FULL SYLLABUS TEST - 1 (FST-1)

JEE ADVANCED
TARGET : JEE (ADVANCED)-2013
DATE : 01-05-2013 COURSE NAME : REVISION CLASSES

HINTS & SOLUTIONS

PAPER-1 7. The resistivity of a wire...................................
Ans. (D)
PART-I (Physics)
8. Two voltmeters V1 and V2 ...............................
1. Select correct alternative................................ Ans. (B)
Ans. (C)
9. Distance of image after.................................
2. Select correct alternative..........................
Ans. (B) n 2 n1 n 2  n1
Sol. (B)  =
3. The string AB vibrates in....................... v u R

T1 (3)2 1.5 1 1.5  1

 9  =
Sol. (B) = ,T =T –B  B = T1 – T 2 v  105 / 2  35
T2 ( 2)2 4 2 1
v = –45 cm.
wt. in air T1 10. Separation between the...........................
specific gravity of block = Sol. (B) From IInd surface,
loss in wt. in water = T1  T2
n 2 n1 n 2  n1
1 1  =
9 v u R
= =
T2 4 = 5 = 1.8
1 1 1 .5 2 1.5  1
T1 9  =
v 35  35
4. A time-dependent magnetic ..........................
v = –21 cm
 d Hence separation = 2 × 35 – (45 + 21) = 4 cm.
Sol. (D)  E.d   (B 0 t  R 2 )
dt 11. If 1 = 1.5, then for....................
Sol. (D) As from Ist surface,
E  2r   B0 R 2 v = –45 cm
Hence image distance from second surface
= 70 – 45 = 25 cm
B0 R 2
E n 2 n1 n 2  n1
2r Then,  =
v u R
B0 R 2 
–  2 2 2  1
2r  =
 25 35  35
5. A wire of length L and...........................
3E 2 1 2 2
Sol. (B) Explanation in the first case, i  = 
R 35 35 25 35
where E is the emf of each cells and R   L  is the resistance 1 20 2
=
of the wire. 35 25  35
Also i2Rt = m.s. T ...(i) 2 = 2.5.
where m = mass of L length of wire and S is the specific heat of
12. Time taken by the........................................
the material of the wire
dis tan ce 
NE Sol. (A) Relative to wedge time = = .
In the second case, i'  speed v
R'
13. Normal reaction between..................
2 Sol. (B) N sin = ma
where R '  2 L and i ' R ' t  m '.s.T ...(ii)
Dividing equation (ii) by equation (i), we have N sin = mg tan
2
 i'  R'  m' N = mg sec.
i .  
  R m
14. Normal reaction offered ..........................
2 2 Sol. (A) N = (M + m)g
N R m' N 1
 .   . 2  N=6
9 R' m 9 2
6. Three samples of a radioactive..............................
Ans. (A)

RESONANCE SOL010513 - 1
15. Sound of frequency 1000 Hz...............................
Ans. 4 (2 sin – 3 )( 3 sin + 1) = 0

 V  v0   330  30  3
Sol. f'  f    f' = 1000  330  sin = ,  = 60º
 V  vs    2
Ans. 4
 330   360  21. A man can swim with a......................................
f "  f '  f "  1000  300 
 330  30    Ans. 6

f "  1200Hz 2d
Sol. Ist case: T1 =
16. When a system is taken from..................................
v m
Ans. 5
2d
Sol. Q acb  U acb  Wacb IInd case: T2 = 2 2
v m  v 
Q bda  U bda  Wbda
d d 2dv m
Q acb  Q bda   U acb  U bda   Wacb  Wbda 
IIIrd case: T3 = = 2 2
v m  v  v m  v  v m  v 
U acb  U bda  0 Then, T22 = T1T3 = 3 × 12  T2 = 6 sec.
 60  Q bda  30  10 22. The cross–section of a glass.....................................
Ans. 2
Q bda  40J  Q adb  40J Sol. PQ & RS are parallel (normal to force)
Then,  = 2
17. In the given potentiometer arrangement................................... But,  + 2 = 180º
Ans. 5  = 36º
Sol. Amptitude of SHM, A = 5 cm, initial position of jockey is at A/2 and Then, x = 2.
moving towards extreme.
23. A glass bottole when full of........................................
T T Ans. 8
t 
6 4 mass expelled 3
Sol. Mass of Hg =
18. A block of mass 5 kg is............................... (  Hg   glass )T 15  10 5  20 = 1000 gm
=
An s . 3
Sol. As seen from an inside observer, the forces acting on the Initial mass of Hg = 1000 + 3 = 1003 gm
block are pseudoforce, frictional force and the applied force. Mass of empty bottle = 1123 – 1003 = 120 gm
When the applied force is in the direction of pseudo force x = 8.
(in this case less force will be required to move the block) 24. The work of 147 kilojoule is......................................
10 + pseudoforce = µmg ........(1) Ans. 5
When the applied force is opposite to the pseudoforce,
20 – pseudo force = µmg ........(2) f
Adding (1) & (2) Sol. Q = U + W  W = –U = nRT
2
30 = 2 µmg = 2µ50  µ = 0.3
19. The molar heat capacity of a................................ f 147
An s . 3 147 = × 8.4 × 7  f = = 5.
2 7  4.2
Sol. Proces PV2 = constant & f=5
PART-II (Chemistry)
f R 5 3 xR 25 (A)
C= R+ = R–R= R =
2  2 1 2 2 2 R
x = 3. Sol. Cm = Cv + +
1 x
20. An elastic ball thrown with a........................... (A) PV–1 = constant
Ans. 4 X=–1
2v 0 sin 
Sol. Total time of flight T = R
g Cm = Cv +
2
v0 (B) PV–2 = constant
Time from A to B t1 = X=–2
g sin 
Then, B to C = T – t1 R
Cm = Cv + = Cv – R
2v 0
1 3
But, T – t1 = (maximum possible time)
2 3 g (C) PV2 = constant
X=2
2v 0 sin  v0 v0 1
  R
g g sin  = g 3 Cm = Cv + = Cv – R
1
sin
2 sin2 – 1 = (D) PV3 = constant
3 X=3

2 3 sin2 – sin – 3 =0 R
Cm = Cv +
2
2 3 sin2 – 3 sin + 2 sin – 3 =0
Heat exchanges Cm so highest heat exchange is in (A).

3 sin (2 sin – 3 ) + 1(2 sin – 3 )=0

RESONANCE SOL010513 - 2
26. (C) two diastereomeric amides
–
O

Sol. O S O O H
39. (9)
O Sol. Initial moles of H2O2 = 2 × 2 = 4

Borax 5B—O—B linkage 1

Moles of H2O2 left after 20 min. = 4 × =1
P4O10 6P—O—P linkage 22
(2 half lives)
O Moles of H2O2 decomposed 20 min. = 4 – 1 = 3
1
+3 +5 H2O2  H2O + O
O S S O 2 2
3
Moles of O2 formed during 20 min. =
OH OH 2
Both sulphur having sp3 hybridisation but oxidation state of 3
sulphur is different. R T
Volume change = 2
27. (C)
P
6 q=0 U = W
Sol. Co has t 2g eg0 configuraton in its +3 O.S.
3
W = –Pext (V2–V1) = – Pext V =  × 2 × 300 = – 900 Cal.
2
40. (7)
Sol. (i) Planar molecules : XeF2, ClF3, H2O, [XeF5]–, I3–, BCl3, XeF4.
(ii) SF4 – See - Saw shape
PCl5 – Trigonal bipyramidal
SF6 – Square bipyramidal
IF7 – Pentagonal bipyramidal
Complex-1 O2–1 Paramagnetic
Complex-2 O2–2 Diamagnetic 41. (5)
Sol. [Pt(NH3)Cl(H2O)Br], [Cu(NH3)4]2+, [Co(en3)]3+, XeF4, XeO64–.
dx2 – y2orbital involved in dsp2 & sp3d2/d2sp3 hybridisation
(1) dsp2 [Pt(NH3)Cl(H2O)Br]  Square planar
O2– is reduced in O22– in the present of reducing agent.
(2) sp3d SF4  See-Saw sp3d
28. (B)
(3) dsp2 [Cu(NH3)4]2+  Square planar
Sol. ZnS + O2  ZnO + SO2 
ZnO + C  Zn + CO (4) sp3d [XeO3F2]  Trigonal bipyramidal

29. (C) (5) sp3d [XeO2F2]  See-Saw

Sol. Refer class notes.
(6) d2sp3 [Co(en3)]3+  Octahdral
30. (C)
(7) dsp3 [Fe(CO)5]  Square pyramidal

(8) sp3 POCl3  Tetrahedral

Sol.
(9) sp3d2 XeF4  Square planar

(10) sp3d2 XeO64–  Square bipyramidal

Anti M.K. addition
42. (5)
31. (C) 32. (D) Sol. A.3H2O(s) A.H2O (s) + 2H2O (g)
33. (B) 34. (A) 1 mol a mol
35. (B) 36. (D) 0 mol a-2 mol
37. (B)
38. (B) (a  2) 0.0821  300
=3
24.63
a=5
43. (3)
Sol. +
Sol. 3Fe2O3 + CO 80%
  2Fe O 3 4
+ CO2
60%
1Fe3O4 + CO 3FeO + CO
 2

50%
1FeO + CO  Fe + CO
 2

Br2 / KOH /  2
     100  0.8  3  0.6  0.5
retension
3 = 3.
16

RESONANCE SOL010513 - 3
44. (6) PART-III (Mathematics)
49. (C)
Sol. Using property g1g100 = g2 g99 = g3 g98 = .... = g50 g51 = ab
and a1 + a100 = a2 + a99 = a3 + a98 = .... = a50 + a51 = a + b

(ab)50 (ab) 49 ab
given expression = 50 + 49 + ..... +
(a  b ) (a  b ) ab
Sol.
  h  50 
    1
50 49
h h  h  h   2  

=   +   + ..... +   =
45. (9) 2 2 2 2 h 
  1
Sol. H2N–CH2–COOH (Glycine) + 2 

h(h50  2 50 )
(1) Gly–Gly (2) Gly–ala(+) (3) Gly-ala (–) =
(4) Ala(+) – Gly
250 (h  2)
(5) Ala (–)–Gly (6) Ala(+) – Ala(+) (7) ala (–)–ala(–) 50. (C)
(8) ala (+)–ala(–) 1/ n
(9) ala(–)–ala(+)  n! 
Sol. nlim  
   (mn)n 
46. (3)  
  1/ n
CF CH O
3 2 CH CH O
3 2  1 2 3 n 
= nlim
Sol. (P)   CH3 – CH2 – Br     . . ....... 
(1) ( 2) 
 mn mn mn mn 
In reaction 2nd Nucleophile is stronger.
(Q) (Alkene)  1 2 3 n 
lim 1  . . ....... 
(1) ( 2) = e n  n n  mn mn mn
 C2H5O
         (Alkene) mn 
( CH3 )3 CBr /  ( CH3 )2 CHCH2Br / 
n 1
st
In reaction 1 3º alkyl halide 1 r  x
n   dx
 1  1
1>2 =
lim
 n =  m =
n  
=
(R) In reaction 1st stable carbocation is formed
e n  n r 1
mn e 0 
e  em  em
Ans. (C) is correct.

51. (B)
(Cyclopropyl methyl C) Sol. Focus of x2 = 4y is (0, 1)
1>2 Mid-point of chord of circle is of the form (t2 , 2t)
(S) In reaction 1st reagent in HI.  t4 + 4t2 < r2 .....(i)
and t2x + 2ty = t4 + 4t2
HI is more ionised, gives sufficent concentration of H ion
It passes through (0, 1)  2t = t4 + 4t2
and I is a good Nucleophile also.  t = 0 or t3 + 4t – 2 = 0
1>2 t = 0 gives axis of parabola x2 = 4y
t3 + 4t – 2 = 0 gives exactly one real root ( f(t) = 3t2 + 4 > 0)
47. (6) If this value of t satisfies (i), then one line is obtained.

Sol. 3 O NH OH / H
2  
52. (B)
  
excess
7 6 x 2  13
2 x 2  13 2
Sol. =0
2
x  13 3 7
R1  R1 + R2 + R3
cis - cis
trans - trans x2  4 x2  4 x2  4
cis R trans 2
trans S cis 2 x  13 2
=0
Total isomeric product = 4 x 2  13 3 7
Optical active = 2

48. (6) 1 0 0
C 2 2
x  15 0
| (x2 – 4) =0
Sol. C–C–C–Cl x  13  x  16 20  x 2
2 2
|
C (x2 – 4) (x2 – 15) (20 – x2) = 0
 roots are ±2, ± 15 , ± 20
 sum of roots other than 2 is –2.

RESONANCE SOL010513 - 4
53. (D)
Sol. Required area is
1

 [( x
2
– 2x – 1) – (– e x – 1)] dx = 2  e – 1
–1
3 e
 graph of region is

54. (C)
Sol.  f(x) = f(x) × f(x)
Let f(x) be a polynomial of degree n  x = c cuts the graph at two different points if c > 0.
 degree of f(x) = n – 1 & degree of f(x) = (n – 3) i.e c  (0,)
 n = (n – 1) + (n – 3)  n = 4
also f(x) = 0 satisfies x = 1, 2, 3 only 60. (A)
 f(x) = (x – 1)2 (x – 2) (x – 3) or f(x) = (x – 1) (x – 2)2 (x – 3)
or f(x) = (x – 1) (x – 2) (x – 3)2 x 2  mx  1
This implies that either f(1) = 0 or f(2) = 0 or f(3) = 0 Sol. –1   1,  x  R
 f(1) f(2) f(3) = 0 (C) is correct. 3( x 2  x  1)
 –3x2 – 3x – 3  x2 + mx + 1  3x2 + 3x + 3
55. (B)  4x2 + (m + 3) x + 4  0 and 2x2 + (3 – m) x + 2  0,  x  R
Sol. Let center be (– r, – r)  (m + 3)2 – 64  0 and (3 – m)2 – 16  0
 m2 + 6m – 55  0 and m2 – 6m – 7  0
 2r  r  1  (m + 11) (m – 5)  0 and (m – 7) (m + 1)  0
=r  –11  m  5 and –1  m  7
5  –1  m  5
(3r – 1)2 = 5r2
9r2 – 6r + 1 = 5r2 61. (C)
4r2 – 6r + 1 = 0 Sol. f(x) = x2 + 2x – 3 = (x + 1)2 – 4 is increasing in [–1, 5]
f(–1) = – 4 and f(5) = 32  D = [– 4, 32]

 6  36  16 3 5 62. (B)

r= r= Sol.  S  D = [–4, 32]
8 4
  = 33 and n = 5 i.e.  + n = 38  – n = 28
Let center be (– r, – r) sum of roots = 66 and product of roots = 38 × 28 = 1064
 the equation is x2 – 66x + 1064 = 0
 2r  r  1
=r 63. (1)
5 /4
(r – 1)2 = 5r2 n
r2 – 2r + 1 = 5r2
Sol. In+2 =  tan x dx . tan2x dx
4r2 + 2r – 1 = 0 0
/4 /4 /4
 2  4  16 tann x (sec2x – 1) dx = tann x sec2x dx – n
r=
8
=
0

0
 tan
0
x dx

 1 5 1
r= .  t n 1 
4 
= 
 –I
 n  10
 n
also let center be (r, – r)
(r + 1)2 = 5r2
 4r2 – 2r – 1 = 5r 2 1
In + In+2 =
1 5 n 1
r=
4 1
nn+1  In+3 + In+1 =
3 5 n2
radius of larger circle is
4 n n
1
56. (A)
Sol. 1000C2 – 250C2 – (250C2 – 1) = 437251
Sn =   (
n0
n n 2 )   n 3  n   n 2  = 
n 1
n1   n3 
n 0

57. (B) n n
Sol. Let (x,y) be any point whose distance from (0,0) is 1. 1 1  1 1 
 the region is | x | + | y | = 1. It intersects y = 2x at two =  n  1 n  2    n  1 – n  2 
n 0 n0
points sum of whose absissae is 0.
58. ( A)
 1  1 1  1 1  1
Sol. The region intersects x-axis at two points (–1, 0) and (1,0)  1 –    –   .....   –   1–
=
 2 2 3 n 1 n  2 n2
 the required difference between the maximum and mini-
mum distance of region from the point (, 0) = distance lim Sn = 1 – 0 = 1
between the points (–1, 0) and (1,0) = 2. n 

59. (D)
64. (2)
Sol. Let (x,y) be point on the locus, then | x + 1 | = | x – 1 | + | y |
Sol. 2 cos 3B + 3 cos 4A = 3
2 x if 0x  1  2 cos 3B = 3 (1 – cos 4A) = 6 sin22A
|y|=|x+1|–|x–1|=  and 2 sin 3B – 3 sin 4A = 0
 2 if 1 x  2 sin 3B = 6 sin 2A cos 2A
then cot 3B = tan 2A

RESONANCE SOL010513 - 5
 69. (9)
cos 3B sin 2 A Sol. There are two sets of five parallel lines at equal distance. Clearly,
i.e. = i.e. cos (2A + 3B) = 0
sin 3B cos 2 A lines 1, 2, m1, m3 form a squares whose diagonal's length is 2
So, the number of required squares = 3 × 3 = 9

since 0 < A, B <
4
5 
 0 < 2A + 3B <  2A + 3B =
4 2
65. (3)

 3 1  3 1
Sol. Point B  –
 , – , A (0, 1), D 
 , 
 2 2   2 2 

70. (2)
Sol. If the roots are x1, x2, x3, x4
then x1 + x2 + x3 + x4 = 4
Area (quad. z1 z2 z3 (–z2)) = AB × AD = AB x1  x 2  x 3  x 4
{ AD = 1}  =1
4
= 3  square of the area = 3 and x1x2x3x4 = 1
since A.M. = G.M. then
66. (3) x1 = x2 = x3 = x4 = 1
Sol. g(x) = 2 – x1/3 Let x1/3 = t so by theory of equations we get a = 6 and b = –4 only values
g(t) = 2 – t possible so a + b = 2.
Now f(2 – t) = –t3 + 5t – t2
71. (1)
= (2 – t)3 – 7(2 – t)2 + 11(2 – t) – 2
 f(t) = t3 – 7t2 + 11t – 2 x
Now f(x) = x – 7x2/3 + 11 x1/3 – 2 Sol. Put x = 1 in 2f(x) = f(xy) + f   .............(1)
y
14 11  1
f(x) = 1 – x–1/3 + x–2/3 = 0  
3 3 2f(1) = f(y) + f ............(2)
x–1/3 = 1, 3/11
y
Replace x by y and y by x in (1)
14 22
f(x) = x–4/3 – x–5/3 x=1 y
9 9 2f(y) = f(yx) + f   ..........(3)
f(x) < 0 x
 x = 1 is the point of local maxima (1) – (3)
Local maximum value of f(x) = 3
x    x  x
67. (0) 2{f(x) – f(y)} = f   – – f    2f   ..........(4)
Sol. f(x) = ax3 + bx2 + cx + d y
     y y
As eccentricities of a parabola and a rectangular hyperbola are
the roots of f(x) = 0 x
f(x) – f(y) = f   ...........(5)
y

f (1  h) – f (1)
lim = f(1) = 1
as a, b, c, d   h 0 h
f(1) must be equal to 0.
 f(1) = a + b + c + d = 0 f (1  h)
lim = 1 as f(1) = 0
68. (1)
h0 h
Sol. 1x + 2x + 3x + ...... + nx = (n + 1)x
f ( x  h) – f ( x )
x x x f(x) = lim
 1   2   n  h 0 h
  +  +......... +   =1
 n  1   n  1  n  1  h
Now drawing the graph of
f 1   1
= lim  x =
x x x
h 0 h x
 1   2   n 
f(x) =   +   +.........+   f(x) = log|x| + c
 n  1  n  1  n  1
f(1) = 0  c = 0
Which is stricity decreasing and g(x) = 1
f(e) = 1

72. (7)
Sol. n (S) = 6 × 6 × 6 = 216
also to get sum of '8' x1+ x2 + x3 = 8
where 1  xi  6
xi = ti + 1 0  t1  5
t1 + t2 + t3 = 5

RESONANCE SOL010513 - 6
 by fictious partition method number of solution of this equation is 3f1 = 4f2 = 12Hz  f1 = 4Hz & f2 = 3Hz.
7
C2 (A) |5f1 – 4f2| = |20 – 12| = 8 (r)
21 7 (B) 3f1  3f 2  12  9  3 (q)
n (E) = 21 P = =
216 72
(C) 9f1  8f 2  36  24  12 (s)
PAPER-2 (D) 5f1  5f 2  20  15  5 (t)
PART-I (Physics)
1. Two point charges q1 and q2 ................................. 8. A train is moving with a constant.............................
Sol. (A,B) The charge q3 must lie on the line (3x + 4y – 12 = 0) joining Ans. 3
charges q1 and q2 to be in electrostatic equilibrium.
 V  VO 
2. Two conducting plates A and B............................... Sol. f 'f  
Sol. (C,D) Let a charge q’ be present on the inner surface of plate  V  VS 
A so that on its outer surface the charge is (q 1 – q’).
Obviously a charge -q’ will get induced on the inner surface of  V  15 cos 45 
the plate B and a charge (q2 + q’) will move to its outer surface. =  f
With these charges, write the net electric field at a point inside  V  15 cos 45 
the plate and equate it to zero. This relation can be simplified to
get the value of q’ and hence the conclusions. f '  f  1.5kHz = 3/2kHz
3. A uniform rod AB of mass m...................................... 9. A man of mass m starts moving..................................
Sol. (B,C,D) Point A is constrained to move along circular path. Ans. 3m/s
Initial velocity of point A is zero.
 ac = 0 i.e. along the string (1) f
at  0 i.e. perpendicular to string (1) Sol. Magnification m  m = –2
3f
4. A hydrogen atom of mass.............................. f 
Sol. (A,D) From conservation of momentum 2
hf h Taking the direction in the right hand side Vim   m 2 Vom
mv  
c 
Assuming all the energy is taken by the photon. Vim 
 velocity of image w.r.t. mirror
3 3 E0 h
hf  E  E  V  Vom 
 velocity of object w.r.t mirror
4 0 4mc m
5. Charge +q is uniformly distributed................................  Vim  4u
Sol. (A,C) Energy conservation
mu u
1 2 1 2  kq  2 Vm    
 × 2 + kq = 0 + 0 + q ×  velocity of platform (minor)
mu + mu + q ×  m  2m 3
2 2  3R  6R
Vim  Vi  Vm
 kq 
  × 2 + kq
2 5kq2
 u= Vi 
 velocity of image w.r.t ground
R 2R 3mR
6. Column-I gives certain situations................................... u 13
 Vi =  4u   Vi   u
Ans. (A) – s, t ; (B) – p, s ; (C) – p, r ; (D) – q, r 3 3
Q V Vi = 3m/s
Sol. (A) E or E
A 0 d 10. A glass rod of rectangular cross-section................................
Ans. 2
for Q = const.
Sol. A ray entering through surface A and travelling along the inner
E = const.
side of the rod will be reflected by the outer side with the smallest
If V = const. and d increases.  E decreases (s, t)
angle  , at which the reflected ray is tangent to the inner side.
Q2 1
(B) U or U  CV 2
2C 2 1
If the plates are pulled apart, C decreases.
   critical  sin 1  
n
 Q = const.
U increases 1
for V = const. sin   n
U decreases. (p, s)
(C) On insertion of a dielectric, the capacitance of a capacitor R
always increases. (p, r) but sin   R  d
Q2 1
(D) U or U CV 2
2C 2 R 1
for Q = const.  
U = decreases
R d 3/ 2
for V = const
U increases. (q, r)
Rd 3
 
7. A closed organ pipe P1 .................................. R 2
Ans. (A) – r ; (B) – q ; (C) – s ; (D) – t
Sol. Let f1 and f2 be the fundamental frequencies of P1 and P2.

RESONANCE SOL010513 - 7
 d 1 R mu 2 3 3
  2  N=  mg
R 2 d R 2
R FMin  2N cos 300  mg
  2
 d min
3mu 2 9
=  mg  mg  FMin  1 newton
11. Figure shows the variation of................................ R 2
Ans. 2
Sol. For rectangular hyperbola 15. To reduce the light reflected by....................................
XY = constant Ans. 3
U  = constant 
n CVT  = constant Sol. 2d   2n  1 (n = 1, 2, 3,.....)
2
5 M  2n  1 
n R T  constant  d
2 V 4
5 VM For light of wavelength
P  constant  P = constant (isobaric process) d Layer
2 V 1  700nm
5 700 2100 3500 Glass
U BA  7  2  5J  nRT d1  , ,
2 4 4 4
2J  nRT  W  2J for light of wavelength  2  420nm
12. The potential energy function ................................... 420 1260 2100
Ans. 2 d2  , ,
Sol. The force acting on the particle can be given by 4 4 4
 U
F  6 î  4 ĵ 2100
r 2100 
 d min  7
Thus acceleration of this particle would be ax = 6ms-2 and ay = 4 4
4ms-2 4
when the particle crosses the 'x' axis
d min  300nm  3  107 m
1
8   4t2   t2 = 4  t = 2s
2
13. Two uniform rods tied together....................................... PART-II (Chemistry)
Ans. 3 16. (AC)
Sol. the FBD of any one rod is
T
2  R  320
Sol. V1 =
T  N ...(i) 4
mg = N ...(ii) N 2  R  640
Taking torque about point 'P' mg 37
0
V2 =
8
L N P V = 0
mg cos 37 0 = TL sin 37º so w = 0
2 H = nCp T

mg 4 2mg 7
 =2× × 2 ×320 = 4480 Cal
T= 2
2 3 3 (B) E = q + w
E = q = 3200 Cal
2mg
 mg    23 (D) E = nCV dT
3 5
=2× × 2 × 320 = 3200 Cal
14. A hollow cylinder of mass m = 1kg .................................. 2
Ans. 1
17. (ABD)
mV 2 3
Sol.  mg  N V O
R 2 N N
%s %s
P P
1 1 3 %s %s
mg mg
mV 2  mu 2  mgR O O O O
2 2 2
O O
Sol. O P P O P P
2 2 O O
mV mu
   3mg O O O O
R R
P P
mu 2 3
 3mg = mg  N O
R 2

RESONANCE SOL010513 - 8
 P–O–P bond length in P4O6 is more than P4O10
P4O6 due to the absence of  bond, p – d bond is not present  paramagnetic

18. (ABC) (iii) K4[Fe(CN)5O2]  paramagnetic

Sol. PQ = SR = PA and PR = PB
PT = PA + PB = 100 + 350 = 450 and PB = PºBXB (iv) K3[Co(CN)5O2]  paramagnetic
PB 350 7
X'B (vapour phase) = (v) [Fe(CN)5O2]5–  diamagnetic
PT = 450 = 9 350 = 500 XB

(vi) Na2[Fe(CN)5NO+]  diamagnetic

2 7 3
X'A = 1 – X'B = XA = 1 – =
9 10 10 (vii) K4[Co(CN)5O2]  diamagnetic
19. (ABC)
Sol. C4H8O
D.U. = 4 + 1 – 4 = 1
(viii)

CH2 =

 diamagnetic

(ix)

20. (AC)  paramagnetic

Sol. (i) + 26. (4)

Sol. Rate of reaction = K[A][B]
Case-1 [A] is in excess.
Rate of reaction = K'[B]
t7/8 = 3 t1/2
reaction is first order with respect to B.
Case-2 [B] is in excess.
Rate of reaction = K"[A]
t7/8 = 7 t1/2
reaction is second order with respect to [A]
(ii) + Rate of reaction = K [A]2 [B]1
Case-3 [B] is in excess.
Rate of reaction = (K[B]) [A]2
Rate of reaction = K"[A]2
+ C2H5OH
1 1
t1/2 =
K " C A = K[B][ A ]
21. (A–q, r, s,t), (B–p,r, s), (C–q, s,t), (D–q) (t1/2) [B] [A]=constant
Sol. Refer class notes. {(t1/2) [B] [A]}exp. (ii)= {(t1/2) [B] [A]}exp.(iii)
10 × 400 × 3 = t1/2 × 800 × 6
22. A - t ; B - s ; C - r ; D - q. t1/2= 2.5 min.
t7/8 = 17.5 min.
23. (6) Case-4 [A] is in excess.
Sol. PCl5, SF4, ClF3, [SF5]+, [ClF4]+, [XeF3]+. Rate of reaction = [K[A]2] [B]1
PCl5  sp3d ln 2
SF4  t1/2 =
ClF3 sp3d [XeF2 sp3d K[ A ]2
[SF5]+ sp3d
[ClF4]+  sp3d ln 2
[XeF3]+ sp3d t1/2 [A]2 = = constant
K
24. (5) (t1/2 [A]2)exp. (i)= ([t1/2] [A]2)exp.(iv)
Sol. H6P6O18, P4O10, Na2B4O5(OH)4.8H2O, K2S2O7, K2Cr2O7.
30 × (500)2 = t1/2 × (250)2
t1/2= 120 min.
25. (4)
t7/8 = 360 min.
Sol. If the central metal ion having t2g6 egº configuration than Fe and Co
show +2 and +3 oxidation state respectively.
27. (5)
In the presence of O2– complex show paramagnetic behaviour.
Sol. Since value of equilibrium constant is very high, reaction is com-
(i) K4[Fe(CN)6]  diamagnetic pletely shifted forward. So total equilibrium pressure is caused
by C(g) & D(g) only.

 PC  PD  10
so,  = = 5.
 2  2
(ii)

RESONANCE SOL010513 - 9
28. (3) PART-III (Mathematics)
31. (ABC)
Sol. Plane P1 = 2(x – 1) – 2(y + 1) + 2(z – 1) = 0  x – y + z = 3
OH Plane P2 = 2(x – 1) – 3(y – 2) – 2(z – 1) = 0
Sol.  
  2x – 3y – 2z + 6 = 0
so P1 + P2 = 0  (x – y + z – 3) + (2x – 3y – 2z + 6) = 0
(1 – 1 – 3) + (2 + 2 + 6) = 0
3
=
+ 10
10(x – y + z – 3) + 3(2x – 3y – 2z + 6) = 0
16x – 19y + 4z – 12 = 0
put z = 0 in P1 and P2
x – y = 3, 2x – 3y = – 6
By solving we get x = 15, y = 12, z = 0

32. (AD)
+ r
Sol. (A) If R is its radius then, sin (/n) =
R–r

(y = 3)

29. (4)

I / OH
2  Na metal  R = r(1 + cosec (/n))
Sol. C9H12O4   CHI3 + y    2H2  + salt
H 2
DU = 4 (No. of active H = 4)   
 sin  cos 
 2 2
Since  1 + cosec 
sin 

33. (AD)
 Sol. f(x) = max {|2 – x|, 2 – x3}, then
2  I / OH f(x) is continuous  x  R
 
H and f(x) is non-differentiable at x = ±1, 0, 2
f(x) = max {|2 – x|, 2 – x3},

COOH
| Na metal
HOOC — C — COOH + 4CHI3    2H2  + C(COONa)4
|
COOH
Ans. 4 moles of CHI3 formed.

30. (6)

Ans. (A and D are correct)

CH3MgBr ( excess) 34. (A)
Sol.      x /2
( ether ) d d
Sol. f(x) =   
cos  sin 
0 x

1 1
f(x) = –
cos x sin x
sin x – cos x
=
sin x cos x

f(x) change sign –t0 + at x =
4

so f(x) takes minimum value at x =
Ans. 5 molecules of MeMgBr. 4

RESONANCE SOL010513 - 10
 /4 /2 1  i 3
(C) z = ±
f(x) =  sec  d   cos ec d 2
0 /4
2 
 Principal argument of z is or –
= nsec   tan  /4
+ ncos ec – cot  /2 3 3
0 /4
  1 i 3 
= n  2  1 – n (1  0)  n1 – n ( 2 – 1) (D) z = ± 

2


 
 2  1
n   2 2 
=  2 – 1  = n
 
 2  1 = 2n ( 2  1)  Principal argument of z is –
3
or
3
.

37. (A) - s, (B) - p (C) - t, (D) - p

35. (ABCD) x
Sol. y = x1/3(x – 1) x( 4 – x )
dy 4 1/3 1 1 1
Sol. ( A) I=  xe
4– x
dx ........(i)

= x – · 2/3  [4x – 1]
dx 3 3 x 3x 2 / 3 Using IV property
x
hence f is for x >
1 ( 4 – x )x
4
I=  (4 – x ) e
4– x
dx ........(ii)

Adding we get
x
( 4 – x )x
2I =  4e dx
1 4– x
and f for x <
4 x
x( 4 – x )
4 1/ 3 1 – 3
x – x
2 2I = 4(2) (Given e dx  2 )
f(x) = (non existent at x = 0 , vertical tangent) 4– x
3 3 I=4
4 1 1 2 1
n o w f(x) = 2 / 3 + · · 5/3 102
9 x 3 3 x –1

2  1 2  2x  1
(B) k =  [ cot
0
x ] dx
= 2  x    
9x 2 / 3   9x 2 / 3  x 

cot 1 102 cot 1

–1 –1
 f(x) = 0 at x = –
1
(inflection point) =  [ cot x ] dx +  [ cot x ] dx =  1 dx  0
2 0 cot 1 0
graph of f(x) is as
1
k= x cot
0
1
= cot1
1 [k] = [cot1] = 0
4/3 3 3/7 3 4/3
A=
 x – x1 / 3 dx 
 x – x  3
7 4  3
0 0 (C) I=  ( x – 1)  ( 4 – x )3  x cosx dx  ........(1)
2
3 3 4–7 9
= – =3   (D) 3
7 4 28 28 I = 3
 ( 4 – 5  x )3  (5 – x ) cos( )(5 – x ) dx
 (4 – 3)
2

36. (A)  (q, r), (B)  (p, s), (C)  (p, r), (D)  (q, s) 3
3
1 i 3 I= –  (4 – 3)  ( x – 1)3  5 – x cos x dx 
Sol. (A) z =
2 2
(1) + (2)
 
 Principal argument of z is or – 3
3 3
 1 i 3
2I =  ( x – 5  x ) cos x dx
2
(B) z =
2 3
3
 sin x  sin x
 Principal argument of z is
2
or –
2 2I =  ( 2x – 5)
  2
 – 2 
dx
3 3 2

RESONANCE SOL010513 - 11
 Now from (1)
3 3
2 2  cos x  
= (0 – 0) – sin dx
 =    2 | b |2
    2 (1) ( | b | ) – =8
2 2

2 2 | b |2
= 2
cos 3 – cos 2 = – 1 – 1 =8
 2 2

4 2 | b |= 4
=– 2  I= –  |2 | = 2
 2
10 2 42. (0 )
(D)  sgn (sin x ) dx = 5 sgn (sin x ) dx
 xf ( x )
0 0 Sol. lim f(x) = xlim = lim (f(x) + xf(x)) = a
x   x x 

1 2   lim xf(x) = 0
5  1dx  (–1) dx 
  1 2 x 
=
  = 5x 0  5– x 1 = 5 – 5 = 0
0 1  x 2f ' (x)
Now lim xf(x) = lim = lim (2xf(x) + x2f(x)) = 0
38. (2) x  x  x x 
Sol. The number of integers in [– 5, 30] is 36  lim x2 f(x) = 0.
y is positive for all x. x 
Discriminant < 0
4(a + 4)2 – 4(64 – 5a) < 0 43. (9 )
a2 + 13a – 48 < 0
(a + 16) (a – 3) < 0 dx x 2007  1 – x 2007
a (– 16, 3) Sol.  =  x( x 2007
  dx
But a  [– 5, 30]  1) x( x 2007  1)
possible integral values satisfying  are – 5, – 4, – 3, – 2, – 1,
0, 1, 2, = 8 1 2006
 – x

 dx
8

2 =   x 1  x 2007



Probability =  = 2
36 9
1
39. (3 ) = nx – ln (1 + x2007)
2007
Sol. sin2x + sin22x – sin23x – sin24x = 0
or (sin2x – sin23x) + (sin22x – sin24x) = 0  x 2007
sin 2x [sin4x + sin6x] = 0
nx 2007 – n(1  x 2007 ) 1 
C
 =  n  2007 
 2 sin2x sin 5x cos x = 0 2007 2007  1 x 
 sin2x = 0or sin5x = 0or cosx = 0
p + q + r = 6021 = 9
n n 
 x= or x= or x = (2n + 1) 44. (1 )
2 5 2
1 10 102 103 10 2n
Sol. 2n 2n 2n
  n – n . C1 + n . C2 – n . C3 + ...... +
solutions in the interval  0,
2 
81 81 81 81 81n

1
  2 = [1 – 10. 2nC1 + 102 . 2nC2 – 103. 2nC3 + .............+ 102n ]
are x = , and 81n
2 5 5
Hence 3 solutions. 1
= [2nC0 – 10. 2nC1 + 102 . 2nC2 – 103. 2nC3 + .............+ 102n. 2nC2n]
40. (4)
81n
Sol. 77 ends with 01
 74k + r ends with same two digit number as does 7r
1 1 1
2n 2n
= n [1 – 10] n (–9) = . 81n = 1
therefore the given number ends with the same two digits as 73. 81 81 81n

45. (2 )
41. (4) Sol. Equation of directrix is x = – 1 +  but equation of directrix is x =
     1 (given)
Sol. | a | = 1 , a.(b  (a  b)) = 8
 = 2.
       point on intersection of 2y = – 4x + 11 and x = 1 is (1, 7 / 2)

a. (b. b) a – (a. b ) b  8   tangent at Q passes through (1, 7 / 2) and is perpendicular to
    2y = – 4x + 11
| a |2 | b |2 – (a. b)2 = 8 .........(1)  equation of the tangent is x – 2y + 6 = 0
     x2 = 6
since a. b = | a || b | cos The point (6,6) lies on the parabola.
 (6 – )2 = 4 (6 – 2) = 16
 = 2,10
  1 
= (1) | b |  
 2

  2 | b |2
(a. b) =
2

RESONANCE SOL010513 - 12