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Energy Conversion and Management 174 (2018) 537–551

Contents lists available at ScienceDirect

Energy Conversion and Management


journal homepage: www.elsevier.com/locate/enconman

Multi-objective optimization and exergetic analysis of a low-grade waste T


heat recovery ORC application on a Brazilian FPSO

Thiago Gotelip Correa Veloso, César Adolfo Rodriguez Sotomonte, Christian J.R. Coronado ,
Marco A.R. Nascimento
Itajubá Federal University – UNIFEI, Mechanical Engineering Institute – IEM, Av. BPS 1303, Itajubá, MG CEP 37500-903, Brazil

A R T I C LE I N FO A B S T R A C T

Keywords: This paper presents an analysis of the application of an Organic Rankine cycle (ORC) for power generation of a
Organic Rankine Cycle Brazilian FPSO (Floating Product Storage Offload). The peculiarity of this analysis is the investigation of power
Waste heat recovery generation using low-temperature waste heat sources. Low-grade sources represent a significant amount of heat
Optimization rejected on the platform. The primary production in the platform processes was evaluated using ASPEN-HYSYS®
FPSO
software v.8.6. The main sources of low-temperature residual heat were preliminarily identified, and the highest
potential for energy recovery was: the heat rejected in the intercoolers and aftercoolers of the compression
processes in the Main Compression Unit and the CO2 Compression Unit. For the development of this study, a
computational tool was elaborated in MATLAB® to evaluate the thermodynamic performance and to predict the
design of the heat exchanger of the ORC. A multi-objective optimization was conducted to verify the ORC
application at the established sources. The higher net power was obtained at Main Compression Unit heat re-
covery, operating with R245CB2 as working fluid. This application allows to generate up to 2063 kW with a heat
transfer area of 2997 m2, providing a 23.6% increase in exergy efficiency of the system. The results of this study
suggest that the application of ORC cycles on FPSO platforms for heat recovery from low-temperature sources
allows an essential increase in the energy and exergetic efficiency of the production processes of the platform.
Although the ORC doesn’t give a substantial increase in the supply of electricity, they contribute to less gas
consumption in gas turbines. In this way, contributing to a significant reduction of GHG emissions.

1. Introduction being investigated to assess the efficiency of offshore oil and gas pro-
cessing [1]. Pinch-based methods are promising tools used to optimize
Floating Production Storage and Offloading (FPSO), which is con- the efficiency of industrial processes to improve the procedure and the
ceptually floating production, storage and transfer units, has become utility of sites, including fuel cost reduction, process de-bottlenecking,
one of the commercially viable technology options for exploration of efficiency improvement, capital planning, and investment reduction
deep-sea oil deposits. Within these perspectives, offshore platforms [2].
have been used to expand the exploration and processing of oil and gas Exergy analysis is used to characterize the thermodynamic perfor-
in several regions of the world. mance of these processes and identify possible ways of increasing the
In Brazil, the expansion of FPSO use is due to the recent oil dis- overall performance of platforms. These analyses are essential to pre-
coveries in the Pre-salt layer. Significant efforts are being made over- dict different scenarios to improve the energy performance of oil and
coming technological and development of national engineering, re- gas facilities. Vanner [3] classified these strategies into two categories.
garding the challenges in the exploration and production of oil and The first possibility is to increase the efficiency of the most energy-
natural gas in ultra-deep and offshore waters. intensive processes to reduce the energy requirements of the processing
The offshore processing of oil and gas is an energy-intensive sector. plant.
Improving the energy generation system in FPSO is an issue of in- Gallo et al. [4] identified the major sources of irreversibility in an
creasing importance, due to the necessity for reducing CO2 and other offshore platform to improve energy use, exergy efficiencies and pos-
greenhouse emissions and improving the efficiency of the platform. sibilities for waste heat recovery. They focused on the diagnosis of the
Different methods, such as pinch- and exergy-based methods, are compression systems of the proposed FPSO. The authors listed the


Corresponding author.
E-mail address: christian@unifei.edu.br (C.J.R. Coronado).

https://doi.org/10.1016/j.enconman.2018.08.042
Received 2 May 2018; Received in revised form 3 August 2018; Accepted 11 August 2018
0196-8904/ © 2018 Elsevier Ltd. All rights reserved.
T. Gotelip Correa Veloso et al. Energy Conversion and Management 174 (2018) 537–551

Nomenclature η efficiency
η0 extended surface efficiency [-]
A total heat transfer area [m2] ε heat transfer effectiveness
cp specific heat of fluid at constant pressure [J/kgK] ρ fluid density [kg/m3]
e specific exergy [J/kg] σ ratio of free flow area to frontal area [–]
E exergy [J]
f fanning friction factor [-] Subscriptions
gc proportionally constant in Newton’s second law of motion
[-] 1 evaporator exit/Turbine entrance
Gn fluid mass velocity based on the minimum free area [kg/ 2 turbine exit/Recuperator entrance
m2] 3 recuperator exit/Condenser entrance
h specific enthalpy [J/kg] 4 condenser exit/ Pump entrance
h heat transfer coefficient [W/m2K] 5 pump exit/Recuperator entrance
hf heat transfer coefficient at fin [W/m2K] 6 recuperator Exit/Evaporator entrance
ke contraction loss coefficient for flow at heat exchanger exit 1s saturated vapor condition at evaporator
[-] f super heater entrance (Heat source)*
kc contraction loss coefficient for flow at heat exchanger f1 evaporator entrance*
entrance [-] fout evaporator exit*
L fluid flow (core) length [m] c cold side
ṁ mass flow [kg/s] c1 cooling water entrance
P pressure [Pa] c2 cooling water exit
Q̇ total heat transfer rate [W] con condenser
Rh hot-side film resistance [K/W] evp evaporator
Rh, f hot-side fouling resistance [K/W] rec recuperator
Rw wall thermal resistance [K/W] P pump
R c, f cold-side fouling resistance [K/W] S source
Rc cold-side film resistance [K/W] m mean
S entropy [J/K] max maximum
T temperature [K] min minimum
U overall heat transfer coefficient [W/m2] net net
W power [W] wf working fluid
h hot side
Abbreviations T turbine

CCU CO2 compression unit Superscript


GPP gas processing plant
MCU main compression unit ph physical
ORC organic rankine cycle ch chemical
ODP ozone depletion potencial kn kinetics
PCHE printed circuit heat exchanger pt potential

Greek letters

Δ variation

opportunities for increasing the exergy efficiency of some processes. platforms. They simulated the using Aspen HYSYS®. The exergy con-
Nguyen et al. [5] investigated several technologies for increasing sumption required for the petroleum heating in the separation process
the energy efficiency of these plants. They aim at reducing electrical or has a noticeable influence on the whole plant irreversibility.
thermal energy usage, by re-designing some sections of the processing The second possibility is to improve energy conversion processes.
plant (production manifolds), re-dimensioning the compressors (gas One way of allowing this improvement is to convert the existing gas
recompression and treatment), promoting energy and process integra- turbines and furnaces into cogeneration plants. The challenges of in-
tion (heat exchanger network), implementing expanders and waste- tegration of steam bottoming cycles are discussed by [8]. Combined
heat recovery cycles. The authors conclude that the most significant cycle power plants with steam cycles installed on the Oseberg, Snorre
energy saving improvement is associated with the limitation, if pos- and Eldfisk field to minimize the weight of the heat transfer equipment
sible, of anti-surge recycling by, for example, adding parallel trains or are discussed by [9,10]. The air bottoming cycle is evaluated by [11],
re-wheeling them. and results proved that, despite the low gain in performance, low
Voldsund et al. [6] analyzed and compared the oil and gas proces- weight and short pay-back time are attained.
sing plants of four North Sea offshore platforms, based on the exergy The difficulties of bottoming cycle implementation are the restric-
analysis method. The results of the analysis show that 27–57% of the tions on weight and physical space, although considerable fuel savings
exergy destruction takes place in the gas treatment sections, 13–29% and reductions of environmental pollutants are achieved. In this re-
take place in the gas recompression sections, and 10–24% occur in the spect, alternative energy generation cycles such as ORC are presented
production manifolds. with high potential for this application, because it is a compact system
Sánchez [7] used a exergy balance formulations to assess the per- with a good economic performance due to the simplicity of the cycle
formance of primary petroleum processing operations in offshore configuration.

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According to [12], it is not economical and practical to have a steam present the analysis of an ORC that uses waste exhaust energy from a
bottoming cycle to increase the efficiency of electricity production, due diesel generator on a naval ship operating with 500 kW when cruising.
to low gas turbine outlet temperature, space and weight restrictions and The ideal ORC could produce 118 kW power with the working fluid
the need for make-up water. A more promising option for use offshore is toluene, saving 25,500 L of diesel fuel and reducing CO2 emission by
the Organic Rankine Cycles (ORC). 67.2 tons at the end of 1000 operating hours.
Mondejar et al.[29] proposed a quasi-steady state simulation of a
1.1. Motivation regenerative organic Rankine cycle (ORC) integrated into a passenger
vessel for waste heat recovery from the exhaust gases. The maximum
This study is based on the basic design data for production modules net power production of the ORC during the round trip was estimated
of eight standard FPSOs proposed for Pre-salt application, the so-called to supply approximately 22% of the total on board power demand.
“replicant FPSO.” The purpose of standardizing process modules and Suárez et al. [30] analyzed the practical application of exhaust gas
utilities is to facilitate manufacturing, construction, and assembly. The waste heat recovery from the main engines of merchant ships. The
equipment contained in each module, whenever possible, should also author compared a water-based Rankine Cycle with five organic Ran-
be standardized. The amount of equipment per module may vary to suit kine cycle systems using benzene, heptane, hexamethyldisiloxane, to-
the different fields of oil exploration. Interfaces between modules luene and R245fa. They demonstrated with the aid of a case study that a
should be standardized [13]. marine ORC WHRS could achieve yearly fuel savings of around €154 k
Most of the studies for FPSO energy generation by residual heat and CO2 emission reductions of around 705 ton, which performs an
recovery are based on the use of exhaust gas heat from the gas turbines EEDI decrease of approximately 1.9%. Furthermore, ORC WHRS could
already installed on the platforms, providing medium and high-tem- outperform a simple RC by an increase in power output of about 12.0%.
perature heat sources [13]. An ORC WHRS achieves up to 17.0% savings in both fuel consumption
The energy potential of each waste heat source is decisive for the and CO2 emissions when compared to a typical RC. The work also
evaluation of the operating parameters of the ORC cycle, to allow shows that the use of a marine WHRS on board recovers the initial
higher power generation with reduced areas. Heat recovery from ex- investment in less than three years, regardless of the working fluid
haust gas from gas turbine on an FPSO platform is the best alternative selected.
for this plant power support [14]. Nguyen and Fülöp et al. [1] conducted a multi-objective optimiza-
This study presents a novel investigation to quantifying the poten- tion for evaluating the integration of steam heat recovering from the
tial of different sources of waste heat recovery on the FPSO. This re- turbine exhausts and organic Rankine cycles recovering heat from the
search reveal that low-grade sources represent a significant amount of exported gas. The integration of a steam Rankine cycle appeared to be
heat rejected on the platform. In this way the potential of ORC to low- the most promising option between these two distinct applications.
temperature waste heat recovery from the platform process was eval- Pierobon et al. [31] proposed a multi-objective optimization for gas
uated. The intention is to increase the electric power generation, in- turbine waste heat recovery on an offshore platform using ORC. The
crease the overall efficiency of the platform process and contribute to objectives considered were thermal efficiency, the total volume of the
the reducing of GHG emissions. system and net present value. Results suggest two optimal working
The main objective of this study is to develop a computational fluids, i.e. acetone and cyclopentane. Barrera et al. [32] presented an
calculation tool to optimize ORC cycles, establishing a mathematical exergy performance analysis of the processes on board a Brazilian FPSO
model to evaluate the thermodynamic performance of the ORC cycle, and proposed the integration of an ORC for improving its efficiency.
and a mathematical model to predict the design of the heat exchanger. Walnum et al. [33] studied the possibility of using heat recovery for
With this data, the evaluation of the potential for using the ORC cycle further power generation from the exhaust heat using CO2 bottoming
on a Brazilian FPSO platform proposed for the pre-salt oil character- cycles under design and off-design conditions. The results showed that
istics will be suggested. this technology can increase plant efficiency under design and part-load
The great challenge for power generation to support the demand of conditions. The CO2 bottoming cycles were analyzed as well, and the
this input on an FPSO is mainly due to its restrictions on physical space, results show that CO2-cycles may be much less space-demanding for
weight limitation and security. In this respect, the ORC cycle is a similar efficiencies and capacities [34,35].
technology with high-potential for this application, since it is a compact Nguyen et al. [5] suggest that importing electricity from the shore
system, as well as having an appreciable economic performance due to would be an alternative way of improving energy conversion processes,
the simplicity of the cycle configuration. or by replacing the existing gas turbines with smaller and more effi-
The physical area availability of each platform should be different to cient-ones, if possible.
meet the characteristics of the fields where they will be installed. Most industrial activities reject about half of all heat generated in
Because of that, the calculation tool developed allows delimiting a set their production processes [36]. Residual heat recovery as a heat source
of optimal solutions that will be presented from the optimized ORC accounts for about 12.7% of all installed capacity of ORC cycle appli-
operation. cations, with 116.8 MW installed. The main sources of heat used are gas
In this way, this analysis allows evaluating the best configuration turbine exhaust gases and internal combustion engines, representing
according to the available areas on the different platforms. 66.8% of the installed capacity for this application.
Rohde et al. [37] analyzed the power production from compressed
1.2. Organic Rankine cycle export gas on offshore platforms, with a subcritical propane cycle, a
transcritical CO2 cycle and a transcritical cycle with a mixture of pro-
ORC cycles have the same operating principles as the conventional pane and ethane. The author concludes that more than 10% of the
Rankine cycle, the difference between both is the used working fluid. export gas compression work could be recovered.
Working fluids in an ORC cycle have a low boiling point and a latent
heat of vaporization below that of the water, allowing evaporation at 2. Technical description
lower temperatures. This grant better match with the source, eviden-
cing its use for low and medium temperature sources. Usually, the technical specifications for FPSO processing capabilities
The main applications of ORC cycles correspond to the use of are designed according to the production field in which it they will be
thermal sources: solar energy [15–17], geothermal [18–20], biomass finally installed, considering the reservoir characteristics (gas-to-oil
[21–23] and waste heat recovery [24–27]. ratio, water-to-oil ratio, rock permeability and so on), properties of the
FPSO’s are generally converted from oil ships. Girgin and Ezgi [28] extracted fluid (hydrocarbon characteristics), technical requirements

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and decisions on technology implementations [4]. another dehydrating agent such as methanol. After the re-compression
Oil by itself has a low water content and a small number of light unit, a dehydration step is necessary to prevent corrosion problems
hydrocarbons in its composition, but its extraction process occurs along from forming hydrates in the gas pipes, and to meet the specifications
with the presence of water and gases. According to [38], offshore se- for sale or injection.
paration of these three phases is necessary to maximize oil production Dew point Control System: This unit is designed to inhibit the for-
and minimize its gas and water content for economic reasons and mation of solid hydrates in gas streams, and by default, they perform a
production process requirements. level of dehydration. Hydrocarbon condensates that may affect the gas
Oil extraction activity involves the removal of various materials transportation by pipelines for exportation.
such as gas, water, sand, and salt together with the well fluid. These CO2 Removal Unit: Separation of CO2 from natural gas is performed
impurities must be removed from the crude oil before being processed by membranes to meet gas export specifications.
in refineries or used as fuel. The main objective of an FPSO production Gas Exportation Compression: When possible, most of the separated
unit is to separate the fluid from reservoir exploration in oil, gas, and gas is sold and exported to the mainland via pipelines. The capacity of
water. Then, each of these streams passes through a series of operations the compressors, and therefore their energy consumption, depends on
order to satisfy specifications until their end use, which may be ex- the gas flow and the pressure drop along the lines. This process consists
portation, treatment for use in the process, or disposal. of two compressor trains with two stages each, driven by induction
The FPSO platforms are equipped with storage systems that corre- motors.
spond to large tanks where the oil is stored on deck until it is sent to oil CO2 Compression Unit: At the CO2 Compression Unit (CCU), the
tankers, or directly to the continent via pipelines. In the Gas Processing CO2 removed in the oil and gas processing undergoes two parallel
Plant (GPP), the extracted and separated natural gas is subjected to a compression trains with four-compression stages, an intercooler of
series of treatment processes according to its final purpose. The gas can printed circuit type switches follows each step. A gas turbine powers
be exported to the continent, used for injection in wells, lifting, and each compression train.
used on platforms for generating power. Gas Injection Compression: This unit has two compression trains
The offshore separation of these three phases is necessary to max- driven by induction motors to inject the produced gas into the re-
imize oil production and minimize its gas and water content, for eco- servoirs.
nomic reasons and production process requirements. Fig. 1 summarizes Produced Water Treatment: The wastewater treatment system re-
the operation of an FPSO based on [13], described below: moves oil and solid waste from the water stream using hydrocyclones to
Production Manifold: Crude oil is extracted from one or more wells meet the specifications for its final use. Seawater is supplied to the
and transferred to the work of ducts and a system of collectors. A system system, pumped and processed in the cooling water system. A large part
of valves delivers the fluids to the separation unit. is used in the process of re-injecting water into the oil extraction tank to
Separation and oil treatment: In the separation unit, the flow is maintain the oil pressure and provide a secondary oil recovery.
separated into oil, water, and gas, by gravity, dehydration and heating Fuel Gas System: During the operation mode of the gas plant, with
process. The treatment of the oil aims to reduce the water content of the the removal of CO2 through the membrane system, the fuel gas must be
oil until it reaches the level required for sale, generally evaluated by the taken on the side of the natural gas, downstream of the membranes.
BSW (Bottom Sediments and Water) indicator. Fuel gas can also be collected from any stage or downstream of the
Vapor Recovery Unit: This unit includes a compression step fol- export compression system if turbine manufacturers require more
lowed by condensation, absorption, and adsorption. This system aims to pressure.
reduce GHG venting and use the recovered gas in the next stages of the The GPP is made up of sectors with high electricity demand.
plant. A screw compressor composes this system with two stages driven Substantial exergy destruction is associated with the gas compression
by an electric motor. train, as the compressors typically used on offshore oil platforms feature
Main Compression Unit: In the Main Compression Unit (MCU), there a relatively low isentropic efficiency and gas recirculation. Therefore,
is a re-compression of the gases from the gas separation processes. flow variations are expected and surge must be prevented [39].
Gas dehydration Unit: Gas dehydration on off-shore platforms is According to [1] the efficiency of the compressors is higher at peak
conventionally achieved by a glycol absorption or adsorption system or production since they are designed for this operating condition.

Fig. 1. Summary of Operation in an FPSO.

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Equipment efficiencies do not vary significantly during the FPSO op- operation. Hydrocarbons, Ethers, and Alcohols were disregarded be-
erating period (5% over the period) since gas flow rates at their inlets cause of their flammability characteristics. Siloxanes and Inorganics
are adjusted by gas recirculation. In addition, the regular service and fluids did not present a good thermodynamic performance for the
constant maintenance activities of the compressors are directed at analyzed heat sources and were disregarded in the optimization pro-
eliminating the negative effects of degradation and incrustations. cess. In Fig. 4 the fluids evaluated in this study are presented, according
Using this waste heat to generate electricity is a very attractive to the critical pressure and temperature parameters and the maximum
proposition because the heat exchangers must be installed anyway and operating temperature.
thus the added installation weight and cost for a power generation
system are relatively low. The energy recovery potential is still mod-
erate due to the low-temperature level and obviously depends on the 3.1. Waste heat evaluation
heat source conditions [37].
The focus of the thermodynamic model development is the char-
3. Methodology acterization of the waste heat sources at the production stages in the
GPP. The first step in the development of the thermodynamic model is
In this study a physical model of the systems of interest was de- to determine the energy potential of each source as a function of its
veloped, using ASPEN-HYSYS® software v.8.6 for simulation of the chemical composition, pressure, temperature and molar flow.
processes according to the operation data, based on measurements The analysis for integrating these sources into the ORC cycle con-
provided by the FPSO replicant project [13]. From this simulation, the sists of determining the amount of thermal energy available in each of
properties and compositions of each material and energy stream of the these. The modeling of the heat sources allows the equation of these for
FPSO were determined. This analysis comprises a mass, energy and integration into the thermodynamic analysis model of the ORC cycle.
exergy balances for each process and equipment. The MCU consists of three parallel compressor trains to accom-
From this analysis, it was possible to identify preliminarily the main modate the gas flow.11 MW induction motors drive each compression
sources of waste heat from the platform. According to this analysis, the train through variable speed drives. After compression, the gas flow
most significant amount of waste heat generated in the platform is due passes through a printed circuit type aftercooling condenser. The in-
to the heat generated during gas compression activities by the GPP. The tercooler ensures that the dehydration takes place under optimum
major exergy losses on the platform are associated with this rejection of conditions and reduces the power demand of the second compression;
high-temperature exhaust gases since only a minor fraction of this the aftercooling prevents unacceptably high gas temperatures at the
waste heat is recovered [1]. pipeline inlet. The heat is released into the sea and therefore wasted.
The measurement of the maximum heat available in the heat source The proposed integration of the ORC cycle in the MCU is shown in
in GPP operations is calculated by lowering the initial temperature to Fig. 2.
the outlet temperature of the FPSO condenser. According to the con- The CCU presents a high potential for residual heat recovery. A
dition of the operational limit imposed in the platform process. representation of the process can be seen in Fig. 3. The application of
According to [40] working fluids in ORC cycles can be categorized the ORC cycle was investigated by recovering heat individually, in the
into seven major classes: Hydrocarbons; Perfluorocarbons; Siloxanes; intercoolers between the four stages of compression, and in the after-
Ethers; Alcohols; Perfluorocarbons and straight chain hydrocarbons cooler after the fourth stage of compression.
partially substituted by fluorine. In this study 26 different working The gas flow composition at CCU and MCU are presented in Table 1
fluids of the halogenated classes (with hydrogen atoms partially or according to the general process specification for the FPSO studied.
totally replaced by fluorine atoms) were evaluated. These fluids are Table 2 presents the operating conditions of each Unit evaluated using
considered inert and stable, with a complex molecule structure and the ASPEN-HYSYS® software v.8.6.
with a significant ODP level (often equal to zero), although not pro- The results of the simulations of the processes are consistent with
viding the best thermodynamic conditions. the platform operation data. In this way, it can be affirmed that the use
The characteristics of these fluids make them favorable to their of the tool was efficient to evaluate the heat recovery potential in the
application in FPSO, mainly in relation to the safety level of the FPSO.

Fig. 2. ORC integration at CO2 Compression Unit.

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Fig. 3. ORC integration at Main Compression Unit.

3.2. Thermodynamic model of ORC cycle Table 1


Composition of gases.
The properties of the working fluids, operating parameters and the Component Composition
configuration of the thermal system play a fundamental role in the
thermodynamic efficiency and economic viability of the ORC cycle. CCU [%] MCU [%]
Mass and energy balance equations that describe the performance of
H2O 0.002 0.5562
each component in the thermal system were integrated into a Matlab
N2 0.2034 –
2014ª® computational model. This analysis provides the steady-state CO2 70.7978 2.9909
operating point for a given target application (platform heat source) Methane 27.5123 76.9367
and environmental conditions. The thermodynamic properties of the Ethane 1.2103 9.2106
Propane 0.2140 5.9823
different working fluids are evaluated using the REFPROP 9.1® data-
Others 0.0602 4.3233
base. The diagram in Fig. 5 describes the ORC cycle configuration in-
tegrated with the heat source.
For the system simulation, it was assumed that the cycle operates Table 2
under steady-state conditions, pipe pressure drop is ignored, and heat Operation condition data.
losses to or from the surroundings together with potential and kinetic
Unit Temperature [°C] Pressure Mass flow [kg/ Heat [kW]
energy changes are ignored. The quality of the fluid at the exhaust of
[kPa] s]
the turbine is higher than 0.9. The turbine and pump efficiency are
constant. 1° Stage CCU 415.15 1144.4 55.5 6588.0
Generally, radial-inflow turbine efficiency is assumed to be a con- 2° Stage CCU 417.15 3133.8 55.5 7025.2
3° Stage CCU 418.15 8825.6 55.5 9094.4
stant value in the conventional ORC system analysis. In these analyses a
4° Stage CCU 408.15 25109.9 55.5 10918.8
common value of turbine and pump isentropic efficiency for ORC ap- MCU 431.15 8196.1 61.8 19980.0
plications is 80%, as presented respectively by [41,42].
Song et al. [41] conducted a thermodynamic analysis of the ORC
system with a model-predicted turbine efficiency and a constant turbine lead to different radial-inflow turbine design and then different turbine
efficiency and compared the results with each other. Considering the efficiency, and vice versa. The main design parameters of the turbine
turbine efficiency as constant, it will impact the ORC system parameter geometry are also determinant for the efficiency of the equipment [43],
determination. Different thermal parameters of the ORC system would as well its operation condition [44].

Fig. 4. Working fluid characteristics.

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Fig. 5. ORC diagram.

Table 3 ̇ and cycle efficiency ηORC are given by:


Finally, net power Wnet
Thermodynamic model validation.
̇ = WT −WP
Wnet (9)
Parameter EBSILON 12.05 Model Error [%]
̇
Wnet
Temperature Tf [K] 667.910 667.910 0.000% ηORC =
̇ , ORC
Qin (10)
Temperature Tf2 [K] 590.538 590.548 0.002%
Temperature Tfout [K] 573.114 573.128 0.002% The model assumptions and parameters constrain at thermo-
Temperature T1s [K] 490.549 490.548 0.000% dynamic model are, based on [45]:
Temperature T1 [K] 650.540 650.548 0.001%
Temperature T2 [K] 376.680 376.680 0.000% PP = Tf 2−T1s ≥ 3[K ] (11)
Temperature T3 [K] 376.680 376.680 0.000%
Temperature T4 [K] 374.730 374.730 0.000% ΔT = Tf −T1 ≥ 10[K ] (12)
Temperature T5 [K] 375.008 375.007 0.000%
Temperature T6 [K] 375.008 375.007 0.000% ΔT0 = Tfout−T6 ≥ 5[K ] (13)
High pressure (1, 1s, 5, 6) [kPa] 2206.400 2206.400 0.000%
Low pressure (2, 3, 4) [kPa] 107.271 107.271 0.000% The numerical solution of the mathematical model was validated
with EBSILON@Professional 12.05 software, which uses the REFPROP
9.1® data library, as in the proposed model, in which case there is no
The working fluid at the condenser outlet is saturated liquid. The significant error in the results as shown in Tables 2 and 3. These pro-
condensation pressure of the cycle is determined as a function of the fessional software’s are used to describe ORC operation parameters.
condensation temperature T4, the lowest condensing temperature con- Kalina el al. [46] use the EBSILON to modeling a newly built biomass
sidered is 40 °C [13]. Working fluids operate only in subcritical con- fired system, that consists of VAS thermal oil boiler and the Turboden
dition. T6-CHP ORC commercial unit of 606 kW electric power output.
Eqs. (1)–(4) show energy balance and isentropic efficiency defini-
tions for the expander and pump respectively. 3.3. Heat exchanger design
WṪ = ṁ wf (h1−h2) (1)
The ORC cycle equipment design is essential for a more realistic
h1−h2 assessment of the cycle's operating parameters so that it can evaluate
ηT =
h1−h2, is (2) more practical results in the optimization process.
Most of the authors in their ORC cycle optimization proposals as-
ẆP = ṁ wf (h5−h4 ) (3) sume several simplifications concerning the major components of the
cycle. Such simplifications have a significant influence on the perfor-
h5−h4, is
ηP = mance and cost of these technologies, leading to results that are not
h5−h4 (4)
always realistic [47].
Eqs. (5)–(7) give the energy balance of the condenser and eva- An analysis of the performance of a heat exchanger was proposed
porator. for a printed circuit heat exchanger (PCHE) with two different channel
geometries: wavy (zigzag) channels, offset strip fins. The heat ex-
̇ = ṁ wf (h3−h4 ) = ṁ c (hc1−hc 2)
Qcon (5) changer thermal design is based on [48,49] studies, using the classic
̇ = ṁ s (hf −h f ) = ṁ wf (h1−h6) LMTD method summarized in Fig. 6:
Qevp out (6)
The main equations are briefly described below:
Eqs. (7)–(8) show the effectiveness definition and energy balance of
Qḣ = ṁ h cp h (Th, i−Th, o) (14)
the recuperator.
T6−T5 Qċ = ṁ c cp c (Tc, o−Tc, i ) (15)
εrec =
T2−T5 (7)
Q̇ Ch (Th, i−Th, o) Cc (Tc, o−Tc, i )
ε= = =
̇ = ṁ wf (h2−h3) = ṁ wf (h6−h5)
Qrec (8) ̇
Qmax Cmin (Th, i−Tc, i ) Cmin (Th, i−Tc, i ) (16)

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e = e ph + e ch + e kn + e pt (20)
In this study, the kinetic and potential effects on the exergy asso-
ciated with material flows are considered negligible compared to the
physical and chemical contributions. The terms of potential exergy are
negligible in compressible fluids, which are the object of study of this
work. The term kinetic exergy is important in turbine-related flows but
can be discarded considering that this term in the output of equipment
is used in the following equipment and does not affect the analysis of
the whole [51].
According to a study by [1], in practice, there is energy consump-
tion in the elevation of water and other fluids in the platform, and
height differences are considered in the calculations of pressure and
physical exergy. The kinetic exergy is destroyed in the wells and ducts
as there is a reduction of the velocity of the oil and gas flows to facil-
itate the separation between the vapor and liquid phases. Likewise, in
the exergy evaluation of an oil exploration plant, Nguyen et al. [52]
states that the estimation of kinetic and potential exergy in a plant is
impaired by the lack of measurement of these parameters throughout
the processes and their effects can be neglected.
In this way, the exergy of the evaluated systems is only a function of
the physical exergy component. According to [53], in the particular
case of a mass flow of a stable open system, the physical exergy off a
mass flow can be obtained by the following expression:
EPH = (H −H0)−T0 (S−S0) (21)
Bejan et al. [50], defines that those flows that act as sources of
exergy are called resources (F) necessary for the manufacture of a given
product (P). It can be affirmed that every thermal system interacts with
its environment consuming external resources (F) that are later trans-
formed into products (P). Besides, it is probable that within the system
there are flows whose utility is zero, and these are considered as losses
(L). The application of these concepts is used to apply the balance of
Fig. 6. Heat exchanger design diagram. exergy in the evaluated FPSO systems, Table 4.

3.5. Optimization
Table 4
Thermodynamic model validation (Equipment).
Defining the best ORC cycle configuration integrated with residual
Parameter EBSILON 12.05 Model Error [%]
heat sources in an FPSO is not a simple intelligible process. The para-
Turbine power [kW] 2794.057 2794.074 0.001% metric evaluation is not sufficient for a satisfactory analysis of the
Pump power [kW] 14.995 14.994 0.007% thermodynamic performance of the system since the implementation of
Condenser duty [kW] 12323.304 12323.308 0.000% the ORC cycle for FPSO application considers conflicting objectives: the
Evaporator duty [kW] 15107.994 15108.016 0.000%
maximization of the power generation and the minimization of the area
UA condenser [kW/K] 174.498 174.494 0.002%
UA evaporator [kW/K] 131.031 131.032 0.001%
of the equipment that composes the cycle.
The multi-objective optimization proposed in this study aims to
better configure the ORC cycle by evaluating the objective functions
2gc η Δp ⎛ j ⎞ ⎤
1/2 independently. In this aspect, the optimization process evaluates dif-
Gn = ⎡ · o ferent combinations of cycle design parameters (working fluid, pinch
⎢ (1/ ρ)m ·Pr 2/3 ntu ⎜ f ⎟ ⎥
⎣ ⎝ ⎠⎦ (17) point in the evaporator and condenser, overheating, vaporization
pressure and heat recovery efficiency).
1 1 1
= Rh + Rh, f + Rw + R c, f + R c = + + Rw A multi-objective problem requires the simultaneous satisfaction of
UA (ηo hA)h (ηo hf A)h
many different and often conflicting objectives, making it impossible to
1 1 find a solution that satisfies all the objectives simultaneously.
+ +
(ηo hf A)c (ηo hA)c (18) Therefore, it is necessary to find the set of optimal solutions.
The optimal Pareto solution is the critical concept to establish a
hierarchy among the solutions of a multi-objective optimization pro-
Δp =
⎡ 2 ρi
( ) L
Gn2 ⎢ (1−σ + K c ) + 2 ρo −1 + f rh ρi ( ) ⎤⎥
1
ρ m blem, determining if this solution is indeed one of the possible best
2gc ρi ⎢ ρ
− (1−σ 2−K e ) ρ i ⎥ results. Thus, a solution is an optimal Pareto point if no other point in

⎣ o ⎥
⎦ (19)
the search space is better for all goals.
In this research, the NSGA-II method described by [54] is used,
which is a multi-objective Genetic Algorithm that classifies the optimal
3.4. Exergy analysis solutions according to the concept of Pareto dominance.
Each optimization case considers two objective functions:
In the absence of nuclear, magnetic and electrical interactions, the
exergy associated with the flow of matter is a function of the physical
• Maximization of net electric power Wn [kW]
exergy components eph, chemical ech, kinetics ekn and potential ept, and
is expressed as [50]:
• Minimization of the heat exchanger area [m ]. 2

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T. Gotelip Correa Veloso et al. Energy Conversion and Management 174 (2018) 537–551

Fig. 7. Results of Stage 1 CCU optimization.

Fig. 8. Results of Stage 2 CCU optimization.

The considered area is the sum of the whole of the heat exchange best performance of the ORC cycle, according to the objective func-
surface area of this equipment. This area is calculated using the sub- tions. The minimum power generation limited for each source was
routine (Fig. 6) design program to design a printed circuit and plate-fin 200 kW. Lower values were considered not appropriate for this appli-
heat exchanger. cation [13].
The results presented are the Pareto frontiers of the optimization
process. Different fluids made up the Pareto frontier for maximizing
4. Results
power generation in parallel with the minimization of the total area of
the ORC cycle. In this way, the results presented from the lowest es-
The multi-objective optimization process maps the decision vari-
tablished net power up to the maximum generated, are results of the
ables to find a series of procedures for how to combine the input con-
combination of ORC cycle parameters that allow the smallest possible
ditions, such that the values of the objective functions are acceptable, or
area for that condition. The choice of a single optimal result will depend
in some sense optimal. The optimization of the problem evaluation led
preponderantly on the constraint of the physical area of each platform.
to the set of optimal solutions in the search space, thus determining the
At CCU the ORC application was investigated to heat recovery from
Pareto frontier according to the established objective functions.
the intercoolers between the four stages of compression, and in the
The results for heat recovery in low-temperature platform sources
aftercooler after the fourth stage of compression individually.
are presented below for the CCU and MCU. In this procedure, the op-
In the first stage of compression two working fluids make up the
timization of the operating parameters of the cycle, for each working
frontier of optimal results. The different combinations of ORC cycle
fluid evaluated and for the different heat sources investigated, allowed
operation parameters allow the generation of power with the minimum
the determination of the set of operating conditions that guarantee the

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T. Gotelip Correa Veloso et al. Energy Conversion and Management 174 (2018) 537–551

Fig. 9. Results of Stage 3 CCU optimization.

Fig. 10. Results of Stage 4 CCU optimization.

area of 220 [m2] operating with R245fa fluid. The highest net power stage, it was possible to generate 938.8 kW of net power requiring a
generated by the ORC cycle was 597.7 kW, with a total heat transfer total heat transfer area of 1340 [m2], and the minimum area of
area of 2312.2 [m2] with R236fa working fluid, Fig. 7. 163 [m2], Fig. 10.
In the intermediate stage of the second compression stage, the range The analysis of heat recovery at CCU reveals an increase in the
of results requires the minimum total area from 179.6 [m2] to the amount of energy from the waste heat flow rejected by the condenser in
maximum area of 2261.2 [m2] for the highest power of 692.2 [kW]. each stage. In this way the energy generation by the ORC cycle in-
Two working fluids determined the optimal results, R245ca for a range creases at each stage, followed by the decrease of the required heat
between 200 and 300 kW, and R236fa above that, Fig. 8. transfer area.
The recovery of residual heat from the third compression stage al- At MCU three fluids make up the optimal results frontier for dif-
lowed the generation of 888.6 [kW] of net power, with an area of ferent operating ranges of the ORC cycle, Fig. 11. For the generation of
2228.3 [m2]. As in the first two stages, the highest power generation lower net power, between 200 and 470 kW, the optimum fluid was
resulting from the optimization of the ORC cycle was obtained with R1233ZD with a minimum area of 130 [m2]. For average net power
R236fa working fluid. For power ratings below 230 [kW], the selected between 470 and 750 kW the best operating condition is with R245FA.
working fluid would be R1233ZD, with the minimum area of Above this range, the fluid that provided the highest net power gen-
179.2 [m2], Fig. 9. eration was R245CB2 reaching 2063 kW with a heat transfer area of
In the heat recovery of the aftercooler after the fourth stage of 2997 m2.
compression, only RC318 fluid composes the optimal results. At this The comparison of the ORC cycle optimization results for heat

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T. Gotelip Correa Veloso et al. Energy Conversion and Management 174 (2018) 537–551

Fig. 11. Results of Stage MCU optimization.

Fig. 12. Low-grade waste heat recovery comparison.

recovery in low-temperature sources in the FPSO is presented in Fig. 12. waste heat source cause the required heat exchange area to increase
From this analysis, it was concluded that among the low-quality significantly for higher power generation.
sources, the most significant potential for heat recovery would be the The use of low-quality waste heat sources has less potential for
MCU. In this way, this application should be considered the most sui- electricity generation than turbine heat recovery. However, this ana-
table for the implementation of an ORC cycle, providing the highest net lysis has an impact on increasing the efficiency of the systems. The net
power generation aligned with smaller areas. Evaluating only CCU power produced by the ORC cycle in the aftercooler of the fourth
sources, the third stage of compression allows the highest power gen- compression stage represents 21.4% of the consumption of this com-
eration combined with smaller areas in the range of 200–700 kW. pressor, Table 5.
Above this value, heat recovery from the compressor aftercooler pro- The evaluation of exergy in the systems presented reveals the po-
vides the optimal ORC results. tential of implementing ORC cycles in FPSO processes. In Fig. 14, an
The relation between the net power produced by the ORC cycle and exergetic analysis is presented concerning the optimized results of ORC
the total heat transfer shown in Fig. 13 confirms the most considerable cycles. The increase in the exergy efficiency of the ORC cycle is directly
advantages of using heat recovery in the MCU and the best range of related to the increase of the net power produced by the cycle, and
operation in the CCU. There is a significant decrease in this relation as consequently an increment of the efficiency of the compression system.
the power generation increases. The low quality and temperature of the The use of ORC cycles promotes a significant gain in exergetic efficiency

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T. Gotelip Correa Veloso et al. Energy Conversion and Management 174 (2018) 537–551

Fig. 13. Net power Ratio.

Table 5
Schematic diagram of exergy evaluation.
Resources Product Efficiency

FPSO compressor Wc ̇ −EFa


EFb ̇ ̇ − EFa
EFb ̇
ηII =
Wc

ORC EḞ −EFout


̇ Wn =WT −WP ηII =
Wn
̇ − EFout
EF ̇

FPSO compressor + ORC Wc ̇ −EFa


EFb ̇ + Wn ̇ − EFa
EFb ̇ + Wn
ηII =
Wc

in all evaluated systems. The implement of the ORC cycle in the exergetic efficiency of the compression stage is increased from 43.94 to
aftercooler of the CCU provides the highest exergy efficiency increases 65.36%, representing an increase of 48% (see Table 7).
for the compression stage. In a scenario of operation with ORC cycles at each of the com-
In Table 6 the results of the exergy evaluation for the conditions of pression stages of the CO2, Compression Unit the cumulative capacity of
greater generation of net power by the cycle ORC are presented. The the power generation cycles would be 3117.3 [kW]. This power gen-
thermal efficiency values of the ORC cycles are between 9.23 and eration represents 14% of the unit's total power consumption. Also, the
10.84%, the current amount for the operation of these cycles. The ex- exergy efficiency of the whole unit would increase from 55.61% to
ergetic efficiency of the ORC cycles under these conditions is in the 69.64%, an increase of more than 25%. This scenario is not a realistic
range of 50.9–56.14%. It can be observed that the use of the ORC cycle option regarding the availability of the physical area on the platform.
provided an increase in exergetic efficiency at each of the compression The heat recovery only in the last stage of compression of the CCU
stages of the CCU and in the MCU. In the aftercooler of the CCU, the allows a power generation by the ORC cycle which represents 4.22% of

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T. Gotelip Correa Veloso et al. Energy Conversion and Management 174 (2018) 537–551

Fig. 14. Exergetic analysis of ORC cycle application.

Table 6 and minimize the area. A mathematical model to evaluate the ther-
Relevance of ORC application. modynamic performance of the ORC cycle and to predict the design of
Unit ORC Net ORC Area Compressor Rate [%]
the heat exchanger was developed in MATLAB®.
power [kW] [m2] consumption [kW] The results presented constitute the Pareto frontier of the proposed
optimization. In this way, each of these is an optimal result, which
1° Stage 597.7 2312.1 6181.8 9.66 guarantees the best combination of ORC cycle parameters. Since the
CCU
2° Stage 692.2 2261.1 6062.9 11.4
physical area availability of each platform should be different to meet
CCU the characteristics of the fields, the presented methodology allows
3° Stage 888.6 2228.3 5585.5 15.9 evaluating different configurations according to the area possibility of
CCU each platform.
4° Stage 938.8 1340.1 4383.5 21.4
The FPSO process analyses indicate that there is a very significant
CCU
MCU 2063.3 2997.7 14809.5 13.9 amount of waste heat at the compression systems in CCU and MCU.
Heat recovery in MCU and CCU aftercoolers are the most promising
options for FPSO low-temperature heat recovery. In the MCU it was
the overall consumption of the compressor, and an increase of the ex- possible to generate higher net power by operating with R245CB2 fluid.
ergetic efficiency of each unit in the order of 7%. The implementation This operation allows the generation of up to 2063 kW with a heat
of the system in the MCU allows a more significant power generation, transfer area of 2997 m2, providing a 23.6% increase in exergy effi-
which represents 13.93% of the compressor consumption in the unit, in ciency of the system.
addition to a 23.6% increase in exergy efficiency of the operation. The highest net power generated in the CCU was 938.8 kW oper-
ating with RC318 fluid, requiring a total heat transfer area of 1340 m2.
Net power generation at this stage represents 21.4% of the stage's
5. Conclusion power consumption and 4.22% of all compression compressors, in ad-
dition to an increase of 48.74% in the exergetic efficiency of the stage
This study presented a multiobjective optimization of the ORC ap- and 7.0% about the unit’s entire compressor system. Different working
plication for low-quality residual heat recovery for the Brazilian FPSO. fluids made up the Pareto frontier at the different sources.
This analysis is based on the basic design data for production modules The results of this study suggest that the application of ORC cycles
of eight standard FPSOs proposed for application in the Pre-salt. The on FPSO platforms for heat recovery from low-temperature sources
optimization objective functions were maximizing the ORC net power

Table 7
Exergetic analysis.
Unit Net Power [kW] ORC ηI [%] ORC ηII [%] CSηII [%] CS + ORC ηII [%] ηII increase [%]

1° Stage CCU 597.7 10.47 51.87 63.06 72.73 15.33


2° Stage CCU 692.2 10.84 54.85 61.00 72.42 18.71
3° Stage CCU 888.6 10.48 56.14 54.70 70.61 29.10
4° Stage CCU 938.8 9.23 50.97 43.94 65.36 48.74
MCU 2063.3 11.37 56.13 59.05 73.00 23.60

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