arzr019 Engineering the Low-Temperature Performance of Li-S Batter
Mesting Abstracts
inaccoa org
‘Absrest Mazoro-0% 497
Engineering the Low-Temperature
Performance of Li-S Batteries
id Arumugam Manthirarn®
Author sitions
Abstract
For the last ow docatos, ihiun-on batts employing iseton-compound cathodes
‘and graphite rods have become the standard in consumer eecrnce anc have even
become sonmonelace in appliations wth exteme-opratng enuronmers, such 28
stone to space. Ae auch misslone increase incomslexty and apploatons coninos|
to requre icrasingly greater epee enarny, the energy dansty of secondary
botaries needs to silat erase, Ltun-aulur (LS) bates have the potent
offer Sgniteant mprovemerts due to te euureahode's nigh tnoretelcapacty of
4.872 mAM Gand yates theortalanargydenay of 2.509 Win kg!
Convenor hisn-on bates exparonca a sharp fst in neray and power dent
at tomperatres below 0'C, which sigfianty Impacts casi paremators fo
appicatons tks space missions. Dung charge and discharge, low tomporatures
Keestcaly impede all saps of mass transfor of thium lors though the bata,
parsulaty through tho Increasingly vscous elocro}ta a6 well 25 the elecrose
ecto} inertace. This ultimately leads to reduced capacty and ulation of active
mats? in this work, we show that many of these same vends nald sue for LS
Dateries at ow temperatures, Not only a there @ severe crop in access capac
wih decreasing temperatures, bul ths los pinay exhtod by 2 shortening
length of te second votag plateau" Tis plateau conesponds tthe fermaton ofthe
inealuble spaces nonaqueous solvents at low famperaires, We exclore ts
behavior in deal and essuss our forts In olctelyte co-solent and adeno
enginorng wards designing a L-S batry capable o porating at lw tomperaties.
‘Acknowdgemar
Falowati,
This work was supported by @ NASA Space Technology Research
References:
4.M.6. Sma 8, L Luh, $ Dalav FC. Keauee, a 8, V Ratakumar, J
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3.6. Znuetel, Power Sources, 200, 29-40 2018)
4. aha and JR. Aelage, J Eletochom. Soe, 150, AS05-ASHY
(2003,
Figure caption:
Figure 1. Third cycle dacharge-charge curves of a standard LS ost
Figure
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