ORGANIC CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 28

This DPP is to be discussed in the week (14-09-2015 to 19-09-2015)

DPP No. # 28 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

1. Acetaldehyde and Acetone can be distinguish by :

(A) 2,4–DNP (B) I2/NaOH (C) Lucas reagent (D*) Ammonical AgNO3
,slhVSfYMgkbM vkSj ,lhVksu ds e/; fdlds }kjk foHksnu dj ldrs gS :
(A) 2,4–DNP (B) I2/NaOH (C) Y;wdkWl vfHkdeZd (D*) veksuhd`r AgNO3
Sol. Acetaldehyde give positive Tollen (Ammonical AgNO3) but ketones are not
,slhVSfYMgkbM VkWysu (veksuhd`r AgNO3) ds lkFk /kukRed ijh{k.k nsrs gSa] ysfdu dhVksu ugha
2. Acetaldehyde and Propyne can be distinguish by :
,slhVSfYMgkbM vkSj izksikbu dks fdlds }kjk foHksfnr fd;k tk ldrk gS %
(A) NaHCO3 (B*) I2/NaOH (C) Lucas reagent (D) neutral FeCl3
(A) NaHCO3 (B*) I2/NaOH (C) Y;wdkWl vfHkdeZd (D) mnklhu FeCl3
Sol. Acetaldehyde and Propyne can be distinguish by Iodoform test.
,slhVSfYMgkbM vkSj izksikbu dks vk;ksMksQkeZ ijh{k.k }kjk foHksfnr fd;k tk ldrk gSA

3. and can be distinguished by :

(A) Iodoform test (B) Tollen's test

(C*) Fehling solution test (D) 2,4-DNP test

rFkk dks fdlds }kjk foHksfnr dj ldrs gS %

(A) vk;ksMksQkWeZ ijh{k.k (B) VkWysu ijh{k.k

(C*) Qsgfyax foy;u ijh{k.k (D) 2,4-DNP ijh{k.k

4. I and II are homologues. These can be distinguished by using :

I rFkk II letkr gS aA fdlds mi;ksx }kjk buesa foHks n fd;k tk ldrk gS :

(A) Tollen’s reagent (B) 2, 4 – DNP (C) Baeyer’s reagent (D*) I 2 + NaOH
(A) VkWysu vfHkdeZd (B) 2, 4 – DNP (C) cs;j vfHkdeZd (D*) I2 + NaOH

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5. Which of the following compound will give black or silver ppt. with Tollen's reagent.
fuEu esa ls dkSulk ;kSfxd VkWysu vfHkdeZd ds lkFk dkyk ;k jtr vo{ksi nsrk gSA
(A) H  C  C – CH2  C  CH3 (B) CH3  C  C  C  CH3
|| ||
O O

(C*) CH3 – C  C – CH2 – CHO (D) CH2  CH  C  CH  CH2

||
O
Sol. Aldehydes gives black or silver ppt. with tollen's reagent.
,fYMgkbM VkWysu vfHkdeZd ds lkFk dkyk ;k jtr vo{ksi nsrk gSA
6. Tollen’s reagent (AgNO 3 + NH4OH) can be used to distinguish between.

(A) and (B) and

(C*) and (D) and

VkWysu vfHkdeZd (AgNO3 + NH4OH) ls fuEu esa foHksn dj ldrs gSA

(A) rFkk (B) rFkk

(C*) rFkk (D) rFkk

Sol. Aldehydes gives black or silver ppt. with tollen's reagent.

gy % ,fYMgkbM VkWysu vfHkdeZd ds lkFk dkyk ;k jtr vo{ksi nsrk gSA

7. 2-Pentanone can be distinguished from 3- Pentanone by which reagent ?

(A) 2, 4- Dinitrophenyl hydrazine (B) Tollen's reagent
(C*) I2 and dilute NaOH (D) Fehling solution
2-isUVsukWu vkSj 3- isUVsukWu dks fuEu esa ls fdl vfHkdeZd }kjk foHksfnr fd;k tk ldrk gSA
(A) 2, 4-MkbukbVªks QSfuy gkbMªsthu (B) VkWysuvfHkdeZd
(C*) I2 vkSj
ruq NaOH (D) Qsgfyax foy;u
Sol. Iodoform test. (vk;ksMksQkeZ ijh{k.k)

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8. Which of the following compound will not react with I2 /OH–.
fuEu esa ls dkSulk ;kSfxd I2 /OH– ds lkFk vfHkfØ;k ugh djrk gSaA

(A) (B) (C*) (D) CH3 – CHO

Sol. group gives positive iodoform test. gy % lewg /kukRed vkW;ksMksQkWeZ ijh{k.k nsrk gSA

9. The compound A gives following reactions.

Its structure can be

;kSfxd 'A' fuEufyf[kr vfHkfØ;k,sa nsrk gS %

mi;qDr vfHkfØ;kvksa ds vk/kkj ij ;kSfxd 'A' dh lajpuk gksxh \

(A) (B) OHC – (CH2)2 – CH = CH – COOH

(C*) (D)

Sol.

Sol.

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10. A alkene on ozonolysis give only one product(x). x does not respond with Tollen’s reagent and NaOI but give
yellow precipitate with 2,4-DNP, The structure of alkene can be-
,d ,Ydhu vkstksuhvi?kVu ij dsoy ,d mRikn (x) nsrh gSA x, VkWysu vfHkdeZd rFkk NaOI ds lkFk fØ;k ugh nsrk ijUrq
2,4-DNP ds lkFk ihyk vo{ksi nsrk gSA ,Ydhu dh lajpuk gks ldrh gS %

(A) (B) (C*) (D)

11. Which of the following compound can not be formed in given aldol condensation reaction :
nh xbZ ,YMksy la?kuu vfHkfØ;k esa fuEu esa ls dkSulk ;kSfxd ugh cusxkA
Dil. NaOH NaOH
CH3CHO + CH3COCH3   




(A) CH3–CH=CH–CHO (B) CH3–C=CH–CHO

CH3
(C) CH3–C=CH–C–CH3 (D*) CH3–CH2–CH=CH–CHO
CH3 O

O
Dil. NaOH
12. 
 Major product, Major product is –

O
O
NaOH


 eq[; mRikn] eq[; mRikn gS –
O

O
(A) (B*) (C) (D)
O O O

13. Which of the following can show Aldol condensation reaction :

fuEu esa ls dkSulk ;kSfxd ,YMksy la?kuu vfHkfØ;k n'kkZ ldrk gSA
O

(A*) (B) O (C) (D) H–C–D

O
O

Dil. NaOH
14.   Major product, Major product is :


NaOH


 eq[; mRikn] eq[; mRikn –

(A*) (B)

(C) (D)

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 O3 OH 
15.  Y + Z 
X 
Zn,H2O 

Compound X in the above reaction is

mijksDr vfHkfØ;k esa ;kSfxd X gSA

(A) (B*)

(C) (D)

O / Zn
Sol. 3 
 +

 
OH H
  


16. Which of the following can not show Cannizzaro reaction :

fuEu esa ls dkSu dsfutkjks vfHkfØ;k iznf'kZr ugh dj ldrk gS %

H–C–D
(A) CHO (B) (C) (D*) CD3CHO
O O

17. Conc. NaOH

C6H5CHO   C6H5COONa + X
‘X’ is :
NaOH
C6H5CHO 

 C6H5COONa + X
‘X’ gS :
(A*) C6H5CH2OH (B) C6H5OH (C) C6H5COCH3 (D) C6H5COOH

18. Which can not show Cannizzaro reaction :

dkSu dsfutkjks vfHkfØ;k iznf'kZr ugh dj ldrk gS%

(A) (B) H–C–D (C*) CCl3CHO (D)

O

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19. Conc. NaOH
X  

X is :

NaOH
X 



X gSA :

(A*) (B) (C) (D)

(1) Conc. NaOH Conc. H SO

20.     2
4
 Product is :
( 2 ) H 

(1) NaOH
H2 SO 4
    mRikn gSA
(2) H 

(A*) (B)

(C) (D)

NaOH H Conc. H SO
Sol.  
 
 2
4



NaOH H H SO
Sol.  
 
 
2 4



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