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CLASS TEST 10 THERMODYNAMICS CHEMISTRY (FOUNDATION)

Dear student following is an Moderate level [ ] test paper. Score of 15 Marks in 15 Minutes
would be a satisfactory performance. Questions 1-10 (+3, –1). (More than Single Options may be correct)

PASSAGE -Q. 1 to 3 Q.3 Which of the following having highest


Some organic compound contanins double heat of hydrogenation?
bonds. The simplest example is ethene, C2H4 (A) But – 1- ene (B) cis-But-2-ene
.Such Compounds are said to be unsaturated, (C) Trans-But-2-ene (D) Ethene
they contain less than the maximum amount
of hydrogen. Ethene for example can be Q.4 Two atoms of hydrogen comibne to form
converted into ethane C2H6. The reaction of a molecule of hydrogen gas, the energy
adding hydrogen to a double bond is known of the H2 molecule is
as hydrogenation. The heat change in a (A) Greater than that of the separate atoms
hydrogenation reaction is the enthalpy of (B) Equal to that of separate atoms
hydrogenation. (C) Lower than that of separate atoms
(D) Sometimes lower and sometimes higher

Q.5 A mixture of hydrogen and chlorine on


exposure to ultra violet sunlight reacts
with explosion. The step involved in the
initiation of the reaction is.
(A) H2 → H• + H• (B) Cl• + Cl• → Cl2
(C) H2 + Cl2 → 2HCl
(D) Cl2 → Cl• + Cl•

Q.6 When water is added to quick lime, the


reaction is :
(A) Explosive (B) Endothermic
(C) Exothermic (D) None of these

Q.7 Heat of fusion of a molecular solid is


Q.1 If enthalpy of hydrogenation of benzene (A) Very high (B) High
is ∆ H 1 . The resonance energy of (C) Low (D) None of these
benzene is
Q.8 The heats of neutralisation of four acids
(A) 3 ∆ H1 – ∆ H2 (B) 3 ∆ H2 – ∆ H1 A, B, C, D are – 13.7, – 9.4, – 11.2 and
(C) 3 ∆ H1 + ∆ H2 (D) 3 ∆ H1 + 2 ∆ H2 – 12.4 kcal respectively when they are
neutralised by a common base. The
Q.2 Calculate the enthalpy of the following acidic character obeys the order
reaction. (A) A > B > C > D (B) A > D > C > B
CH2 = CH2(g) + H2(g) CH3— CH3(g) (C) D > C > B > A (D) D > B > C > A
The bond energies of C—H, C—C, C = C
and H—H are 414, 347, 615 and 435 kJ Q.9 In a chemical reaction if all reactants
mol–1 respectively. and products are in liquid state then :
(A) –125 kJ mol–1 (B) 125 kJ mol–1 (A) ∆ H > ∆ U (B) ∆ H < ∆ U
(C) – 733 kJ mol–1 (D) + 733 KJ mol–1 (C) ∆ H = ∆ U (D) None of these

 
CHEMISTRY FOUNDATION (CLASS TEST 10) (THERMODYNAMICS) A N S W E R K E Y
Name : .......................................................................................... Roll No. : ..................................

A B C D A B C D A B C D
1. 4. 7.
2. 5. 8.
3. 6. 9.

E D U C A T I O N S
, 608-A, TALWANDI KOTA (RAJ.) Ph. 0744 - 6450883, 2405510 PAGE # 1
CLASS TEST 10 THERMODYNAMICS CHEMISTRY (FOUNDATION)

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9
Ans. A A D C D A C B C

SOLUTIONS
Sol.6 (A)
Sol.1 (A)
CaO + H2O → Ca(OH)2 ; ∆ H = – ve; the
3 ∆ H1 – ∆ H2
soluition of lime heats up.

Sol.2 (A)
Sol.7 (C)
– 125 Kj mol–1
Molecular solids are covalent compounds
having low m.p.
Sol.3 (D)
Ethene Sol.8 (B)
Lower is heat of neutralisation, more is
Sol.4 (C) dissociation energy, weaker is acid.

Bond formation is always exothermic.


Sol.9 (C)

Sol.5 (D) ∆ n = 0 for such reactions


it is Cl2 Molecule which dissociates to give Since, ∆ H = ∆ U + ∆ nRT
free radicals on exposure to light.
Therefore ∆ H = ∆ U

E D U C A T I O N S
, 608-A, TALWANDI KOTA (RAJ.) Ph. 0744 - 6450883, 2405510 PAGE # 2

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