arzr019 ‘Metal-Organic Frameworks As Solid-State Lon Electrolyte Mesting Abstracts inaccoa org ‘Absrost MAz015-03 476 Metal-Organic Frameworks As Solid-State Li-Ion Electrolyte Maarton J. Moss", Gaotrey Pourtols’, Andre Stasmans", Stefan Ds Gendt” Maradsana Crestore®, W.M.M. Kessela' and Philippe M. Vereecken” El autor ataions Abstract The use of nanoabuctued malafale can moke © sigafiant contbuton to the evelopment of sole-slate bala [1] We here focus on a class of nanostetred materi called meakorgaic frameworks (MOF. which exits promising ropes that potenaly moet the raquiemens ofa sokdtate Lon secre in es of igh lorie conduetuly (> 10" Siem) and low electonic leakage. MOFs are rybrs ranoporous soi tht osu fom a encion of organ pans and metalic ets 0 Ccoate a too-smensionalconalledskabion. Fg 1 hates the eysial stirs of tho $0 callod MIL-121 MOF [4]. Th 1D pores of is structure by which the kanspor of Ions scared out hav promising diansions. Indeed he arg nano-ysaine pores of tba MOFs ae expected sft a igh ionic conduct, a the rable lens ae not ‘terial hinged nie tne pres, The auon mechani na functionals MOF le ‘xoectd fo occur in a silar wey to the one of an adatom ontop of a eure. A g2neral used aporosch to create aL lon conducbve MOF focusses onthe inci of 2 Weium satin te MOF pores, Yana! ot a(S] eportad thet the incorparaten of = Complex of poyethyeneglcl wi) LB to the nanachannels of « Zn MOF lads 1 tue tke mobliyof the Lone (ectvaon energy of atusion equals 0.18 eV), Wire ff a demonstrates the upake of tum sapraponde (LOI) salt ina MOF. The 38 lechostatealy Sound to the open mal centers of tht Me-MOF. An one conductvay of 81x10 Siem i rpored. By a sear approach Arelot ef a invoices Hhium san & Z+MOF. Hae, the Itson ste chemiealy Bons othe organi Igand of he MOF Fa, + snows the crystal stile of fhe MIL21 whieh we Invested with fet pines techniques bssed on densty urctona theory (DFT) The earaxyharous {hs stueue folate herseles such thal thei acdle Famework protons (beled A in Fe. 1) inavact wih two carboxylgoups. Cansequenty, an apan-pre stuctua Ie blind Tne lu nthe ores the 121 he aise fame proane by Hist of 7. Only her, the lhiumproton exchange reacton occurs on | cmtortatoep rer then om wt one The ie city ofthe earbayrorurs wih respect to th hon ones potently resus ina high Iitbiam concerraton. Furthermore, the weak boné between ths ~COO" anon and he Li" cation, andthe rotational tredom of tho carboxy-reup ae expected to futher improve tho ionic conduct, Wo wt present the modeling matodology tat erates us to siulsle Lion ‘conductiay in bw MOF pores, fotowed by a dscusion on the obtanad resus. The onesies of the deren cise famewerk prolons A.B, and C (soe Fig. 1) ae ‘compar to sath other. Fnay, tho dyeamics of he atoms inte uit call of he ML 121 is susies for the highest possble itu concentation in whch all accie framework protons A are subsite by a Li" jon. The resus of this sty go US omit Insight on the behavior ofthe Luons in MOF pores, These resus less 10 sel suggastono further develop MOF as sa-stata Lin locos. [H1Lu, ©. U, F, Ma, LP, and Cheng, HM. (2070) Aabancee Maer, 22, £28 — [2] Patt A, Pat V, Shin, D. W Chol, JAP, Pak, O-S., and Yoon, SJ. (2008) Matonls Research Bult 9, 1013-1942, [5] ang ¥ and Gao, 6.2008) Advanced Matera, 20, 2251-2269. lel Votsinger ©. Loseau,T. Gullo. Férey.G., Haouas, M. aul, F, Ekin, {and Stock. (2010) Inorgant enemisy, 48, 9852. [5] Yona, N, Uemura, T, Hotke, S, Shmomut, Sand Kiagaws,S. (2012) Chemear ‘Communications (Camondge, Unted Kingsom), 4, 1722. [2] Amaoo,R, Aubry. M. Ws, BM, Gémera-igueoa, A. P, Pla. SN. Balsa, NN.P, and Long, dR (2019) Ghomisty- A European Jounal, 1, 5533 ‘ma.ecsalarg/contentMA20 15-09/21476 abstract ?sid=2b676d13-a216-407t-9e03-2ac639b0332— 1srerie0t9 ‘Metal-Organic Framaworks As Solid-State LHlon Electrolyte (71 Hina, ©, Wallacher, ©, ane Hermann, M. (2009) Angewandte Chemie (otomationa en Engle) 48,4839, May bo of intorest Innovate High Perforring Meta Organic Framework (MO=}Lacen CComposte Palmer Elactyts for ‘MI Salié Stato Litem Batteries Claude Geral etal, EOS Mesting Dnstacs odie Mata Organi Frameworks ((O=s)onic iui Matrices for Enicent Charge Storage Akt Singh etal, Journal of The Electochanveal Solty Enhanced Electrochemical Pertrmance ofthe Cabede for Linum lon Secondary Battery Using Lutsum lon Conauctve last Ceramics Meecular Dynamic Sintations of lon Transport in Pol-Erylane Oxide Mostng Absiracis| Gurel Based Electrohtes Based on U6 75.a3.XMAZ.75TA0.25012-D tor Al Sali State Litum Batis: Systematic Doping on th Lanthanum ‘Se wn Two and Three Valent Mhal Snake al, ECS Mastng Powered by TREND ETE ‘ne-Pot Syvess of Co-Basod Coordination Polymer Nanowire for Lion Bsteses wits Great Capacity and Stable Cycing labiiy ‘Th Surface Coat of Commercial LiFeP0e by Uezing ZI-8 for High Elscrochenscal Peformance Lion len Batiry XiaoLong Xue a, Nano Mero Radaton grat of aryamide onto poethylane soparatrs or hanson batteries Xino-L Mino otal, Nicar Siones and Teciquee| ako Forest, uantapors Tweak ‘Array Producton Mstnod in Pursuit of Sol State Nanopoes wih Opti Detection Genomes ihty Selactve Linum on ‘Adsorvents Polymeric Prous Merospare wit Croan Ether Groups Caldeng Yuan et a, Transactons of 1s orgicontentMAZ016-03/2/76 abstract?sid=2be76413-3216-407F-See3-2ac83009332a 22