Solutions: Section A

Mock Test-4 Paper-2 (100391.
1)-CMP-IITJEE-22
SOLUTIONS
PART I
SECTION A
1 2Q q Q q q 2Q q Q q
1. q q
4 0 R R c
Q
q
4 0R v1 v2
2 v1 v2
c
2
2. 6.77 10
2
-2
m/s
RT MV 2
also v 1.4
M RT
diatomic
e
4. i
T
Now T 2 r 3 and r n2 T n3
fw dw 1
5. 1
f0 d 2
f 1 d
1
fa 3 d
d
1.18
dw
6. use the concept of relative velocity.
7. Let 1 and 2 be the speed of the body before and after striking.
1 sin 2 cos (as there is no friction)
e 1 cos 2 cos
2
2 sin
e tan2
1 cos
10V
9. 50 A gives full scale deflection.
200k
5 mA through 1 gives 5 mV drop, which across 100 micro-ammeter gives 50 A.
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Mock Test-4 Paper-2 (100391.1)-CMP-IITJEE-23
WS
10. Energy received at photo sensitive surface per unit time .
4 a2
Number of photons = energy per unit time energy of a photon.
11. In longitudinal stationary waves, displacement node is pressure antinode, while displacement
antinode is pressure node.
12. If speed > 0, then friction is required to provide necessary centripetal force.
But as the frictional force has a limitation, it cannot negotiate at any speed.
SECTION C
4. The equivalent circuit just after closing the 2 2
Req = 3 + 2 = 5
10
I0 2A 3
Req 5
= 10V
5. The force acts along the tangential direction
6. For plane convex lens

1 1 1 12 1 1 1 1 1 5
1 ; f ;
f R 5 u f 3 12
1 1
12m .
12
PART II
SECTION A
1. B
th
10 lines are obtained as a result of electronic transition from 5 level to lower levels and lines
corresponding to UV spectrum are as follows:
5
2. C
(A) is not -anomer
(B) is not a pyranose sugar
(D) is not a D-sugar
While (C) follows all criteria.
3. C
H2N CH2 CH2 COOH
(Hoffmann Bromamide reaction)
4. D
K 2Cr2 O7 4H2 SO 4 3H2 S K 2 SO4 Cr2 SO4 3
7H2 O 3S
Every 294 g K2Cr2O7 gives 96 g of S, so 3062.5 kg of K2Cr2O7 is required to produce 1000 kg of
sulphur.
5. D
Foam comes from gas bubbles trapped in the cream. The best gas for making the cream would be
r for a gas that is less soluble.
6. D
ClCH2COOH ClCH2 COO H
1 x x x
So i = 1 + x
Tf i K f m
1.93
i 1.037 hence x=0.037,
1.86 1
0.037 0.037
Ka 0.00142
0.963
7. C
o
The boiling of water at 100 c and 1 atm P is in equilibrium so Suni 0
8. B
E I t
w
96500
w d V
-3 -3
= 19.3 g cm
w = 7.575 g
7.575 96500 3
t
197 0.02
= 556589.5 sec
6.45 days
9. A, C, D
CH3
O
CH3 O3 O
Zn
NH2 OH
O OH
H3C C NH CH3 PCl5 N
MW 73 g Beckmann rearrangement
10. A, C
11. B, C, D
Li2CO3 Li2O CO2 only acidic gas
1
NaNO3 NaNO 2 O2
2
Na2SO4 4C Na 2S 4CO
Li3N 3H2O 3LiOH NH3
12. B, C, D
Annulenes are conjugated monocyclic hydrocarbon
(B) is antiaromatic annulene
(C) is not an annulene as it is not monocyclic
(D) is aromatic but it is not an annulene.
SECTION B
1. A ); B ;C ); D )
CH CH COOH
Cinnamic acid
OH
H 2C CH2 COOH HOOC C H
HOOC CH2 C CH2 COOH
COOH H 2C CH2 COOH HOOC C H
Citric acid
Adipic acid Maleic acid
2. A ); B ;C ); D )
4r 2a
3 o
Distance between fourth nearest neighbors is a 5.14 A
2
a
Distance between second nearest neighbors is
2
o
Distance between third nearest neighbors is a = 2 r r = 11.88 A

o
Edge length a = 2 r r = 11.88 A
o
+
Distance between first nearest neighbors is r r = r + 4.2 A
SECTION C
1. 2
x+
equ. of MnO 4 = equ. of M
x)
x=2
2. 1
Compounds (C), (F) are only optically active
Those which can exhibit only geometrical isomerism are compound (A), (B),(D), (G), (H) and (I).
Compound which can exhibit both kind of isomerism is only (E).
3. 6
Species C, G and I cannot exhibit resonance.
4. 4
en, ox, phen, dipy are bidentate ligands with identical donor atoms?
gly is bidentate but with different donor atoms.
dien tridentate
trien tetradentate
py monodentate
S CN ambidentate
5. 7
O O
5
P3 NH C H
H O CH 2 CH2 O
1 O 4 6 7
2 H
6. 6
(A), (C), (D), (F), (G) & (H) are correct.
PART III
SECTION A
2 2
x 1 y 1
1. 1
a2 b2
The coordinates of the point Kr will be (1 + R cos , 1 + R sin ), where R is AKr and
r R 2 cos2 R2 sin2 Kn
=1 Kr (1+ Rcos , 1+ Rsin )
2n a2 b2 R K1
n
1 2 (1, 1)
lim AKr
n n r 1
n 1
1 1 a2 b2
lim dx
n nr cos2 r / 2n sin2 (r / 2n) 2 2 2 2
1 0 b cos x a sin x
a2 b2 2 2
2. 1 2
2 P(x, y)
1
2
1 2 2 1
2
2 2 1
2 1 2
O(0, 0)
2 tan 2 1
2 tan
1 tan 2 1
dy
2
dx x
2 y
dy
1
dx
2 2
dy dy dy dy
2y x x x 2y x
dx dx dx dx
10!
3. Total arrangement =
2! 2! 2!
The number of arrangement if atleast one kind of alike letter are together
9! 8!
= 3 3 7!
2! 2! 2!
4. (n 1)!n! (n 2)!(n 1)! 2n 2 C1 = (n 1)!(n 2)! {n(n 1) (2n 2)}

2
= (n 1)!(n 2)! {n 3n + 2}
3lnk 2
5. k3
1
1 P
1
, 3lnk
k3 k3
3
So, f(k) = k + 3lnk 1
1
f f e 0 ( 1, 2)
e
2
6. a a b a.b a a.a b = a b
Continuing in the same manner
2 2 2 4
C a a a b a a b a b
4
C a b 24 3 48
7. Using length of direct common tangent P R

2 Q
PQ 4r1r2
PQ PR QR C
QR2 4r1r3
A B
1 1 1
r3 r1 r2
a4 a4 b6 b6 b6 b6 c8 c8 1
2 2 4 4 4 4 2 2 a8b24c16 8
8.
8 212
Equality hold for a = 1, b = 21/6, c = 1
9. Shown in the figure y-axis
y = {x}
x-axis
0 3 4
3
x x
2 2
7/8
10. I f f x dx ..... (1)
1/8
7/8 7/8
I f f 1 x dx f 1 f x dx ..... (2)
1/8 1/8
3
So, 2I
4
11. f ( 2) = 3 and f ( 3) is negative

So, equation has one real root in between ( 3, 2).
, b 0
1
12. I= tan bn / 2, b 0
2
0, b 0
SECTION B
1. (B) Use binomial expansion
1
1
(C) I = cos x3 3x dx
1
1
(D) Put x =
t
2. (A) Range of the function is (0, ).

(B) Function is decreasing.
(C) Range of function is not R and function is one-one.
(D) The function is clearly many-one because the value of function is zero at x = and .
And range cannot be R.
SECTION C
1. Number is 5999
2. Shifting origin at (1, 2 2 )

2
Y 2 2 4 X 1 4
Let chord is Y = mX + c
Y mX Y mX
Y 2 4 2Y 4 0
c c
Coefficient of X2 + coefficient Y2 = 0
4 2 4m
1 0
c c
c + 4 2 + 4m = 0
Y = mX 4 2 4m
(Y + 4 2 ) m(X 4) = 0
X = 4, Y = 4 2
x = 5, y = 2 2 4 2.
3. Tr 1 1 = 1 = 1
2
= 1 2 88 =
x 13 3 x
5. f f 1 7 9 15
2 2 0 2 3 5 6 8 9
2 2 2 2
f(x) = f(8 x)
f (x) = f (8 x)
1 15
f f 0
2 2
f (2) = f (6) = 0
f (3) = f (5) = 0
9 7
f f 0
2 2
d
f (0) = f (8); h x f x f x
dx
Clearly: h(x) has minimum 18 zeroes
ar 2i
6. X iy 2
ar 4
ar 2
X , Y
ar2 4 ar2 4
2 2 1
X +Y = Y
2
1
X2 Y2 Y 0
2
2 2 y
So all points lies on circle x + y 0
2
1
r
4
1 2 2 1 1 1 1
Area of regular octagon = 8 r sin =8 .
2 8 2 16 2 4 2

Solutions: Section A

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Solutions: Section A

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Mock Test-4 Paper-2 (100391.

6. use the concept of relative velocity.

5. The force acts along the tangential direction

6. For plane convex lens

Distance between third nearest neighbors is a = 2 r r = 11.88 A

Edge length a = 2 r r = 11.88 A

4. (n 1)!n! (n 2)!(n 1)! 2n 2 C1 = (n 1)!(n 2)! {n(n 1) (2n 2)}

7. Using length of direct common tangent P R

9. Shown in the figure y-axis

11. f ( 2) = 3 and f ( 3) is negative

2. (A) Range of the function is (0, ).

2. Shifting origin at (1, 2 2 )

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