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FIITJEE

ALL INDIA TEST SERIES


FULL TEST – IV

JEE (Advanced)-2019
PAPER –2

ANSWERS, HINTS & SOLUTIONS


Physics PART – I

SECTION – A
1. A
Sol. Using conservation of angular momentum about fixed charged.
V V
MV sin 30R = Mv'.r  R  r
2 3
3
r R
2
2. A
Sol. Charge on sphere will redistribute due to electric filed produced by thin plate. Electric field at any
point (say P) due to charges on sphere is
A
+ P +
E 0 +
O +
+
+ +
+
+ + + +


E (so that field at P may become zero combinedly due to thin plate and sphere) Now due
2o0
to sphere: V0  VA  E cos 0  R
VA  V0  Er cos 0
kQ  
  R cos  
R 20 3
kQ R
 
R 40
[Here all the calculations are done only for the charges on spheres].

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 2

3. D
Sol. Figure shows the forces action on the smaller cylinder. N1 is reaction between the two cylinders
and N2 the normal reaction between the smaller cylinder and the horizontal surface.
N2


N1

N1
O2
O1 Rr
90  
Rr  N2
O2 mg

The conditions of equilibrium are


 Fx  N1 cos   N2  N1 cos(90   )  0 ….(i)
Taking torque about O 2 , centre of smaller sphere,
   N1r  N2r  0
N1  N2 ….(ii)
On substituting equations (ii) in (i), we obtain
N1  N1 sin   N1 cos 
(1  sin  )  cos  ….(iii)
Rr 2 Rr
From figure (b), sin   ,cos  
Rr Rr
 R  r  2 Rr r
Now equations (iii) becomes;   1   
 Rr  Rr R
r
Hence the required condition is   .
R
4. A, B, C
Sol. The path different at point P is
x  S1E  2D cos 
P
E

 
S1 O S2

For maxima, 2D cos   m D


m
 cos  
2
The possible value of m in first quadrant is 0, 1, 2.
Thus number of maxima in all four quadrants is eight.
D
For minima, x   2m  1
2

cos  
 2m  1
4

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3 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

Thus possible value of m in first quadrant is 1, 2


Thus, total number of minima in all four quadrant is eight.

5. A, D
Sol. PA  P  P0  gh ….(i)
Apply Bernoulli’s theorem at A and C and E
V2
(P  P0 )  gh  Pc   c
2
VE2
 P0   ….(ii)
2
Pc  P0  gh1 ….(iii)
A c Vc  AE VE
A 
A c Vc   c  VE ….(iv)
 2 
From eq. (i),
V2
(P0  gh1 )   c  P0  (2Vc )2
2
 7V 2 
P  gh  g  c 
 2 
(P  gh)
v 2c 
4
1/2
 (P  gh) 
Discharge rate  A c Vc  A  
 4 

6. A, C
Sol. The free body diagram of block + tube inclusive of water is as shown below
B
air l/3
l

Since the block + tube system shown in figure is in equilibrium


 Net weight of system = buoyant force
2l
2d Vg  r 2 dg  (V  r 2l)dg
3
Where V is the volume of block B
r 2ld r 2l
(2d  d)V  or V 
3 3
The pressure of the air trapped inside the tube is same as pressure at point A in the water as
shown in figure.

h
B
air l/3
l

T
r

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 4

 l  l
P  P0   h   dg Pa  P0  dg  h  
 3  3

7. C, D
Sol. The temperature gradient (which causes the heat to flow) is only along the length. The
temperature at any point of a given cross-section is the same and
so Qa  Qb  0 .
In the steady state, Q1 is constant  0

8. B, C
Sol. As shown in the curve, if wave is moving alogn x axis, VP is positive.
y VW

Vp 53o
A x

Vp
  tan 
Vw
 tan    1  VP  VW .

9. C

10. D

SECTION – C

11. 6
Sol. BE of X = 6A
Be of Y = 6A - 2 + 1 = 6A - 1
[Because absorption of energy decreases BE and release of energy increases BE] In Y nucleus
there are A + 1 nucleus.
BE 6A  1
 
nuclon A 1

12. 0
Sol. When switch S2 is closed, due to symmetry no charge will flow through S2.

13. 5
Sol. Let initial extension in spring is x 0 , then
2kx0 cos 45o  mg sin 45o  2kx 0  mg
Let after cutting right spring, acc. of ball is a1 along the inclined plane and a2 perpendicular to a1
mgmg 1 g
   ma1  a1 
2 2 2 2 2
o o
Then mgsin 45  kx0 cos 45  ma1
g
kx 0 sin 45o  ma2  a2 
2 2

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5 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

g
Net acceleration a  a12  a 22   5 m / s2
2

14. 6
Sol. Applying Bernoulli’s theorem for above the plate (2) and below the plate (1), we have
1
p1  p2  pv 2
2
1
 p1  p2  pv 2
2
1
Upward force is (p1  p 2 )A  pv 2 A
2
1 2
 pv A  mg
2
2mg mg
 v 6
pA 18pA
 6

15. 4
Sol. Mass of air entering in 1 s is m  b2 vp
Change in momentum in 1 s  mv  0  b2 pv 2
Thus, F  b2pv 2
F b2pv 2
Pressure due to this force is p    pv 2
A b2
4T
When this excess pressure equals to , the bubble gets separated.
R
4T 4T
 pv 2  R  2
R pv
So, 4

16. 5
Sol. The F.B.D. of wire PQ is the force due to surface tension  FST  2T  2AD tan 
FST  (2T) 2AD tan  FST  (2T) 2(AD  x) tan 

P Q x
P Q

mg mg

Figure (a) Figure (b)


For wire to be in equilibrium (Figure (a))
4T AD tan   mg
If the wire PQ is at a distance x below the mean position, the restoring force on the wire is (Figure
(b))
ma  4T tan (AD  x)  mg  4T tan  x
Hence, the wire PQ executes SHM

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 6

4T
a tan  X
m
Comparing with a  2 x, we get
4T
2  tan 
m
m 1 103 
or T  2  2 3
 s
4T tan  4  25  10 5

17. 6
Sol. In the figure,   30o .
When displacement is each ball x, the extension in each spring is
3
x '  x cos   x
2
Each spring is connected to two balls.
So, net extension of each spring  2x '  3x
Force along the direction of displacement on each ball is
F  k 3x cos30o  k 3x cos30o  3kx
F  3 kx [negative because restoring in nature]
F 3k 3k
 a  x
m m m
2 3k 1 6k
 f  6
2 m 2 2m

18. 2
Sol. amax  2 A  g
2v F
 ,v 
 
4 2F F
 2  
2 
42F
 amax  .A min  g
 2
g  2  2 
A min   ( 2  g)
42F 4F
(0.5)2 (0.1)
A min 
4(3.125)
 2  10 3 m  2 mm

19. 4
Sol. Let the velocities of car 1 and car 2 be V1 m / s and V2 m / s
 Apparent frequencies of sound emitted by car 1 and car 2 as detected at end point are
V V
f1  f0 , f2  f0
V  V1 V  V2
330 330
 330  300 , 360  300
330  V1 330  V2
 V1  20 m / s and V2  100 m / s.

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7 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

The distance between both the cars just when the 2nd car reach and point B (as shown in figure
is)
V2 t

V1t 1
2

A B
100 m
100 m  V2 t  V1t  t  4 sec.

20. 1
1 F
Sol. f
2L 
f c F
1
where constant c 
2L 
df 1
 c.
dF 2 F
df 1 1 1 F
or  . 
dF 2L  2 F 2L  2F
df 1 F 1 f
 . 
dF 2L  2F 2F
fdF (200)(1)
df    1 s 1
2F 2(100)
 Beat frequency = 1 s1

SECTION – D

21. 00002.67
Sol. Fup

Mg

At equilibrium, Fup  Mg

22. 00015.70
Sol. y  2  sinkx  cos t 
Now, we can compare with given equation.

23. 00000.16
Sol.    0   , r  r0  r
By using formula for fundamental frequency.

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 8

Chemistry PART – II

SECTION – A

24. B
Sol. Ph
Mg
Ph
C MgBr
ether
Br a

CH 2 CH 2 C C Ph

i) H CHO
ii) H+

Ph C C CH 2 CH 2 CH 2 OH (B)

25. A
Sol. Tetrad AOS is C4 & diad is C2

26. D
Sol. Yellow turbidity of Sulphur is obtained in all the cases.

27. D
Sol. K 2 SO4 .Al2  SO 4 3 .24H2 O  2K   2Al3   4SO24
n factor = 8 1 mole 2 mol 2 mol 4 mole
8 gm eq 2 gm eq 6 gm eq 8 gm eq
1 gm eq 1 gm eq cations 1 gm eq

28. A
Sol. 2.18  10 18  9 2.18  1018  9
E 4  E3   
16 9
18 7 19
 2.18  10   9.53  10
16

29. A, C, D
Sol. CH 3 CH CH 2 CH3
CH3
In (b) one carbon is extra.

30. A, C, D
Sol. O – nitrobenzoic acid is stronger than m, p nitro derivatives as well as benzoic acid o –
nitrophenol is weaker acid than P – nitrophenol due to intramolecular H – bonding.

31. B
Sol.   iCRT
  3  0.4  0.0821 298
 29.358 atm
As osmotic pressure is more than applied pressure so osmosis will occur.

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9 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

32. B
Sol. Li N2 
 Li3 N
M A

Li3N  H2 O 
 LiOH  NH3 
B C

NH3  CaOCl2  N2  Ca Cl2  H2O


E
D  F

1100o C
N2  CaC2 
 CaCN2  C
D G H

C O2  CO2
H

Ca CN2  H2 O 
 CaCO3  NH4 OH
G I J
C

33. C

Sol. NH4NO3   N2  O2  H2 O

CaCO3   CaO  CO 2

SECTION – C

34. 3
Sol.  A is 20 Alcohol
mol , wt of A  60.
 formula  C3 H 8o

35. 2
Sol.
In & Ph CH CH CH3 rearrangement will give different products.
Cl
CH3 Cl

36. 5
Sol. HI n  H   In
Color A Colour B
 H    In  
k In 
 HI n 
The midpoint of the colour change of an indicator HI n is the point at which
 I n     HI n 
 ph  5

37. 6
Sol. C xH y  O 2  C o2  H 2 o
x  100  300
x  3
38. 8
Sol. Tc  3.4.2k

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 10

8a

27Rb
Tc 8b

Pc R
4 3
b  4NA  r
3
 r  1.62  10 8 cm
Pc  72.9 atm
a

27b2

39. 6
Sol. Let mol. wt of salt is M
(i) n-factor in acid – base titration = y
(ii) n – factor in redox titration = 2xz
Max of acid in 30 mL = Max of NaOH
9.15
30   y  27  0.12 ........(i)
M
9.15
30   (27)  36  0.12 ........(ii)
M
y 3
  ..........(iii)
z 2
Total cationic charge = Total ammonic chare x + y = 2z
x:y:z=1:3:2

40. 1
x 2x(2.18  x)
Sol.   0.0187
x  16 2x  48
x  99  100

41. 2
Sol. Ma3 b3 has two geometrical isomers i.e. fac & mer & both are optically inactive so x = 0
M  AA 3 has one pair of enantiomers
y 1
& Z=1
so x + y + z = 2

42. 5
Sol. Ag  O2  H2 S  Ag2S  H2 O
Ag  H2 S 
 Ag2 S  H2
HgS,PbS & CuS are black
cds is yellow.

43. 8
Sol. HCl  O3  Cl2  H2 O  O2
PbS  O3  PbSO4  O2
As  O3  H2 O  H3 AsO4  O2

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11 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

I2  O3  I4 O9  O2
O3  K 2MnO 4  H2 O  KMnO 4  O 2  KOH
Hg  O3 
 Hg2 O  O2
O3  SO2 
 SO3
O3  KI  I2  O2  KOH

SECTION – D

44. 00087.50
30
Sol. % Enantomomeric excess =  100  75
40
25
So % of d = 75   87.5
2

45. 00001.66
Sol. Nearest distance between two ‘A’ layers = 3a
3a  8 6  a  8 2 nm
8 2
a8 2 r  r= 4
2 2
rv.
 0.414
r
ro.v  0.414  4
 1.656 nm

46. 00007.00

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 12

Mathematics PART – III

SECTION – A

47. B
1  a1 1  a2 1  an
Sol. Pn    .........
a1 a2 an
a2 a an an 1
  3  ........  
2  a1 3  a2 n  an1 n  1 an
an 1 n  1 an  1
Pn  
n1 n  1 n
1 an 1 n 1  an 1 
   
n n n n n 1


1

1
 .................... 
1  a1 
n n 1 1
1 1 1
 1    ........... 
1 2 n
lim Pn  e
n

48. D
 
Sol. , , r, r 3 are terms
r3 r
 
Equation – 1 3   r  r 3  a
r r
 1 1
  r   r3  3   a ...........  A 
 r r 
Equation – 2  4  d ........... B 
2 2
Equation – 3    2   2   2r 2   2r 4  b
r4 r2
3 3
Equation – 4 2   3r  3 r 3   C .............  C 
r r
 A  C 
1 a c2
2
  2
 c a
2 2
dc /a
c 2  dac

49. C
0 1
Sol.   f  x 1 f  x 
0

1/ 3 3 1
0  
1 1 3 1  0
1
3

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13 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

1 3 2 1
   1   1   1  1/ 2
4 4 4 2
1 1 1
  x  f  x  .dx  xf '  x     f '  x 
1 1 1

1
 1 f ' 1  0  0   1/ 2
4
1
  1/ 2  1
2

50. A, B, D
Sol.  SAB is right angle at S
 1 7 1  6 
Centre C is  ,    4,  3 
 2 2 
   4 and   3
     1 and     7
SC is radius and AB is diameter
1 1 85
 SC  36  49  85   21.25
2 2 4

51. A, B, D
Sol. Confocalconics always intersect orthogonally & circle touches at vertex of ellipse.
k  1

52. A, D
Sol. y 3  3x2 y  x3  0
dy   6 xy  3 x  3  2 xy  x  y
2 2

   
dx  3 y 2  3x2  3 y2  x2  x
 dy  y
    dx i.e.,  dx  y  c
 dx  x
 f  x   c or xf '  x   c

53. A, B, C, D
Sol. 2 A2  2 A  144
22 A A  I  144
2
  2   1  36
   1  6 or  6
 2    6  0 or  2    6  0
1  1  24
  3  2   0 or  
2 1
1 23
  3 or  2  i
2 2
 tr  A   2

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 14

= 6 or –4 or 1 (Real part)
A   2  9 or 4

54. A, B, D
x sin x 1  sin x
Sol.  1 cos x cos x  0
0 sin x sin x

 x   2n  1
2

55. C
4 
Sol.  f  x  1  x2 
3 12
  4 
 range is   , ,  
 12 3 12 

56. A

SECTION – C

57. 4
Sol.  
2 a2  b2  4  a2  b 2  8
a2  b2
  ab
2
 ab  4

58. 2
 
1 1 
Sol.  f  x     
  i  1 x  1 ix  1
i1 

 1 
 f  x   lim 1  
n 
 nx  1
 f  x  1
 1
f    1
x
 1
 f  x  f    2
x

59. 4
2 
Sol.  tan1 x   for  1  2  x 2  1
3 2

 tan1 x   3   x 2  1
6
1
x 1 x  3
3
1  x  3

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15 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

 have no solution for x < 1 or x  3


So, max  1 and min  3

60. 4
2 3
x3  3x2 3x  5
Sol. I  and J  
1
ln  x  1 2
ln  x  2 
2
3x  2
J 
1
ln  x  1
3

J I 
2
x 3  3 x 2  3x  2
2

 x  1  1 dx
1
ln  x  1 1
ln  x  1
3


 x  1  1
2 1 3
dx  
x 1
dx  ln 4
1
ln  x  1 0
ln x
 eln 4  4
61. 2

Sol. OA  aiˆ  bjˆ  ckˆ and a 2  b 2  c 2  4
 
 AB   25  24cos 2 
 2
2 
 QD  cos
5 2
 25 QD  2

62. 4
3x2  1 3x2  1 x2  1  2 x 2
Sol.  
x4  x 2 x x2  1 x x2  1
x2  1 2x
  2 2
x x2 1
f  x  2 2
 x2  1  2 x2
x2  1
x  1 x 1
2
 3x 2  1 dx 2 2 2 4

0 x4  x2

63. 2
Sol. Given a11  b11 , a22  b22 , a12  b12 , a21  b21
and AB  BA  I

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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 16

 a11 a12 
 A  and A  1
 a21 a11 
 a112  a12 a21  1
a12 a21  a112  1
 a12 or a21   a11  1 or  a11  1
 a12  a21  2

64. 5

Sol. f  x 
 5 1   f 2  5 1
 sin

2x 4 10

 sin1  f  2   
10

65. 5
Sol.   r 2  4r  2  Sr
r  2011
r 1 r
  r
r 3
2

 4r  2 Sr  
r3 r 2

66. 5
a tan x  b sin x  cx 2  x 3
Sol. lim 
x 0 x3 2
0 a sec 2 x  bcos x  2cx  1
Then, form  lim
0 x 0 3x 2
0
Now, form means a  b  1  0 ………….. (1)
0
Again L’Hospital rule,
2a sec 2 x tan x  b sin x  2c
lim
x 0 6x
0
form means c = 0
0
2a sec 2 x  6a tan2 x sec 2 x  b cos x
lim
x 0 6
0 2a  b 3
form means   2a  b  9 ……….. (2)
0 6 2
10
 3a  10 and b  1
3
10 7
a and b 
3 3
17
a  b  c   5.66......  a  b  c   5
3

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17 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

SECTION – D

67. 00003.20
4
1
8 4  5  1 and e  1
Sol.  2cos 1   cos 1   tan 1 
5 5 2 4 3 2
1
5
1

2 1 2
 tan  
2 3 3
2
2 3  3
  2 
2 4 2
1 8 4 16
 
 B  0,  3  AB  2  2    4 
2 5 5 5

68. 00540.00
th
Sol.  a12  b12  c12  a22  b22  c 22  a32  b32  c 32  7 , where ai , bi , ci are elements of i row.
 Case I: All seven entries are 1 and rest of all zero
9
C7  9 C2  36
Case II: Only one entry is 2 & three entries are 1 and rest of all 0’s.
9
C4  4 C1  504
 Total = 540

69. 00000.75
Sol. Let t  log 3x  4  2x  1
1 1
 2t  3  t  1 or
t 2
1 3
log 3x  4   2x  1   x  1 or
2 4
3
 only solution is x 
4

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