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Problem Statement:
SOLUTION:
u2 - u1 = q12,in - w12,out
= h2 - h1 = hfg
Problem Statement:
SOLUTION:
a) Checking Table 11s, we find that the initial state is in the superheat region.
Increasing the volume will move the state further into the superheat region. The P-v
diagram thus appears as below. From Table 12s, v1 = 0.1254 m3/kg, and h1 = 3022.7
kJ/kg. Also, since the mass in the system is constant,
At state 2, we know P = 2000 kPa and v2 = 0.2508 m3/kg. By interpolation from the
Superheat Table 12s, h2 = 4192.6 kJ/kg, so
Example 4-3
Problem Statement:
A cylinder-piston system contains 2 kg of H2O at 150 kPa and has a volume of 0.35
m3. The piston is moved so that the final volume of the inside the cylinder is 2.319 m3.
During the piston motion from the initial to the final state, there is heat transfer to the
cylinder in such a way as to hold the temperature constant.
(a) What is the final pressure in the cylinder?
(b) How much work was done by the steam?
(c) Evaluate the heat transfer during the process.
(d) Sketch the process on P-v and P-h diagrams, labeling the initial state as 1 and the
final state as 2.
SOLUTION:
a)
b)
c)
d)
Example 4-4
Problem Statement:
Develop an equation for the heat transfer to an ideal gas during a constant-pressure
expansion in terms of the initial pressure P1, the initial and final volumes V1 and V2,
and cp (assumed temperature independent) and R for the gas.
SOLUTION:
Example 4-9
Problem Statement:
SOLUTION:
The air and nitrogen are in thermal equilibrium, so throughout the process, T air = TN2.
Example 4-21
Problem Statement:
SOLUTION
Example 5-1
Problem Statement:
Indicate whether the process for the control mass is reversible or not when the
following processes are complete. Explain your answer.
SOLUTION:
a) Only work is done on the gas (no heat transfer), and if the work is done slowly and
without friction (no dissipation), then the process is reversible.
c) This is similar to case (b) except that the piston/cylinder friction produces energy
dissipation, so this process is irreversible.
d) Heat transfer must occur from the control mass to the surroundings according to the
First Law, and this is very nearly a reversible (non-dissipative) process.
e) This is a highly dissipative process, in which directed energy (KE of the putty at the
time of impact) is converted into internal energy of the putty, increasing the putty
temperature and increasing the putty entropy. If we then wait, the putty will transfer
heat to the tile floor. This process is irreversible.
f) In this process, bead internal energy is gained by the bead-wire frictional work
being partially converted into bead internal energy during the sliding process, and
bead internal energy is decreased as the frictionally heated bead undergoes heat
transfer with the surroundings. The final result will be the same as for part (e), so this
process is irreversible.
In all of these processes, we considered only the dissipative losses of the control mass,
and not the effect on the surroundings.
Example 7-1
Problem Statement:
SOLUTION:
Treating the two containers as the system, the diagram is shown above. Then the laws
can be written as:
T1A(K) sgen(kJ/kg·K)
100 0.989
200 0.517
400 0.174
600 0.055
800 0.010
1000 0
COMMENTS: As T1,A approaches T1,N, the value of Sgen approaches zero. Obviously,
if the two containers are at the same temperature when they are brought together, they
will transfer no heat between themselves, and no entropy will be generated.
Example 7-2
Problem Statement:
(a) Derive an expression for the ratio of the work done if the process is isentropic, w s,
to the work done if the process is isobaric (constant pressure), wP, in terms of k only.
(b) Sketch the two processes on P-v and T-s diagrams. Label all states.
SOLUTION:
a)
b)
COMMENT: Note that the final state and the path differ for the isobaric and
isentropic processes. Only the final temperature is prescribed as the same for both.
Example 7-3
Problem Statement:
A closed copper vessel has a volume of 2 m3. In the vessel is 4 kg of water (liquid
plus vapor) at a pressure of 200 kPa. The surroundings are at a temperature of 160°C.
There is a heat transfer to the vessel until the water is all just evaporated.
(b) What is the entropy change of the water in the vessel during the heat transfer
process?
(c) What is the entropy change of the surroundings due to the heat transfer process?
(d) What is the entropy generation for the water due to the heat transfer process?
SOLUTION:
a) At state 2, v2 = v1 = 0.5 m3/kg and the water is in the form of saturated vapor. From
Table 10s,
and
c)
d)
Example 7-4
Problem Statement:
SOLUTION:
Example 7-5
Problem Statement:
SOLUTION:
1st Law:
2nd Law
Example 7-7
Problem Statement:
A reversible process for a piston-cylinder control mass is shown on the P-v and T-s
diagrams. Evaluate the change in internal energy per unit mass for the process.
SOLUTION:
1st Law
Thus
Example 7-9
Problem Statement:
SOLUTION:
Two carnot engines work in series b/w source & sink
temp. 550K & 350K.If both engines develop equal
power.....?
Two carnot engines work in series b/w source & sink temp. 550K & 350K.If both engines
develop equal power , determine the intermediate temp.
η = 1 - Tc/T'
Since, the heat rejected from the 1st engine is the heat input to the other engine:
(1)
Coming back to your problem, the two reversible engines have equal efficiencies, so
and hence
, but and so
, or and so
(2)
Equation 2, which only applies when the thermal efficiencies of the two heat engines are equal,
can be used to find the temperature of the common, intermediate, thermal reservoir.
Applying equation 1 to engine 1
(3)
Equation 3 can be used to find the heat input when the heat rejection and the temperatures of
the thermal reservoirs are known.
There are various ways in which you could go about calculating the net work
outputs and using the expressions already mentioned above. Once you have found the
temperature of the intermediate thermal reservoir, and as the temperatures of the other two
reservoirs are given, you can calculate ther thermal efficiency, which is the same for both heat
engines. Once you have found the heat transfer to the first heat engine and as the heat transfer
to the second heat engine is given, you can multiply each heat input amount by the thermal
efficiency to find the work output of the engine.
Alternatively you could find the work quantities as the difference between the heat input and
the heat rejection of each engine. For the second engine the heat rejection could be calculated
from the heat input using equation 1, applied to that heat engine.
The temperatures in the expressions are all absolute temperatures, so don't forget to convert the
Celsius values to Kelvin (0°C corresponds to 273.15 K).
From equation 2
From equation 3
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