Professional Documents
Culture Documents
ON
HIMANSHU SINGH
Of
4th Year, B.Tech.
Chemical Engineering Department
Submitted To-
Er. Dhananjay Singh
And
Durgesh Pratap
We express our heartfelt gratitude to Mr Durgesh Pratap Singh for their expert guidance
constant inspiration which made possible the compilation of the report. Indeed we consider
ourselves fortunate to have worked under their supervision. He has inspired us at all stages
and spared invaluable time for discussion, whenever we needed it.
HIMANSHU SINGH
WW
CONTENTS
1. Introduction………………………………………………………………………….
2. Metal Matrix Composites…………………………………………………………….
3. MMC Properties Compared to Other Structural Materials……………………………
A broad definition of composite is: Two or more chemically distinct materials which when
combined have improved properties over the individual materials. Composites could be
natural or synthetic. Wood is a good example of a natural composite, combination of
cellulose fiber and lignin. The cellulose fiber provides strength and the lignin is the "glue"
that bonds and stabilizes the fiber. Bamboo is a very efficient wood composite structure. The
components are cellulose and lignin, as in all other wood, however bamboo is hollow. This
results in a very light yet stiff structure. Composite fishing poles and golf club shafts copy
this natural design. The ancient Egyptians manufactured composites! Adobe bricks are a
good example. The combination of mud and straw forms a composite that is stronger than
either the mud or the straw by itself.
Composites are combinations of two materials in which one of the material is called the
reinforcing phase, is in the form of fibers, sheets, or particles, and is embedded in the other
material called the matrix phase.
Typically, reinforcing materials are strong with low densities while the matrix is usually a
ductile or tough material. If the composite is designed and fabricated correctly, it combines
the strength of the reinforcement with the toughness of the matrix to achieve a combination
of desirable properties not available in any single conventional material.
The essence of the concept of composites is that the load is applied over a large surface area of the
matrix. Matrix then transfers the load to the reinforcement, which being stiffer, increases the
strength of the composite. It is important to note that there are many matrix materials and even
more fiber types, which can be combined in countless ways to produce just the desired properties.
Composites are broadly known as reinforced plastics.
Metal matrix composites (MMCs) usually consist of a low-density metal, such as aluminum
or magnesium, reinforced with particulate or fibers of a ceramic material, such as silicon
carbide or graphite. Compared with unreinforced metals, MMCs offer higher specific
strength and stiffness, higher operating temperature, and greater wear resistance, as well as
the opportunity to tailor these properties for a particular application. However, MMCs also
have some disadvantages compared with metals. Chief among these are the higher cost of
fabrication for high-performance MMCs, and lower ductility and toughness. Presently,
MMCs tend to cluster around two extreme types. One consists of very high performance
composites reinforced with expensive continuous fibers and requiring expensive processing
methods. The other consists of relatively low-cost and low-performance composites
reinforced with relatively inexpensive particulate or fibers. The cost of the first type is too
high for any but military or space applications, whereas the cost/benefit advantages of the
second type over unreinforced metal alloys remain in doubt.
A metal matrix composite system is generally designated simply by the metal alloy
designation of the matrix and the material type, volume fraction and form of the ceramic
reinforcement.
MMCs differ from other composite materials in several ways. Some of these general
distinctions are as follows:
1. The matrix phase of an MMC is either a pure or alloy metal as opposed to a polymer or
ceramic.
2. MMCs evidence higher ductility and toughness than ceramics or CMCs, although they
have lower ductility and toughness than their respective unreinforced metal matrix alloys.
3. The role of the reinforcement in MMCs is to increase strength and modulus as is the case
with PMCs. Reinforcement in CMCs is generally to provide improved damage tolerance.
4. MMCs have a temperature capability generally higher than polymers and PMCs but less
than ceramics and CMCs.
5. Low to moderately reinforced MMCs are formable by processes normally associated with
unreinforced metals.
The metal matrix composites offer higher modulus of elasticity, ductility, and resistance to
elevated temperature than polymer matrix composites. But, they are heavier and more
difficult to process
Fig. 2 : Typical MMC’s with their applications
MMCs offer improved elevated-temperature strength and modulus over both PMCs and
metals.
Reinforcements make it possible to extend the useful temperature range of low density metals
such as aluminum, which have limited hightemperature capability. MMCs typically have
higher strength and stiffness than PMCs at 200 to 300° C (342 to 5720 F), although
development resins with higher temperature capabilities may be eroding this advantage. No
other structural material, however, can compete with ceramics at very high temperature.
Fiber-reinforced MMCs experience matrix/reinforcement interface reactions at high tempera-
tures. In addition, the transverse high-temperature strength of fiber-reinforced MMCs is only
as good as that of the matrix metal, since mechanical properties in the transverse direction are
dominated by the matrix and the fiber/matrix interface.
3.3Wear Resistance
Wear resistance of MMCs is excellent compared to that of monolithic metals and PMCs,
owing to the presence of the hard ceramic reinforcements. For instance, in one test, the
abrasive wear of 2024 aluminum under a 1 kilogram load was shown to be 6 times greater
than the wear of the same alloy containing 20 percent volume fraction of silicon carbide
whiskers.8 An alumina-silicfiber-reinforced aluminum piston used in Toyota automobiles
demonstrated an 85 percent improvement in wear resistance over the cast iron piston with
nickel insert used previously.
There is a wide variation in fracture toughness among MMCs, although it is generally lower
than that of the monolithic metal. Fracture toughness can vary between 65 and 100 percent of
the fracture toughness of the monolithic metal alloy.Lower toughness is a trade-off for higher
strength and stiffness. Particulate-reinforced MMCs have a lower ultimate tensile strain than
the unreinforced metals which may be important in some applications. This brittleness can
complicate the design process and make joining more difficult as well. Comparison to PMCs
is difficult, because the toughness of PMCs is very temperature-dependent.
3.5Thermal Properties
The introduction of silicon carbide particulate into aluminum results in materials having
lower coefficients of thermal expansion, a desirable property for some types of applications.
By choosing an appropriate composition, the coefficient of thermal expansion can be near
zero in some MMCs. MMCs also tend to be good heat conductors. Using high thermal
conductivity graphite fibers, aluminum-matrix or copper-matrix MMCs can have very high
thermal conductivity, compared with other types of composites.
4. Classification of MMC
Metal matrix composites can be classified in various ways. One classification is the
consideration of type and contribution of reinforcement components in particle-, layer-, fiber-
and penetration composite materials. Fiber composite materials can be further classified into
continuous fiber composite materials (multi- and monofilament) and short fibers or, rather,
whisker composite materials.
5. Discontinuous Reinforcement
There are two types of discontinuous reinforcement or MMCs: particulate and whiskers. The
most common types of particulate are alumina, boron carbide, silicon carbide, titanium
carbide, and tungsten carbide. The most common type of whisker is silicon carbide, but
whiskers of alumina and silicon nitride have also been produced. Whiskers generally cost
more than particulat. For in stance, silicon carbide whiskers cost $95 per pound, whereas
silicon carbide particulate costs $3 per pound. Cost projections show that although this
difference will decrease as production volumes increase, particulate will always have a cost
advantage.
In terms of tailorability, a very important advantage in MMC applications, particulate
reinforcement offers various desirable properties. Boron carbide and silicon carbide, for
instance, are widely used, inexpensive, commercial abrasives that can offer good wear
resistance as well as high specific stiffness. Titanium carbide offers a high melting point and
chemical inertness which are desirable properties for processing and stability in use.
Tungsten carbide has high strength and hardness at high temperature. In composites, a
general rule is that mechanical properties such as strength and stiffness tend to increase as
reinforcement length increases.Particulate can be considered to be the limit of short fibers.
Particulate-reinforced composites are isotropic, having the same mechanical properties in all
directions.
In principle, whiskers should confer superior properties because of their higher aspect ratio
(length divided by diameter). However, whiskers are ‘brittle and tend to break up into shorter
lengths during processing. This reduces their reinforcement efficiency, and makes the much
higher cost of whisker reinforcement hard to justify. Development of improved processing
techniques could produce whisker-reinforced- MMCs with mechanical properties superior to
those made from particulates. Another disadvantage of using whisker reinforcement is that
whiskers tend to become oriented by some processes, such as rolling and extrusion,
producing composites with different properties in different directions (anisotropy)
Anisotropy can be a desirable property, but it is a disadvantage if it cannot be controlled
precisely in the manufacture of the material. It is also more difficult to pack whiskers than
particulate, and thus it is possible to obtain higher reinforcement: matrix ratios (fiber volume
fraction, v/o) with particulate. Higher reinforcement percentages lead to better mechanical
properties such as higher strength.
6. Continuous Reinforcement
In fiber reinforcement, by far the most common kind of continuous reinforcement, many
types of fibers are used; most of them are carbon or ceramic. Carbon types are referred to as
graphite and are based on pitch or polyacrylonitrile (PAN) precursor. Ceramic types include
alumina, silica, boron, alumina-silica, alumina-boriasilica, zirconia, magnesia, mullite, boron
nitride, titanium diboride, silicon carbide, and boron carbide.
All of these fibers are brittle, flaw-sensitive materials. As such, they exhibit the phenomenon
of size effect i.e., the strength of these fibers decreases as the length increases. Fiber/matrix
interface coatings offer another
dimension of tailorability to MMCs. Coatings are very important to the behavior of MMCs to
prevent undesirable reactions, improve the strength of the fibers, and tailor the bond strength
between fiber and matrix. A reaction barrier is needed for some fiber/matrix combinations,
particularly when the composite is exposed to high temperatures in processing or service. For
example, boron fiber can be coated with boron carbide and silicon carbide reaction barriers to
prevent diffusion and chemical reactions with the matrix that decrease the strength of the
composite.
Alumina fibers can be given a surface coating of silica to improve tensile strength. Coatings
can also be used to tailor the bond strength between fiber and matrix. If adhesion between
fiber and matrix is too good, cracks in the matrix propagate right through the fibers, and the
composite is brittle. By reducing the bond strength, coatings can enhance crack deflection at
the interface, and lead to higher energy absorption during fracture through fiber pullout
mechanisms. Sometimes a coating is needed to promote wetting between the matrix and the
fiber, and thereby achieve a good bond. Graphite can be coated with titanium diboride in
order to promote wetting. processing techniques, as well as coatings, can be used to control
deleterious fiber/matrix interactions. The application of pressure can be used to force intimate
contact between fiber and matrix and thus promote wetting; squeeze casting is one process
that does this. A less common type of continuous reinforcement is wire reinforcement. Wires
are made of such metals as titanium, tungsten, molybdenum, beryllium, and stainless steel.
Such wires offer some tailorability for certain niche applications; for example, tungsten wire
offers good high-temperature creep resistance, which is an advantage in fighter aircraft jet
engines and other aerospace applications.
Metal matrix composite materials can be produced by many different techniques. The focus
of the selection of suitable process engineering is the desired kind, quantity and distribution
of the reinforcement components (particles and fibers), the matrix alloy and the application.
By altering the manufacturing method, the processing and the finishing, as well as by the
form of the reinforcement components it is possible to obtain different characteristic profiles,
although the same composition and amounts of the components are involved. The production
of a suitable precursor material, the processing to a construction unit or a semi-finished
material (profile) and the finishing treatment must be separated. For cost effective reasons
prototypes, with dimensions close to the final product, and reforming procedures are used,
which can minimize the mechanical finishing of the construction units.
In general the following product engineering types are possible:
• Melting metallurgical processes
– infiltration of short fiber-, particle- or hybrid preforms by squeeze casting, vacuum
infiltration or pressure infiltration
– reaction infiltration of fiber- or particle preforms
– processing of precursor material by stirring the particles in metallic melts, followed
by sand casting, permanent mold casting or high pressure die casting.
• Powder metallurgical processes
– pressing and sintering and/or forging of powder mixtures and composite
powders
– extrusion or forging of metal-powder particle mixtures
– extrusion or forging of spraying compatible precursor materials
• Hot isostatic pressing of powder mixtures and fiber clutches
• Further processing of precursor material from the melting metallurgy by thixocasting
or -forming, extrusion, forging, cold massive forming or super plastic
forming
• Joining and welding of semi-manufactured products
• Finishing by machining techniques
• Combined deformation of metal wires (group superconductors).
Melting metallurgy for the production of MMCs is at present of greater technical importance
than powder metallurgy. It is more economical and has the advantage of being able to use
well proven casting processes for the production of MMCs. Figure 1.6 shows schematically
the possible methods of melting metallurgical production. For melting metallurgical
processing of composite materials three procedures
are mainly used:
• compo-casting or melt stirring
• gas pressure infiltration
• squeeze casting or pressure casting.
Both the terms compo-casting and melt stirring are used for stirring particles into a light alloy
melt. Figure 1.7 shows the schematic operational sequence of this procedure. The particles
are often tend to form agglomerates, which can be only dissolved by intense stirring.
However, here gas access into the melt must be absolutely avoided, since this could lead to
unwanted porosities or reactions. Careful attention must be paid to the dispersion of the
reinforcement components, so that the reactivity of the components used is coordinated with
the temperature of the melt and the duration of stirring, since reactions with the melt can lead
to the dissolution of the reinforcement components. Because of the lower surface to volume
ratio of spherical particles, reactivity is usually less critical with stirred particle reinforcement
than with fibers. The melt can be cast directly or processed with alternative procedures such
as squeeze casting or thixocasting. Melt stirring is used by the Duralcan Company for the
production of particle-strengthened aluminum alloys. At the Lanxide Company a similar
process is used, with additional reactions between the reinforcement components and the
molten matrix being purposefully promoted to obtain a qualitatively high-grade composite
material In the reaction procedures of the Lanxide Company it may be desirable that the
reinforcement component reacts completely with the melt to form the component in situ,
which then transfers the actual reinforcement effect to the second phase in the MMC.
Squeeze casting or pressure casting are the most common manufacturing variants for MMCs.
After a slow mold filling the melt solidifies under very high pressure, which leads to a fine-
grained structure. In comparison with die-casted parts the squeeze-casted parts do not contain
gas inclusions, which permits thermal treatment of the produced parts. One can differentiate
between direct and indirect squeeze casting (Fig. 1.9). With direct squeeze casting the
pressure for the infiltration of the prefabricated preforms is applied directly to the melt. The
die is thereby part of the mold, which simplifies the structure of the tools substantially.
However, with the direct procedure there is a disadvantage in that the volume of the melt
must be determined exactly, since no gate is present and thus the quantity of the melt
determines the size of the cast construction unit. A further disadvantage is the appearance of
oxidation products, formed in the cast part during dosage. In contrast, in indirect squeeze
casting, where the melt is pressed into the form via a gate system, the residues will remain in
this gate. The flow rate of the melt through a gate is, due to its larger diameter, substantially
less than with die casting, which results in a less turbulent mold filling and gas admission to
the melt by turbulences is avoided. Both pressure casting processes make the production of
composite materials possible, as prefabricated fiber or particle preforms are infiltrated with
melt and solidify under pressure. A two-stage process is often used. In the first stage the melt
is pressed into the form at low pressure and then at high pressure for the solidification phase.
This prevents damage to the preform by too fast infiltration. The squeeze casting permits the
use of relatively reactive materials, since the duration of the infiltration and thus the response
time, are relatively short. A further advantage is the possibility to manufacture difficultly
shaped construction units and to provide partial reinforcement, to strengthen those areas
which are exposed to a higher stress during service.
8. Mechanism of Reinforcement
Simply, we can consider a fiber and/or a plate model. Depending on the load direction,
different elastic constants in the metallic composite material can result. Figure 8 illustrates
the two different models and shows the resulting E and G moduli as a function of the load.
9.Solid State Processing
Current markets for MMCs are primarily in military and aerospace applications.
Experimental MMC components have been developed for use in aircraft, satellites, jet
engines, missiles, and the National Aeronautics and Space Administration (NASA) space
shuttle. The first production application of a particulate-reinforced MMC in the United States
is a set of covers for a missile guidance system. The most important commercial application
to date is the MMC diesel engine piston This composite piston offers better wear resistance
and high-temperature strength than the cast iron piston it replaced. This development is very
impor- tant because it demonstrates that MMCs are at least not prohibitively expensive for a
very cost sensitive application. Other commercial applications include cutting tools and
circuit-breaker contacts.
Metal matrix composites with high specific stiffness and strength could be used in
applications in which saving weight is an important factor. Included in this category are
robots, high-speed machinery, and high-speed rotating shafts for ships or land vehicles. Good
wear resistance, along with high specific strength, also favors MMC use in automotive engine
and brake parts. Tailorable coefficient of thermal expansion and thermal conductivity make
them good candidates for lasers, precision machinery, and electronic packaging. However,
the current level of development ef- fort appears to be inadequate to bring about com-
mercialization of any of these in the next 5 years, with the possible exception of diesel engine
pistons.
10.Conclusions