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J Mater Cycles Waste Manag (2008) 10:110–115 © Springer 2008

DOI 10.1007/s10163-007-0206-9

SPECIAL FEATURE: ORIGINAL ARTICLE


4th I-CPEC, Part 2

Sławomir Stelmach · Ryszard Wasielewski

Co-combustion of dried sewage sludge and coal in a pulverized coal boiler

Received: March 2, 2007 / Accepted: December 13, 2007

Abstract More than 1.1 million tons of municipal and and in 2010 this figure is expected to exceed 600 000 Mg per
industrial sewage sludge is produced annually in Poland. year and will continue increasing up to 700 000 Mg in 2015.1
Most of this sewage sludge is landfilled or used for recultiva- Simultaneously, about 640 000 Mg d.b. of industrial sewage
tion and fertilization of soil. After accession of Poland to sludge was produced in Poland in 2005. Landfilling of this
the EU, large investments are planned for wastewater treat- biodegradable waste and the possibility of its agricultural
ment, so it is expected that the amount of sewage sludge use are more and more limited by restrictive environmental
produced in Poland will grow in the near future. It is well legislation.
known that the combustion of sewage sludge is becoming a In highly developed countries, the combustion and co-
more and more popular utilization method of such waste. combustion of municipal sewage sludge are increasingly
Unfortunately, the current situation in Poland makes it common methods of its management.2,3 At present co-
impossible to incinerate the sewage sludge because of a lack combustion of municipal sewage sludge with coal is realized
of incinerators. One possible solution for Poland is the co- in many European power plants, mainly localized in
firing of dried sewage sludge in existing coal-fired utility Germany, but also found in Belgium, Holland, and Austria.
boilers. This article presents results of initial Polish indus- Among German power plants, which realize co-combustion
trial trials of dried municipal sewage sludge and hard coal of more than 10 000 Mg d.b. of municipal sewage sludge
co-combustion in an OP-230 pulverized coal boiler. Such a annually, Duisburg H. Stadtwerke, Franken II Bayern-
solution was shown to be technically viable and not to werke, Heilbronn EnBW, Weiher II SaarEnergie, and
require changes to the existing technological system. Co- Zolling Bayernwerke are worthy of mention.4 In the above-
combustion of sewage sludge with coal in power plants mentioned power plants, the amount of municipal sewage
seems to be the best solution for sludge utilization in the sludge in the fuel blend usually does not exceed 10 wt%
near future in Poland. (d.b.). Generally, there have been no significant changes in
operational parameters of the installations compared to
Key words Sewage sludge · Coal · Co-combustion · coal combustion alone in the same boiler. There are only
Emission slight changes of emission factors and heavy metal content
in the fly ash. Although co-combustion of municipal sewage
sludge with coal seems to be a very interesting solution for
Introduction sludge utilization, there is relatively little research work
carried out on the subject. Since 2000, Elsevier, one of the
Sewage sludge management is one of the most important world’s leading publishers, has published only about 20 sci-
environmental problems in Poland. Construction of new entific articles concerning co-combustion of sewage sludge
biological municipal wastewater treatment plants has with coal.5
resulted in a continuous increase in the volume of sewage The situation in the field of thermal utilization of waste
sludge generated. More than 480 000 Mg dry basis (d.b.) of in Poland (lack of waste incinerators) currently excludes
municipal sewage sludge was produced in Poland in 2005, the possibility of utilization of large volumes of sludge by
incineration. In the current situation, the co-combustion of
sewage sludge in power boilers seems to be the best method
for sewage sludge utilization, allowing the use of already
S. Stelmach (*) · R. Wasielewski existing plants and avoiding, or substantially reducing, the
Institute for Chemical Processing of Coal, 1 Zamkowa St., 41-803
Zabrze, Poland
investment expenditure. The co-combustion of dried sewage
Tel. +48-32-271-00-41; Fax +48-32-271-08-09 sludge with coal in pulverized coal boilers may be one of
e-mail: sstel@ichpw.zabrze.pl technological options for such a process.6
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Municipal sewage sludge – in the light of new bind the situation concerning the determination of emission
ing Polish environmental legislation – is treated as a non- standards for co-combustion of nonhazardous waste in
hazardous waste. Co-combustion of stabilized municipal Poland. It should be stated that the case existing in Polish
sewage sludge with hard coal is a process of thermal law – which is very relevant for Polish plants which intend
processing of a nonhazardous waste, and the industrial to use a waste material as an additional fuel – has no equiva-
installation where the process is carried out is a waste co- lent in European environmental law, principally the 2000/76/
combustion installation. The most important technical EC Directive,7 and it is hard to judge how long this special
requirements that must be met by a sewage sludge co- case will exist in Polish law. However, at present it is still
combustion installation are as follows: valid, and power plants are very interested in co-
combustion of waste with its share in the fuel blend being
– The temperature of gases generated during combustion
up to 1 wt% because they can avoid additional expenditure
must be maintained at a level above 850°C for at least 2 s
for expanded monitoring of emissions.
(for waste containing not more than 1 wt% of haloge-
The first industrial power-emission tests of dried munici-
nated organic compounds converted into chlorine).
pal sewage sludge co-combustion in an OP-230 pulverized
– The total organic carbon (TOC) in incineration slag and
coal boiler were carried out in Poland in October 2005. The
ashes shall not exceed 3 wt% or the share of inflammable
Institute for Chemical Processing of Coal in Zabrze super-
matter in incineration slag and ashes shall not exceed
vised the tests and was the main contractor. The tests were
5 wt%.
aimed at determining the technical and engineering possi-
– Co-combustion installations must be equipped with an
bilities of processing 1 wt% of waste in the fuel stream, as
automatic system of waste feeding.
well as at meeting the national legislation requirements for
– For co-combustion with coal of up to 1 wt% of waste, an
tested boiler.
installation shall be equipped with a system of continuous
monitoring of dust, NOx (converted into NO2), CO, SO2,
and O2 emissions, in addition to the monitoring of rela- Experimental
tive flue gas humidity and its temperature and pressure.
– For co-combustion with coal exceeding 1 wt% of waste
Tests of municipal sewage sludge co-combustion with coal
in the fuel blend, expanded emission monitoring is
in an OP-230 pulverized coal boiler were carried out in a
required, i.e., continuous measurements of: dust, SO2,
domestic combined heat and power plant. The schematic of
NOx (converted into NO2), CO, TOC, O2, HCl, HF, the
the tested boiler is presented in Fig. 2. This boiler has three
flue gas flow rate or its dynamic pressure, and the flue gas
rows of pulverized fuel burners fed by four ring-ball mills,
temperature, static pressure, and humidity. In addition,
of which one is a standby. Each mill feeds two pulverized
periodic measurements are required for Hg, Cd, and Tl;
fuel burners. Above the burners, on the front and back wall
total heavy metals (Pb, Cr, Cu, Mn, Ni, As, Sb, V, Co,
of the boiler, three over-fire air nozzles (OFA) are installed,
Sn); and dioxins and furans.
fed from the hot air collector. Flue gas cleaning in the test
As can be seen from the above information, waste co- boiler was carried out with an electrostatic precipitator
combustion is a special case in Polish law. It is possible in only.
Poland to co-combust nonhazardous waste with fossil fuel Municipal sewage sludge originating from a municipal
without changes in the current emission standards estab- wastewater treatment plant situated in the same city as the
lished for a particular installation. This situation applies combined heat and power plant was hot-air predried in a
when up to 1 wt% of nonhazardous waste is co-combusted mobile installation equipped with a fluidized bed reactor. A
with fossil fuel. Figure 1 presents a graphical explanation of view of the drying system, a dried sewage sludge sample,
and a schematic of the installation are presented in Fig. 3.
Dried sewage sludge (approximately 26 Mg) was delivered
to the combined heat and power plant by motor transport
(a tanker). Sludge was batched to the boiler’s coal-feeding
standard for fossil fuel
emission standard

system using a specially designed and constructed installa-


tion equipped with a buffer tank, a rotary pocket feeder,
standard for fuel blend and a feeding screw. Sludge from the tanker was reloaded
to the buffer tank of the sludge batching installation by
means of pneumatic transport. Sludge was batched together
standard for waste with the coal for one coal mill. The other two coal mills were
fed with coal only. From the mill holding sewage sludge and
coal, the fuel blend was fed to two burners situated in the
middle and upper zones of boiler firing. Directing the fuel
blend to these burners was intended to ensure complete
1 97 98 99 100
burning of the sludge before it was likely to enter the slag-
share of waste in fuel blend [% m/m]
draining zone. Coal and sludge feeders were calibrated
Fig. 1. Principles of emission standards determination for nonhazard- before starting the tests. The coal feeders’ capacities were
ous waste co-combustion in Poland defined from their characteristics based on readings of the
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Fig. 2. Schematic of the OP-230


pulverized coal boiler. Numbers
1–7 indicate measurement points
steam superheater
(steam parameters)

boiler drum
(water parameters)

combustion chamber
(temperatures)

flue
(flue gases parameters)

(fly ash parameters)

fuel blend duct deslagging system


(fuel blend parameters) (slag parameters)

water
(~10m3/h)
Tw2 =21oC Tw1 = 41oC

air + vapours COOLER


Tp2 = 96oC
DEDUSTING
FLUID BED
DRIER

dust condensate
Tk = 39oC

flue gases
air FAN
SCREW Tp1 = 135oC
PUMP

dried sewage
sludge COMBUSTION
CHAMBER
heating oil (~40 dm3/h)
AND HEAT
mechanically EXCHANGER air
dewatered
sewage sludge
(~0,4 m3/h)

Fig. 3. View and schematic of the mobile installation for sewage sludge drying and a view of a dried sludge sample
113

control settings in the control room. The appropriate setting Table 1. Physicochemical properties of the fuel blend components
for the sewage sludge batcher was selected according to the Property Coal Sewage sludge
determined total volume of coal so as to ensure the required
amount in the fuel blend. Sludge was co-combusted for Proximate analysis
about 18 h. Power-emission tests of the boiler during sewage Moisture (%) 9.80 7.40
Ash (%) 17.90 36.80
sludge co-combustion were carried out on a comparative Volatile matter (%) 34.36 52.03
basis for cases of coal combustion (one test) and fuel blends Fixed carbon (%) 47.74 11.17
containing about 1 wt% of dried sewage sludge (three tests) LHV (MJ/kg) 22.96 11.86
at the same boiler rating. Ultimate analysis
C (%) 67.05 33.58
Boiler tests and calculations were carried out according H (%) 4.73 4.82
to Polish standard PN-72/M-34128 Steam Boilers: Accep- O (%) 8.28 18.45
tance Requirement and Tests and the procedures of the N (%) 1.46 4.82
accredited Combustion Laboratory of the Institute for S (%) 0.47 1.34
Cl (%) 0.047 0.095
Chemical Processing of Coal. In each test, measurements
were carried out for 6 h during stable operating conditions All percentages except for moisture are dry base
of the boiler. The scope of measurements comprised:
– determination of temperature distribution in various
in the operation of the sludge batching system or of the
zones of the boiler’s combustion chamber,
boiler. Table 1 contains the basic physicochemical para-
– studies on physicochemical properties of coal, dried
meters of the coal and sewage sludge used in the co-
sewage sludge, and combustion/co-combustion by-
combustion tests.
products,
The chemical compositions of the tested sewage sludge
– determination of pollutant emissions as for waste co-
did not differ from sludge compositions presented in the
combustion (except dioxins and furans).
literature.2,3 It is worth noting the relatively high nitrogen
Basic measurements were carried out as follows: content of sewage sludge, which is atypical of fossil fuels.
The ash content in the tested sludge – although around
– The temperature in the combustion chamber was mea-
twice as high as that for coal – was relatively low; much
sured at three levels: 11.4, 18.4, and 24 m (Fig. 2) by
higher values of this parameter are encountered in practice,
means of S-type PtRh90/10%Pt and K-type NiCr–NiAl
exceeding even 60 wt%. The tested sludge had high levels
thermocouples as well as a TES 1314 temperature
of volatile matter, typical of sewage sludge. The calorific
meter. (INTROL Sp. zo.o., Katowice, Poland)
value of the dried sludge in the working conditions, around
– The dynamic pressure field was measured in flue cross-
11.9 MJ/kg, was relatively high for such a material. The
sections before the electrostatic precipitator by means of
chlorine content of the sludge, although higher than that of
a Prandtl probe with a pressure meter CMP-10, ZAM
coal, is not likely to result in major operational complica-
Ke˛ty (ZAM, Ke˛ty, Poland).
tions in the boiler because of the small amount of sludge in
– The temperature and static pressure of flue gas in the flue
the blend cocombusted with coal. The sulfur content in the
were measured by means of a digital temperature meter
sludge samples tested was relatively low (there are hard
with a NiCr–NiAl sensor (CZAKI, Raszyn-Rybie,
coals with sulfur contents higher than that in the sludge
Poland) and a Prandtl probe.
samples); however, it was almost three times that of the coal
– The flue gas moisture content was measured by means of
combusted in these tests.
a digital CMZG-10 (ZAM, Ke˛ty, Poland) gas moisture
Figure 4 presents the temperature distribution of the flue
meter.
gas along the combustion chamber at heights from 11.4 to
– The flue gas composition (CO, CO2, NO, SO2, O2) was
26 m, taking into account the distance from the screen sur-
measured using a mobile set of flue gas composition ana-
faces. It can be seen that the required minimum tempera-
lyzers (SIEMENS, Berlin and Munich, Germany).
ture of flue gas, i.e., 850°C, was easily exceeded during the
– To determine HCl, HF, and Hg vapors, a special sam-
entire considered volume of the combustion chamber
pling system was used, consisting of a pump, washer with
(between the second level of burners and the end of the
an absorber, heated filter, and a gas meter.
combustion chamber).
– TOC emission was determined using a separate sampling
Unfortunately, based on calculations performed (some
system consisting of a heated filter, a steam separator, a
relevant data are presented in Table 2), the average resi-
set of containers with activated carbon and XAD-2 adsor-
dence time of flue gas in the zone after the last air supply
bent, a membrane pump, and a gas meter with a glass
(from OFA nozzles) was found not to comply with the leg-
thermometer.
islative requirement of flue gas residence (i.e., 2 s) in the
temperature zone above 850°C. The obtained values were
practically half of the required figure and resulted from the
Results and discussion section of flue gas flow being too short (H = 5.1 m). Increas-
ing the time of flue gas residence in the temperature zone
During the tests of sewage sludge co-combustion with coal above 850°C would require reducing its volume, which
in an OP-230 boiler, no basic technical problems were found would result in a decline in boiler capacity. Another
114

Table 2. Selected data used for calculation of average flue gas residence times in the zone with a temperature above 850°C, after the last air
supply
Parameter Unit Fuel

Coal Coal + sewage sludge

Mean flue gas temperature in combustion chamber °C 1 052.50 981.50


Flue gas flow (normal conditions) mn3/h 201 701.76 204 960.34
Flue gas flow (real conditions) m3/h 979 324.85 941 841.56
Mean flue gas velocity m/s 4.90 4.71
Length of combustion chamber section with temperature above 850°C m 5.10 5.10
Flue gas residence time in the zone with temperature above 850°C s 1.04 1.08

Table 3. Results of power measurements for the tested boiler


Parameter Unit Fuel

Coal Coal + sewage sludge

Steaming rate of the boiler ton/h 202.00 201.40


Thermal power MW 142.12 142.10
Heat load % 87.83 87.57
Mean stream of the fuel ton/h 24.22 24.34
Chemical energy of the fuel MW 153.68 154.45
Energy of steam stream MW 187.57 187.52
MW 11.56 12.35
Sum of heat losses % 7.53 8.00
Boiler efficiency % 92.48 92.00

1500 Table 4. Results of emission measurements for the tested boiler


Parameter Unit Emission Fuel
1300 standard for
tested boiler Coal Coal + sewage
Flue gas temperature, ºC

sludge
1100
O2 % v/v – 6.00 6.00
NOx mg/m3n 500 476.68 471.79
900 The lowest permissible temperature SO2 mg/m3n 1550 1305.49 1144.60
CO mg/m3n 225 14.90 13.63
Dust mg/m3n 350 31.99 36.40
700 HCl mg/m3n n.s. <0.22 0.57
HF mg/m3n n.s. <0.35 <0.35
TOC mg/m3n n.s. 7.55 27.55
500
Hg mg/m3n n.s. 0.0062 0.0064
TOC, total organic carbon; n.s, not specified
300
10 12 14 16 18 20 22 24 26
Measurements point height, m Table 5. Inflammable matter in combustion/co-combustion by-
products
5 cm 10 cm 30 cm 50 cm
Parameter Unit Sludge share in the
fuel
Fig. 4. Flue gas temperature distribution along the height of the com-
bustion chamber and for different distances from the screen surfaces 0 wt% 1 wt%

Inflammable matter in ash wt% 4.9 5.2


potential solution of this issue could consist of lowering the Inflammable matter in slag wt% 5.2 3.2
level of the OFA nozzles; however, the calculated height of
their installation to comply with the required time of flue
gas residence in the temperature zone above 850°C would decline in boiler efficiency during sewage sludge co-
amount to around 14 m, so it is unrealistic on account of the combustion were barely noticeable. From the figures pre-
level of the upper burners in the tested boiler. sented in Table 4, it is clear that the tested boiler complied
Tables 3 and 4 present results of power-emission mea- with current emission standards for pollutants for both coal
surements for the combustion of coal and sewage sludge combustion and 1 wt% of sewage sludge in the fuel blend.
co-combustion with coal. It can be seen from the Table 3 Table 5 shows the inflammable matter content in samples
that differences in the power parameters and especially the of combustion/co-combustion by-products. Taking into
115

account domestic requirements on slag and ash from waste 4. Compliance with current emission standards is
co-combustion, which specifies the maximum permissible possible for the tested boiler if it starts sewage sludge
inflammable matter content in incineration slag and ashes co-combustion at a share of 1 wt% in the fuel blend.
at 5 wt%, for slag from sewage sludge co-combustion in an
Summarizing, the process of dried sludge co-combustion in
OP-230 boiler this condition was found to be met. However,
pulverized hard coal boilers at an amount in the fuel of up
a slight excess of inflammable matter content in the ash
to 1 wt% does not create any technical or engineering prob-
from sludge co-combustion was found. As this parameter
lems. The process does not create excessive environmental
was already exceeded for slag from coal combustion, it may
hazards resulting from increased pollutant emissions. Given
be concluded that the lack of compliance with the required
the current situation in Poland, the processing of sewage
inflammable matter content was not caused by the addition
sludge by co-combustion with coal in existing power boilers
of sewage sludge to coal but resulted only from the process
seems the most promising way of municipal sewage sludge
conditions of combustion.
utilization in the immediate future.

Conclusions
References
Industrial tests of dried municipal sludge co-combustion
1. www.stat.gov.pl/gus/rolnic_lesnict_srodowi_PLK_HTML.htm
with hard coal carried out in an OP-230 pulverized coal (Environmental Protection 2006; 14.04.2006) (in Polish)
boiler have shown that: 2. Disposal and recycling routes for sewage sludge. European
Commission, October 23, 2001, http://ec.europa.eu/environment/
1. The influence of dried municipal sludge co-combustion waste/sludge/sludge_disposal.htm
on the boiler’s efficiency is minimal at 1 wt% sludge in 3. Werther J, Ogada T (1999) Sewage sludge combustion. Prog Energy
the fuel blend. Combust Sci 25:55–116
2. The design of the boiler tested does not allow compli- 4. Richers U, Scheurer W, Seifert H, Hein KRG (2002) Present status
and perspectives of co-combustion in German power plants.
ance with the formal requirement on flue gas residence Forschungszentrum Karlsruhe, Karlsruhe
time of 2 s. 5. http://www.sciencedirect.com (19.01.2007) www.elsevier.com
3. The obtained results of inflammable matter content 6. Stelmach S, Wasielewski R, Zuwała J (2006) Co-combustion of
and total organic carbon in some cases exceeded the sewage sludge with hard coals as a chance of real environmental
problem solution in Poland (in Polish). Karbo 4:234–240
maximum permissible values; however, compliance with 7. Directive 2000/76/EC of the European Parliament and of the
these parameters is possible once combustion conditions Council of 4 December 2000 on the incineration of waste. (Official
are optimized. Journal L 332, 28/12/2000 p. 0091–0111)

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