Soludon: (1) Fora binary system obeying Raoutt’s law, Par PB wo yea PQ equations (1)= 2) give ay Pax BO ax, Asyity2 1 and +29 1, therefore Pap Sax (P! 7 @ Equation 3 predicts that P is linear in:x Thus ao maximm or minim can exist in this relation. Since such an extremum is required forthe existence of an azeotrope, no azcotrope 4s possible,oes laa “os ie P= 00M oe ieee fs rf) P= ule Ores aa “s vie evan1046 Presuresin kPa ae Ee SS sa(am) - eplaxz) ym) sem Ax) (sot) valet) Pat =a 81%) Pe (9) UBL cai aan arta Rats F.8) Pau a DEW Palen: an omen Gus yn 08 Para Tt Gren ppP = xrd(ti tm) Paty Pea syyafsie! <1} Paty + (t= poafet-t-m)) Bah a) Gls) RBA a ‘The pressure range for to phasis fom the denpoint tothe Dubbiepoint: From 3 $44 to 56.745kPa (© BUBLP aleulaton: HEME x-iy sevafxi dni), (0 See Example 10.09. 00) ana Sa