The document defines the anti-sealing effect as consisting of three elements: 1) proper sealing cannot be achieved even at high temperatures, 2) sealability can be restored by cleaning with a polar solvent, and 3) infrared spectroscopy shows polyurea peaks on the seal surface. The anti-sealing effect is caused by monomeric MDI in adhesives migrating through polyethylene film and reacting with water and carbon dioxide on the surface to form polyurea. Experience shows adhesives with monomeric MDI can cause this effect under unfavorable conditions like mix ratio deviations or with certain film formulations.
Original Description:
Análisis del problema de antisello en empaques laminados
The document defines the anti-sealing effect as consisting of three elements: 1) proper sealing cannot be achieved even at high temperatures, 2) sealability can be restored by cleaning with a polar solvent, and 3) infrared spectroscopy shows polyurea peaks on the seal surface. The anti-sealing effect is caused by monomeric MDI in adhesives migrating through polyethylene film and reacting with water and carbon dioxide on the surface to form polyurea. Experience shows adhesives with monomeric MDI can cause this effect under unfavorable conditions like mix ratio deviations or with certain film formulations.
The document defines the anti-sealing effect as consisting of three elements: 1) proper sealing cannot be achieved even at high temperatures, 2) sealability can be restored by cleaning with a polar solvent, and 3) infrared spectroscopy shows polyurea peaks on the seal surface. The anti-sealing effect is caused by monomeric MDI in adhesives migrating through polyethylene film and reacting with water and carbon dioxide on the surface to form polyurea. Experience shows adhesives with monomeric MDI can cause this effect under unfavorable conditions like mix ratio deviations or with certain film formulations.
An adhesive-linked „anti-sealing effect“ has to consist of the following three elements:
1. Proper sealing cannot be achieved, not even when
acceptable high seal temperatures are being applied.
2. The sealability can be restored by cleaning the film surface
with a polar solvent.
3. The infrared spectrum of the seal layer surface clearly
shows polyurea peaks. Cleaning the surface with polar solvent Polyurea- peaks
Peak at 1645 cm-1 is covered by slip
Polyurea- peaks Polyurea- peaks Polyurea- peaks Causes of the anti-sealing-effect The „anti-sealing effect“ has so far only been noticed with adhesives containing monomeric diphenylmethane diisocyanate (MDI). It is attributed to the following process:
Monomeric MDI migrates through the polyethylene
film. It reacts on its way or on the surface with water. Carbon dioxide splits off and the corresponding amine (MDA) is formed. This reacts with MDI to form urea/polyurea. Reaction Isocyanate + Water R1 N H O NH O R1 C H C H O O
Isocyanate Water Carbamic acid
R1 NH2 CO2
Amine Carbon dioxide
Reaction Isocyanate + Amine
R1 N NH NH R 1 NH2 R1 C R1 C
O O
Isocyanate Amine Urea
Some experiences of the last years
Adhesives containing monomeric MDI may cause an anti-
sealing effect under unfavourable circumstances:
* deviation in mix ratio
* higher risk with films containing: VA high slip white pigments