removal by decreasing
duce along the channel from the inlet to the dead end, e.g. the outlet channel volume as well as by reducing the depth
the inlet channel can increase in width towards its terminus of it relative to inlet channel or reducing the outlet channel
and outlet channel can increase in width away from its ter- length relative to the inlet channel.
minus. This will result in a closer positioning of the inlet and For improved water removal, Issacci and Rehg [36] con-
the outlet channel in the direction of flow of the fluids. This sidered the gas block mechanism for cathode and anode
370 X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371
sides in a fuel cell. In this design, they used one or more sistance to corrosion) to improve gas distribution on the cell
porous gas block media at points adjacent to the flow field, plane. Proposals have been made to fabricate BPPs from
as illustrated in Fig. 21, that have pore size such that water metals such as titanium, chromium, stainless steel, niobium,
is sipped off to the outside of the flow field by capillary flow etc. [38–41]. Figs. 23 and 24 illustrate possible configura-
and the cathode gas is blocked from flowing through the tions for the reactant and cooling flow fields. The plates com-
medium. On the other surface of the plate is channel in fluid prise corrosion-resistant thin metal sheets brazed together to
communication with each porous gas block medium [36]. provide a cooling flow field between the sheets and reactant
The patented ‘Biomimetic’ BPP technology developed by gas flow fields on the two outside surfaces of the sheets.
MFC (Morgan fuel cell) drew its inspiration from the natural Such a BPP design eliminates the need for a separate cool-
world [37]. It mimics the structure as seen in animal lungs ing plate, decreases material usage for stack construction
and plant tissues to allow the gases to flow through the plate and reduces the weight and volume of the stack.
in a far more efficient way than has never been achieved Rock [40] proposed a stamped BPP for PEM fuel cells
before. The Biomimetic plates also have the added advan- from a single metallic sheet. The plate has a serpentine
tage of being produced using MFC’s patented ElectroEtch flow field formed on one side and an interdigitated flow
system, which allows them to be manufactured at a fraction field formed on the opposite side such that a single plate
of the time and cost of conventional methods. Looking at member is usable as an anode and cathode side flow fields
how animal lungs and plant leaves ‘breathe’, a structure con- for adjacent fuel cells (Fig. 25).
sisting of large distribution channels feeding progressively
to smaller capillaries is the most efficient way to distribute
reactants, as shown in Fig. 22. This structure reduces the 4. Conclusions
pressure drop found in the industry-standard serpentine de-
sign of flow field and ensures a more even delivery of gas Bipolar plate is one of the key components in PEM fuel
across the BPP, so that more power can be extracted from cell stacks, and it performs a number of essential func-
the fuel cell. Initial results are very promising, with tests tions in stack operation, such as reactants supply to the cell
already confirming a 16% increase in peak power [37]. active area, current collection, mechanical support to the
MEA, water management, heat management and maintain-
3.6. Flow channels from metal sheets ing the reactants separate. In practice, PEM fuel cell stack
design often boils down to bipolar plate design, which in
Flow through porous carbon has also been proposed for turn is basically the design of flow channels formed on the
improved water management; a better method may be the two surfaces of the bipolar plates, because the requirements
use of flow through porous metallic meshes (with high re- on carrying out the bipolar plate functions optimally are
X. Li, I. Sabir / International Journal of Hydrogen Energy 30 (2005) 359 – 371 371
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