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JEE (Advanced)-2019
PAPER – 1
2. A, B, C, D
Sol. Let potential of point A is x and potential of point B is zero. Consider charge flown through 3V
battery is q0.
2 3 x q0 0 x 2 0 …(1)
q0 x 3 1 2 x 3 2 0 …(2)
3. A, B, C
Sol. In figure-1
1 1 1
v u f
1 1 1
v 60 30
V = – 60
v
Hence m 1
v
In figure-2, images will not separated.
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AITS-OT-(Paper-1)-PCM(Sol.)-JEE(Advanced)/19 2
4. A, B
Sol. If v a 0 , then there must be a component of a along v
If r v 0 , then there must be a component of v along r
5. B, C, D
Sol. Phase difference between two particles in standing wave is either zero or at any instant of time.
Potential energy depends upon strain. Particle near to nodes will experience more strain.
6. A, B, C
Sol. a0 (2giˆ gj) ˆ
FB V(a0 g) 2Vg(iˆ ˆj)
Fnet FB mg 2Vg(iˆ ˆj) 0 Vgjˆ
2 ˆ ˆ
anet g(i j) gjˆ
0
arelative anet a0
7. C
8. C
Sol. (for Q. 7 to Q. 8)
ft = mg = 8N …(i)
f f = I
11
rad/s2 …(ii)
7
v 22
ad/sec …(iii)
R 7
2 02 2
= rad …(iv)
= 0 + t
t = 2 sec …(v)
1
y 2 1m …(vi)
2
1
x R m …(vii)
2
9. C
10. B
Sol. (for Q. 9 to Q. 10)
P1(V1) = P2(V2)
4/3
V 50
P2 = P1 1 21
V2 400
1
21
16
= 1.3125 atm
Work done =
P1V1 P2 V2
=
21 50 1.3125 400 105 10 6 = 157.5 Joule
1 4
1
3
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3 AITS-OT-(Paper-1)-PCM(Sol.)-JEE(Advanced)/19
SECTION – D
11. 00000.88
dp P m
Sol. F u.
dt t t
200
2 2.2
1000
= 0.88 Newton
12. 00031.63
1 2 GmM GmM
Sol. mv – =
2 r 2a
2 1
v 2 GM
r a
2 1
= 6.67 10–11 2 1030 1011 =10.005 108
2 4
v = 31.63 km/sec
13. 00007.10
Sol. 1 MSD = 1 mm
1 VSD = 0.9 mm
L.C. = 0.1 mm
ve error = 4 0.1 mm = 0.4 mm
Reading = 6 mm + 7 0.1 mm = 6.7 mm
Diameter = 6.7 + 0.4 = 7.1 mm
14. 00003.00
R
Sol. q0 dv 0 r n 4 r 2 dr
0
R/2
n
q dv 0 r .4r 2 dr
0
kq0 kq
16.
R2 R
2
2
So n=3
15. 01800.00
Sol. x 2 16y Q
16dy
2x
dx 20 3 30 m
dy x 60°
3 P
dx 8
10 3
60
12 m
W K
WF Wff Wg WN 0
WF Wff Wg 8 3
mg 8 3 10 3 mg 42
= 1800 J
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AITS-OT-(Paper-1)-PCM(Sol.)-JEE(Advanced)/19 4
16. 00256.00
1
Sol. a 4
n
where, a is acceleration of electron and ‘n’ is no. orbits.
17. 00033.33
100 v
Sol. Acceleration of container a
200 t
v 100
dv dt
100 v 200 t
0 0
100
v m/ s.
3
18. 00001.33
I1 mL2
Sol. T1 2 , I1 mL2
mgd 3
2
I2 mL2 m L / 2
T2 2 , I2 mL2
mgd 3 6
T1 I 4 6
1 ,
T2 I2 3 11
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5 AITS-OT-(Paper-1)-PCM(Sol.)-JEE(Advanced)/19
Chemistry PART – II
SECTION – A
19. A, B
Sol. In first molecule, lone pair of electrons lie in equatorial position, hence decreases 2 more rapidly
the 2 . In second molecule, -electron cloud lie closer to axial bonds and pushes them more, so
1 1 .
20. A, B, D
Sol. Since AB is an isobaric process, so
VB TB T
2 B TB 600K
VA TA 300
WABCDA WAB WBC WCD WDA
WAB nRT 1200 cal
VC V
WBC 2.303nRTB log 2.303nRTB log B as VC VD
VB VD
VB VA
WBC 2.303 2 2 600 log
VA VD
= 2.303 × 2 × 2 × 600 × log 2/4
= - 1663.68 cal.
WCD 0
VD
WD A 2.303nRTA log
VA
= 2.303 × 2 × 2 × 300 × log4
= 1663.68 cal.
WA BCD A 1200 1663.68 0 1663.68
= - 1200 cal
21. A, B, C, D
Sol. A → Curtius degradation type reaction
B → Hydration + deprotonation + tautomerisation
C → Friedel-Crafts reaction followed by benzylic acid rearrangement
D → Baeyer-Villiger + Perkin condensation reaction.
22. A, B, C, D
Sol. All substrates give the same major product which is given below
OH
23. A, B, C, D
Sol. Coordination number of Al in AlCl3(s) is 6.
Anhydrous AlCl3 is covalent but becomes ionic when dissolved in water.
BI3 is the strongest Lewis acid among all boron halides.
All BX3 are covalent in nature.
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AITS-OT-(Paper-1)-PCM(Sol.)-JEE(Advanced)/19 6
24. A, C, D
Sol.
CuCl2 O C NH2
2 Dichloridodicarbamidocopper II
2
25. C
Sol.
2
1 1s2
1s1
3 4 5 6 7 8
[ ] 2s1 [ ] 2s2 2s22p1 2s22p2 2s22p3 2s22p4
9
[ ] 3s1 10 11 12 13 14
[ ] 3s 2 3s23p1 3s23p2 3s23p3 3s23p4
15 16 17 22 23 24
18 19 20 21
[ ] 4s1 [ ] 4s2 4s 3d1
2 2 4 1 2 4 2 4s23d44p3 2 4 4
4s2, 3d2 4s , 3d3
2 2 4
4s , 3d 4s 3d 4p 4s 3d 4p 4s 3d 4p
26. C
Sol. Lewis structures 3 – 1; 1 – 4 – 1;
1
5 ; 6 ; 7 1
1 1 1
1
27. D
28. C
Sol. (for Q. 27 to Q. 28)
(i) The solid must contain Na and I. The yellow colouration of the flame indicates the presence of
Na+ ion; a yellow silver salt that is dissolved only by strong complexing agent such as CN or
S2 O 32 must be AgI.
(ii) Reaction (i) to (iv) indicates a sodium salt of an oxygen containing acid containing iodine.
Both SO2 and I– are oxidized, while in the first case I is formed with an intermediate of I2 or
I 3 (brown solution) and in the second I2 or ( I 3 ) is formed. As the solution is neutral NaIO3 or
NaIO4 come into consideration.
(iii) Conditions given in observation(v) proves that solid (x) is NaIO4.
2
1 mole of NaIO4 = 213.90 g NaIO4 = 8 moles of S2 O3 .
0.1000 8
0.1000 g NaIO4 3.740 10 3 mol of S 2O32
213.90
IO4 7I 8H
4I2 4H2O
SECTION – D
29. 00006.11
30. 00002.20
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7 AITS-OT-(Paper-1)-PCM(Sol.)-JEE(Advanced)/19
Sol. O O O
OH O
N OH O O
C C
C OH
P Q R S
31. 00003.50
Sol. PV = RT (for 1 mole of ideal gas)
PV = R(K + V2)
RK
P RV
V
For minimum pressure
dP d2P
0 and 2 ve
dV dV
So, Pmin 2R K
32. 00000.61
Sol. H2O
s
cos104.5o s 0.20
s 1
So, fraction of s-character of lone pair in H2O = 0.30
Similarly, fraction of s-character of lone pair in NH3 = 0.31
33. 00001.25
Sol. x = 5 and y = 4
Only a, b, d, e and h will form buffer.
34. 00002.50
Sol. O S O O O O
O S S ; S ; S S O ; O S S O;
O O O
O O
O O O O O O
O S S O ; O S O S O; O S ;O O S O
O O O O O O
x = 5, y = z = 1
35. 00001.80
Sol. NH2
O
CH CH C CH3
N CH3
(A) (B)
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AITS-OT-(Paper-1)-PCM(Sol.)-JEE(Advanced)/19 8
36. 00007.50
Sol. Let, x ml of 2.0 M NaOH solution be added, then
H3PO 4 NaOH NaH2PO 4 H2O
millimoles 10 2x 0 0
0 2x 10
NaH2PO 4 NaOH Na2HPO 4 H2O
10 2x 10 0
10 2x 10 0 2x 10
= 20 – 2x
2x 10
So, 7.2 7.2 log , on solving x = 7.5
20 2x
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9 AITS-OT-(Paper-1)-PCM(Sol.)-JEE(Advanced)/19
37. A, B
Sol. x = 4k + 1, y = 2m (k1m N)
yx = (2m)4n + 1 (it is divisible by 8)
y 2m
x = (4n + 1) (it leave remainder 1)
38. A, C, D
Sol. As f(x)f(x) > 0 x R
For y = f(x)f(x); y = (f(x))2 + f(x)f(x) > 0
If f(x)0 < 0 then f(x0) < 0
39. B, D
Sol. If it is parallelogram z1 + z3 = z2 + z4 = 0 (in some order)
d
If it is rhombus then area is 2|z1||z2| where |z1|2|z2|2 =
a
40. A, C, D
Sol. y = fk(x) is periodic with period 10 and fk(f4k + 1(x) – x) = 0
41. B, C, D
Sol. R.H.D. at x = –1 is (p – m2) where n = 2m or 2m – 1
L.H.D. at x = –1 is (m2 – p) for differentiability m2 = p
42. A, C
Sol. x3 – 3x + 2 = 2; x = 0, 3
3(f 2(t) – 1)f(t) = 1
43. B
Sol. x2 + y2 = r2 and (x – 1)2 + (y – 5)2 = 4 must be orthogonal
44. C
Sol. OP·OP = r2
Using P(r1 cos , r1 sin )
Locus of P is
mr 2 r2
x 2 y2 x y 0
c c
45. D
46. A
Sol. (for Q. 45 to Q. 46)
3 2
ax + bx = 8a + 2b (x – 2)(ax + 2ax + 4a + b) = 0
3
D = 0 3a + b = 0 as a = 1 f(x) = x – 3x
Similarly for g(x) = 4x + ax + bx + c, f(x) = (4x3 – 3x) and f(1) = 1
3 2
SECTION – D
47. 00010.00
Sol. Minimum will occur at z = 0
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AITS-OT-(Paper-1)-PCM(Sol.)-JEE(Advanced)/19 10
4 2019
1
1010 10
k 0 r 0
48. 00009.00
Sol. Let ABCD have coordinates P
O, (i + j), (j + k), (i + k) respectively
d1 d1
cosec 3
d d
Where is angle between AB and normal of BCD
B Q
49. 00002.25
3 3
Sol. 4f (x) = f (2x + 1) + c
1 3 5
By taking x , , and 6, we get
8 4 2
3 5 3 5
f 3 c 4 , f 3 c 4f 3 , 4f 3 f 3 6 c
4 2 4 2
8 8
So, we c i.e., 4f 3(x) = f 3(2x + 1) +
3 3
50. 00002.00
Sol. The given equation reduces to 4f2(x) + x2 = 9, an ellipse.
As in the figure it has two solutions
51. 00035.32
4 k
C1 4 C2 2! 6 C2k 2 2k 2! 10 2k! 8
Sol. P x and P(d) = 0.4
k 1 10! 21
52. 00480.00
1 eto e to e to e to to P0(to)
Sol. ydx
2 2 2 0
2
1 2to
e e 2to
to e t e t
dt
to
240 O
8 0
4 2
to = 480
53. 00003.00
Sol. I = cos cos + sin2 sin – cos2 sin cos cos + sin sin = cos( – )
– = 0 & cos = 0, sin = 1
===
2
54. 57060.00
Sol. For point of intersection we take say two points A and B, from each we can draw 9C2 lines cut of
which 8C2 are parallel. So total number of intersection points are
10
2
C2 36 28 57060
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