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JEE (Advanced)-2019
PAPER –2
SECTION – A
1. A
Sol. Using conservation of angular momentum about fixed charged.
V V
MV sin 30R = Mv'.r R r
2 3
3
r R
2
2. A
Sol. Charge on sphere will redistribute due to electric filed produced by thin plate. Electric field at any
point (say P) due to charges on sphere is
A
+ P +
E 0 +
O +
+
+ +
+
+ + + +
E (so that field at P may become zero combinedly due to thin plate and sphere) Now due
2o0
to sphere: V0 VA E cos 0 R
VA V0 Er cos 0
kQ
R cos
R 20 3
kQ R
R 40
[Here all the calculations are done only for the charges on spheres].
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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 2
3. D
Sol. Figure shows the forces action on the smaller cylinder. N1 is reaction between the two cylinders
and N2 the normal reaction between the smaller cylinder and the horizontal surface.
N2
N1
N1
O2
O1 Rr
90
Rr N2
O2 mg
S1 O S2
cos
2m 1
4
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3 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
5. A, D
Sol. PA P P0 gh ….(i)
Apply Bernoulli’s theorem at A and C and E
V2
(P P0 ) gh Pc c
2
VE2
P0 ….(ii)
2
Pc P0 gh1 ….(iii)
A c Vc AE VE
A
A c Vc c VE ….(iv)
2
From eq. (i),
V2
(P0 gh1 ) c P0 (2Vc )2
2
7V 2
P gh g c
2
(P gh)
v 2c
4
1/2
(P gh)
Discharge rate A c Vc A
4
6. A, C
Sol. The free body diagram of block + tube inclusive of water is as shown below
B
air l/3
l
h
B
air l/3
l
T
r
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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 4
l l
P P0 h dg Pa P0 dg h
3 3
7. C, D
Sol. The temperature gradient (which causes the heat to flow) is only along the length. The
temperature at any point of a given cross-section is the same and
so Qa Qb 0 .
In the steady state, Q1 is constant 0
8. B, C
Sol. As shown in the curve, if wave is moving alogn x axis, VP is positive.
y VW
Vp 53o
A x
Vp
tan
Vw
tan 1 VP VW .
9. C
10. D
SECTION – C
11. 6
Sol. BE of X = 6A
Be of Y = 6A - 2 + 1 = 6A - 1
[Because absorption of energy decreases BE and release of energy increases BE] In Y nucleus
there are A + 1 nucleus.
BE 6A 1
nuclon A 1
12. 0
Sol. When switch S2 is closed, due to symmetry no charge will flow through S2.
13. 5
Sol. Let initial extension in spring is x 0 , then
2kx0 cos 45o mg sin 45o 2kx 0 mg
Let after cutting right spring, acc. of ball is a1 along the inclined plane and a2 perpendicular to a1
mgmg 1 g
ma1 a1
2 2 2 2 2
o o
Then mgsin 45 kx0 cos 45 ma1
g
kx 0 sin 45o ma2 a2
2 2
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5 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
g
Net acceleration a a12 a 22 5 m / s2
2
14. 6
Sol. Applying Bernoulli’s theorem for above the plate (2) and below the plate (1), we have
1
p1 p2 pv 2
2
1
p1 p2 pv 2
2
1
Upward force is (p1 p 2 )A pv 2 A
2
1 2
pv A mg
2
2mg mg
v 6
pA 18pA
6
15. 4
Sol. Mass of air entering in 1 s is m b2 vp
Change in momentum in 1 s mv 0 b2 pv 2
Thus, F b2pv 2
F b2pv 2
Pressure due to this force is p pv 2
A b2
4T
When this excess pressure equals to , the bubble gets separated.
R
4T 4T
pv 2 R 2
R pv
So, 4
16. 5
Sol. The F.B.D. of wire PQ is the force due to surface tension FST 2T 2AD tan
FST (2T) 2AD tan FST (2T) 2(AD x) tan
P Q x
P Q
mg mg
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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 6
4T
a tan X
m
Comparing with a 2 x, we get
4T
2 tan
m
m 1 103
or T 2 2 3
s
4T tan 4 25 10 5
17. 6
Sol. In the figure, 30o .
When displacement is each ball x, the extension in each spring is
3
x ' x cos x
2
Each spring is connected to two balls.
So, net extension of each spring 2x ' 3x
Force along the direction of displacement on each ball is
F k 3x cos30o k 3x cos30o 3kx
F 3 kx [negative because restoring in nature]
F 3k 3k
a x
m m m
2 3k 1 6k
f 6
2 m 2 2m
18. 2
Sol. amax 2 A g
2v F
,v
4 2F F
2
2
42F
amax .A min g
2
g 2 2
A min ( 2 g)
42F 4F
(0.5)2 (0.1)
A min
4(3.125)
2 10 3 m 2 mm
19. 4
Sol. Let the velocities of car 1 and car 2 be V1 m / s and V2 m / s
Apparent frequencies of sound emitted by car 1 and car 2 as detected at end point are
V V
f1 f0 , f2 f0
V V1 V V2
330 330
330 300 , 360 300
330 V1 330 V2
V1 20 m / s and V2 100 m / s.
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7 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
The distance between both the cars just when the 2nd car reach and point B (as shown in figure
is)
V2 t
V1t 1
2
A B
100 m
100 m V2 t V1t t 4 sec.
20. 1
1 F
Sol. f
2L
f c F
1
where constant c
2L
df 1
c.
dF 2 F
df 1 1 1 F
or .
dF 2L 2 F 2L 2F
df 1 F 1 f
.
dF 2L 2F 2F
fdF (200)(1)
df 1 s 1
2F 2(100)
Beat frequency = 1 s1
SECTION – D
21. 00002.67
Sol. Fup
Mg
At equilibrium, Fup Mg
22. 00015.70
Sol. y 2 sinkx cos t
Now, we can compare with given equation.
23. 00000.16
Sol. 0 , r r0 r
By using formula for fundamental frequency.
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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 8
Chemistry PART – II
SECTION – A
24. B
Sol. Ph
Mg
Ph
C MgBr
ether
Br a
CH 2 CH 2 C C Ph
i) H CHO
ii) H+
Ph C C CH 2 CH 2 CH 2 OH (B)
25. A
Sol. Tetrad AOS is C4 & diad is C2
26. D
Sol. Yellow turbidity of Sulphur is obtained in all the cases.
27. D
Sol. K 2 SO4 .Al2 SO 4 3 .24H2 O 2K 2Al3 4SO24
n factor = 8 1 mole 2 mol 2 mol 4 mole
8 gm eq 2 gm eq 6 gm eq 8 gm eq
1 gm eq 1 gm eq cations 1 gm eq
28. A
Sol. 2.18 10 18 9 2.18 1018 9
E 4 E3
16 9
18 7 19
2.18 10 9.53 10
16
29. A, C, D
Sol. CH 3 CH CH 2 CH3
CH3
In (b) one carbon is extra.
30. A, C, D
Sol. O – nitrobenzoic acid is stronger than m, p nitro derivatives as well as benzoic acid o –
nitrophenol is weaker acid than P – nitrophenol due to intramolecular H – bonding.
31. B
Sol. iCRT
3 0.4 0.0821 298
29.358 atm
As osmotic pressure is more than applied pressure so osmosis will occur.
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9 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
32. B
Sol. Li N2
Li3 N
M A
Li3N H2 O
LiOH NH3
B C
1100o C
N2 CaC2
CaCN2 C
D G H
C O2 CO2
H
Ca CN2 H2 O
CaCO3 NH4 OH
G I J
C
33. C
Sol. NH4NO3 N2 O2 H2 O
CaCO3 CaO CO 2
SECTION – C
34. 3
Sol. A is 20 Alcohol
mol , wt of A 60.
formula C3 H 8o
35. 2
Sol.
In & Ph CH CH CH3 rearrangement will give different products.
Cl
CH3 Cl
36. 5
Sol. HI n H In
Color A Colour B
H In
k In
HI n
The midpoint of the colour change of an indicator HI n is the point at which
I n HI n
ph 5
37. 6
Sol. C xH y O 2 C o2 H 2 o
x 100 300
x 3
38. 8
Sol. Tc 3.4.2k
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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 10
8a
27Rb
Tc 8b
Pc R
4 3
b 4NA r
3
r 1.62 10 8 cm
Pc 72.9 atm
a
27b2
39. 6
Sol. Let mol. wt of salt is M
(i) n-factor in acid – base titration = y
(ii) n – factor in redox titration = 2xz
Max of acid in 30 mL = Max of NaOH
9.15
30 y 27 0.12 ........(i)
M
9.15
30 (27) 36 0.12 ........(ii)
M
y 3
..........(iii)
z 2
Total cationic charge = Total ammonic chare x + y = 2z
x:y:z=1:3:2
40. 1
x 2x(2.18 x)
Sol. 0.0187
x 16 2x 48
x 99 100
41. 2
Sol. Ma3 b3 has two geometrical isomers i.e. fac & mer & both are optically inactive so x = 0
M AA 3 has one pair of enantiomers
y 1
& Z=1
so x + y + z = 2
42. 5
Sol. Ag O2 H2 S Ag2S H2 O
Ag H2 S
Ag2 S H2
HgS,PbS & CuS are black
cds is yellow.
43. 8
Sol. HCl O3 Cl2 H2 O O2
PbS O3 PbSO4 O2
As O3 H2 O H3 AsO4 O2
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11 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
I2 O3 I4 O9 O2
O3 K 2MnO 4 H2 O KMnO 4 O 2 KOH
Hg O3
Hg2 O O2
O3 SO2
SO3
O3 KI I2 O2 KOH
SECTION – D
44. 00087.50
30
Sol. % Enantomomeric excess = 100 75
40
25
So % of d = 75 87.5
2
45. 00001.66
Sol. Nearest distance between two ‘A’ layers = 3a
3a 8 6 a 8 2 nm
8 2
a8 2 r r= 4
2 2
rv.
0.414
r
ro.v 0.414 4
1.656 nm
46. 00007.00
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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 12
SECTION – A
47. B
1 a1 1 a2 1 an
Sol. Pn .........
a1 a2 an
a2 a an an 1
3 ........
2 a1 3 a2 n an1 n 1 an
an 1 n 1 an 1
Pn
n1 n 1 n
1 an 1 n 1 an 1
n n n n n 1
1
1
....................
1 a1
n n 1 1
1 1 1
1 ...........
1 2 n
lim Pn e
n
48. D
Sol. , , r, r 3 are terms
r3 r
Equation – 1 3 r r 3 a
r r
1 1
r r3 3 a ........... A
r r
Equation – 2 4 d ........... B
2 2
Equation – 3 2 2 2r 2 2r 4 b
r4 r2
3 3
Equation – 4 2 3r 3 r 3 C ............. C
r r
A C
1 a c2
2
2
c a
2 2
dc /a
c 2 dac
49. C
0 1
Sol. f x 1 f x
0
1/ 3 3 1
0
1 1 3 1 0
1
3
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13 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
1 3 2 1
1 1 1 1/ 2
4 4 4 2
1 1 1
x f x .dx xf ' x f ' x
1 1 1
1
1 f ' 1 0 0 1/ 2
4
1
1/ 2 1
2
50. A, B, D
Sol. SAB is right angle at S
1 7 1 6
Centre C is , 4, 3
2 2
4 and 3
1 and 7
SC is radius and AB is diameter
1 1 85
SC 36 49 85 21.25
2 2 4
51. A, B, D
Sol. Confocalconics always intersect orthogonally & circle touches at vertex of ellipse.
k 1
52. A, D
Sol. y 3 3x2 y x3 0
dy 6 xy 3 x 3 2 xy x y
2 2
dx 3 y 2 3x2 3 y2 x2 x
dy y
dx i.e., dx y c
dx x
f x c or xf ' x c
53. A, B, C, D
Sol. 2 A2 2 A 144
22 A A I 144
2
2 1 36
1 6 or 6
2 6 0 or 2 6 0
1 1 24
3 2 0 or
2 1
1 23
3 or 2 i
2 2
tr A 2
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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 14
= 6 or –4 or 1 (Real part)
A 2 9 or 4
54. A, B, D
x sin x 1 sin x
Sol. 1 cos x cos x 0
0 sin x sin x
x 2n 1
2
55. C
4
Sol. f x 1 x2
3 12
4
range is , ,
12 3 12
56. A
SECTION – C
57. 4
Sol.
2 a2 b2 4 a2 b 2 8
a2 b2
ab
2
ab 4
58. 2
1 1
Sol. f x
i 1 x 1 ix 1
i1
1
f x lim 1
n
nx 1
f x 1
1
f 1
x
1
f x f 2
x
59. 4
2
Sol. tan1 x for 1 2 x 2 1
3 2
tan1 x 3 x 2 1
6
1
x 1 x 3
3
1 x 3
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15 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
60. 4
2 3
x3 3x2 3x 5
Sol. I and J
1
ln x 1 2
ln x 2
2
3x 2
J
1
ln x 1
3
J I
2
x 3 3 x 2 3x 2
2
x 1 1 dx
1
ln x 1 1
ln x 1
3
x 1 1
2 1 3
dx
x 1
dx ln 4
1
ln x 1 0
ln x
eln 4 4
61. 2
Sol. OA aiˆ bjˆ ckˆ and a 2 b 2 c 2 4
AB 25 24cos 2
2
2
QD cos
5 2
25 QD 2
62. 4
3x2 1 3x2 1 x2 1 2 x 2
Sol.
x4 x 2 x x2 1 x x2 1
x2 1 2x
2 2
x x2 1
f x 2 2
x2 1 2 x2
x2 1
x 1 x 1
2
3x 2 1 dx 2 2 2 4
0 x4 x2
63. 2
Sol. Given a11 b11 , a22 b22 , a12 b12 , a21 b21
and AB BA I
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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 16
a11 a12
A and A 1
a21 a11
a112 a12 a21 1
a12 a21 a112 1
a12 or a21 a11 1 or a11 1
a12 a21 2
64. 5
Sol. f x
5 1 f 2 5 1
sin
2x 4 10
sin1 f 2
10
65. 5
Sol. r 2 4r 2 Sr
r 2011
r 1 r
r
r 3
2
4r 2 Sr
r3 r 2
66. 5
a tan x b sin x cx 2 x 3
Sol. lim
x 0 x3 2
0 a sec 2 x bcos x 2cx 1
Then, form lim
0 x 0 3x 2
0
Now, form means a b 1 0 ………….. (1)
0
Again L’Hospital rule,
2a sec 2 x tan x b sin x 2c
lim
x 0 6x
0
form means c = 0
0
2a sec 2 x 6a tan2 x sec 2 x b cos x
lim
x 0 6
0 2a b 3
form means 2a b 9 ……….. (2)
0 6 2
10
3a 10 and b 1
3
10 7
a and b
3 3
17
a b c 5.66...... a b c 5
3
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17 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
SECTION – D
67. 00003.20
4
1
8 4 5 1 and e 1
Sol. 2cos 1 cos 1 tan 1
5 5 2 4 3 2
1
5
1
2 1 2
tan
2 3 3
2
2 3 3
2
2 4 2
1 8 4 16
B 0, 3 AB 2 2 4
2 5 5 5
68. 00540.00
th
Sol. a12 b12 c12 a22 b22 c 22 a32 b32 c 32 7 , where ai , bi , ci are elements of i row.
Case I: All seven entries are 1 and rest of all zero
9
C7 9 C2 36
Case II: Only one entry is 2 & three entries are 1 and rest of all 0’s.
9
C4 4 C1 504
Total = 540
69. 00000.75
Sol. Let t log 3x 4 2x 1
1 1
2t 3 t 1 or
t 2
1 3
log 3x 4 2x 1 x 1 or
2 4
3
only solution is x
4
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