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I Trinidad and Tobago
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.i TESTCODE22112010
FORM TP2008166 ~~'t'.;f ~..;;i::i:;;;.,;.,...
MAY/JUNE2008
CARIBBEAN EXAMINATIONS COUNCIL
ADVANCEDPROFICIENCYEXAMINATION
CHEMISTRY-UNIT 1
PaperOl
90minutes
( 04JULY2008(a.m.) )
5. Onyouranswcrsheet,fmdthenumbcrwhichcorrespondstOyouritemandshadethespacehavingthe
samb lettcr as the answer you have chosen. Look at the sample item below.
Sarnple Item
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WhjchofthefollowingistheHIGHESTenergytransitioninanorganiccompound?
-
(A)' ntocr• SarnpleAnswer
(B) • nto7t•
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(C) I cr to cr• @@•@
(D): 7t to 1t*
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Tuel best answer to this item is "cr to cr•", so answer space (C) has been shaded.
6. • Ifyqu wantto change your answer, erase it completely and fill in your new choice.
7. Whenyouaretoldtobegin,turnthepageandworkasquicklyandascarefullyasyoucan. Ifyoucannot
!IDSWcranitem,omititandgoontothenextone. Yourscorewillbethetotalnumberofcorrectanswers.
8. Yo'tmaydoanyroughworkinthisbooklet.
9. Fi~es are not necessarily drawn to scale.
ASJA GIRLS COLLEGE
10. The~ofnon-programmablecalculators is allowed.
..
LIBRARY
Ir I DO NOT TURN T!IJS PAGE .UNTJL YOU All TOLD TO DO so.
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WJiich of th~ following postulates concerning S. Which of.the following pairs of elements
Dalton's A~omic Theory is known to be would be expected to form the compound
correct by modem theory? with the MOST ionic character?
~
7. The bond angles in the PH, molecule are the
3. When an i$otope, X, is bombarded with a same as that of NCI,. Its shape would
therefore be
i
neutron the jisotope Li and an alpha particle
are produc~. The equation is as follows: (A) linear
(B) octahedral
(C) pyramidal
(D) tetrahedral
Isotope X is MOST likely
: !
~·~··:db>&
(B)
:~
effec:tive by
nuclar c;harge
""'.relectrons
Ilion betWeen the paired 2p
; . ..
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9. Sodi~m azide, NaN, is used in air bags for 12. Which ofthe following diagrams correctly
cars.I On heating, it decomposes into sodium represents the behaviour of a fixed mass of
and rlitrogen. an ideal gas at a constant temperature?
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;
. What volume of nitrogen, at room
II temitrature, would be produced by heating PV
' one qiole of sodium azide? {A)
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{A) 24dm 3
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(B) 36dm'
I {C)
{D)
48dm'
. 72dm3 p
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PV
{B)
The~implest formula for a compound that
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. 10. '
I con ins 50 % S and 50 % 0 by mass is
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II i
{A) I s,o.
II
(B) s,o v
{C) so, p
{C)
{D) so
,.
-4-
Which of the following is NOT an 15. What is the standard heat of reaction
endothennib process? (~H _.,.,)at 101.325 kPa of pressure and
298 K, for the equation given below?
(A) Iceimelting
(B) Water boiling Zn (s) +Cu"' (aq) ~ Zn2+ (aq) +Cu (s)
(C) wa:ter .
' evaporating
(D) W~tervapourcondensing ~H·.....,,..,., =+64.4kJmol·' for Cui+
~·.....,,..,., = -152.4 kJ moJ- for Zn2•
1
F
Rate k[CH,COCH, (aq)] [H•(aq)], which of the following BEST illustrates the slow
step?,
' 0 OH
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(A) CH3 - C - CH3 + tt• ~CH3 - C - CH3
Ell
0 I
II I
(B) i CH,-c-cH, + 12 ~CH,-c -CH,+1-
, Ell
0 I
II I
(C) CH3- C -CH3 + 1- ~ CH 3 - C- CH ]
Ell
0 OH
11 I
(D) CH,- C- CH, + '2 +ff+~ CH,- f-CH,
. I
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17. The tertiary halogenoalkane, 2-chloro-2- 18. Which ofthe followj.ng statements about a
methylpropane undergoes hydrolysis with an catalyst is or are true?
alkali as shown below.
I. It increases the equilibrium constant
1
CH3 CH3 forthe forward reaction only.
! I I
Slow II. It increases the equilibrium constant
CH3-k;-CI CH3 - c Ell +er
I for both the forward and backward
'I
.CH3 CH3 reactions.
III. It has no effect on the position of
fH3 TH3 equilibrium.
. CH3-(/;Ell+OH- Fast > CH3-C-OH
. ! I (A) !only
CH3 . CH3 (B) Ill only
(C) I and III only
The Jnergy profile diagram for the reaction is (p) JI and III only
'
Energy
19. Which ofthe following statements does NOT
(A)
refer to a system in dynamic equilibrium?
I (C)
(D)
The concentrations of all reactants
and products are equal.
The rate of the forward reaction is
Energy
equal to the rate of the backward
reaction.
Energy
[caCCJi(s)]
(D) (C)
co> ·
·· [cao <s>l[fof1
[CllCo3 <•>
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0
21. : W/tich oftile following statements are correct 23. Which of the following statements are true
based on tile equation below? for the titration between a strong acid and a
strong base?
, 2S02 (g)+p 2 (g)~2SO,(g)
M,i' = -98 kµI mot·' I. There is no significant change in pH
' at the beginning ofthe titration.
L II. There is a large change in pH close
In4reasingthetemperaturedecreases
to the neutralisation point
~e rate of the forward reaction.
In9reasing the pressure increases the
III. The neutralisation point and the
~uilibriwn yield ofSO,(g).
equivalence point are the same.
lit Th~ maximum mass of sulphur
*"ioxide that can be made from
(A) I and II only
(B) I and III only
~4 g ofS02 is 80 g.
(C) II IU)d III only
(A) I mild II only (D) I, II and Ill
(B) I 8*d III only
(C) II ilnd III only
Item 24 refers to the figure below which
(D) II
I, and III
shows the pH change as propanoic acid is
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4
(A) 5
2
(B) 6
(C) 7
(D) 8 3
Volwne of sodium hydroxide added (cm )
Indicator pH range
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Th~ pH of an acid buffer can be calculated 27. Silver chromate(VI), Ag,CrO4 , is sparingly
usirg the Henderson - Hasselbalch equation. soluble in water. The units for the solubility
product (K.,,) for silver chromate(VI) are
i [salt]
p~ = pK, +log (acid] (A) moldm·'
(B) mol'dm..
(C) mol'dm·•
W~ich ofthe following are assumptions made (D) mol4 dm· 12
w~en using the equation?
I.[ The acid remains undissociated. Item 28 refers to the electrochemical cell
II; · All the H• ions come from the acid. below.
mi pK, is constant at a given
temperature. Zn(s) I Zn,. (aq) II Ag•(aq) /Ag(s)
2~.
I
~ fullowing equation is often used to explain (C) Ag'(aq)/Ag( s) II Zn(s) /Zn,.(aq)
wtly hydrogen carbonate ions.can act as a
bu!fer. (D) Zn( s) /Zn2+(aq) II Ag• (aq) IAg( s)
H¢. 0
1 )
-+ H 20 _..i.
~
H
3
o• + CO) 2-
Item 29 refers to the Daniell cell illustrated
W~ich ofthe following explain the buffering below.
a~ion of hydrogen carbonate? (',
I Imulated wire
I; Carbonate ions can combine with
,
hydroxonium ions to increase pH.
· ' - - Colourless ZnS04 (aq)
n; Hydrogen carbonate ions can
combine with water to form Zn electrode
111:
hydroxonium ions and carbonate
ions.
Hydroxonium ions combine with
Porous
medium
- ~
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-- Blue CuS04 (aq)
Cu electrode
hydrogen carbonate ions to form
carbon dioxide end water.
29. Which of the following statements is NOT
) (A) land II only true about what happens in the cell after it
\ (B)
(Q
I and III only
II and III only
·has been running for some time?
(A)! I j II only
(B)I I an III only
0
(C)I II i d III only Na Mg Al Si p s
(D), I, III and Ill
Melting
pointl"C
(B)
. Melting
(C) point/°C
0-+~~r-~~~~~~~
NaMgAI Si P S Cl Ar
Melting
point/°C
(D)
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32; Wtiich of the following BEST describes the 36. The. high melting point of graphite can be
reaction ofaluminium with oxygen? attributed to the
Acidic Amphoteric Basic 37. As one descends Group IV, the stability of
(A), MgO
the+2 oxidation state
so, cao
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(B)i co, Al,0 3 CuO (A) increases
(C)i so, co Na,O (B) decreases
(D) so, P,0 10 so, (C) remains the same
(D) steadily decreases then increases
Iterµs 40-41 refer to the following options. 43. The Cr20,Z-(aq) I Cr'•(aq) system is often
used to illustrate redox systems because
(A) Li..mvt
(B)! ~lex (A) Cr20,'-ion isadifferentcolourfrom
(C)' Cau)Jyst the Cr'+ ion
(D) Coop:lination number (B) Cr, O,'- and Cr'• are abundant in
nature
Maitch eac~ item below with one of the (C) Cr20,Z.. ion is more stable than the
options abo~e, each of which may be used Cr'+ ion
on¢e, more than once or not at all. (D) Cr,07"" is a good reducing agent
!
42. Th~ first i~nisation energy of tt:ansition 45. An excess of aqueous silver nitrate is added
elqnents inbreases gently from scapdium to to aqueous barium chloride and the precipitate
copper witll a sharp increase from copper to is removed by filtration. The main ions in the
zinc. The s'1arl> increase is caused by filtrate are
rfY9UFINI$HBEFORETIMEISCALLED,CHECKYOURWORKONTIIlSTEST.
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