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The Oyut Ulaan Volcanic Group: Stratigraphy, magmatic evolution and timing
of Carboniferous arc development in SE Mongolia

Article  in  Journal of the Geological Society · April 2010


DOI: 10.1144/0016-76492009-094

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Journal of the Geological Society, London, Vol. 167, 2010, pp. 491–509. doi: 10.1144/0016-76492009-094.

The Oyut Ulaan Volcanic Group: stratigraphy, magmatic evolution and timing of
Carboniferous arc development in SE Mongolia

JA M E S H . S . B L I G H T 1 * , M I C H A E L G . P E T T E R S O N 2 , Q U E N T I N G . C ROW L E Y 3,4
& DICKSON CUNNINGHAM 1
1
Department of Geology, University of Leicester, Leicester LE1 7RH, UK
2
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK
3
NERC Isotope Geosciences Laboratory, Keyworth, Nottingham NG12 5GG, UK
4
Department of Geology, School of Natural Sciences, Trinity College Dublin, Dublin, Ireland
*Corresponding author (e-mail: jamesblight@gmail.com)

Abstract: The Palaeozoic–Mesozoic tectonic evolution of Central Asia, including the vast terrane collage that
makes up Mongolia, has been a topic of considerable debate. The Oyut Ulaan Volcanic Group is a sequence
of volcanic and sedimentary rocks in SE Mongolia that forms the southern part of the Devonian–Permian
Saykhandulaan Inlier. Fieldwork traverses and mapping have established four distinct formations in the Oyut
Ulaan Volcanic Group that record the nature of arc activity in part of the Central Asian Orogenic Belt during
the Carboniferous. Physical volcanological and sedimentological characteristics of the four formations suggest
three clear eruptive styles: (1) periodic andesite volcanism in an actively eroding arc setting that also
contained large rivers and swamps; (2) highly effusive plateau andesite volcanism; (3) explosive rhyolitic
effusion. Geochemical analyses of volcanic lithologies suggest that the group represents subduction-related,
mature, continental arc volcanism. Geochemical results document an evolving magma system to which surface
processes of the volcano-sedimentary model may be linked. Magma pulses and replenishments are identified
from variations in chemostratigraphy. Newly obtained zircon ages from the volcanic succession fix its
emplacement (eruption) at 323.0  0.7 Ma (mid-Carboniferous or late Mississippian). A granite cobble from
the lower part of the Oyut Ulaan Volcanic Group gives a U–Pb zircon age of 338.9  0.4 Ma indicating that
arc plutons were emplaced 10 Ma prior to the Oyut Ulaan volcanism and were eroded soon after. Our work
provides timing constraints for final accretion and continental assembly in SE Mongolia, and also sheds light
on the petrological development of a magmatic arc system within an evolving accretionary orogen.

The Gobi region of southeastern Mongolia lies within the Central (Blight et al. 2008). We present detailed field observations,
Asian Orogenic Belt (Fig. 1), Earth’s largest area of Phanerozoic geochemical data and U–Pb zircon age constraints that form the
continental growth, and is a natural laboratory for documenting basis for interpreting the group’s eruptive history and the
processes of volcanic arc growth, terrane accretion and crustal volcanological processes that occur during the evolution of a
amalgamation. There is considerable debate regarding the major arc terrane.
Palaeozoic–Mesozoic tectonic evolution of this region. Important
mineral deposits have been discovered in the SE Gobi region of
Mongolia during the last decade and consequently, the region is
Regional geology
now a major mineral exploration province (Seltmann & Porter The Central Asian Orogenic Belt records terrane accretion and
2005). Nevertheless, few studies exist documenting the Palaeo- crustal growth between the Angaran Craton (also known as the
zoic evolution and lithotectonic context of the SE Gobi mineral Siberian Craton) and the North China and Tarim Cratons from
belt. This is partly because the area is remote, has low relief, and the Neoproterozoic to the Permian (Fig. 1). The Central Asian
in general displays poor exposure. However, the Saykhandulaan Orogenic Belt extends from Kazakhstan to Eastern Siberia and
Inlier (Figs 1 and 2), which crops out 400 km to the south of averages around 300 km wide (Xiao et al. 2003, 2004). Terranes
Ulaan Baatar, is unusual because it contains a large area of in southern Mongolia lie within the Central Asian Orogenic Belt
basement exposure and provides a good opportunity for unravel- to the north of the Solonker suture, which marks the final closure
ling the major Palaeozoic tectonic, metamorphic and intrusive of the Palaeo-Asian Ocean in the Permian (Xiao 2003; Fig. 1).
events that have affected the South Gobi Mineral Belt. In The basement geology of south Mongolia consists of island-arc,
addition, it hosts the Oyut Ulaan Cu–Au porphyry prospect and back-arc–forearc basin and accretionary prism terranes that
is along strike of other major intrusion-hosted exploration targets accreted around a postulated Precambrian cratonic block that
in the region. Therefore, a detailed multidisciplinary study underlies the Hangay Dome in central Mongolia (Fig. 1; Şengör
incorporating field investigations and structural and geochemical & Natal’in 1996; Badarch et al. 2002). These terranes are
analyses was carried out during 2004–2006 to document the intruded by voluminous alkali granitoids, which have been
crustal evolution of the Saykhandulaan Inlier and the terrane interpreted to have been caused either by slab break-off (Wu et
context of SE Gobi mineralization. al. 2000, 2002; Zhu et al. 2001) or a Mongolian mantle hotspot
This paper focuses on a succession of volcanic rocks within (Kovalenko et al. 2004, 2006). Although primarily Palaeozoic in
the Saykhandulaan Inlier named the Oyut Ulaan Volcanic Group age, the region also contains Proterozoic crust: the south

491
492 J. H . S . B L I G H T E T A L .

Fig. 1. Tectonostratigraphic terrane map of SE Mongolia, after Badarch et al. (2002). Location and offset sense of Zuunbayan Fault after Lamb et al.
(1999). Location of Solonker Suture after Xaio et al. (2003). Location of terrane boundaries in China is not shown because of uncertain terrane
correlations across border. Inset maps show regional political boundaries (top) and locations of Precambrian cratons and terrane collage forming the
Central Asian Orogenic Belt (CAOB) after Şengör & Natal’in (1996) and Helo et al. (2006) (bottom).

Mongolian microcontinent and the Baga Bogd massif (Wang et


al. 2001; Demoux et al. 2007). These terranes record the tectonic
evolution of the northern margin of the Palaeo-Asian Ocean
during the Palaeozoic, generally interpreted to have taken place
above a northward-dipping subduction zone (Windley et al.
2007).
Two hypotheses exist for the formation of the Mongolian
Central Asian Orogenic Belt crust during the Palaeozoic. A
majority of workers have suggested the existence of multiple
island arcs drifting across the Palaeo-Asian Ocean and accreting
various arc-marginal basin terranes and ophiolite slivers before
terminal collision against the southern margin of Siberia–Hangay
(Ruzhentsev & Pospelov 1992; Zorin et al. 1993; Badarch et al.
2002). In an alternative model, Şengör et al. (1993) and Şengör
& Natal’in (1996) postulated one long-lived island arc, with a
complex history of magmatic front migration, strike-slip motion
and oroclinal bending along its length prior to terminal accre-
tion.
The construction of a palinspastic model for southern Mon-
golia has been complicated by a lack of detailed field data. Lamb
& Badarch (1997, 2001) addressed this by documenting Palaeo-
zoic stratigraphic successions and their geochemical character-
istics from a range of localities throughout southern Mongolia.
They proposed that an island arc existed between Edren in the
west and Tsagaan Suvarga in the east during the Devonian (Fig.
Fig. 2. Palaeogeographical interpretations of south Mongolia redrawn 2a). In the Carboniferous, arc activity was split into two separate
from Lamb & Badarch (2001): (a) Devonian; (b) Carboniferous. Location fronts, both built on the existing Devonian arc crust (Fig. 2b).
of Gurvansayhan and Edren localities from Lamb & Badarch (2001) is The mechanism that produced this duplication of arc fronts in
shown. The Saykhandulaan Inlier is the field area for this study. Question the Carboniferous was not discussed, although several other
marks indicate extrapolation of the broad palaeogeographical model of palinspastic models for the region show dextral strike-slip
Lamb & Badarch to the east, beyond the areas covered in their study. duplication of arc sections during the Devonian and Carbonifer-
T H E OY U T U L A A N VO L C A N I C G RO U P 493

ous (Şengör & Natal’in 1996; Badarch et al. 2002). All arcs in The contiguous succession is around 4.6 km thick and is
both the multiple-arc and single-arc models are interpreted to composed of a variety of extrusive lithologies from basalt to
have developed above northward-dipping subduction zones rhyolite lavas and volcaniclastic sediments locally interbedded
(Şengör & Natal’in 1996; Lamb & Badarch 1997, 2001; Badarch with a wide range of siliciclastic sediments. The total strati-
et al. 2002; Windley et al. 2007; Xiao et al. 2009). However, graphic thickness of 4.6 km is a minimum value, as neither the
Rippington et al. (2008) proposed a south-dipping Carboniferous base nor the top of the group is constrained, the outcrop being
subduction zone in the south central Gobi region, based on the surrounded by inferred faults and overstepped by poorly lithified
juxtaposition of different lithotectonic belts and the geometry of Mesozoic sediments on all sides.
contractional structures. The Oyut Ulaan Volcanic Group is tightly folded with hinges
Lamb & Badarch’s (1997, 2001) tectonic model benefits both parallel to the regional east–west structural grain. The main
from being based on original field observations and from being western outcrops occur within the north-dipping limb and hinge
focused on a relatively small area, compared with some of the zone of a major syncline. Folds are upright, have an inter-limb
grand syntheses available elsewhere. Work by Rippington et al. angle of c. 708, and plunge on average 308 to the west. Cleavage
(2008) and Blight et al. (2008) followed a similar field-based, is rare and the rocks are relatively unmetamorphosed.
focused approach. The Oyut Ulaan Volcanic Group has not previously been
Geochemical and Nd isotope data from the Gurvansayhan described in the literature. The geological map of Mongolia
Range suggest that a juvenile oceanic arc was active in the (Tomurtogoo et al. 2000) shows the area as an undifferentiated
region in the late Silurian to early Devonian (Helo et al. 2006). block of Carboniferous volcanic rocks. The geographically
These data, considered together with the work of Lamb & closest relevant work is that of Lamb & Badarch (1997, 2001),
Badarch (2001), support the existence of an incipient, juvenile who described rocks 150 km to the west of the Saykhandulaan
island arc, which originated in the Silurian and became more Inlier. Lamb & Cox (1998) noted Carboniferous sedimentary and
evolved and alkaline during the Devonian, before the effects of volcanic strata overlying the Devonian Tsagaan Suvarga por-
back-arc rifting spread south into the area in the Carboniferous. phyry copper–molybdenum deposit, which is situated 150 km to
There is a general paucity of geochronological data from the the SW of the Saykhandulaan Inlier (Fig. 1).
region, although some ore bodies have been dated, including
Tsagaan Suvarga (364.9  3.5 Ma; Ar/Ar date for sericitic
Field data
alteration; Lamb & Cox 1998; 370.4  0.8 Ma; Re/Os on
molybdenite; Watanabe & Stein 2000) and Oyu Tolgoi (411  Fieldwork was conducted to establish a detailed stratigraphy for
3 Ma; K/Ar on K-silicate alteration halo; Perello et al. 2001). the Oyut Ulaan Volcanic Group. Field data and rock samples for
More recently Yarmolyuk et al. (2008) have defined a ‘Carboni- petrological and geochemical analysis were collected along a
ferous–Permian marginal continental magmatic belt’ featuring a series of lithological and structural traverses directed across the
suite of differentiated calc-alkaline material with an age range of structural grain of the area (Fig. 3c). The key results are
350–330 Ma and a later suite with a bimodal affinity and an age presented below, first progressing upwards through the contig-
range of 320–290 Ma. uous succession from east to west, then describing the separate
Whereas other parts of the Gobi Altai have been a focus for exposure area in the east (Fig. 3).
detailed work on Palaeozoic–Cenozoic crustal evolution in the
last decade (Zorin et al. 1993; Lamb & Badarch 1997; Cunning-
ham 1998, 2005; Lamb et al. 1999; Zorin 1999; Buchan et al.
Gurvan Morin Höndiy Formation
2001; Cunningham et al. 2001; Lamb & Badarch 2001; Perello The c. 1500 m thick Gurvan Morin Höndiy (Three Horse Valley)
et al. 2001; Wang et al. 2001; Helo et al. 2006; Demoux et al. Formation crops out in the east of the contiguous succession, and
2007; Xiao et al. 2009), the easterly reaches of the Mongolian is the stratigraphically lowest part of this sucession. The forma-
Gobi are much less studied. The field area for this study was tion was principally observed in a dry river valley (line of
selected, therefore, to partly address this imbalance and to transect shown in Fig. 3) that cuts across the dominant east–
document the volcanic-arc setting of the South Gobi Mineral west-trending structural grain (Fig. 3). It is composed of 10–
Belt and test existing terrane models for south Mongolia. 150 m thick intermediate lavas and coarse conglomerates inter-
The Saykhandulaan Inlier is situated around 150 km to the NE bedded with .15 m thick feldspathic sandstone sequences (Fig.
of Tsagaan Suvarga (Fig. 1) and is composed of a series of east– 4). The lavas and conglomerates are cliff-forming units separated
west-trending lithotectonic domains (Blight et al. 2008). The by zones of little to no outcrop. Lavas and conglomerates are
inlier records the Devonian–Carboniferous history of the bound- mainly within the southern limb of a first-order syncline and dip
ary between island arc dominated lithologies in the south and steeply to the north. Farther north, the upper parts of the
rocks formed from craton-derived basin sediments in the north. succession are deformed into a number of second-order folds
The southernmost domain is a folded succession of Carbonifer- indicative of their proximity to the first-order hinge. In the south,
ous volcanic and sedimentary rocks named the Oyut Ulaan the formation is fault bound; its base is not exposed.
Volcanic Group (Blight et al. 2008), which is the subject of this The formation is subdivided into three units, designated A, B
paper. and C (Fig. 4). Unit A, at the base of the formation, is 500 m
thick and is composed of basic to intermediate lavas. These lavas
occur in five ‘stacks’ in which single flow units are indistinguish-
Oyut Ulaan Volcanic Group
able; three of these stacks are 70–90 m thick and form major
The Oyut Ulaan Volcanic Group crops out along the southern topographic ridges composed primarily of feldspar-phyric ande-
margin of the Saykhandulaan Inlier in a 45 km long east–west- site.
trending belt (Fig. 3). The main outcrops are in the west of this Unit B, which conformably overlies Unit A, contains similar
belt in a 25 km east–west range of hills. The eastern outcrops extrusive lithologies along with thick successions of conglomer-
form the country rocks to the Oyut Ulaan Intrusion and are ates and some sandstones. The base of Unit B is defined by
separated from the western outcrops by an area of no exposure. exposures of sedimentary rocks that do not occur lower in the
494 J. H . S . B L I G H T E T A L .

Fig. 3. Maps of Oyut Ulaan Volcanic Group outcrop areas, showing the vertically contiguous Gurvan Morin Höndiy, Shargyn Moghai and Tsagaan Nuruu
Formations in the west and the Yasun Eliy-e Formation in the east, in contact with the Oyut Ulaan intrusion. (a) Map of SE Mongolia showing locations
of Palaeozoic inliers after Tomurtogoo et al. (2000); location of Saykhandulaan inlier marked by box. (b) Satellite image interpretation of the
Saykhandulaan Inlier showing location of (c). In (c), dotted lines indicate locations of transects or stratigraphic sections in study areas from various
formations: 1, Gurvan Morin Höndiy Formation; 2, 3, 4, Shargyn Moghai Formation; 5, Tsagaan Nuruu Formation; 6, Yasun Eliy-e Formation. Points
sm1–9 indicate locations of Shargyn Moghai Formation samples not marked on stratigraphy in Figure 4.

formation (Fig. 5a). This sequence includes conglomerates, 10 to 100 cm. Compared with Units A and B, Unit C is
siltstones and several 1–3 m thick lavas, separated from each better exposed as a result of its location in the core of the
other by thin sediment screens. In contrast to the extrusive regional syncline.
lithologies from Unit A, the lavas in this sequence are dark grey At the outcrop scale, tectonic structures are rarely seen in the
and aphyric, or contain only sparse (,1 mm diameter) horn- Gurvan Morin Höndiy Formation, with the exception of the
blende phenocrysts. The conglomerates are poorly sorted and upper parts of Unit C, where the relatively thinly bedded
predominantly composed of well-rounded, pebble-to-boulder sediments contain many small-scale folds; these minor folds
andesitic clasts, supported by a coarse immature volcanic– verge to the north and plunge to the west at c. 308. The formation
sandstone matrix. Sandstone and siltstone horizons define the is most altered at its northern and southern margins and at the
upper parts of unit B, in which a number of sedimentary margins of thick lava sequences, where carbonate veins have
structures occur including graded sandstones with cross-strati- epidotized haloes.
fied bases and bioturbation and siltstones with lycopsid bark
impressions (Fig. 5c–e; H. Falcon-Lang, pers. comm.). One
segment of lycopsid trunk occurs in apparent life position (Fig.
Shargyn Moghai Formation
5d), whereas others are parallel to bedding (Fig. 5e). Thin 1– The c. 2000 m thick Shargyn Moghai (Yellow Snake) Formation
3 cm thick seams of coal with Fe-oxide haloes occur in these is situated stratigraphically and conformably above the Gurvan
units. Morin Höndiy Formation (Figs 3 and 4). It is made up of a
Unit C is lithologically similar to Unit B and contains relatively monotonous succession of basaltic andesites and
thick conglomerates and andesites. The lithologies of Unit C andesites (Fig. 4). Around 600 m of stratigraphy from the upper
were traced laterally around a series of second-order folds in half of this formation were recorded along one continuous
the northern part of the Gurvan Morin Höndiy Formation transect, and an additional succession from a parallel shorter
outcrop area, documenting lateral transitions in the succes- transect along-strike to the west was also documented. The
sion. Sequences of polymict conglomerate, 50–80 m thick, transects cut through the southern limb of the regional syncline
occur within Unit C, containing rounded clasts of granite, (Fig. 3). The uppermost parts of the formation were recorded
andesite, sandstone, siltstone, basalt and dacite, of which on the northern limb, below the overlying Tsagaan Nuruu
granite clasts are the most numerous. Clast sizes range from Formation. Reconnaissance fieldwork across the remainder of
T H E OY U T U L A A N VO L C A N I C G RO U P 495

Fig. 4. Stratigraphic columns for each of the four principal formations in the Oyut Ulaan Volcanic Group. Grey pattern-fill indicates interpretative sections
in more poorly exposed areas. Location of key transects is shown in Figure 3. Numbers to the right of columns indicate positions of geochemically
analysed samples. A, B and C to the left of Gurvan Morin Höndiy column indicate position of ‘units’ as described in text.
496 J. H . S . B L I G H T E T A L .

Fig. 5. (a–c) Lithological logs from Gurvan


Morin Höndiy Formation (stratigraphic
positions shown in Fig. 4).
(a) Stratigraphically lowest sedimentary
units; sediment screens within lava
sequence bound lava flow units.
(b) Sandstone and conglomerate beds and
an intercalated carbon-rich black shale unit.
(c) Sandstone–shale beds featuring lycopsid
bark impressions in mudstones and fine
sandstones. (d) Photograph showing tree
trunk apparently in life position
perpendicular to the bedding surface.
(e) Photograph showing in situ lycopsid
tree-bark impressions.

the Shargyn Moghai Formation outcrop area indicated that the relatively massive interiors and brecciated flow margins. Both
formation deviates little from the lithologies seen along the aphyric and porphyritic textures occur, the latter dominantly
transects. featuring euhedral plagioclase phenocrysts. Groundmasses pri-
Bed thicknesses range from 2 to 10 m and are mainly marily consist of plagioclase microlaths. Small, partially re-
identified through scarp and dip slopes. There is rarely more sorbed granitoid particles occur in one section and are
than 1–2 cm of rubbly volcanic detritus between lava sheets; interpreted to represent wall-rock xenoliths, introduced during
most contacts are lava on lava, suggesting high effusion rates. ascent. Exposures in the uppermost 150 m of the formation
Single flows exhibit variations in phenocryst phase and size, contain siltstone-grade laminated volcaniclastic sediments that
vesicularity, flow banding and brecciation; most sheets have crop out between c. 10 m thick basalt lavas.
T H E OY U T U L A A N VO L C A N I C G RO U P 497

laminated siltstones. The bases of the massive sandstone beds


Tsagaan Nuruu Formation
contain rip-up clasts of the underlying siltstone (Fig. 6b and c).
The c. 1000 m thick Tsagaan Nuruu (White Ridge) Formation The upper parts of the Tsagaan Nuruu Formation differ from the
crops out in the northwestern part of the area of contiguous rhyolitic lava composition that dominates the majority of the
stratigraphy (Fig. 3c) within the core of the first-order regional formation; andesite and basalt units are also present.
syncline. It is composed of a number of distinctive 5–10 m thick The Tsagaan Nuruu Formation may be considerably thicker
felsic units that are blocky and crystalline and form positive than recorded here, as the syncline plunges to the west, where
topography, interbedded with c. 60 m thick fine-grained volcani- there is more outcrop. However, the stratigraphic relationship
clastic sediments that are sparsely exposed (Fig. 4). Near its top, between the rocks farther to the west and the Tsagaan Nuruu
between felsic units, the formation contains basalt lavas, sand- Formation stratigraphy as described here is ambiguous, as the
stone and black organic mudstones with plant fragments. The two are divided by large outcrop gaps interpreted to represent
high competency contrast between the relatively thin but erosion- major structural breaks.
ally resistant felsic units and the thick intercalated tuff sequences
results in topographically expressed second-order folds, which
form ridges snaking across the landscape.
Yasun Eliy-e Formation
The lower part of the Tsagaan Nuruu Formation is poorly The Yasun Eliy-e (Dead Vulture) Formation lies in the east,
exposed and composed of regular repeating sequences of blocky isolated from the rest of the group stratigraphy. It has a minimum
rhyolite units interbedded with sediments, including conglomer- thickness of 1500 m (Fig. 4). It forms the host rocks to the Oyut
ate containing basalt and andesite clasts, and finely laminated Ulaan intrusion (Fig. 3) and is the least chemically evolved of the
and highly silicic fine-grained units. In thin section, the rhyolites formations. Volcanic sandstones and trachybasaltic lithologies are
are predominantly composed of a fine-grained groundmass dominant. The Yasun Eliy-e Formation was observed in a river-
featuring spherulites of intergrown quartz and plagioclase with valley transect that crosses the regional structural grain in the west
euhedral phenocrysts of orthoclase constituting 5–10% of the of the formation’s outcrop area. Beds in the Yasun Eliy-e
rock mass. Formation dip between 258 and 608 to the north.
In the upper part of the Tsagaan Nuruu Formation, intervals The lowest units of the formation (which are exposed north of
between blocky crystalline units are thinner, and sequences are Mesozoic basin sequences situated to the south of the area) are
better exposed. In a 5 m thick bed of black shale beneath a feldspar-phyric basalts that are interbedded in places with coarse,
rhyolitic flow deposit, Cordaites leaf impressions occur on immature sandstones. Farther up-section, 10–20 m thick trachy-
bedding-parallel surfaces (Fig. 6a). Interbedded 1 m thick mas- basalts are interbedded with poorly sorted breccia–conglomer-
sive sandstones and carbon-rich black shales occur below the ates, exhibiting clast sizes of up to boulder grade with basalt
ninth rhyolitic unit (Fig. 6b). The black shaly tops of graded andesite and basalt compositions dominating. A series of finely
sandstones exhibit wood and leaf fragments and are overlain by laminated volcaniclastic lithologies are exposed at a stratigraphic

Fig. 6. Lithological log and photographs


from upper part of Tsagaan Nuruu
Formation (for stratigraphic position see
Fig. 4): (a) lithological log of sandstones
and mudstones with plant fragments; (b)
Cordiates leaf fragment; (c) rip-up clast of
laminated mudstone in coarse sandstone.
498 J. H . S . B L I G H T E T A L .

height of 475 m above the base of the measured section, procedures as adapted from Noble et al. (1993). One dated
consisting of a number of 5–10 cm thick, coarse, lapilli-grade sample was a welded ignimbrite from the lower part of the
horizons, interbedded with 20–30 cm thick ash-fall tuffs. Farther Tsagaan Nuruu Formation stratigraphy, the other was a granite
up the sequence, along with thick (110 m) volcanic sandstone clast from the coarse conglomerates in lower part of the Gurvan
units, further monomict conglomerates occur, forming well- Morin Höndiy Formation (for results, see Table 1 and Fig. 8).
defined escarpments, and drift-covered lee slopes. Sub-angular Zircon crystals were separated from ,355 ìm grained bulk-
andesitic clasts with vesicles and feldspar phenocrysts occur in a rock powder using standard vibrating-table, specific gravity and
coarse matrix that again resembles the fine groundmass of the magnetic techniques. Crystal fractions for analysis were picked
clasts. by hand in alcohol under a binocular microscope; all analysed
The Yasun Eliy-e Formation is the only part of the Oyut Ulaan fractions consisted of single grains. Some zircon crystals were
Volcanic Group observed to be cut by minor discordant intru- subjected to air abrasion (Krogh 1982), whereas a modified
sions. In the north, a 1 m wide olivine-phyric basalt dyke trends chemical abrasion technique (Mattinson 2005) was used for
1308; south of this, in the centre of the area, a small dioritic plug others. Chemically abraded zircons were annealed as bulk zircon
with a roughly circular surface expression, 20 m in diameter, cuts fractions between 800 and 900 8C in quartz glass beakers for
the volcanic–sedimentary succession. between 48 and 60 h. The zircon crystals were ultrasonically
The stratigraphic relationship between the Yasun Eliy-e forma- washed in 4N HNO3, rinsed in ultra-pure water, then further
tion and the rest of the group is ambiguous. It lies in the east, washed in warm 4N HNO3 prior to rinsing with distilled water to
and the group younging direction is with the plunge of the major remove surface contamination. The annealed, cleaned bulk zircon
syncline to the west, suggesting that the Yasun Eliy-e Formation fractions were then chemically treated in 200 ìl 29N HF and
predates the Gurvan Morin Höndiy Formation. However, there is 20 ìl 8N HNO3 between 120 and 180 8C for 12 h to minimize or
a 16 km gap in outcrop between the recorded sections of each eliminate Pb loss. Both air abraded and chemically abraded
formation (Fig. 7), and the possibility that there is some zircons were washed several times in ultra-pure water, cleaned in
alternative association between the two cannot be ruled out. One warm 4N HNO3 for several hours on a hot plate, rinsed again in
explanation for the gap in the stratigraphy may be post- ultra-pure water and 8N HNO3, and split into single-grain
Palaeozoic brittle deformation. Evidence for a Mesozoic sinistral fractions ready for dissolution. A mixed 205 Pb– 235 U or 205 Pb–
233
strike-slip regime has been recorded from both the greater region U– 235 U tracer was used to spike all fractions. Dissolved,
(Lamb et al. 1999) and the Saykhandulaan Inlier (Blight et al. spike-equilibrated samples were not subjected to ion-exchange
2008). On satellite imagery, it appears that the area of poor procedures but were converted to chloride and loaded onto
exposure that separates the two formations is at the intersection degassed rhenium filaments in silica gel following a procedure
of several major lineaments (Fig. 7a). If the sinistral and dextral modified after Mundil et al. (2004). Isotope data were collected
(antithetic) fault movements interpreted from aerial photographs using a Thermo Electron Triton with SEM for ion counting and
are reversed, the Yasun Eliy-e Formation moves closer to the Faraday cups for voltage measurement when ion counts exceeded
base of the Gurvan Morin Höndiy Formation (Fig. 7b). 800 000 s 1 . Errors were calculated using numerical error propa-
gation (Ludwig 1980). Isotope ratios were plotted using Isoplot
version 3 (Ludwig 1993, 2003), and error ellipses reflect 2ó
U–Pb dating of the Oyut Ulaan Volcanic Group
uncertainty.
Single zircons from two samples were analysed by isotope Procedural blanks recorded during four separate batches of
dilution thermal ionization mass spectrometry (ID-TIMS) at the analysis were in the range of 1.2–0.2 pg for Pb and 0.1–0.05 pg
NERC Isotope Geosciences Laboratory (NIGL), using analytical for U. Samples were blank-corrected using a blank

Fig. 7. Structural relationship between


Gurvan Morin Höndiy Formation and Yasun
Eliy-e Formation outcrop areas. (a) Aerial
photograph (courtesy of the Institute of
Geology and Mineral Resources, Mongolian
Academy of Sciences) with interpreted
locations and movement sense of major and
minor faults. (b) Reconstruction to show
suggested pre-deformation juxtaposition of
the two formations. Location of figure is
shown in Figure 3.
Table 1. U–Pb Isotope compositions of single zircon grains from a rhyolite of the Tsagaan Nuruu Formation and a granite cobble from the Gurvan Morin Höndiy Formation
206
Fraction Weight (ìg) U (ppm) Cm-Pb (ppm)* Pb/204 Pb† Ratios Ages (Ma)

207
Pb/206 Pb‡ 2ó% 206
Pb/238 U‡ 2ó% 207
Pb/235 U‡ 2ó% Rho 207
Pb/206 Pb 2ó abs 206
Pb/238 U 2ó abs 207
Pb/235 U 2ó abs

Sample 95:3A
Z-12 0.6 682 0.86 1921 0.05152 0.88 0.03806 0.47 0.2704 1.03 0.53 264.3 20.2 240.8 0.6 243.0 2.3
Z-13 0.6 1030 3.27 926 0.05265 0.43 0.04575 0.26 0.3321 0.52 0.56 313.8 9.7 288.4 0.4 291.2 1.4
Z-14 4.1 50 0.21 907 0.05379 0.38 0.05818 0.59 0.4314 0.71 0.84 362.1 8.4 364.5 1.1 364.2 1.8
Z-15 2 55 0.34 435 0.05220 0.97 0.04034 1.54 0.2903 1.84 0.85 294.1 21.9 254.9 1.9 258.8 3.2
Z-16 1.6 296 0.01 113773 0.05141 0.21 0.03655 0.13 0.2591 0.25 0.55 259.3 4.7 231.4 0.5 233.9 0.7
Z-17 2.8 156 0.92 1548 0.05309 0.16 0.05136 0.21 0.3760 0.26 0.80 332.7 3.6 322.9 10.6 324.1 9.9
Z-19 206 2 0.58 1715 0.05301 0.25 0.04565 0.32 0.3337 0.41 0.80 329.4 5.6 287.8 14.5 292.4 13.5
Sample 55.22A
Z-20 3 246 0.67 3753 0.05335 0.09 0.05370 0.17 0.3950 0.20 0.89 343.8 2.0 337.2 9.4 338.0 7.7
Z-1 0.9 897 0.50 5529 0.05331 0.09 0.05395 0.21 0.3966 0.22 0.92 342.2 2.0 338.7 11.2 339.2 8.9
Z-2 0.9 1416 0.07 58668 0.05320 0.09 0.05400 0.18 0.3961 0.20 0.91 337.3 1.9 339.0 10.0 338.8 8.0
Z-3 0.5 1137 1.11 1763 0.05324 0.25 0.05397 0.22 0.3962 0.33 0.68 339.0 5.6 338.9 11.9 338.9 13.2
Z-4 0.7 651 0.21 7530 0.05343 0.31 0.05394 0.35 0.3973 0.47 0.74 347.0 7.1 338.6 18.6 339.7 18.6

T H E OY U T U L A A N VO L C A N I C G RO U P
All errors are 2ó (per cent for ratios, absolute for ages).
*Total common Pb in analysis, corrected for spike and fractionation (0.09% per atomic mass unit).
†Measured ratio, corrected for spike and Pb fractionation.
‡Corrected for blank Pb, U and common Pb (Stacey & Kramers 1975).
four-point discordia.
it is not within error of the upper intercept age calculated from a
1.1 Ma and is interpreted as representing a xenocrystic grain, as
Zircon fraction Z-14 yields an older 206 Pb/238 U age of 364.5 
upper concordia intercept age of 323.0  3.5 Ma (MSWD 0.15).
supported by a less precise four-point discordia that gives an
youngest formation of the Oyut Ulaan Volcanic Group. This is
which is interpreted to represent the age of the base of the
8a). Fraction Z-17 gives a 206 Pb/238 U age of 323.0  0.7 Ma,
were concordant and five discordant as a result of Pb loss (Fig.
Tsagaan Nuruu Formation rhyolite (sample 95:3A), two of which

was negligible, as the Pb blank dominated the correction.


however, the amount of common lead in the analysed zircons
common lead evolutionary model of Stacey & Kramers (1975);
for common lead in all samples was carried out using the
204

including decay constant errors.


and corresponding errors. Wide grey diagonal line is the concordia
Gurvan Morin Hondiy Formation. Black ellipses show the data points,
of the Tsagaan Nuruu Formation and (b) the granite cobble from the
Fig. 8. Concordia diagrams for (a) the rhyolitic unit from the lower part
Seven single-grain zircon fractions were analysed for the

Pb:206 Pb:207 Pb:208 Pb ratio of 1:18.70:15.15:36.82. Correction

499
500 J. H . S . B L I G H T E T A L .

Seven single-grain zircon fractions were analysed for the


Geochemical data
granite cobble (sample 55:2A) from the Gurvan Morin Höndiy
Formation. Four overlapping, concordant analyses (Fig. 8b) give One hundred representative whole-rock samples from the Oyut
a concordia age of 338.9  0.8 Ma (concordance and equiva- Ulaan Volcanic Group were analysed using standard X-ray
lence MSWD 2.5, probability 0.013) and a mean 206 Pb/238 U age fluorescence (XRF) spectrometry techniques at the University of
of 338.9  0.4 Ma (MSWD 0.17, probability of fit 0.92) the Leicester (Table 2). Twelve samples were analysed in duplicate
latter of which is taken as the best estimate of the emplacement or triplicate to constrain uncertainty related to experimental
age of the granite protolith. Three further analyses, one of which precision, resulting in a total of 121 analyses. Geochemical data
is plotted in Figure 8b, are discordant as a result of Pb loss. from the South Sandwich Islands, New Hebrides Arc, The Lesser
One other age is of relevance to the Oyut Ulaan Volcanic Antilles, Honshu Arc, Sunda Arc, and the Andean Central
Group and, together with the ages detailed above, sets the timing Volcanic Zone were used for comparison of the Oyut Ulaan
of magmatic evolution within the group. This is the Oyut Ulaan Volcanic Group with known tectonic regimes. Comparison data
granite (330 Ma; Blight et al. 2010). This intrusion is hosted by were acquired from the Georoc online geochemical database
the Oyut Ulaan Volcanic Group (specifically the Yasun Eliy-e (http://georoc.mpch-mainz.gwdg.degeoroc/).
formation); therefore, the Yasun Eliy-e Formation must predate The total alkali–silica (TAS) diagram illustrates a range of
330 Ma. key compositional characteristics (Fig. 9), as follows.
Because of the age gap between emplacement of the intrusion (1) The Oyut Ulaan Volcanic Group varies in composition
that yielded the cobble and the deposition of the cobble in the from Na  K-enriched basalt and trachybasalt, through andesite
conglomerate (interpreted to have occurred sometime between and trachyandesite, dacite and trachydacite to rhyolites. The Na
330 and 323 Ma), it is apparent that the conglomerate included  K-enriched signature appears to reflect original composition
detritus derived from fairly recently intruded granites from and not secondary processes, as this signature is a constant
within the arc terrane and that emplacement, uplift and erosion across the whole arc, whereas metamorphism is low to non-
occurred on a scale of 10–20 Ma. existent and alteration is a local field phenomenon.

Table 2. Elemental abundances for representative samples from the four formations of the Oyut Ulaan Volcanic Group

Yasun Eliy-e Gurvan Morin Höndiy Shargyn Moghai Tsagaan Nuruu

Sample: 89.12A 89.10A 88.7A 54.20A 54.3A 55.1A 3/08_2 56.17A 31/07_1 95.1A 95.5A 91.3B

wt%
SiO2 51.37 49.52 49.18 56.77 58.07 63.52 64.62 53.78 59.42 73.68 71.99 50.89
TiO2 0.77 1.02 0.84 0.75 0.65 0.59 0.51 0.66 0.71 0.27 0.35 1.97
Al2 O3 17.30 19.33 18.87 18.45 16.89 16.72 16.89 16.61 15.09 12.97 14.00 17.25
Fe2 O3 8.39 8.50 11.05 5.90 5.99 4.09 4.27 6.56 6.32 1.38 1.09 11.36
MnO 0.17 0.13 0.17 0.09 0.09 0.03 0.06 0.14 0.09 0.01 0.01 0.28
MgO 3.87 1.95 3.74 1.99 2.93 1.58 1.24 4.67 2.49 0.07 0.08 2.34
CaO 7.28 8.37 8.69 3.56 4.82 1.42 1.85 6.91 5.97 0.88 1.04 3.40
Na2 O 4.16 4.58 2.64 7.44 4.69 5.45 5.40 5.40 4.55 5.16 5.44 6.97
K2 O 0.79 1.12 1.83 2.36 3.02 3.52 3.02 1.45 0.88 4.31 5.55 0.36
P2 O5 0.19 0.50 0.48 0.33 0.29 0.16 0.23 0.24 0.32 0.03 0.11 0.77
SO3 0.03 0.03 0.19 0.04 0.08 0.24 0.01 0.07 0.02 0.05 0.06 0.02
ppm
As 10.47 32.54 19.75 5.57 6.15 38.47 2.83 8.78 58.63 28.93 8.37 38.54
Ba 411.23 517.58 362.96 677.95 1027.70 1798.76 964.35 1312.96 611.07 394.95 592.83 181.64
Ce 29.75 43.28 49.87 34.81 30.35 18.50 21.25 26.51 29.55 401.50 126.99 80.74
Co 28.19 25.00 37.04 18.60 18.28 11.19 13.02 26.52 19.12 0.88 0.69 39.01
Cr 7.81 18.29 67.93 b.d.l. 70.00 867.78 35.64 404.85 47.89 b.d.l. b.d.l. 61.53
Cs 2.76 0.53 1.48 2.49 b.d.l. 2.88 1.00 b.d.l. b.d.l. 11.62 1.15 5.64
Cu 76.92 145.65 70.84 94.30 118.21 79.39 48.39 77.13 43.75 b.d.l. b.d.l. 102.16
Ga 19.48 20.60 21.30 17.83 21.69 15.36 18.77 17.71 14.96 26.46 26.78 23.14
La 4.59 14.74 14.12 14.04 13.49 11.39 15.83 10.24 14.31 177.11 53.42 30.13
Mo 1.32 2.22 1.78 1.30 2.13 3.90 0.54 2.43 1.48 3.04 2.90 2.66
Nb 0.74 7.12 5.27 2.02 3.45 4.04 2.91 2.48 4.31 24.72 24.61 9.83
Nd 11.68 22.97 23.12 14.46 17.24 13.84 13.57 13.47 19.39 211.13 71.83 40.65
Ni 4.69 2.05 1.76 3.98 10.54 5.26 26.97 115.55 22.08 3.60 2.45 32.32
Pb 1.86 8.29 7.05 11.35 6.11 11.08 6.71 2.57 5.04 25.34 15.85 5.03
Rb 13.14 20.62 41.78 39.26 45.44 56.80 54.97 19.81 13.76 75.04 98.08 7.66
Sc 32.79 20.18 22.18 21.64 16.10 16.19 6.94 29.71 16.26 6.31 5.86 30.98
Sr 719.63 667.37 596.19 1541.07 1187.51 1270.68 927.56 1278.96 981.23 39.84 62.68 654.84
Th 3.45 4.02 5.60 2.99 3.04 4.44 6.98 4.41 5.07 13.96 14.18 4.49
U b.d.l. 2.88 3.16 0.12 b.d.l. 0.47 1.68 1.23 0.25 4.71 5.80 1.92
V 258.23 171.35 256.22 208.72 180.05 204.10 93.56 186.25 143.61 4.38 7.63 266.68
Y 16.70 33.02 30.38 9.64 11.42 12.94 10.73 12.56 17.68 133.58 119.77 58.39
Zn 75.01 82.35 129.68 53.79 60.59 32.29 53.70 60.76 55.36 59.67 59.76 156.56
Zr 75.17 134.64 103.20 102.47 122.54 123.33 120.40 82.81 137.79 909.10 964.17 330.84

b.d.l., below detection limit.


T H E OY U T U L A A N VO L C A N I C G RO U P 501

Fig. 9. Total alkalis–silica (TAS) diagram


after Le Bas et al. (1986) for Oyut Ulaan
Volcanic Group rocks showing wide range
of compositions for both silica and alkalis.
Thumbnail graph below shows fields of
analyses for each formation. It should be
noted that despite considerable
compositional overlap, each formation is
more evolved than its predecessor.

(2) There is a distinct and well-defined magmatic evolutionary general increases. Stratigraphic variations in some elemental
trend from less to more evolved compositions with time. The abundances (e.g. Zr, Nb and Y) show variations that are more
most basic parts of each formation become more evolved with intricate, illustrating the development of the underlying magma
time (Fig. 9). system with time (Fig. 12).
(3) There is a sharp rise in silica values in the Tsagaan Nuruu The Tsagaan Nuruu Formation represents the upper, most
Formation compared with the other formations. silicic part in the evolutionary trend of the Oyut Ulaan Volcanic
Trace element variograms illustrate the key characteristics of Group; however, the chemistry of this formation shows some
subduction-zone derived magmas; for example, high ratios of other significant differences from the rest of the group. The
low field strength elements to high field strength elements rhyolites of the Tsagaan Nuruu Formation are weakly peralkaline
(LFSE:HFSE) and a negative Nb anomaly (Saunders et al. 1980; to peraluminous (the other formations have a metaluminous
Wilson 1989). Furthermore, the trace element signature of the signature) and have an A2 -type signature when plotted on granite
Oyut Ulaan Volcanic Group most closely resembles patterns discrimination diagrams developed by Eby (1990, 1992; Fig. 13a
from mature oceanic or continental arcs. Multi-element vario- and b). The A2 -type signature relates to granitoid magma
grams (Fig. 10) show that the closest compositional analogues chemistries generated in extensional environments. Mafic and
are arcs and cordillera such as Sunda, Honshu and the Andes, intermediate units from the upper parts of the Tsagaan Nuruu
with elevated, convex-upwards Sr–Th patterns and negative to Formation have higher Y, Nb Zr and TiO2 abundances than
gently concave-upwards Ce–Y patterns. Ratio–ratio plots invol- similar lithologies from the other formations in the Oyut Ulaan
ving Zr, Ti, Nb, Ce, and Y (e.g. Nb/Y v. Zr/Y; Fig. 11) confirm Volcanic Group (Fig. 13c). Abundances of other elements are
that when the data are plotted in tightly constrained fields, the consistent with the broad evolutionary trend of the group as a
Oyut Ulaan Volcanic Group exhibits very similar compositions whole.
to highly evolved arcs such as Sunda, Honshu and the Central
Andes.
Geochemical results generally show an evolutionary trend
Discussion
within the Oyut Ulaan Volcanic Group, from basalts at its base
to volcaniclastic deposits of rhyolitic composition in its upper
Physical volcanic model
reaches. Abundances of CaO, TiO2, Al2 O3 and Fe2 O3 generally The three contiguous formations in the west contain 4.6 km of
fall with stratigraphic height, whereas SiO2, Ba and Sr show stratigraphy from an evolving volcanic–sedimentary system, and
502 J. H . S . B L I G H T E T A L .

Fig. 10. Spidergrams for trace elements


from Yasun Eliy-e Formation (YEF),
Gurvan Morin Höndiy Formation (GMHF)
and Shargyn Moghai Formation (SMF).
White line on main plot shows average of
all results. Lower plots show comparison of
this average with other magmatic arcs
worldwide (data from Georoc database,
http://georoc.mpch-mainz.gwdg.degeoroc/).
All data are normalized to mid-ocean ridge
basalt (MORB) values of Pearce (1983).

Fig. 11. Trace element ratio–ratio plots to


show comparison between results from
Oyut Ulaan Volcanic Group and other arc
environments worldwide.

record three distinct stages of volcanism: (1) commencement of ing a stable sediment-dominated palaeo-environment (Fig. 14a).
volcanic activity within an energetic fluvial sedimentary environ- Volcaniclastic horizons suggest explosive eruptions. The sand-
ment; (2) high rates of basaltic and andesitic effusion; (3) dominated sedimentary sequences suggest a shallow marine or
explosive, mainly felsic volcanism with some bimodal affinities lacustrine environment, perhaps leading to phreato-magmatic
(Fig. 14). activity. The lack of thick, erosion-resistant sequences of the
The Yasun Eliy-e Formation is interpreted to represent the coarse fluvial conglomerates that characterize the Gurvan Morin
beginnings of volcanism in the group, with basic lavas interrupt- Höndiy Formation suggests that Yasun Eliy-e Formation volcan-
T H E OY U T U L A A N VO L C A N I C G RO U P 503

Fig. 12. Various elements plotted against


relative vertical stratigraphic position to
show systematic variations in elemental
abundances with time in the Oyut Ulaan
Volcanic Group. Scale on y-axis is
numerical order of sample in Oyut Ulaan
Volcanic Group, starting with the
stratigraphically lowest at one.

ism predates the major uplift and erosion of older crust, or is a arc. Although their heterolithic nature points to a widespread
lateral facies variant of the Gurvan Morin Höndiy Formation. provenance, the high proportion of large granite clasts suggests
The Gurvan Morin Höndiy Formation represents intermittent that the provenance zone included older arc plutons. This
volcanism within an active, high-energy sedimentary environ- suggests that at the beginning of Oyut Ulaan Volcanic Group
ment (Fig. 14b). In its lower parts (Unit A), andesite sheets are volcanism the area was not a simple immature island arc but had
intermixed with coarse heterolithic conglomerates, interpreted to more in common with either an evolved island arc or a
have been deposited by large river systems eroding the uplands continental margin. The polymict nature of the succession’s
and depositing alluvial-fan sequences in the lower parts of the voluminous conglomerates shows that a varied geological hinter-
504 J. H . S . B L I G H T E T A L .

Fig. 13. (a, b) Diagrams after Eby (1990,


1992) to show A2-type signature of the
rhyolitic components of the Tsagaan Nuruu
Formation. (c) Harker plots against SiO2 to
show elevated values of various elements in
the basic units of the Tsagaan Nuruu
Formation compared with the other
formations of the Oyut Ulaan Volcanic
Group.

land was undergoing erosion contemporaneously with the Oyut sediment, resulting in loading structures. Pillow andesites at the
Ulaan volcanism. top of the formation suggest that some lava was being extruded
Higher in the succession conglomerates have smaller clast within a subaqueous environment; in light of the other evidence,
sizes, are more thinly bedded, and finer siliciclastic sediments it is suggested that this was lacustrine or swamp-like rather than
become more common. Sandstones are commonly graded and marine. The presence of bioclastic limestone cobbles in con-
have mudstone or siltstone caps, suggesting current sorting in a glomerates in the upper parts of the formation suggests proximal
fluvial–deltaic environment. Evidence of mature vegetation sug- erosion of marine sequences, highlighting the growth of the arc
gests a stable terrestrial landscape and long inter-eruptive from earlier marine settings.
periods, leading to growth of plant life within a swamp-like In conclusion, it is hypothesized that the first stage of Oyut
environment. This is consistent with a palaeo-environment of Ulaan Volcanic Group volcanism exhibited periodic andesitic
braided rivers flowing into lakes and swamps in a warm humid effusion with long periods of volcanic quiescence within a wet–
climate. The northwards thinning observed in lava sheets sug- humid semi-tropical environment. Initially, volcanism occurred
gests that volcanic vents were located to the south and that lavas within the rifted lowlands of a mature arc close to geologically
have wedge-like thickness patterns. Lava–sediment mixing at the diverse uplands. This environment probably contained large,
base of some sheets suggests lava was emplaced onto wet intermittently powerful rivers that had the capacity to transport
T H E OY U T U L A A N VO L C A N I C G RO U P 505

Fig. 14. Interpretative volcanic environment


and magma-chamber models for the various
formations of the Oyut Ulaan Volcanic
Group. (a) Yasun Eliy-e Formation;
(b) Gurvan Morin Höndiy Formation;
(c) Shargyn Moghai Formation; (d) pre-
Tsagaan Nuruu Formation; (e) Tsagaan
Nuruu Formation.

and deposit large volumes of coarse material from the precursor tive of a subaerial andesite field with multiple low-angle shield-
arc-hinterland to the volcanically active arc-graben. As time style vents, similar to that of the Birker Fell Formation in the
progressed the rate of effusion increased, as did the extent of low Borrowdale Volcanic Group, Lake District, UK (Petterson et al.
swamplands with standing lacustrine bodies and braided sand- 1992; McConnell et al. 2002). Andesite fields feature tabular
and silt-bearing river systems. lava deposits of considerable areal extent, and are a feature of
The Shargyn Moghai Formation represents an abrupt change many pre-stratocone and pre-caldera sequences worldwide. Pre-
in volcanic style. It is composed almost entirely of basaltic caldera andesite fields occur in a range of locations, including
andesite and andesite lava sheets lacking intercalated sediments, beneath both the Loma Seca Tuff in Central Chile (Hildreth et
suggesting an increase in effusion rates. Many sheet-on-sheet al. 1984) and the Santorini ignimbrites (Druitt et al. 1989). In
contacts are evident, expressed as trap topography. Pillow lavas the Shargyn Moghai Formation, voluminous and regular out-
do not occur, implying that the great bulk of volcanism took pourings of lava appear to have prevented the re-establishment of
place subaerially. Voluminous volcanic deposition rapidly filled- Carboniferous flora, in spite of a probably humid, warm climate.
in and buried the aqueous environment present in the upper and Modern analogues of this type of volcanic landscape could
northern parts of the Gurvan Morin Höndiy Formation. No include an energetic, Tongariro-style, North Island New Zealand
pyroclastic activity is recorded; this implies that even during province (Nairn et al. 1998).
extrusion of intermediate compositions, degassing was wide- The Tsagaan Nuruu Formation is the uppermost part of the
spread and magma paths to the surface were numerous. Thin, Oyut Ulaan Volcanic Group, and represents another change in
lobate, channel-bound deposits, which are typical of steep-sided volcanic style. Andesite sheets, notable for their voluminous
volcanic-cone sequences, do not occur within the Shargyn presence elsewhere in the stratigraphy, are absent. The formation
Moghai Formation. The stratigraphy of this formation is sugges- is dominated by deposits resulting from explosive felsic volcan-
506 J. H . S . B L I G H T E T A L .

ism, including thick sequences of ash-fall tuffs, interrupted by sequences (Fig. 14c). This scenario supports the interpretation of
lava-like welded ignimbrites or low-viscosity rhyolite lavas (Fig. high effusion rates in the Shargyn Moghai Formation.
14e). Large volumes of fine-grained material suggest that the The Tsagaan Nuruu Formation is predominantly composed of
Tsagaan Nuruu strata may have been deposited within a highly evolved silicic volcaniclastic deposits, and the geochem-
syndepositional volcano-tectonic depression. The upper parts of ical results reflect this; most elemental abundances show a
the formation show a gradual lessening of extrusion rates and a significant compositional gap from preceding evolutionary trends
return to a fluvial–swamp-dominated depositional environment (Fig. 14). Intermediate and basic lava units at the top of the
for the first time since the deposition of the upper parts of the Tsagaan Nuruu Formation show a return to a similar effusive
Gurvan Morin Höndiy Formation. Again, the presence of plant eruptive style that occurred in earlier formations. However, the
detritus in carbon-rich shale units is indicative of a relatively chemistry of these units indicates a potentially different source;
quiescent and moist environment at this time; vegetation was elevated values of Y, Nb, Zr and TiO2 suggest contamination by
established on the land once more, and low-energy sedimentation deeper, mantle-derived alkaline magmas. Abundances of the
in lacustrine or deltaic flood-plain environments could take place. same elements in the felsic parts of the Tsagaan Nuruu Forma-
The occurrence of more basic lithologies, near the top of the tion may also be elevated above those that would result from a
formation, illustrates the bimodal nature of the Tsagaan Nuruu simple evolutionary trend in the Oyut Ulaan Volcanic Group.
Formation. The general interpretations of the variation of Oyut Ulaan
Volcanic Group geochemical data with stratigraphic height (Fig.
12) are as follows: (1) an overall trend towards more SiO2 -rich
magmas with time; (2) sawtooth patterns of elemental abun-
Geochemical implications for the physical volcanic model dances with stratigraphic height, suggestive of a dynamic magma
The least evolved formation is the Yasun Eliy-e Formation, environment with pulses of primitive magma being introduced
which field and remote-sensing evidence suggests represents the into the magma chamber(s) episodically; (3) indications of
deepest stratigraphy. The formation’s vertical geochemical varia- magmatic evolutionary trends that differ from the predominant
tion corroborates this interpretation, fitting in as least evolved at trend; (4) a clear compositional gap between the Tsagaan Nuruu
the base of the group and becoming slightly more silicic with Formation rhyolites and the older parts of the Oyut Ulaan
height (Fig. 12). The Yasun Eliy-e Formation varies from the rest Volcanic Group.
of the group’s Na-transitional signature; it is predominantly K-
series alkaline. Zirconium abundances rise in the Yasun Eliy-e
Magmatic–tectonic model
Formation, showing a simple evolving trend of fractional crystal-
lization, with the residual magma becoming gradually more The Oyut Ulaan Volcanic Group is interpreted to record a series
evolved. These data are consistent with a simple andesitic of tectonic events affecting a mature continental-style arc (Figs
fractionation trend, with intermittent eruptions that tapped this 14 and 15). The group constitutes a more northeasterly expres-
gradually evolving source (Figs 12 and 14a). sion of volcanic activity than has previously been recorded for
Unit A, at the base of the Gurvan Morin Höndiy Formation, the southern Mongolia Carboniferous arc (see Lamb & Badarch
has distinctive decreasing abundances of Zr and La with 2001).
stratigraphic height (Fig. 12); this counter-evolutionary trend Magmatism began in the Yasun Eliy-e Formation within a
may result from a new influx of basaltic parent magma. The fact relatively stable environment. Its K-alkaline signature may
that this is expressed as a smooth trend rather than a sudden step signify an arc-front setting somewhat removed from the subduct-
suggests that the remaining residual magma from the Yasun Eliy- ing trench, if a simple K-h style trend (in which magmatism
e Formation was mixed with a new, more primitive magma becomes more alkaline with distance from the trench) was
influx, whilst concurrent eruptions tapped the chamber (Fig. operational (Gill 1981; Wilson 1989).
14b). The thick andesite sheets of the Gurvan Morin Höndiy Extension is interpreted as the trigger for volcanism in the
Formation provide further evidence for periods of heightened Oyut Ulaan Volcanic Group, and particularly the increasing
magma chamber throughput. Upper parts of the Gurvan Morin effusion rates of the Shargyn Moghai and Tsagaan Nuruu
Höndiy Formation show minor systematic fluctuations in Zr; both formations. The extension may have been produced by roll-back
Unit B and Unit A show similar slight increasing trends with of the subducting slab, or transtension along the arc. This
height (Fig. 12), which are interpreted as having been caused by extension would have been geomorphologically expressed by
new influxes of magma that were introduced to the underlying rejuvenated mountain fronts and river systems, and could have
chamber, and which progressed through fractional-crystallization promoted an increase in the number of potential magma
controlled evolutionary trends in a similar manner to the Yasun conduits. The coarse conglomerates and thick andesite sequences
Eliy-e Formation. It is interpreted that this pulsing magma of the Gurvan Morin Höndiy Formation suggest an intra-arc
replenishment produced long inter-eruption time gaps leading to extensional graben environment, with footwall uplift providing a
the establishment of the relatively stable swamp environments in hinterland source of older-arc material for erosion. Similar,
the upper parts of the Gurvan Morin Höndiy Formation. ancient arc-graben depressions occur in the southwestern USA,
The Shargyn Moghai Formation exhibits two consecutive and a modern analogue occurs in the Guatemala–Nicaragua
sequences of decreasing Zr trends with height (Fig. 12). Other sections of the Central American arc (Fisher & Schmincke
incompatible HFSE also fall, but trends are less distinct. The 1994). Increasing extension, during Shargyn Moghai Formation
highest abundances of Cr and Ni from the whole group are seen times, led to the development of many magma conduits and
in the upper parts of the Shargyn Moghai Formation, as are vents, resulting in high effusion rates. Some Shargyn Moghai
enriched TiO2, Al2 O3 and Fe2 O3, indicating fresh and volumi- Formation lavas contain xenoliths of granite that are lithologi-
nous inputs of more primitive magma at this interval. These cally similar to the nearby Oyut Ulaan intrusion. Andesitic dykes
trends imply that magma input rate into the underlying chamber cut the intrusion and are geochemically similar to the Shargyn
was exceeding the rate of extrusion at the time of the Shargyn Moghai Formation. These dykes may represent the feeder
Moghai Formation, causing the eruption of less evolved lava structures to the Shargyn Moghai Formation.
T H E OY U T U L A A N VO L C A N I C G RO U P 507

Fig. 15. Interpretation of sequence of


tectonic events that controlled the Oyut
Ulaan volcanism.

Two possible hypotheses for the high-silica sequences of the volcanism, after the high effusive rates of the Shargyn Moghai
Tsagaan Nuruu Formation are suggested. A first hypothesis is Formation, appears counterintuitive to this interpreted trend.
that the Tsagaan Nuruu Formation followed a period of volcanic
quiescence; the trapping of substantial magma volumes at
shallow levels allowed for a protracted period of fractionation
Regional implications
and led to the development of a stratified magma chamber, with The Oyut Ulaan Volcanic Group represents mid-Carboniferous
a concentration of volatile-rich rhyolitic fluids in its upper parts. volcanism within a mature continental arc environment. Evi-
This scenario could have led to explosive felsic eruptions, and dence for continuing uplift and magmatism in the arc through
the rapid emptying of the stratified chamber. Once the main earlier parts of the Carboniferous occurs locally as granite
chamber had been largely emptied, basic magma from its deeper cobbles within the Oyut Ulaan Volcanic Group succession,
parts was tapped and emplaced into a relatively quiescent whereas, on a regional scale, the arc had been active since the
environment, suggested by the black shales and organic matter in Devonian (Lamb & Cox 1998; Perello et al. 2001). Field and
the upper parts of the Tsagaan Nuruu Formation. However, it is geochemical data from the Oyut Ulaan Volcanic Group are
not clear what process would have caused the pause in volcanism consistent with the suggestion of Lamb & Badarch (2001) that
during which the magma chamber stratification could take place. the southern Mongolia Carboniferous arc may ‘continue eastward
A second hypothesis, that the Tsagaan Nuruu Formation repre- for several hundred kilometres’ from Tsagaan Suvarga (Fig. 2).
sents the beginnings of extension-related bimodal volcanism in It also further supports the continental nature of the arc in this
the Oyut Ulaan Volcanic Group, is supported by the A-type area. Along-strike to the west of the Oyut Ulaan Volcanic Group,
chemistry of the rhyolites. The age of the Tsagaan Nuruu lithologies cropping out within the Gurvansayhan range record
Formation also agrees with the 320–290 Ma regional bimodal arc activity in the Devonian, but a back-arc basin environment
suite postulated by Yarmolyuk et al. (2008). Furthermore, the during the early and middle Carboniferous (Fig. 2; Lamb &
chemistry of basalts and andesites at the top of the Tsagaan Badarch 2001). The same tensional stress field that is interpreted
Nuruu Formation suggests the influence of alkaline mantle- to have facilitated the eruption of the Oyut Ulaan Volcanic Group
derived magmas that could have been introduced into the source may have caused this change in environments further west.
area during crustal extension. It is possible that such magmas Various regional models suggest Carboniferous dextral move-
provided additional heat for melting of the felsic crust of the ments along the arc front in the area (Şengör & Natal’in 1996;
continental arc, resulting in the explosive rhyolitic volcanism of Badarch et al. 2002). The extension may thus be transtensional
the Tsagaan Nuruu Formation. This second hypothesis appears in nature and a product of oblique subduction, which was
more likely, as other characteristics of the Oyut Ulaan Volcanic apparently an important feature of Devonian–Permian closure of
Group indicate increasing extension; and a sudden pause in the Palaeo-Asian Ocean (Dobretsov & Buslov 2005). An increase
508 J. H . S . B L I G H T E T A L .

in the intensity of extension is tentatively interpreted during Kröner and R. Seltmann are thanked for their detailed and positive
deposition of the Tsagaan Nuruu Formation, based on the comments.
evolving change in eruption style to bimodal volcanism. The A-
type signature of rhyolitic lithologies within the Tsagaan Nuruu
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Received 23 June 2009; revised typescript accepted 1 December 2009.


Scientific editing by Alan Collins.

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