Material Safety Data Sheet Page No.

1/11
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Palklin 160 (CL - 160) Revision date: 1 Jan 2013
Ref. code: MS_154

Palklin 160 (CL - 160)

MATERIAL SAFETY DATA SHEET

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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: Palklin 160 (CL - 160)
Manufacture: Nihon Parkerizing (India) Private Limited
Plot No. SP-2, 16-17, RIICO New Industrial Complex, Majrakath,
Neemrana, Dist. Alwar, Rajastan, India
Tel: +91 1494 670400
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2. HAZARDS IDENTIFICATION
GHS classification:
Physical hazards:
Explosives: Not applicable
Flammable gases: Not applicable
Flammable aerosols: Not applicable
Oxidizing gases: Not applicable
Gases under pressure: Not applicable
Flammable liquids: Category 3
Flammable solids: Not applicable
Self-reactive substances and mixtures: Not applicable
Pyrophoric liquids: Classification not possible
Pyrophoric solids: Not applicable
Self-heating substances and mixtures: Classification not possible
Substances and mixtures, which in contact with: Not applicable
water emit flammable gases
Oxidizing liquids: Classification not possible
Oxidizing solids: Not applicable
Organic peroxides: Not applicable
Corrosive to metals: Classification not possible
Health hazard：
Acute toxicity – oral: Not classified
Acute toxicity – dermal: Not classified
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Palklin 160 (CL - 160) Revision date: 1 Jan 2013
Ref. code: MS_154

Acute toxicity - inhalation (gases): Not applicable

Acute toxicity - inhalation (vapours): Not classified
Acute toxicity - inhalation (dusts and mists): Not classified
Skin corrosion/irritation: Category 2
Serious eye damage/eye irritation: Category 2
Respiratory sensitization: Classification not possible
Skin sensitization: Classification not possible
Germ cell mutagenicity: Not classified
Carcinogenicity: Classification not possible
Reproductive toxicity: Classification not possible
Specific target organ toxicity (single exposure): Classification not possible
Specific target organ toxicity (repeated exposure): Classification not possible
Aspiration toxicity: Classification not possible
Environmental hazards:
Hazardous to the aquatic environment acute hazard:
Classification not possible
Hazardous to the aquatic environment chronic hazard:
Classification not possible
GHS label elements:
Pictogram:

Signal word: Warning

Hazard statements: Flammable liquid and vapour
Causes skin irritation
Causes serious eye irritation
Precautionary statements:
Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No
smoking.
Keep container tightly closed.
Ground/Bond container and receiving equipment - if electrostatically
sensitive material is for reloading. - if product is as volatile as to
generate hazardous atmosphere.
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Palklin 160 (CL - 160) Revision date: 1 Jan 2013
Ref. code: MS_154

Use explosion-proof electrical, ventilating, lighting equipment.

Use only non-sparking tools.
Take precautionary measures against static discharge
Wash hands, face thoroughly after handling.
Wear protective gloves.
Wear eye protection/face protection.
Response: If skin irritation occurs: Get medical advice/attention.
If eye irritation persists, get medical advice/attention.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
IF ON SKIN: Wash with plenty of soap and water.
IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
Take off contaminated clothing and wash before reuse.
In case of fire, use foam, carbon dioxide, dry chemical powder and
so on for extinction.
Storage: Keep cool. Store in a well-ventilated place.
Disposal: Dispose of contents/container through a licensed disposal agent in
Accordance with local/ regional/ national/ international regulations
(to be specified).
Hazard information which do not fall under GHS classification:
Hazard statements: flammable liquids
Precautionary statements:
Prevention: keep away from flames/hot surface.-no smoking wear protective gloves.
Wear eye protection/face protection.
Response: In case of fire, use foam, carbon dioxide, dry chemical powder and so on for extinction.
Storage: keep cool.store in a well-ventilated place.
Disposal: No information
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3. COMPOSITION/ INFORMATION ON INGREDIENTS
Division of chemical substance/ mixture: Mixture
Chemical name or generic name: Palklin 160 (CL - 160) HP
Ingredient:
Ingredient CAS number Content(%)
Kerosene 64742-81-0 80～90
Isobutanol 78-83-1 1- 10
Surfactant 1- 10
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Palklin 160 (CL - 160) Revision date: 1 Jan 2013
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4. FIRST- AID MEASURES
If inhaled:
If feel unwell. Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
If feel unwell, properly call a POISON CENTER or doctor/ physician.
If on skin:
IF ON SKIN: Wash with plenty of soap and water.
Flammable. Wash the victim's skin with running water or shower.
If skin irritation, pain, blisters or rash occurs or if you feel unwell: Call a POISON
CENTER or doctor/physician.
Remove/Take off immediately all contaminated clothing.
Take off contaminated clothing and wash before reuse.
If in eyes:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
If eye irritation persists, get medical advice/attention.
If swallowed:
If necessary, rinse mouth.
If you feel unwell, call a POISON CENTER or doctor/physician. Get medical
advice/ attention.
If the victim is vomiting, keep calm; turn the head to the side so that the airways
are not blocked.
Protection for first-aiders:
Personal protective equipment described in Section 8: Exposure
control/Personal protection.
Ventilate area, if gases, vapors, mists or dusts occur.
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5. FIRE- FIGHTING MEASURES
Suitable extinguishing media:
Foam, carbon dioxide, dry chemical powder and so on.
Extinguishant which you must not use：
Water
Specific extinguishing method:
Remove combustible materials from fire area. Move container from fire areas if
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Palklin 160 (CL - 160) Revision date: 1 Jan 2013
Ref. code: MS_154

possible to do so without hazard. Cool down container and the surrounding

area by water, if the container can not be moved.
Protection of fire-fighters:
Fight a fire from windward to avoid inhalation of vapour and combustion gases.
In fire fighting, wear proper protective equipment (fire fighter protective clothing,
respiratory protection) to avoid inhale and contact the chemical.
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6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment, and emergency procedures:
Wear protective equipments regulated in section 8: Exposure Control and
Personal Protection to avoid contact to eyes or skin and inhalate gases, dust and
fumes. Set up off-limits area to prevent secondary disaster. Use local
exhaust to avoid inhalate gases, mist, vapor or dust for indoor work.
Environmental precautions:
Take caution to avoid possible environmental impact at spill or disposal to
natural water system. In case of using waste water treatment equipment, call the
administrator to avoid discharge the waste water involving the product.
Methods and materials for containment and cleaning up:
Use spark proof tools and explosion proof equipment.
Retrieve spilled material. absorb by dry sand, soil, other non-inflammable things
Retrieve spilled material, using shovel or waste cotton.
Dike to contain spill in case of large spill.
Retrieve spilled material, collect and store in suitable.
Spilled materials and contaminated substances should be disposed as regulated
Secondary disaster prevention measures:
Immediately remove ignition sources, hot surface and combustible materials.
Prepare proper extinguisher regulated in section 5: Fire-Fighting Measures, in
case of ignition.
Set up off-limits area to prevent secondary disaster.
Call to the section relating safety, hygiene, environment, disaster prevention etc.
Take proper measures.
Recovery, neutralization and disposal:
Flammable. Take a measure to prevent electrostatic charge.
In case of small spill, retrieve spilled material using absorbent such as sawdust,
soil, sand, waste cotton.
Dike to contain spill in case of large spill. After collect in suitable area, dispose as Regulated.
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Palklin 160 (CL - 160) Revision date: 1 Jan 2013
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7. HANDLING AND STORAGE
Handling:
Technical measures:
If necessary, use explosion proof equipments.
Use exhaust for ventilation of flammable vapour.
Keep away from heat and ignition source.
Take necessary steps to avoid contact and/or overexposure, for instance
protective facilities, protective equipments regulated in section 8 : Exposure
Control and Personal Protection.
Handle in a well-ventilated place.
Local ventilation / total ventilation:
Take necessary ventilation regulated in section 8 : Exposure Control and
Personal Protection.
Precautionary statements:
Wear suitable protective equipment, gloves, and eye/face protection to avoid
contact to skin, clothing or mucous membrane.
Wash face and hands after handling. Do not bring a polluted protective
equipment into the resting room.
Wear suitable protective equipment and handle in a well-ventilated place.
Safe handling instructions:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/Bond container and receiving equipment - if electrostatically sensitive
material is for reloading. - if product is as volatile as to generate hazardous
atmosphere.
Use explosion-proof electrical, ventilating, lighting equipment.
Take precautionary measures against static discharge.
Use only non-sparking tools.
Avoid rough handling, such as toppling, dropping, exposing shock, dragging.
Call attention to workers about hazard informations by posting MSDS.
Avoid contact:
Refer to incompatible materials shown in section 10: Stability and Reactivity.
Storage：
Suitable conditions:
Keep container tightly closed.
Keep cool. Store in a well-ventilated place.
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Palklin 160 (CL - 160) Revision date: 1 Jan 2013
Ref. code: MS_154

In every use, keep container tightly closed.

Packaging material:
Use product containers or a container having enough strength.
Incompatible materials：
Oxidizing substances
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8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Protective Equipment:
Make available hand wash and face wash in work place. After handling, wash
hands and face.
Use local exhaust, push-pull ventilation system or general ventilation to keep
below specified level.
Occupational exposure limit (Japan Society for Occupational Health):
Ingredient TWA Ceiling Skin Year
Isobutanol 50ppm / 150mg/m3 - 2008

Occupational exposure limit(ACGIH)：

Ingredient TWA STEL Ceiling Skin Year
Isobutanol 50ppm - - 2008
Occupational exposure limit(OSHA)：
Ingredient PEL Ceiling Skin
Isobutanol 100ppm / 300mg/m3 -
Personal protective equipment:
Respiratory protection: If necessary, wear proper respiratory protection.
Hand protection: Wear chemical resistant gloves.
Eye protection: Use proper eye protection.
If necessary, use chemical goggles or face shield.
Skin and body protection: If necessary, wear proper protective clothing.
Appropriate hygiene measures: Wash hands, face thoroughly after handling.
Do not eat, drink or smoke when using this product.
Contaminated work clothing should not be allowed out of
the workplace.
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9. PHISICAL AND CHEMICAL PROPERTIES
Appearance
Physical state: Liquid
Color: Pale brown
Odour: No information
pH: No information
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Palklin 160 (CL - 160) Revision date: 1 Jan 2013
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Melting point/freezing point: No information

Initial boiling point and boiling range: No information
Flash point: 30℃（T.C.C）
Auto-ignition temperature: No information
Upper/lower flammability or explosive limits: No information
Vapour pressure: No information
Vapour density: No information
Evaporation speed: No information
Specific gravity (relative density): No information
Solubility in water: No information
Dissolubility in water: No information
Solubility in organic solvent: No information
Dissolubility in organic solvent: No information
n-octanol / water partition coefficient: No information
Decomposition temperature: No information
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10. STABILITY AND REACTIVITY
Stability /possibility of hazardous reactions: Stable under normal conditions.
Conditions to avoid: No information
Incompatible materials: Oxidizing substances
Hazardous decomposition products: No information
Others: No information
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11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Kerosene LD50 (oral) Rat 5000mg/kg
Kerosene LD50 (dermal) Rabbit 2000mg/kg
Isobutanol LD50 (oral) Rat 2460mg/kg
Isobutanol LD50 (dermal) Rabbit 3400mg/kg
Isobutanol LC50 (vapours) Rat 19.2(1h)
Isobutanol LC50 (vapours) Rat 24.2(1h)
Isobutanol LC50 (vapours) Rat 6.5(4h)
Health hazards category list 1:
Skin Serious eye Respiratory Skin Germ cell Re-
Ingredient corrosion / damage / sensitization sensitization mutagenicity productive
irritation eye irritation toxicity
Kerosene × × × × × ×
Isobutanol 2 2A × × - -
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Palklin 160 (CL - 160) Revision date: 1 Jan 2013
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Surfactant × × × × × ×

Health hazards category list 2:

Specific target organ
Specific target organ toxicity-single exposure Aspiration
Ingredient toxicity-repeated exposure
toxicity
Category 1 Category 2 Category 3 Category 1 Category 2
Kerosene × × × × × ×
Respiratory

tract irritation
Isobutanol - - 2
，Narcotic
effects
Surfactant × × × × × ×
×：Classification not possible
－：Not classified

Carcinogenicity:
Japanese
GHS
EPA EPA EPA EU Society of
Ingredient Classify- IARC NTP ACGIH
1986 1996 2005 Directive Occupational
cation
Health
Kerosene ×
Isobutanol ×
Surfactant ×

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12. ECOLIGICAL INFORMATION
Hazardous to he aquatic environment
Ecotoxicity: No information
Fish toxicity: No information
Effect on animals and plants: No information
Bioaccumulative potential: No information
Environmental effect
Persistence and degradability: No information
Ozone depleting potential: No information
Global Warming potential: No information
Mobility in soil: No information
Other harmful effects: No information
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13. DISPOSAL CONSIDERATION
Residual waste:
Dispose of contents/container through a licensed disposal agent in accordance
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Palklin 160 (CL - 160) Revision date: 1 Jan 2013
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with local /regional/national/international regulations (to be specified).

In case of incinerating waste, incinerate by small volume with an incinerator in
accordance with relevant regulations.
Contaminated container and contaminated packaging:
Reuse containers after cleaning, or dispose properly in accordance with related
lows and local regulations.
Remove contents thoroughly from a container before disposal of it.
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14. TRANSPORT INFORMATION
Make sure no leak in the container. Load steadily to avoid load shifting such as, falling,
dropping and /or being damaged.
Follow the procedure specified in Section 7: Handling and Storage.
Regulatory information with regard to the transportation of this substance is described
below. Regulatory information with regard to the transportation of this substance is
described below.
Land transportation: Follow local regulations.
Marine transportation: Follow the procedure specified by IMDG CODE. Do not discharge
into sea area.
Air transport: Follow the procedure specified by IATA REGULATION.
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15. REGULATORY INFORMATION
The product listed on this MSDS has been classified in accordance with the hazard criteria of
the government controlled products regulations. This MSDS contents all information required
by those regulations.
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16. OTHER INFORMATION
The information above is believed to be accurate and represents the best information
currently available to us. User should make their own investigation to determine the
suitability of the information for their particular purpose. The information in the MSDS is
typical one. We make no warranty with respect to such information. This document presents
basic hazard information to assist in the risk assessment. Additional information is sometimes
required to determine the risks in the workplace on other settings.

References:
 GHS Classification Guidance for Enterprise (March, 2009), Ministry of Economy, Trade
and Industry
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Ref. code: MS_154

 GHS Guideline for Preparation of MSDS and Labeling (2nd edition) Oct. 2008, Japan
Chemical Industry Association.
 GHS Classification results database, Independent administrative organization, National
Institute of Technology and Evaluation
 Information on GHS models, Japan Industrial Safety & Health Association
 Japan Chemical Industry Ecological-Toxicological & Information Center, No.218
2008 TLVs and BEIs, Japan Association for Working Environment Measurement
 Journal of Occupational Health, Vol.50, No.5, September 2008