SULIT 4541/1/2/3

4541/1
Kimia
Kertas 1
Ogos
2007

BAHAGIAN SEKOLAH
KEMENTERIAN PELAJARAN MALAYSIA
______________________________________________
PEPERIKSAAN PERCUBAAN SPM 2007

KIMIA
Peraturan pemarkahan Kertas 1, 2 dan 3
Peraturan pemarkahan ini mengandungi halaman bercetak.

Kertas 1

1 A 21 B 41 A
2 B 22 D 42 A
3 A 23 D 43 C
4 B 24 C 44 B
5 B 25 B 45 B
6 C 26 C 46 B
7 D 27 D 47 B
8 A 28 A 48 A
9 B 29 D 49 C
10 C 30 A 50 B
11 B 31 B
12 A 32 C
13 A 33 C
14 A 34 B
15 A 35 D
16 D 36 A
17 D 37 A
18 D 38 C
19 B 39 A
20 C 40 C

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Kertas 2-Bahagian A

No. Rubric Mark

1 (a) P: liquid 1
S: solid 1

(b)

(c) 1. Particles of Q held together by weak intermolecular forces 1

2. A small amount of heat energy is required to overcome 1

(d) Diagram
1. label 1
2. functional apparatus 1

(e) Temperature /
o
C

Time
( min)
1. label of axis 1
2. shape of graph 1…9

2 (a)(i) 2.8.3 1
(ii) F+3 1

(b) A,D,C,B,G,F,E 1

(c) Atom A has a stable/duplet electron arrangement/2 valance electron 1

(d) 1. Size of atom D is smaller than G 1

2. Strength of the nucleus of atom D to attract electron increase 1

(e)(i) Ionic 1

3
 - xx 2+ -
(e)(ii) x
x x x x
D x E x D
x
xx
1. Number of shells and electrons 1
2. Charge 1

(e) (iii) - has high melting point and boiling point

- conduct electricity in molten state or aqueous solution
- soluble in water
- insoluble in organic solvent 1...10
(Any one)

3 (a) H+ , Cu+2 1

(b) (i) Copper electode becomes thicker//brown solid is deposited 1

(ii) Cu+2 + 2e → Cu 1
(iii) Copper 1
(iv) Oxygen 1

(c) (i) (from zinc plate to copper plate) 1

(ii) Oxidation 1
(iii) 0 to +2 1
(iv) Increases 1

(d) Zn + Cu+2 → Cu + Zn+2 1...10

4 (a) Boron oxide 1

(b) (i) Tin 1
(ii) 1. The presence of tin atoms of different size from the atoms of 1
copper distrupts the orderly arrangements of copper atoms
2. This prevents the layers of atoms from sliding over one another 1
easily

(c) (i) H Cl
| |
C == C 1
| |
H H

(ii) Does not corrode 1

4
 (d) Reinforced concrete 1

(e) (i) 2NH3 + H2SO4 → (NH4)2SO4// 1

2NH4OH + H2SO4 → (NH4)2SO4 + 2H2O
(ii) 1
2(14)
% N in CO(NH2)2 = × 100% = 46.67%
60

2(14) 1
% N in (NH4)2SO4 = × 100 = 21.21%
132
Urea has higher percentage of nitrogen so it is more suitable for the
growth of plants
1…11

5 (a) J: alkene 1
K: alcohol 1

(b)(i) Butan-2-ol 1

(ii) Hydration/addition of steam 1

(c)(i) Orange to green 1

(ii) C3H7COOH 1

(d)(i) C4H8 + 6O2 → 4CO2 + 4H2O 1

5 .6
(ii) No of mole C4H8 =
4(12) + 8(1) 1
5.6
=
56
= 0.1
1 mole of C4H8 → 4 mole CO2
0.1 mole of C4H8 → 0.4 mole CO2 1

Volume of CO2 = 0.4(24)

= 9.6 dm3 / 9600 cm3 1…10

6 (a) Reduce heat released to the surrounding 1

(b)(i) Heat change = 200 x 4.2 x 13

= 10920 J 1

5
(b)(ii) Mole of H+/OH-/water = 100 x 2.0 // 0.2 mol 1
1000
Heat of displacement = - 10920 J // -54.6 kJmol-1 1
0.2 mol
Energy
(c)

H+ + OH-

H2O

1. Label the energy axis & correct energy level of the reactants and 1
product
2. Correct chemical equation// ionic equation 1

(d) Heat released/ produced when 1 mol of water is formed 1

(e)(i) decreases 1

(ii) 1. Ethanoic acid is a weak acid 1

2. Some of the heat given out during the neutralization is used to 1…10
ionize/dissociate the ethanoic acid

6
Essay

No. Rubric Mark

7 (a) 1. pH value of ethanoic acid is higher than nitric acid 1

2. ethanoic acid is a weak acid; nitric acid is a strong acid 1
3. ethanoic acid ionises partially in water to produce lower 1
concentration of hydrogen ion
4. nitric acid ionises completely in water to produce higher
concentration of hydrogen ion 1…4

(b) 1. ammonia exist as molecule in chloroform 1

2. there are no hydroxide ions present; the solution is not alkaline 1
3. when ammonia ionises partially in water to produce hydroxide ion 1
4. NH3 + H2O → NH4+ + OH- 1
5. the presence of OH- ions makes the solution alkali 1…5

(c) 1. Pour [20-100]cm3 of zinc nitrate solution [0.1-1.0]mol dm-3 into a 1

beaker
2. Add [20-100]cm3 of sodium carbonate solution [0.1-1.0]mol dm-3 1
3. Stir and filter the mixture 1
4. Pour [20-100]cm3 dilute/[0.1-1.0]mol dm-3 sulphuric acid into a 1
beaker
5. Add the residue/precipitate into the acid until in excess 1
6. Stir and filter the mixture 1
7. Heat the filterate until saturated/1/3 of original volume 1
8. Cool the saturated solution 1
9. Filter and dry the crystal 1
10. Zn(NO3)2 + Na2CO3 → ZnCO3 + 2NaNO3 1
11. ZnCO3 + H2SO4 → ZnSO4 + H2O + CO2 1...11

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7
No. Rubric Mark

8 (a) Formula that shows the simplest ratio of the number of atoms for
each element in the compound. 1…1

(b) Element C H
Mass (%) 92.3 7.7
Number of 92.3 7.7
= 7.7 = 7.7 1
moles 12 1
Ratio of moles 1 1
1
Empirical formula : CH
1
RMM of (CH)n = 78
[ 12 + 1]n = 78
13 n = 78
n = 6
Molecular formula : C6H6 1
1…5

(c) Procedure:
1. Clean magnesium ribbon with sand paper 1
2. Weigh crucible and its lid 1
3. Put magnesium ribbon into the crucible and weigh the crucible 1
with its lid
4. Heat strongly the crucible without its lid 1
5. Cover the crucible when the magnesium starts to burn and 1
lift/raise the lid a little at intervals
6. Remove the lid when the magnesium burnt completely 1
7. Heat strongly the crucible for a few minutes 1
8. Cool and weigh the crucible with its lid and the content 1
9. Repeat the processes of heating, cooling and weighing until a 1
constant mass is obtained
10. Record all the mass 1

Results:

Mass/g
Crucible + lid x
Crucible + lid + magnesium y 1
Crucible + lid + magnesium oxide z

Calculations:

8
 Element Mg O 1
Mass (g) y-x z-y
1
y−x z−y
Number of moles
24 16
Simplest ratio of moles a b
1...14

Empirical formula: MgaOb / MgO

20

No. Rubric Mark

9 (a) 1. Oxidation - increase in oxidation number 1

2. Reduction – decrease in oxidation number 1…2

(b)(i) 1. Fe+2 → Fe+3 + e 1

2. Br2 + 2e → 2Br – 1
3. Iron(II) ions lose electrons to become iron(III) ions. Iron(II) ions 1
are oxidised
4. Bromine molecules gain electrons to form bromide ions. 1
Bromine molecules are reduced
(a: any suitable reducing agent)

1. Fe+3 + e → Fe+2 1
1
2. Zn → Zn+2 + 2e
1
3. Iron(III) ions gain electrons to become iron(II) ions. Iron(III)
ions are reduced
1…8
4. Zinc atoms lose electrons to form zinc ions. Zinc atoms are
oxidised
(a: any suitable reducing agent)

9
 (c) Diagram:
1. label 1
2. functional apparatus 1

Procedure:
1. Pour dilute sulphuric acid into a U-tube 1
2. Using a dropper, add iron(II) sulphate solution at one side 1
3. and acidified potassium manganate(VII) solution at another side 1
4. Place carbon electrode in each side of the U-tube 1
5. Connect the electrodes to a galvanometer by using connecting 1
wires//Complete the external circuit
6. Record any change that can be observed after a few minutes 1

Observations:
The green colour of iron(II) solution turns to brown 1
The purple colour of acidified potassium manganate(VII) solution is 1…10
decolourised/change to colourless

(a: any suitable cell)

20

No. Rubric Mark

10 (a) (i) Catalyst is a substance that changes the rate of a chemical reaction. 1

(a) (ii) - does not change the amount of product formed.

- unchanged chemically at the end of reaction.
- the amount of catalyst is the same before and after the reaction.
- it is specific for a reaction.
- only small amount is needed to catalyze a reaction.
- less effective when there are impurerities. 1
- most of the catalyst are transition metals or their compound. 1…2
(Any two)

(a) (iii) - Haber process: iron filling

10
 - Contact process: vanadium(V) oxide
- Ostwald process: platinum 1…1
(Any one)

(b) 1 Size of reactant 1

- size of reactant decrease, total surface area exsposed for collision 1
between the particles reactants increase
- frequency of collision between particles increase 1
- frequency of affective collision increase 1…4
rate of reaction increase

2 Concentration of reactant 1
- concentration of a solution increase, number of particles per unit 1
volume increase
- frequency of collision between particles increase 1
- frequency of affective collision increase 1…4
rate of reaction increase

3 Temperature of reaction 1
- temperature of reactants increase, kinetic energy of particles 1
reactants increase
- frequency of collision between particles increase 1
- frequency of affective collision increase 1…4
rate of reaction increase
(Any two)

(c) 1 Cooking of solid food 1

- solid food cut into small piece 1
- total surface area exsposed to heat increase 1
- food cook faster 1…4

2 Cooking of food in a pressure cooker 1

- high pressure raises the boiling point of water. 1
- cooking is carried out at a temperature higher than 100 o C. 1
- food cook faster. 1…4

3 Storing of food in a refrigerator 1

- temperature in refrigerator is lower 1
- microorganisms inactive 1
- slow down rate of food decaying 1…4
(Any two)
(a: any suitable answer than above)

20

11
PAPER 3

1 (a)

Score Rubric
3 [ Able to state all 11 readings correctly ]
• 2 decimal places
• Unit cm3
Suggested answer
49.60, 40.10, 31.50, 24.10, 19.50, 15.10, 11.50, 9.60, 8.10, 8.10. 8.10

2 [ Able to state any 8 readings correctly ]

1 [ Able to state any 4 readings correctly ]
0 No response or wrong response

1 (b)
Score

Rubric

3 [Able to design a table and record the time, buret reading and volume of gas liberated]

1. Time /minute
2. Buret reading /cm3
3. Volume of gas liberated

Suggested answer:

Time 0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5

/min

Buret 49.6 40.1 31.5 24.1 19.5 15.1 11.50 9.60 8.10 8.10 8.10
reading 0 0 0 0 0 0
/cm3
Volume 0.00 9.50 18.1 25.5 30.1 34.5 38.1 40.0 41.5 41.5 41.50
of gas / 0 0 0 0 0 0 0 0
cm3

2 [Able to design a table and record two of the 3 items (time, buret reading and volume of
gas liberated] // [Able to design table without unit]

12
 [Able to give idea on table ]
1 Suggest answer: 2 rows x 11 columns

1 (c)

Score Rubric
3 [ Able to draw 2 graphs of volume of carbon dioxide gas liberated against time
for both experiments on the same axes with all the 4 items below correctly ]
(i) suitable scale used
(ii) axes labelled correctly
(iii) all points plotted correctly
(iv) smooth curve of graphs

2 [Able to draw the graphs of volume of carbon dioxide gas liberated against
time for both experiments on the same axes with at least 3 items correctly] //
[Able to draw one of the graphs volume of carbon dioxide gas liberated against
time with at least 4 items abovebelow correctly]

1 [ Able to manipulate two items correctly ]

0 No response or wrong response

1(d)

Score Rubric
3 [Able to deduce the relationship between the size of marble chips and the rate of
reaction correctly].

Suggested answer:
Small pieces of marble chips have a large total surface area than that a large
pieces of marble chips of the same mass, course the time taken for reaction
more faster / rate of reaction more higher

2 [Able to give incomplete relationship]

Suggested answer:
Small pieces of marble chips have a large total surface area time taken for
reaction more faster / rate of reaction more higher

1 [Able to give an idea ]

Suggested answer:
Small pieces of marble chips have a large total surface area // time taken for
reaction more faster when size of reactant smaller // rate of reaction depend on
the size of reactant
0 No response or wrong response

13
1 (e)

Score
3 [ Able to state three variables and the way to control them correctly ]
Example :
Manipulated variable :
Total suface area of marble
Responding variable :
Rate of reaction // time
Fixed variable :
Mass of marble, volume of
hydrochloric acid, temperature
Rubric
Replace large marble chips with
small small marble chips
Measure the volume of gas collected
at half-minute interval
Use the same mass/5.0 g marble,
same volume/50 cm3 and
concentration/ 0.1 mol dm-3
hydrochloric acid, same tepperature
in each of the experiment

2 [ Able to state any pair of variable and action correctly ]

1 [ Able to state any variable and any action correctly // any two variables
correctly // any two action correctly]

0 No response or wrong response

1 (f)

Score Rubric
3 [Able to state relationship small pieces of meat and time to cook correctly]

Suggested answer
• Smaller pieces of meat has bigger total surface area
• The larger surface area provides a larger area for absorbtion heat
• Increased obsorption of heat shorten cooking time// The rate of reaction
increases
2 [Able to give incomplete relationship ]

Suggested answer
[state the any two items above]

1 [Able to give an idea // state any one items above]

14
 0 No response or wrong response

2 (a)
Score Rubric
3 [Able to give the hypothesis accurately]

Suggested answer :
The further the metal is from copper in the electrochemical series, the greater is
their potential different/ voltage reading. //
The further apart the metal is in the electrochemical series, the greater the
potential different/ voltage reading.

2 [Able to give the hypothesis almost accurately]

Suggested answer :
The further the metal is from copper in the reactivities series, the greater is
their potential different/ voltage reading. //
The further apart the metal is in the reactivities series, the greater the potential
different/ voltage reading.

1 [Able to state an idea of hypothesis]

Suggested answer :
The position of metal influence the different potential/ voltage reading.
Type of metal influence the different potential/ voltage reading.

0 No response or wrong response

2 (b)
Score Rubric
3 [Able to arrange all the 5 metals according to descending order of
electropositivity correctly]

Suggested answer:
Magnesium, Aluminium, Zinc, Iron, Copper
[a: formula]

2 [Able to arrange all the 4 metals but according to increasing order of

electropositivity correctly]

Example:
Mg, Al, Fe, Cu, Zn // Al, Zn, Fe, Cu, Mg // Al, Zn, Mg, Fe, Cu

1 [Able to arrange all the 5 metals but according to ascending order of

15
 electropositivity correctly]
Example ;
Cu, Fe, Zn, Al, Mg

0 No response or wrong response

2 (c)
Score Rubric
3 [Able to state inference correctly].

Suggested answer
• Electrical energy is not produced
• No movement of electron because the same type of metal are used as
electrodes in a voltaic cell

2 [Able to state inference not completely].

Suggested answer
Electrical energy is not produced // no movement of electron because the same
type of metal are used as electrodes in a voltaic cell

1 [Able to state an idea]

Example
No electric/electron/potential difference

0 No response or wrong response

2 (d)

Score Rubric
3 [Able to state three observations correctly]

Suggested answer:
1 Zinc dissolved // becomes thinner
2 Copper becomes thicker // brown solid deposited
3 Blue solution becomes light blue /fading in colour

2 [Able to state two observation correctly]

1 [Able to state one observation/idea about observation of the cell]

0 No response given or wrong response

16
2 (e)

Score Rubric
3 [Able to predict correctly]
Answer: 1.0 V

2 [Able to predict almost correctly]

Example:
1.0
1 [Able to state an idea to arrange the metals]

Example:
Reading is higher than 0.5 / lower than 1.5
0 No response or wrong response

Essay

3 (a) - Statement of the problem

Score Rubric
[ Able to give the statement of problem correctly ]

3 Example :
How the effect on rusting when iron is in contact with another metals?

[ Able to give the statement of problem incorrectly ]

2 Example :
To investigate the effect of other metals on the rusting of iron

1 [ Able to state an idea the statement of problem]

Example :
To study the rusting of iron

17
 0 [ No response or wrong response]

3 (b) - variables

Score Rubric
[ Able to state All variables correctly ]

Suggested answer :
3
Manipulated variable : Different types of metals// Different metals
Responding variable : Rate of rusting // Rusting of iron
Constant variable : Iron nails/temperature

2 [ Able to state any two variables correctly ]

1 [ Able to state any one variables correctly ]

0 [ No response or wrong response]

3 (c) - hypothesis

Score Rubric
3 [Able to give the hypothesis accurately]

Suggested answer :
When a more electropositive metal is in contact with iron, the metal inhabits
rusting // When a less electropositive metal is in contact with iron, the metal
speed up rusting // Iron rusts faster when in contact with metal less
electropositive

2 [Able to give the hypothesis almost accurately]

Suggested answer :
When a more reactive metal is in contact with iron, the metal inhabits rusting

1 [Able to state an idea of hypothesis]

Suggested answer :
When a less electropositive metal is in contact with iron, the metal inhabits
rusting

0 No response or wrong response

18
3 (d) - Apparatus and materials

Score Rubric
[ Able to give the list of the apparatus and substances correctly and
completely]

Suggested answer :
3 Apparatus : Five test tubes, test tube rack
Materials : sand paper, five iron nails, magnesium strip, zinc strip, tin strip,
copper strip, hot agar-agar/jelly solution mixed with potassium
hexacyanoferrate(III) solution and phenolphthalein indicator

[ Able to give the list of the apparatus and substances correctly and but not
completely]

2 Example :
List of apparatus and materials
Test tube, iron nail, magnesium,zinc, tin,copper,water, potassium
hexacyanoferrate(III) / phenolphthalein indicator

[ Able to give an idea about the list of the apparatus and materials correctly]

1 Example :
Any one apparatus and two materials

0 [No response or wrong response]

3 (e) - Procedure of the experiment

Score Rubric
[ Able to state all procedures correctly ]

Suggested answer :
1. Clean all the metal strips with sand paper
2. Coil the metal strip around the iron nails and then put in the each test tube
3 3. Pour the same volume of hot agar-agar/jelly solution has been mixed with
potassium hexacyanoferrate(III) and phenolphthalein indicator
4. Leave the test tubes aside for one day
5. Compare the intensity of the blue and pink colour in each test tube and
recorded

2 [ Able to state 3 steps of procedures correctly ]

19
 Example : Steps 2,3,5
[ Able to state 2 steps of procedures correctly ]
1 Steps 2,3

0 [No response or wrong response]

3 (f) - Tabulation of data

Score Rubric
[ Able to exhibit the tabulation of data correctly ]

Tabulation of data has 6 columns and 3 rows

Example :
3 Test tube A B C D E
Intensity of
blue colour
Intensity of
pink colour

[ Able to exhibit the tabulation of data less accurately ]

2 Tabulation of data has 6 columns and 2 rows

Example :
Test tube A B C D E
Observation

[ Able to state an idea about the tabulation of data ]

Tabulation of data has 2 columns and 2 rows
1

0
[No response or wrong response]

Total 3 × 6 = 18
Max 17

Nota utk pemeriksa*

Markah Kertas 1 + Markah Kertas 2 + Markah Kertas 3 = Markah keseluruhan

2

50 + 100 + 50 = 100%

20
2

END OF MARKING SCHEME

21