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Paper Code

PAPER-I 100394.2

Time: 3 Hours Maximum Marks: 210

1. The question paper consists of 3 Parts (Physics-Part-I, Chemistry-Part-II, and Mathematics-Part-III).

2. Section A(i) contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its

answer, out of which only one is correct.

3. Section A(ii) contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its

answer, out of which one or more is/are correct.

4. Section C contains 5 questions. The answer to each of the questions is a single – digit integer, ranging from 0 to 9.

The answer will have to be appropriately bubbled in the ORS as per the instructions given at the beginning of the

section.

B. Marking Scheme:

5. For each question in Section A(i) you will be awarded 3 marks if you darken the bubble corresponding to the

correct answer and zero mark if no bubble is darkened. In case of bubbling of incorrect answer, minus one (-1)

mark will be awarded.

6. For each question in Section A(ii), you will be awarded 4 marks if you darken the bubble(s) corresponding to the

correct choice(s) for the answer, and zero mark if no bubble is darkened. In all other cases, Minus one (-1) mark

will be awarded.

7. For each question in Section C, you will be awarded 4 marks if you darken the bubble corresponding to the

correct answer and zero mark if no bubble is darkened. In all other cases, minus one (-1) mark will be awarded.

Enrolment No. :

Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Batch : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . . . . . .

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-2

Chemistry PART – I

SECTION – A

Single Correct Choice Type

This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out

of which ONLY ONE is correct.

H2O (l, 1.01325 bar) H2O (g, 0.101325 bar). Given vap H H2 O 37.3 kJmol1

-1 -1 -1 -1

(A) 19.14 JK mol (B) 119.14 JK mol

-1 -1 -1 -1

(C) 80.86 JK mol (D) 180.86 JK mol

2. A mixture of NH3 (g) and N2H4 (g) is placed in a sealed container at 300K .The total pressure of

the gaseous mixture is 0.5 atm . The container is heated to 1200 K at which both NH3 and N2H4

decomposed completely according to the following equation.

2NH3 (g) N2 (g) 3H 2 (g)

N 2H 4 (g) N 2 (g) 2H 2 (g)

After decomposition is complete, the total pressure at 1200 K is found to be 4.5 atm. The mole % of

N2H4 in the initial mixture at 300 K was

(A) 20% (B) 25%

(C) 50% (D) 75%

3. Heat of dissociation of CH4 is x. The bond energy of C –C is y. The heat of dissociation of acetone is

Z.

Calculate the approximate bond dissociation energy of C = O.

6x 6x

(A) Z 2y (B) Z y

4 4

6x x

(C) 4 Z y (D) Z y

2 4

Space for Rough work

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-3

4. N2Cl

O O

K L M

(A) Ba(OH)2, KCN and CHCl3/NaOH heat, H3O+

(B) H2O (boil), CO2/KOH and Ac2O – AcONa, heat

(C) Steam ; CHCl3/NaOH, heat, H3O+ and Ac2O – AcONa, heat

(D) Cu2Cl2/HCl, NaOH/high P and CO2|NaOH, heat

5. H3C C Cl/AlCl 3

i LDA I /NaOH

P Q 2

R S T

O Salt of Acid Salt of Acid ppt.

(ii) Me C Cl

R and S are?

O

+ O

(I) O Na (II) +

H3C C O Na

O O

+

(III) CH2 C O Na

(C) III only (D) none of these

6. A cell consists of two hydrogen electrodes, the negative electrode has [H+] = 107 M.

Find the minimum pH of the other electrode at which, the cell reaction will be spontaneous. (Consider

both cells have equal H2(g) pressure)

(A) less than 7 (B) greater than 7

(C) can not calculated (D) can have any value

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-4

a / dm 6 atm mol 2 b / dm3 mol 1

A 1.360 0.0318

B 3.592 0.0426

The critical parameters Pc , Vc , Tc are related as

(1) Pc A Pc ( B) (2) Vc A Vc ( B) (3) Tc A Tc ( B)

Select the correct one

(A) 1 alone (B) 2&3

(C) 1&2 (D) 1,2 & 3

8.

H

i t BuOK/ i CF COO Hg/H O18

ii D2 /Ni1eq P Q

3 2

2

ii NaBH , OH 4

Br

O 2N

P and Q respectively are

18

OH H

O2N C C ; O2N C C

(A)

D D D D

18

H HO

(B) O2N C C ; O2N C C

D D D D

18

H HO

(C) O2N C C ; O2N C C

D D D D

18

H HO

(D) O 2N C C ; O2 N C C

D D D D

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-5

9. Choose the answer that has the following compounds located correctly in the separation scheme.

4-Nitrotoluene (P), Para – cresol (Q), Para-toluidine (R)

dil.NaOH ppt.(i)

ether

dil.NaOH

dil.HCl

P Q R ether ppt.(ii)

PPt. iii

dil. HCl

dil.NaOH

(A) P Q R

(B) P R Q

(C) Q P R

(D) R Q P

10. 1.0 M solution of weak acid HA is only 0.5% ionized. If 2ml of 1M solution of HA is mixed with

30 ml water, the degree of dissociations of the acid in the resulting solution and [OH-] ion

concentration of the solution will be respectively.

3 3

(A) 0.02 and 1.25 10 M (B) 0.08 and 3.5 10 M

4 12

(C) 0.04 and 3 10 M (D) 0.02 and 8 10 M

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-6

This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its

answer, out which ONE OR MORE is/are correct.

(A) A solution of Ni2+ on addition of NaOH produce a green precipitate. Which does not dissolve on

addition of excess NaOH.

(B) On addition of NH3 solution to a solution of Ni2+ a green precipitate appears which dissolve on

excess of reagent.

2+

(C) When H2S is passed through a solution of Ni , a black colored precipitate is obtained which

dissolves in dil. HCl.

(D) On addition of excess KCN, Ni2+ it forms [Ni(CN)4]-2 whose geometry is square planar.

12. Which of the following does not give the positive Fehling test?

CHO

(A) (B) Ph–CHO

CHO

CHO CH2CHO

(C) (D)

COOH CH2CHO

13. 2 gm of fuming sulphuric acid is diluted with water to make the volume 1 litre, 100 ml of this solution is

then titrated with 0.1 M NaOH solution , the volume of NaOH consumed at equivalence point is

43.25ml . which of the following is/are correct for the above titration-

(A) % of oleum is 105.96 (B) % of free SO3 is 26.5

(C ) Equivalent of SO3 are 0.013 (D) wt of H2SO4 is 1.85

D , the following curves are

plotted. Identify the correct statements.

(A) (t100%) of reaction-I = 2/3(t100%) of reaction-II

1M

3

(B) [A] = [C] at t minutes [A]

4

(C) When [B] = [A] at that time [C] = [D] 0.5M

[C]

(D) if [A0] = [C0] = 1M then (t80%) of reaction-I = 1/3(t80%) of reaction-II

O . 0

60 300

Time

15. Which of the following will produce H2O2 as one of the product.

(A) K 2 S 2O8 H 2O (B) CH 3CHOHCH 3 O2

(C) BaO2 CO2 H 2O (D) PbO2 H 2O

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-7

SECTION –C

This section contains 5 questions. The answer to each question is a single digit integer, ranging from 0 to 9

(both inclusive).

1. Find isoelectric point for the given amino acid. ( pK a1 2.2, pK b2 4.2 )

H3C CH COOH

+

NH 3

Fe(OH)2

Fe(OH) OH

K 1 10 4

Fe(OH) 2

Fe OH

K 2 1 107

3. An inorganic compound (A) is a strong reducing agent. Its hydrolysis in water gives a white turbidity (B).

Aqueous solution of (A) gives a white precipitate (C) with NaOH solution which is soluble in excess of

NaOH. (A) reduces auric chloride to produce purple of cassius. (A) also reduces iodine and gives

chromyl chloride test. Find total number of OH group present in one molecule of product C is

X s

A g 2B g ;K P1 7.2 10 atm

2 3

Y s

2B g C g ;K P2 3.6 10 atm

2 3

The total pressure of gases over the mixture of X and Y is P × 10-1 atm. Find the value of P.

5. What is the sum of the basicity for the following acids H 3 PO4 , H 3 PO3 and H 3 BO3

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-8

Mathematics PART – II

SECTION – A

Single Correct Choice Type

This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out

of which ONLY ONE is correct.

2

1. The range of values of k (k R) for which the equation 2 sin x – k sin x – 1 = 0, will have a real

solution is

(A) (0, ) (B) (–, 0)

(C) (–, 0] (D) (–, )

P(x) = a1x2 + 2b1x + c1

2

Q(x) = a2x + 2b2x + c2 where a1 0, a2 0 and P(x) and Q(x) both take positive values

x R g(x) = a1a2x2 + b1b2x + c1c2 then

(A) g(x) takes positive value only (B) g(x) takes negative value only

(C) g(x) takes both positive and negative value (D) nothing can be said about g(x)

3. Number of ordered pair of positive integer (a, b, c, d) such that LCM of a, b, c, d is 729

(A) 670 (B) 671

(C) 672 (D) 673

200

4. The value of C0 – 200C1 + 200C2 – 200C3 ….. + 200

C148

(A) 200C148 (B) 199C148

(C) 198C148 (D) 197C148

5. The orthogonal of trajectory of the family of curve (x + 2y)2 = a(x + y) and at what angle do the curves

of one family cut the curves of the other family at the origin

1 1

(A) tan1 (B) tan1

2 3

1 2

(C) tan1 (D) tan1

4 3

Rough work

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-9

6. If f(x) < 0 x R, then for any two real number x 1 and x2 (x2 > x1)

x x2 x x2

(A) 2f 1 f x1 f x 2 (B) 2f 1 f x1 f x 2

2 2

x x2 x x2

(C) 2f ' 1 f ' x1 f ' x2 (D) 2f ' 1 f ' x1 f ' x2

2 2

BD 1 AE 1 A

7. In a ABC as in given figure and find

CD 4 CE 5 E

PAE P

ratio of

PBD

B C

D

5 4

(A) (B)

3 3

2 1

(C) (D)

3 3

f(a) = 31/6 if f(x) (f(x))4 + (f(x))–2 then maximum value of a is

(A) (B)

12 3

(C) (D)

6 36

9. The value of (nC0 – nC2 + nC4 – …..)2 + (nC1 – nC3 + nC5 – …..)2 is equal to

(A) 2n (B) 2n – 1

n

(C) 3 (D) 3n – 1

10. Two regular polygons are inscribed in the same circle. The first polygon has 1982 sides and second

has 2973 sides. If the polygons have common vertices, the numbers of such vertices is

(A) 1 (B) 990

(C) 991 (D) 992

Rough work

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-10

This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its

answer, out which ONE OR MORE is/are correct.

(A) maximum cos cos 1 (B) minimum cos 1

(C) maximum cos sin 1 (D) minimum cos cos 1

12. The number of isosceles triangle with integer sides if no side exceeds 2014 is

(A) (1007)2 if equal sides do not exceed 1007

2

(B) 2(1007) if equal sides exceed 1007

(C) 3(1007)2 if equal sides have any length 20014

2

(D) (2014) if equal sides have any length 2014

4 3 2

13. Let f(x) = x + Ax + Bx + Cx + D assume that the graph of y = f(x) is symmetric with respectively to

the y–axis, has a relative maximum at (0, 1) and has an absolute minimum at (k, –3), then

(A) the value of A and C = 0 (B) the value of D = 2

(C) the value of B = –4 (D) the value of k = 2

(A) |f(x)| is decreasing x R

(B) f(x) is not continuous if it is not always of same sign

(C) f(x) is odd function

(D) none of these

a2 b2 c 2

15. Let a, b, c be complex numbers such that |a| = |b| = |c| = 1 and 1 0 then

bc ac ab

|a + b + c| can be

(A) 1 (B) 2

(C) 3 (D) 4

Rough work

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-11

SECTION –C

This section contains 5 questions. The answer to each question is a single digit integer, ranging from 0 to 9

(both inclusive).

1. If (x2 – 5x + 4)(y2 + y + 1) < 2y for all real y then x belongs to the interval (2, b) then b can be _____

(x3 + 3x2 + 9x + 3). Then the value of (a + b + c) is equal to _____

3. If a , b , c and d are non–zero vectors such that no three of them are in the same plane and no two

b c a d c a b d

are orthogonal then the value of the scalar is _____

a b d c

5. Suppose that the function f(x) = ax2 + bx + c, where a, b, c are real constants, satisfy the condition

|f(x)| 1, |x| 1 than maximum value of |f(x)| is _____

Rough work

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-12

SECTION – A

Single Correct Choice Type

This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out

of which ONLY ONE is correct.

1. A body starting from rest slides down an inclined plane of inclination . The coefficient of friction down

the plane varies as = kx. Here k is a positive constant and x is the distance moved by the body

down the plane. Then kinetic energy (K.E.) versus distance (x) graph is

(A) K.E. (B) K.E.

x x

(C) K.E. (D) K.E.

x x

into the plane of the paper. A ring of radius and total

resistance R is fixed. Rod OA and OB are résistanceless and A B

rotating with constant angular velocity ‘’, in the same plane as

that ring, about hinge point ‘O’ and the separation between O

C

and C (centre of ring) is 2 as shown in the figure. Find the

current in the rod ‘OA’ when the both rod becomes tangent to

the ring.

‘B’

17B 2

(A) zero (B)

2R

2

27B 27B2

(C) (D)

4R 2R O

3. The radioactivity of a sample is A1 at a time T1 and A2 at time T2. If the half life of specimen is T, the

number of atoms that have disintegrated in the time interval (T2 T1) is proportional to

(A) (A1 A2)T (B) (A1 A2)T2

(A1 A 2 ) (A1 A 2 )

(C) (D)

T T2

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-13

magnetic field ‘B’ directed inward and is deflected a distance y0 y

after traveling a distance x 0 as shown in the figure. Then the

magnitude of linear momentum of the particle is y0

qBx 0 2

qB x0

(A) (B) x0 q x0 x

2 2 y0

qB 2 qB 2

(C) (x 0 y 20 ) (D) (x 0 y 02 )

2y 0 2y 0

perpendicular to the surface of ABC (part of disc). Find

the flux passing through the surface ABC. A B

q

(A) (B) 30 3 a

40 P

q q C

a

160

q

(C) (D)

320

q

480

6. Two charged particles 4q and q lies on x-axis as shown in the figure. Which of the following graphs

will show the variation of electric field on the x-axis (take the +ve x-axis towards right).

(A) E (B) E

4q q 4q q

(a, 0) O (a, 0) x (a, 0) O (a, 0) x

(C) E (D) E

4q q 4q q

(a, 0) O (a, 0) x (a, 0) O (a, 0) x

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-14

circumference is negligible as shown in figure.

Find the equivalent resistance across AB.

(A) 3R

(B) 3R/2

(C) 3R/4 B

(D) 3R/16

projected horizontally with initial velocity v. Find the minimum value of v

such that one of blocks, either A or B just loses contact with the ground.

(M 2m)g (M 2m)g

(A) (B)

2m 2m

(M m)g (M m)g

(C) (D) v

2m 2m A B m

M M

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-15

connected through string and lies inside the

cavity which is created in the wedge as shown 5kg 25 kg 10 kg

in the figure, mass of the wedge is 25 kg and

(1) (2)

there is no friction between wedge and ground.

Coefficient of friction between the block 5 kg

‘m’

and cavity (1) is 1/2 and between the block 10

kg and cavity (2) is 1/4. For what value of ‘m’

both block 5 kg and 10 kg is in rest w.r.t.

wedge. (g = 10 m/s2)

(A) 40 kg (B) 5 kg

(C) 10 kg (D) not possible

the centre C and both the shells are conducting. The

outer shell is thick and has charge ‘q’ and inner shell

is thin and is earthed, then the graph of potential 2a a

versus distance from centre (r) is C q

3a

(A) V (B) V

Kq Kq

5a 5a

a 2a 3a r a 2a 3a r

(C) V (D) V

Kq Kq

5a 5a

a 2a 3a r a 2a 3a r

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-16

This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out

of which ONE or MORE are correct.

option/options (resistance is nonzero).

(A) Reading of voltmeter V2 may be greater than source R XL XC

voltage V. V4

(B) Reading of voltmeter V4 may be equal to V1

(C) Reading of V4 may be equal to source voltage V. ~

(D) Reading of V1, V2 and V3 may be equal. V

12. The electron in a hydrogen atom makes a transition n1 n2 where n1 and n2 are principal quantum

numbers of two states. Assume the Bohr model to be valid. The time period of the electron in the

initial state is eight times that in the final state. Then the possible value of n1 and n2 is/are

(A) n1 = 2, n2 = 1 (B) n1 = 1, n2 = 2

(C) n1 = 4, n2 = 2 (D) n1 = 6, n2 = 3

13. Initially tube is in rest and a spherical ball floats inside the liquid and

just touches the upper surface of the tube and spherical ball is tied

with a string as shown in the figure. The tube starts rotating with a

constant angular velocity ‘’. Then closed

(A) ball moves away from axis of rotation.

(B) string becomes loose.

(C) the tension in the string increases.

(D) if string is cut ball moves towards axis of rotation.

14. Two plane mirrors AM1 and BM2 lying along x and y-axis, as shown in

M2

the figure. Three point object P1, P2 and P3 lies as shown in the figure.

P2

Then

(A) Number of images of point object P1 formed by two plane mirror is B D

two. P1

(B) Number of images of point object P1 formed by two plane mirror is P3 C

A M1

three.

(C) Number of images of point object P2 formed by two plane mirror is three.

(D) Number of images formed of point object P3 by two plane mirror is one.

is released. Then

(A) Acceleration of 40/3 kg block is zero S1

(B) Acceleration of 10 kg block is 10/3 m/s2

(C) Tension in string S1 is (400/3)N 40/3 kg

S3 S2

(D) Tension in string S2 is (200/3)N

10 kg 5 kg

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Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-17

SECTION –C

Integer Answer Type

This section contains 5 questions. The answer to each question is a single digit integer, ranging from 0 to 9

(both inclusive).

1. A closed vessel has 6 gm of hydrogen at pressure P and temperature 500 K. A small hole is made in

it so that hydrogen leaks out. How much hydrogen (in gm) leaks out if the final pressure is P/2 and

temperature falls to 300 K.

2. Imagine a light planet revolving around a very massive star in a circular orbit of radius R with a period

of revolution T. If the gravitational force of attraction between the planet and the star is inversely

proportional to R5/2, then the time period of revolution is proportional to Rk/4. Find the value of k.

3. Two particle having position vectors r1 3iˆ 5ˆj meters and r2 (5iˆ 3ˆj) meters are moving with

velocities v1 (4iˆ 3ˆj) m/s and v 2 (a ˆi 7ˆj) m/sec. If they collide after 2 sec, find the value of a.

indices and /2. Two points P1 and P2 lying along the path of this

x0 2x0

light as shown in the figure. The phase difference between these

( x 0 ) P1 P2

two point is k . Then find the value of k.

40 20

resistance is k ampere. Find the value of k.

60V 10 V

40 10

80V 40V

5

20V

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

Mock Test-6–Paper-1 (100394.2)-CMP-IITJEE-18

IIT – JEE, 2019

Paper Code

PAPER-I 100394.2

ANSWERS

Chemistry [PART-I]

1. B 2. B 3. A 4. C

5. B 6. A 7. D 8. C

9. C 10. D 11. A, B, D 12. A, B, C

13. A, B, C 14. A, B, D 15. A, B, C

1. 6 2. 4 3. 2 4. 9

5. 6

Mathematics [PART-II]

1. D 2. A 3. B 4. B

5. A 6. A 7. C 8. D

9. A 10. C 11. A, B 12. A, B, C

13. A, C, D 14. A, B 15. A, B

1. 3 2. 2 3. 7 4. 1

5. 4

Physics [PART-III]

1. A 2. D 3. A 4. C

5. D 6. A 7. D 8. B

9. D 10. A 11. A, B, D 12. A, C, D

13. C, D 14. A, C, D 15. A, B, C, D

1. 1 2. 7 3. 8 4. 4

5. 3

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

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