Miscellaneous

SOLUTION TO ASSIGNMENTS
SUBJECTIVE

1. Kinetic energy of electron = h – hcritical

hc hc
= -
  critical
1240nm eV 1240 nm eV
KE =  = 1.22 eV
400 nm 660nm
(Since 1240 nm = 1eV)

2. Let  1 wavelength for the transition 54 and  2 be that of 4  3 transition

1  1 1
 1.094  10 7  3 2  2  2  =  1 = 4.502 × 10-7 m = 450.2 mm
 4 5 
1  1 1 
 1.094  10 7  3 2  2  2 
2 3 4 
 2 = 2.089 × 10 m = 208.9 nm
-7

shorter wavelength is  2 , longer wavelength is  1

stopping potential for the photo electrons ejected by the light of wavelength
2 is 3.95 Volts
Energy corresponding to 2 is
1240
E2  = 5.95 eV
208 .9
since stopping potential = 3.95 V;
K.E. = 3.95 eV
E =  + KE1
5.95 =  + 3.95
 = 2.00 eV
Energy corresponding to 1 is
1240
E1  = 2.75 eV
450 .2
E1 =  + K.E2
2.75 = 2.00 + KE2
KE2 = 0.75 eV
stopping potential = 0.75 V

3. Total energy liberated during transition of electron from nth shell to first excited state
(i.e., 2nd shell) = 10.20 + 17.0 = 27.20 eV = 27.20  1.602  10–12 erg
hc  1 1
  R H Z 2hc  2  2 
 2 n 

FIITJEE Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942
RSM79PhIMis.CH2

1 1
 27.20  1.602  10–12 = RH  Z2  h  c  2  2  … (1)
2 n 
Similarly, total energy liberated during transition of electron from nth shell to second
excited state (i.e., 3rd shell) = 4.25 + 5.95 = 10.20 Ev = 10.20  1.602  10–12 erg
1 1
 10.20  1.602  10–12 = RH  Z2  h  c  2  2  … (2)
3 n 
Dividing Eq. (1) by Eq. (2)
n=6
On substituting the value of n in Eqs. (1) or (2).
Z= 3

0.53  12
4. Radius of 1st orbit of the He+ ion =
2
o
= 0.265 A = 0.265 × 10-10 m
Uncertainty in the location = 1 % of the radius of the 1st orbit
= 0.265 × 10-12 m
h
p × x 
4
h
v 
4mΔx
6.626  10 34

4  3.14  9.1 10 31  0.265  10 12
 2.18 × 108 m/sec
velocity of the electron
2.184  10 6  Z
v= m/sec
n
= 4.368 ×106 m/sec (since Z = 2, n = 1)

5. For half filled stability of N

6. Packing in crystal latice is not compact due to small size of Li+ and bigger size of CO 32  .
But O2– being smaller in size can stabilise Li2O.

7. In case of nitrogen intramolecular multiplicity is possible leading to completion of octet

via  bond formation. Hence octet of N2, gets fulfilled by N  N. In case of P
intramolecular multiplicity is ruled out because of longer P – P single bond. Hence P has
to complete its octet by undergoing sigma bond formation with other phosphorus. Hence
formula is P4.

8. H2 = 1s2 Bond order = 1

H2– = 1s2*1s1 Bond order = 0.5
He2 = 1s21s*2 Bond order = 0
( 3  2)
He2– = 1s2*1s22s1 Bond order = = 0.5
2
H2– and He2– are expected to have same stabilities.

FIITJEE Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942
 RSM79PhIMis.CH3

9. a) i) for ideal gas nature Z = 1

PV = nRT
nRT 0.2  0.0821  273
V= =
P 100
V = 0.0448 litre
ii) for real gas
PV = ZnRT
ZnRT 0.02005  0.2  0.0821  273
V= =
P 100
V = 8.987 × 10-3 litre.
 n2 a 
b) P  2  V  nb  nRT
 V 
nRT n 2a
Dividing by (V-nb) and solving for P,  2 P
V  nb V
Substituting n = 1, R = 0.0821 L atm mol-1 K-1, V = 0.25 L, T = 300 K and the values
of a and b, we have
1 0.0821  300 12  2.253
P   82.82 atm
0.25  1 0.0428  0.25 2
From the ideal gas equation,
nRT
P= = 98.52 atm
V

5.8
10. Meq. of NaHSO3 = Meq of NaIO3 = N  V =  6  1000
198
I5++ 6e  I– (For KIO3, n-factor = 6)
 Meq. of NaHSO3 = 175.76
WNaHSO3 175 .75  104
 1000 = 175.76  WNaHSO3  = 9.14 gm
M/ 2 2  1000
Also Meq. of I– formed using n-factor 6 = 175.76
In step II n-factor of I– is 1 and n-factor for IO3– is 5
175 .76
Meq. of I– formed using n-factor 1 =
6
175 . 76
Meq. of NaIO3used in 2nd step =
6
5.8 175.76
 5 V   VNaIO3 = 20 mL
198 6

11. AgNO3 + KI  AgI + KNO3

Ag present in AgNO3 is removed as AgI by adding 50 mL of KI solution of which 20 mL
requires 30 mL of M/10 KIO3
1
Meq. of KI in 20 mL = Meq. of KIO3 = 30  4 For KIO3
10
 Meq. of KI in 50 ml added to AgNO3 I5+ + 4e I+
30  4  50
= = 30 I–  I–1 + 2e
10  20

FIITJEE Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942
RSM79PhIMis.CH4

1 M
Meq. of KI left unused by AgNO3 = 50   4 = 20  Eq. wt. of KI =
10 2
 Meq. of KI used for AgNO3 = 30 – 20 = 10
 Meq. of AgNO3 = 10
WAgNO3
 2  1000 = 10,  WAgNO3 = 0.85 gm = 85%
170
Mole of AgNO 3 1

Mole of K t I
M
 If equivalent weight of KI =
2
M
Equivalent weight of AgNO3 =
2

12. Let molecular weight of oxalate salt is M

i) n-factor in acid base reaction = 2
ii) n-factor in redox titration = 2  Z (C2O42–  2CO2 + 2e)
 Meq. of acid in 30 ml = Meq. of NaOH used
9.15
30   y = 27  0.12 …(1)
M
9.15
Also 30   (2z) = 36  0.12 …(2)
M
y 27 y 3
From equations (1) & (2) =   …(3)
2z 36 z 2
Also total cationic charge = total anionic charge
 x + y = 2Z …(4)
By equations (3) & (4)
x : y : z :: 1 : 3 : 2
These are in simplest ratio and molecular formula is KH3(C2O4)2.nH2O
Molecular weight of salt = 39 + 3 + 176 + 8n = 218 + 18n
30  9.15  3
From equation (1) M = = 254.16
27  0.12
 218 + 18n = 254.15  n = 2
 Oxalate salt is KH3(C2O4)2.2H2O

13. Let total moles of Mg used for MgO and Mg3N2 be a and b respectively
2Mg + O2  2MgO
a 0
0 a
3Mg + N2  Mg3N2
b 0
0 b/3
 b
Now  a   moles of MgO and Mg3N2 are present in the mixture
 3
MgO + 2HCl  MgCl2 + H2O
Mg3N2 + 8HCl  3MgCl2 + 2NH4Cl

FIITJEE Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942
 RSM79PhIMis.CH5

or solution contains (a) mol of MgCl2 from MgO and (b) moles of MgCl2 from Mg3N2 and
2b
moles of NH4Cl.
3
Now moles of HCl or Meq. of HCl (monobasic) = 60 – 12 = 48
8b
2a + = 48 …(1)
3
Moles of NH4Cl formed = Moles of NH3 liberated = moles of HCl used for absorbing NH3
2b
= (10 – 6) = 4 …(2)
3
86 6
From (1) 2a + = 48 or a = 16% of Mg used for Mg3N2 =  100 = 27.27%
3 (6  16 )

14. Let weight of BaCO3, CaCO3 and CaO are

x, y and z respectively
 x + y + z = 1.249
BaCO3  BaCrO4
Redox charge Cr6+ + 3e  Cr3+
2I–  I2 + 2e
Meq. of BaCO3 = Meq. of BaCrO4 = Meq. of I2
x 100
  1000 = 20  0.05 
197 / 3 10
 x = 0.657 gm …(1)
The equivalent weight of BaCrO4 is M/3 therefore for BaCO3, it should be M/3 also
because mole ratio of BaCO3 and BaCrO4 is 1 : 1
Applying POAc for C atom
Moles of C in BaCO3 + Moles of in CaCO3 = Moles of C in CO2
x y 168
    200x + 294y = 295.5 …(2)
197 100 22400
From equation (1) and (2)
y = 0.416 gm
 0.0657 + 0.416 + z = 1.249
z = 0.176
0.176
% of CaO = = 14.09%
1.249
15. CO2 gas is acidic in nature, it neutralizes the Ba(OH)2 and precipitates BaCO3.
Equations of Ba(OH)2 consumed = equivalents of CO2
50 1 22.5 2 5
equivalents of CO2 =  –  =
1000 25 1000 25 1000  25
5
 moles of CO2 =
1000  25  2
5  22.4  100
% of CO2 in air at NTP = = 0.0224
50  1000  10
Ba(OH)2 + CO2  BaCO3 + H2O
It is a non redox process and Ba(OH)2 has n factor of 2. It reacts with CO2 in molar ratio
of 1:1
 n factor of CO2 is 2

FIITJEE Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942
RSM79PhIMis.CH6

OBJECTIVE

1. Magnetic moment = n(n  2)

where n = no. of unpaired electrons
 4.9 = (n  2)n
 4.9 = (n 2  2n)
 (n2 + 2n) = 4.9  4.9
n2 + 2n = 24.01  4
Hence Mn will exist in Mn+3 form (A)

2. The electron two centre bond

N O
Odd electron molecule

8. 1.05 gm of metal is attached to 2.1 gm of oxygen

1.05  8.0
 8 gm of oxygen will react with =4
2.1
 Equivalent weight of metal is 4

8. KHF2  K+ + HF2–

3RT
14.  vrms =
M
vrms of H2 = 7 vrms of N2
3RTH2 3RTN2
 7
2 28
On solving TN2  2TH2

15. Mohr’s slat is (NH4)2SO4.FeSO4.6H2O

(NH4)2SO4.VSO4.6H2O
 Oxidation number of V in this salt is +2

1 1 1
16. = RH  2  2 
2  n1 n 2 
n1 = 1, n2 = 4
RH = 1.1  107 m–1
1 1 1 
 1.1 10 7   2
 1 ( 4) 
On solving  = 96.97 nm

17. These represent two quantum mechanical spin states which have no classical
analogues.

FIITJEE Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942
 RSM79PhIMis.CH7

126
18. Eq. wt. of COOH 2H2O = = 63
| 2
COOH
6.3 1000
Normality of oxalic acid =  = 0.4 N
63 250
(oxalic acid) (NaOH)
N1V1 = N2V2
0.4  10 = 0.1  V2
 V2 = 40 ml

 1 Molecular w eight of solute 

21. d  M  
m 1000 
 1 40 
d  11.12  
 94.12 1000 
= 11.12 (0.01 + 0.04)
= 0.556 g ml–1

22. [MnO4– + 8H+ + 5e–  Mn2+ + 4H2O]  3

[Fe2+ + C2O42–  Fe3+ + 2CO2 + 3e–]  5
–––––––––––––––––––––––––––––––––––––––––––––––––––––––––
5 Fe2+ + 5C2O42– + 3MnO42– + 24H+  3Mn2+ + 12H2O + 5Fe3+ + 10CO2
–––––––––––––––––––––––––––––––––––––––––––––––––––––––––
5 moles of FeC2O4 requires = 3 moles of KMnO4
3
 1 mole will require = mole of KMnO4
5

23. The atomic mass of carbon is less and therefore no. of moles will be more.

25. 79Au : [Xe] 4f14 5d10 6s1

As CsAuCl3 is diamagnetic, it could not consist of simple Au(II) ions because Au(II) has
an odd number of electrons. Similarly Au(O) is also ruled out. Calculation of oxidation
state of Au indicates that it can either be Au(III) or an equimolar mixture of Au(I) and
Au(III). Therefore correct answer is C. The actual structure consists of an equal number
of [AuCl2]– ions and [AuCl4–] ions each balanced by Cs+ ions

FIITJEE Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942