Professional Documents
Culture Documents
Page 1 von 13
®
= registered trademark of ®
BASF Aktiengesellschaft,
unless otherwise indicated
Neozapon
dyes
Range
Shelf life According to our experience, Neozapon® dyes can be stored for at
least 10 years from the date of delivery when kept in their original,
unopened packaging and under dry conditions. Like most organic
compounds, however, they are combustible, a point to be consid-
ered for storage. Also note that dyes in drums that have been
opened and not resealed may absorb water from atmospheric
humidity.
EVP 001905 e, April 2006 Page 2 of 13 Neozapon® dyes
Properties
0.25 g dye
20 ml ethanol 96 %
5 ml pure water
Solubility Table 2 gives the amount of dye in grams which nearly completely
dissolves in 1 liter of the relevant solvent. Following DIN ISO 757-9,
the dye is added to the solvent in portions and the mixture is
shaken at room temperature (22–25 °C [72–77 °F]) until a significant
amount of dye remains undissolved. Neozapon® dyes, unlike inor-
ganic salts in water, do not form true solutions. Therefore, it is im-
possible to give absolute solubility figures. The values determined
can only serve as a guide, particularly since in practice, almost
always solvent blends or binder solutions are used.
ethylglycol acetate
isopropanol
ethoxy propanol
benzyl alcohol
ethanol 99.5%
ethoxypropyl acetate
methylethyl ketone
acetone
methyl isobutyl ketone
methanol
Solvenon® PM
butyl acetate 85 %2
cyclohexanone
butyl glycol
solvent blend1
ethyl acetate
methoxypropyl acetate
dipropylene glycol
ethanol 96%
phenyl glycol
EVP 001905 e, April 2006
Black X51 < 10 < 10 < 10 150 > 500 100 < 30 < 10 < 10 < 10 < 10 < 10 400 400 100 > 500 400 200 250 < 30
Black X55 > 500 > 500 400 > 500 > 500 > 500 > 500 < 50 150 100 300 300 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500
Yellow 081 > 500 > 500 400 > 500 > 500 > 500 > 500 < 10 < 10 > 500 < 10 < 10 > 500 > 500 > 500 > 500 > 500 400 > 500 > 500
Yellow 157 > 500 80 < 10 > 500 100 > 500 400 < 30 < 50 100 < 30 < 30 200 300 < 30 > 500 > 500 > 500 > 500 > 500
Orange 245 > 500 > 500 400 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500 350
Page 3 of 13
Orange 272 > 500 100 150 > 500 > 500 > 500 60 50 100 100 100 50 > 500 > 500 250 > 500 > 500 > 500 > 500 > 500
Brown 322 < 10 < 30 < 10 > 500 > 500 350 > 500 < 10 > 500 < 10 400 < 10 > 500 > 500 100 > 500 > 500 > 500 > 500 100
Red 335 > 500 > 500 > 500 > 500 > 500 > 500 250 > 500 > 500 > 500 > 500 400 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500
Red 355 < 10 < 10 < 10 100 > 500 > 500 < 10 < 10 50 < 10 100 < 10 200 140 < 30 > 500 400 > 500 > 500 100
Red 365 > 500 > 500 < 10 > 500 > 500 > 500 > 500 < 10 > 500 > 500 > 500 < 10 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500
Red 395 100 100 40 > 500 > 500 > 500 400 100 > 500 400 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500 200
Red 471 200 200 < 10 > 500 > 500 > 500 400 < 10 80 < 10 150 < 10 > 500 > 500 < 50 > 500 > 500 > 500 > 500 > 500
Pink 478 200 200 < 10 < 10 400 > 500 > 500 < 10 < 10 < 10 < 10 < 10 < 10 < 10 < 10 400 > 500 > 500 > 500 > 500
Blue 807 100 < 10 200 400 > 500 > 500 < 10 200 100 400 100 200 > 500 > 500 400 > 500 < 10 > 500 > 500 > 500
Green 975 150 < 10 300 > 500 > 500 > 500 < 10 300 250 > 500 < 10 < 10 > 500 > 500 > 500 > 500 < 10 > 500 > 500 > 500
Neozapon® dyes
EVP 001905 e, April 2006 Page 4 of 13 Neozapon® dyes
Adhesion (table 3) Printing or coating aluminum foil requires good adhesion. The sim-
plest way of determining this property is the adhesive tape pull-off
test: A piece of adhesive tape of specified length and width is
pressed to the printed or coated foil and then pulled off rapidly.
The test is repeated a number of times and the mean value is de-
termined. A poorly adhering film will be completely detached from
the foil.
Fastness to overcoating (table 3) Dyes may tend to bleed when oversprayed with a top coat con-
taining a solvent they are soluble in. This is tested by overcoating
with a white finish based on the same binder/solvent system as the
colored coat, and assessing the coloration of the white coat. Tests
were conducted on an alkyd-melamine coating. Finishes were
baked for 30 minutes at 120 °C (248 °F), oversprayed with the
white finish and baked for another 30 minutes at 180 °C (356 °F).
Migration of the dye into the white film was assessed and is ex-
pressed in ratings from 1 to 5:
Heat stability (table 3) The heat stability of a dye depends largely on the binder and the
duration of the exposure to heat. Neozapon® dyes are tested in an
alkyd-melamine system with a dye concentration of 0.5 %. The
finish was applied to an aluminum sheet, flashed off and baked for
30 minutes. A coating dried at 120 °C (248 °F) served as a com-
parison. Different dye concentrations can lead to a higher or lower
heat stability.
EVP 001905 e, April 2006 Page 6 of 13 Neozapon® dyes
PVC copolymer
combination of cellulose nitrate and a polymer plasticizer
The printing inks were applied to aluminum foil that had been
primed with a PVC binder to a wet-film thickness of 24 µm.
3
1 = very good to good adhesion, 2 = quite good to moderate adhesion
4
Celsius to Fahrenheit conversion: 140 °C = 284 °F, 160 °C = 320 °F, 200 °C = 392 °F, 220 °C = 428 °F, 250 °C = 482 °F
5
not tested
EVP 001905 e, April 2006 Page 7 of 13 Neozapon® dyes
table 4:
fastness properties
curd cheese
water
soap 1 %
sterilization
alkali 1 %
butter
oil
light
paraffin
lactic acid 10 %
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
PVC
PVC
PVC
PVC
PVC
PVC
PVC
PVC
PVC
PVC
EVP 001905 e, April 2006
Neozapon® Orange 245 4–5 4–5 5 5 4–5 5 5 4–5 5 4–5 5 5 5 4–5 5 5 4 3 7 5–6
Page 8 of 13
Neozapon® Red 335 5 4–5 5 5 4–5 4–5 4–5 4–5 4–5 3 5 5 5 4–5 5 5 3–4 2–3 6 3
Neozapon® Red 365 5 4–5 4–5 4–5 4–5 5 4–5 4–5 4 2–3 5 5 5 4 5 5 3 2–3 4 2
Neozapon® Red 395 5 4–5 5 5 4–5 4–5 4–5 4–5 4–5 2–3 5 5 5 4 5 5 3 2 5–6 3–4
Neozapon® Green 975 4–5 4–5 4–5 5 3–4 5 4–5 5 2 4 5 5 5 5 5 5 4 4–5 7 6–7
Neozapon® dyes
EVP 001905 e, April 2006 Page 9 of 13 Neozapon® dyes
EVP 001905 e, April 2006 Page 10 of 13 Neozapon® dyes
Application in coatings
Furniture stains The suitability of Neozapon® dyes for solvent-based furniture stains
depends on their solubility. For water-based stains we recommend
our Basantol® range and the Basantol® U range for stains based on
water/solvent mixes.
Air-drying coatings The suitability of Neozapon® dyes for coatings based on binders
soluble in alcohols or esters depends on their solubility.
Acid-curable coatings Neozapon® dyes except Neozapon® Blue 807 are stable when dis-
solved in a urea resin finish of the following composition:
Amine-curing coatings All Neozapon® dyes are suitable for use in coatings based on
Epikote®7 and Laromin® A 327 as the hardener component.
Baking finishes Heat stability tests have shown that nearly all Neozapon® dyes are
suitable for baking finishes cured at temperatures up to 160 °C
(320 °F). However we recommend tests in the binder system and
under application/drying conditions to be used.
Effect finishes Combining Neozapon® dyes with Paliocrom® effect pigments, alu-
minum or pearlescent pigments opens up a wide range of design
possibilities. The main fields of application are coatings for plastics
as well as motorcycles and bicycles. Note, however, that dyes
generally have limited fastness to light and weathering. For appli-
cations requiring resistance to weathering for 1 year or longer, we
only recommend transparent pigments form the Paliogen®,
Heliogen® and Sicotrans® ranges.
Note that Neozapon® Red 355 and Neozapon® Red 365 contain
rhodamine. Both dyes will tend to migrate through printed polyeth-
ylene film.
5 parts dye
95 parts binder of this composition
18 parts cellulose nitrate A400 isopropanol
moist
6 parts Acronal® 4 F
20 parts ethyl acetate
51 parts ethanol
5 parts Solvenon® PM
EVP 001905 e, April 2006 Page 12 of 13 Neozapon® dyes
VC copolymer
5 parts dye
95 parts binder of this composition
12 parts UCAR™9 VMCH
44 parts ethyl acetate
4 parts methylethyl ketone
Ballpoint ink pastes Because of their solubility in phenyl glycol and benzyl alcohol, the
dyes listed above are suitable for ballpoint ink pastes, both as a
sole dye and for tinting.
Felt- and fiber tip pens All dyes from the Neozapon® range are suitable for alcohol-based
inks (permanent markers, OHP markers etc.). The relatively neutral
pH of the Neozapon® dyes considerably reduces the risk of corro-
sion of aluminum pen bodies. The possible corrosion effect of the
resin component should be considered.
Ink-jet inks Neozapon® dyes are suitable to formulate solvent inks based on
alcohol or methylethyl ketone, e. g., for the continuous jet process
in industrial ink-jet.
Special applications Neozapon® Red 335 and Neozapon® Red 355 are suitable for col-
oring masking films used in the graphics industry.
The metal ions of metal complex dyes are firmly bound into the dye
molecule and are usually not released by 0.07 mol hydrochloric
acid. More information on the suitability of Neozapon® dyes for
coloring children’s toys (European Standard 71, part 3) can be
taken from the Technical Information bulletin Directives and regula-
tions on the use of colorants in food-contact applications and toys
and the brochure Pigments, pigment preparations, soluble dyes,
binders, crosslinkers, light stabilizers, process chemicals for coat-
ings, plastics coloration and stabilizing, graphic arts and specialty
industries. Both documents are available from our sales force or
from the Internet.
Safety
Note
BASF Aktiengesellschaft
Performance Chemicals for
Coatings, Plastics and Specialties
67056 Ludwigshafen, Germany
www.basf.com/pigments
www.basf.com/resins
20060421_evp001905_e_gls_ti_neozapon_range.doc / EVP 001905-0604 E www.basf.com/lightstabilizers