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ABSTRACT
Electron paramagnetic resonance spectroscopy (EPR) is a powerful tool for investigating
paramagnetic species, including organic radicals, inorganic radicals, and triplet states. The basic
principles behind EPR are very similar to the more ubiquitous nuclear magnetic resonance
spectroscopy (NMR), except that EPR focuses on the interaction of an external magnetic field with
the unpaired electron(s) in a molecule, rather than the nuclei of individual atoms. EPR has been used
to investigate kinetics, mechanisms, and structures of paramagnetic species and along with general
chemistry and physics, has applications in biochemistry, polymer science, and geosciences. The use
of cavity stabilised Impatt diode oscillators for ESR spectroscopy is discussed in different
experimental conditions: i.e. as microwave sources in reflection cavity homodyne spectrometers, and
as marginal oscillators in which the oscillator cavity (a TE011 cylindrical cavity) is the observing cavity.
The sensitivity of this second configuration has been theoretically evaluated for the case in which the
Impatt itself is used as a detecting element and in which an external detector is used. For each
situation the sensitivity has been measured with a DPPH sample at various power levels giving a
sensitivity which is comparable with the best commercial units.
Introduction
Also known as….
Electron Paramagnetic Resonance(EPR)
Electron Magnetic Resonance(EMR)
What Is ESR???
· It is a branch of absorption spectroscopy in which radiation having frequency in microwave
region is absorbed by paramagnetic substance to induce transition between magnetic energy level of
electron with unpaired spin. TOP
· Magnetic energy splitting is done by applying a static magnetic field.
(3) ATTENUATORS
The power propagated down the wave guide may be continuously decreased by inserting a piece of
resistive material into the wave guide. The piece is called variable attenuator and used in varying the
power of the sample from the full power of klystron to one attenuated by a force 100 or more.
Rotable cavities and dual cavities have also been used respectively for study in anisotropic effect in
single crystal land simultaneous spectroscopic observation of a sample and standard.
EPR spectra are usually displayed in derivative form to improve the signal-to-noise ratio.
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