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1)-CMP-IITJEE-20
SECTION – A
1. D
H
H
Et Et
H
Et Et
2. B
Cu2 2e Cu;
8.04 60 2.0
m. moles of e- passed = 10.0
96.5
m.moles of Cu2+ reduced = 5.0
5 10 3 63.55
%Cu 100 14.9
2.132
3. B
HO OH
O
H
O CO2 CH CHO
COOH tautomerism
C
O H
4. D
5. D
6. B
7. A
Initial moles of H2O2 = 2 × 2 = 4
1
Moles of H2O2 left after 20 min (2 × t1/2) = 4
1
22
Moles of H2O2 decomposed in 20 min = 4 – 1 = 3
1
H2 O2
H2 O O 2 g
2
Thus 3 mole H2O2 will produce 3/2 mole O2 in 20 min.
3
R T
nRT 2
Volume change
P P
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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-21
8. B
9. C
KP depends only on temperature.
10. D
NH3 NH3
NH4 NH2
NH4 NH2
K ionization
2
2
Ionic product = K ionization NH3 M2
NH3
= 10-30 × (50)2 M2
850
Because NH3 50 M
17
11. A, C
(A) Due to absence of empty orbitals, less nucleophilicity of H2O and steric reasons; CCl4 do not
hydrolysed.
(B) NCl3 3H2 O NH3 3HOCl
OH
BiCl3 2H2 O Bi
OH
(C) Cl
H2 O
BiOCl
H
H
O
(D) OH OH
; One P acts as electrophile other as base Nu :
O P P O
OH
OH
12. A, B, C
When equal amounts of two enantiomers are mixed, racemic mixture is resulted.
13. C, D
OH
HIO 4 O
OH
O
cold dil.KMnO 4
OH
O
14. A, B, C, D
15. B, C
SECTION – C
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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-22
1. 4
Stereoisomers = 8
4 optically active and 4 optically inactive.
2. 2
Wt. of NH3 in the solution = (0.98 V – 500) gm
Where V is the vol. of resulted solution in ml.
0.98V 500
%NH3 = 74.5 100
0.98 V
V = 2000 ml = 2 L
3. 7
Except N3 , CO2 and COS all are non-linear.
4. 4
Cl Cl
Cl
, and their enantiomers
Cl
5. 6
n2 = 4; no of different lines =
n2 1 n2 6
2
Mathematics
SECTION – A
2. Re–arranging
2 2 2
2a 2 2 3b 3 3 4c 4 4 0
a = 3; b = 4; c = 5
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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-23
1 1
3. Let I f f
2 3
/4
1 1
I
0
log e 1 tan t loge 1 tan t dt
2 3
/4
3 2 tan t
I
0
log e dt
2 3 tan t
/4
I log
0
e 3 3 tan t
4 2 tan t
dt
/4
9
2I log
0
e dt
8
5
f 2 2 x
k 1
1
5
1 1 xk 3
3
k 1
3 xk
3
xk
5
= 35 x k 1/ 3
k 1
= 3 5
x1x 2 x3 .....xn 1/ 3 = 35
n n
7. 2 3 2 3 2m , m I
+
lim sin 2 3
n
n
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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-24
= lim sin 2m 2 3
n
n
n
= lim sin 2 3
n
n
= lim sin = 0
n 2 3 n
8. First select any one object and place it anywhere on the circumference of the circle. Now, rest of the
1
(n – 1) objects have 2 choices each, thus the probability that they are on a semi–circle is n 1 .
2
Since, the first object can be selected in n C1 = n–ways, therefore the required probability
n
= n 1
2
dt 2 x 2
Put t = x – cot–1 x =
dx 1 x 2
tan3 t
I sec 4 tdt 1 t t sec tdt
2 2
= tan t
3
c
tan3 x cot 1 x
I tan x cot 1 x c
3
ALITER
Put x = tan t dx = sec2 t dt
x cos x + sin x = sec sin (x + )
1 x 2 2 x2 sec 2 t 1 sec 2 t
x cos x sin x dx = sec 4
sec 2 tdt
4
t sin4 x t
1 sec 2 t 2
= sec 4 tan t t
dt = cosec u du u tan t t
cot u 3 3
1 1 x tan x 1 x tan x
= cot u c = c
3 3 x tan x x tan x
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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-25
ab
12. Let k =
2
By LMVT for x [a, k]
f k f a 2 f k a
f ' c1
ka ba
Also by LMVT for x [k, b]
f b f k 2 b f(k)
f ' c2
bk ba
f(c1) + f(c2) = 2
Hence (A)
ab
Now, by intermediate value theorem there must exist at least one k for which f k
2
By LMVT on [a, k]
f k f a ba
f ' c1
ka 2 k a
Similarly, by LMVT on [k, b]
f b f k ba
f ' c2
bk 2 b k
1 1
2
f ' c1 f ' c 2
Hence (B)
Let g(x) = (a – x)(b – x) ef(x)
g(c) = 0 for some c (a, b)
1 1
f ' c
ac bc
13. AB = BA = 0
An = 3n – 1 A; Bn = 3n – 1 B
14. u = 0, v = x
f(x) + f(–x) = 2f(0) cos x
u
2
v x
2
2f sin x f x f x
2
v
2
u x
2
f(–x) + f( – x) = 0
f(x) = f(x + 2)
AB AC
15. AF ˆi ˆj kˆ
2
ˆi ˆj kˆ
FE : AE = : 1; AE
1
AC AB 2 j k
ˆ ˆ
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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-26
ˆ ˆ
ED j k
2
AD AE ED
AD 4
3
16 2
2
1
1
volume = base area altitude
3
2 3 1 1 ˆ ˆ ˆ ˆ
2 j k jk
3 3 2 2
1
|| = 2 + 1 =
2
SECTION –C
1. f(x) = (x – 2)(x – 3)2(x – 4)3 ….. (x – 100)99 {5050(x – c1)(x – c2) ….. (x – c99)}
where 1 < c1 < 2; 2 < c2 < 3; ….. ; 99 < c99 < 100
Now, the critical points of f(x) are c1, 2, c2, 3, c3, 4, c4, 5, ….., c99, 100
But points such as x = 3, 5, 7, ….. , 99 are neither points of local maxima or minima.
Thus total number of points of local maxima/minima
= 99 + 50 = 149
=
6
2
x 2x
3. Let f(x) = sin cos 2
4 4
x 1 2x 1
f ' x cos sin 1
4 4 2 x 4 4 2 2x
Thus f(x) > 0
2
f 0 cos 2 0
4
2
f 2 sin 1 2 sin 1 2
4 2 2
3
( 2 2 3 sin 2 )
2 2 3 2 2
Hence f(2) > 0
Thus exactly one solution.
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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-27
4. Case 1: If x < 2
x 2
f x x t dt x t dt
0 x
x 2
2
=
x t dt t x dt = x
0 x
– 2x + 2 O 1
Case 2: If x > 2
2 2
f x x t dt x t dt 2x 2
0 0
SECTION – A
1. Pressure in the air inside the column of mercury is equal to the weight of mercury over the air divided
by the internal cross sectional area of the tube. When the temperature increases, the weight of the
upper part of the mercury column does not change. That is why the pressure in the air is also
constant. For the isobaric process, the change in volume is proportional to the change in temperature.
The same is true for the lengths of the air column.
l T lT
l = 0 = 11 cm.
l0 T0 T0
v w u
2. Frequency received by car B is f1 f
v w u
Now the car B will be treated as a source of frequency f1
wavelength of reflected sound received by the driver of car A is
'
v w u v w u v w u
f1 v w u f
330 5 25 330 5 25 31 m
330 5 25 300 36
Hence (B) is correct
dt I
2 5ml2
Bil dt 3
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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-28
5ml2
Bl2 dQ
3
2
5ml
Bl2 Q
3
3BQ
5m
Now using conservation of energy
1 2
I mgh
2
1 5 m2 2 4
(3m)g
2 3 3 3
6. The power developed by the man = power required in the reference frame of the man
= Force velocity = m(g + a).(h/t)
Hence, (A) is correct.
v
F0 Kx max
F
8. a e v dv 0 e Kx dx
m 0 m0
v max2 F F
0 K max 0
2 mK K
FR vB2 2
9. (m + CB22) a =
R
11. For a plane wave intensity (energy crossing per unit area per unit time) is constant at all point
For spherical wave
p 1
I= 2
2
4r r
0 q
12. (A) B
4a
0 q(v r )
(B and D) B
4 r 3
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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-29
13. N = 50 – 20 = 30 N N 20 N
Limiting friction force = µN = 12 N and applied force in horizontal
direction is less than the limiting friction force, therefore the
5N
block will not slide.
For equilibrium in horizontal direction, friction force must be
equal to 5 N.
mg = 50 N
From the top view, it is clear that = 37° i.e. 127° from the x-axis f
that is the direction of the friction force. It is opposite to the
applied force.
53
Contact force = N2 f 2 = 925 N
3iˆ 4 ˆj
1
14. T1 > T2 > T3 as 1 < 2 < 3 (Wien's law)
T
Now as the area under the curve E and gives the intensity; so
Ae3 T34 Ae2 T24 {Areas are same, given}
Now as T3 < T2 e3 > e2.
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Mock Test-5–Paper-1 (100392.1)-CMP-IITJEE-30
SECTION –C
1. The distance by which image appears to be raised is
1 1
d t1 1 t 2 1
1 2
t t 1 t 2
1 1
2 2 2 3
5
3
mg N T
2. a …(i) a
Mm
Taking torque about P, T a
h h Ma
P
Th Mg Ma …(ii)
4 2
mg T = ma …(iii) Mg mg
from (i), (ii) and (iii)
m/M = 1
u2
4. R max
g
u4
So, maximum area covered = R 2max . 4m2
g2
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