PERSAMAAN YANG DIGUNAKAN DALAM MEYELESAIKAN PROBLEM 8.

32 POLLING

 a ij 
1.  ij  exp   
 T 

 a 
2.  ji  exp   ji 
 T 
3. ri
J 

i
rjx j
j

4. qi
Li 
 j
q jx j

5. xiqi
 
 x jq
i
j
j

6.
si   
l
j li

7. UNIQUAC

 Ji Ji 
ln  i  1  J i  ln J i  5qi  
C
1   ln 
 Li Li 
8.
  ij 
ln  i  q i  1  ln s i   
R
 j
sj 
 j 
9.
ln  i  ln  i  ln  i
C R

10. E R
zi  x i
  x i
(1   )

11.
( i x i ) E  ( i xi ) R

12.

E R

Ki  x i
 i


R E
x i i

13. 3
( Ki  1) zi
F ( x R , x E , )   0
i 1 ( Ki  1)  1

14. E
 
F
Soal 14.20 Pure liquid species 2 and 3 are for practical purpose immiscible in one another. Liquid species 1 is solubl

Trial x1a 0.285714 αphase containing species 1 and 2

x1b
0.4 bphase containing species 1 and 3

Results species initial mol

0.3503995 = 0.461954 1 2
2 5
Optimazion 3 3
0.4347454 = 0.434745

Results
x1a 0.371138 Consraint
x1b 0.290693

 
x1 exp 0,4 1 x1  2
  x exp0,81 x  

1
 2
1
her. Liquid species 1 is soluble in both liquid 2 and 3.

Equation
Energi gibbs excess for each phase

G  E 
 0,4x1 x2
RT

G  E 
 0,8x1 x2
RT

 1 x1 x1 x1

ln  ln  1
 1 x1 1 x1 1 x1


8 1 x1  2
