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The effect of different reinforcements

on the fracture toughness of materials


for interim restorations
Greta A.V.M. Geerts, BChD, PDD, MChD,a Jan-Hendrik
Overturf, BChD, MChD,b and Theuns G. Oberholzer, BChD,
MSc, PhDc
Faculty of Dentistry, University of the Western Cape, Tygerberg,
Republic of South Africa; University of Limpopo, Limpopo
Province, Republic of South Africa

Statement of problem. Fracture of an interim fixed partial denture (FPD) may jeopardize the success of the interim
prosthodontic treatment phase and cause patient discomfort.

Purpose. The purpose of this study was to compare the fracture toughness of a polymethyl methacrylate (PMMA)
resin and a bis-acryl composite (BAC) resin reinforced with stainless steel wire, glass fiber, and polyethylene fiber.

Material and methods. Four groups (n=13) of each of the 2 materials were prepared for the single-edge notch 3-
point-bending test. Three groups had the different reinforcements, and the group without reinforcement served as the
control. Using a universal testing machine, peak load to fracture was recorded and fracture toughness (KIC) was calcu-
lated in MNm-1.5. Median KIC values were compared by means of nonparametric ANOVA (Kruskal-Wallis test, α=.05).

Results. For the controls, the fracture toughness for PMMA resin (KIC=27.9) was significantly lower (P<.01) than for
BAC resin (KIC=31.2). Glass fibers and stainless steel wire reinforcements produced significantly higher fracture tough-
ness for both PMMA (KIC=34.4, P<.01, and KIC=39.0, P<.001, respectively) and BAC resin (KIC=42.3, P<.001, and
KIC=44.0, P<.001, respectively), but the polyethylene fibers did not (KIC=25.8, P>.10, for PMMA resin and KIC=33.1,
P>.10, for BAC resin). There was no significant difference between the fracture toughness of the wire and glass fiber
reinforcements for both interim materials (P>.10 in both instances).

Conclusions. Of the 3 reinforcement methods evaluated, wire and glass fiber reinforced the PMMA and BAC resin
materials best. (J Prosthet Dent 2008;99:461-467)

Clinical Implications
When esthetics and space are of concern, glass fiber seems to be the most
appropriate method for reinforcing interim FPDs made from PMMA and
BAC resins. Wire provides the clinician with a less expensive option in areas
of the mouth where esthetics are not crucial and adequate space is avail-
able. All 3 reinforcements evaluated prevent catastrophic failure.

Presented at the South African Division of the International Association for Dental Research, Pretoria, South Africa, September
2006.

The following manufacturers and suppliers provided the products used in this study: Stick Tech, 3M ESPE, Istrodent, and Millners
Dental Suppliers.

a
Principal Specialist and Associate Professor, Department of Restorative Dentistry, University of the Western Cape.
b
Former Resident, Department of Restorative Dentistry, University of the Western Cape.
c
Stomatologist and Professor, Operative Dentistry, Faculty of Dentistry, University of Limpopo.
Geerts et al
462 Volume 99 Issue 6
Polymethyl methacrylate (PMMA), ing test. This test determines critical the specimens. Three of the 4 groups
polyethyl methacrylate, bis-acryl values of stress intensity (KIC) when were reinforced; 1 group without re-
composite (BAC), and epimine resin standardized precracked specimens inforcement served as the control.
are materials commonly used to fab- are loaded until fracture. These loads The reinforcements used were: (1) 1-
ricate interim fixed partial dentures are used to calculate toughness.25 Nu- mm-diameter smooth stainless steel
(FPDs).1 These materials must be merous fracture resistance tests have wire (KC Smith & Co, Monmouth,
strong enough to withstand mastica- been performed for resins reinforced UK), (2) glass fiber (everStick C&B
tory forces, particularly for long-span with steel wire, polyethylene, or glass fiber; Stick Tech Ltd, Turku, Finland),
FPDs, for long-term use, or for pa- fiber.5,8-15,17-21 However, none have and (3) polyethylene fiber (Construct
tients with parafunctional habits.2,3 compared the reinforcement effect braided polyethylene fiber; Kerr Corp,
Different methods of enhancing the of steel wire, polyethylene, and glass Orange, Calif ).
physical properties of interim FPDs fiber on PMMA and BAC resins in a A custom-made stainless steel
have been developed.4 Positive re- single study. mold was used to produce standard-
sults have been achieved with the use The purpose of this study was to ized specimens (Fig. 1). The precrack,
of metal and fiber reinforcements.5-12 compare the fracture toughness of 2 perpendicular to the specimen length,
These studies demonstrate that metal types of materials frequently used for was created by inserting a straight-
wires incorporated into polymers pro- interim FPDs, with and without rein- edged surgical blade (No. 11; Swann-
duce higher transverse strength, but forcement. Stainless steel wire, poly- Morton Ltd, Sheffield, UK), with a
fibers have been demonstrated to be ethylene fiber, and glass fiber were blade edge radius of less than 0.3 μm,
more effective in improving strength.12 used as the 3 materials for reinforce- half the length of the mold; the slot
Various types of fibers have been in- ment. The null hypothesis was that (A=3 mm) extended up half the height
vestigated, including glass, carbon, the 3 reinforcement materials would of the specimen (W=6 mm) to give A/
aramid, and polyethylene fibers. The not significantly alter the fracture W= 0.5 (Fig. 2). The mold used in this
eventual strength of the reinforced toughness of the 2 resins. study could be disassembled com-
resin is influenced by the quantity and pletely so that no force was required
orientation of the fibers, position, fi- MATERIAL AND METHODS to remove the polymerized specimens
ber impregnation, and adhesion of from the mold.
the fibers to the polymer matrix.13-17 Four groups (n=13) of specimens The control groups were fabri-
The degree of adhesion between fi- were prepared from a BAC resin (Pro- cated as follows: the BAC resin was
ber and polymer affects the degree of temp 3 Garant; 3M ESPE, Seefeld, mixed using the automix gun system
reinforcement. The better the bond, Germany) and a PMMA resin (Cold- provided by the manufacturer. For
the better the transfer of stress from pac; The Motloid Co, Chicago, Ill) for the PMMA resin, 0.58 g of powder
the weak polymer matrix to the fibers a single-edge notch 3-point bending was weighed using a precision stan-
with a higher tensile strength.18,19 Uni- test conforming to the British Stan- dard scale (Model TS400 D; Ohaus
directional fibers enhance strength dard 5477 (1977).26 The dimensions Corp, Pine Brook, NJ) and 0.25 ml
and stiffness in 1 direction, while of the specimens were 3 mm x 6 mm x of liquid was measured using a pi-
randomly oriented fibers enhance 26 mm. The depth of the precrack was pette (Pipetman, L 116956; Gilson,
mechanical properties in all direc- 3 mm, which was half the height of Inc, Paris, France) and mixed. This
tions.15 Interim FPDs reinforced with
impregnated fibers demonstrate high-
er fracture resistance than those rein-
forced with nonimpregnated fibers.20
Silanized glass fibers bond readily to
polymers.21 Compared to other types
of fibers, adhesion of polyethylene fi-
bers to polymers is less effective.22
The fracture mechanism approach
is considered a reliable indicator of
the performance of brittle materials.23
A fracture toughness test measures
the resistance of a material to crack
extension.24 Different tests have been
used to quantify the fracture tough- 1 Custom-made stainless steel mold, demonstrating
ness of dental materials. One such test stops (a) with depth of 1.5 mm for positioning of rein-
is the single-edge notch 3-point bend- forcement and position of scalpel (b) to create precrack.

The Journal of Prosthetic Dentistry Geerts et al


June 2008 463
the glass fibers. The smooth 1-mm-
diameter stainless steel wire was also
cut to a length of 27 mm and was em-
bedded into the resin before the mold
was filled.
The specimens were stored in dis-
tilled water at 37°C in an oven for
24 hours before testing. The speci-
mens were placed on the supports of
the 3-point bending apparatus. The
span width of the supports was 20
mm. Mechanical loading was applied
to the center of each specimen at 90
degrees to the specimen axis using a
2 Specimen demonstrating dimensions. Width (B = 3 mm), height (W = 6 stainless steel rod attached to a uni-
mm), precrack (A = 3 mm), span between supports (L = 20 mm). Position of versal testing machine (Model 1446;
reinforcement is indicated by dotted line at distance of 1.5 mm from upper Zwick, Ulm, Germany) and 0.5-kg
surface of specimen, as determined by stops in template. load cell. With a crosshead speed of
1 mm/s, the load was increased un-
powder-liquid ratio is lower than gashi-Hiroshima, Japan) accurate to til the specimen fractured. Peak load
the recommended ratio and resulted 0.001 mm.9 to fracture, and specimen deflection
in a softer consistency for easy flow For the reinforced test groups, all (recorded as load/deflection curves)
into the mold, minimizing voids. The procedures were the same as for the were recorded, and fracture tough-
mold was slightly overfilled and the 2 unreinforced groups, except for the ness (KIC), measured in MNm-1.5, was
surface covered with a plastic matrix insertion of the reinforcement ma- calculated using the following equa-
strip (Odus Universal Strip; Produits terial parallel to the long axis of the tion9:
Dentaire SA, Vevey, Switzerland) and specimens. The mold was filled to the KIC = 3(PL/BW3/2)Y
a thick glass plate. Hand pressure was level of the stops with 1 of the res- where P is peak load at fracture, L is
applied for 30 seconds until contact ins. The reinforcement material was distance between the supports, B is
was established with the top surface placed into the unpolymerized resin specimen width, W is specimen height,
of the template, as visualized through and more resin was added to fill the and Y = 1.93(A/W)1/2 - 3.07(A/W)3/2
the glass plate. The PMMA resin spec- mold, as previously described. Two + 14.53(A/W)5/2 - 25.11(A/W)7/2 +
imens were left to polymerize for 20 lateral stops in the mold ensured that 25.80(A/W)9/2 = 1.77.
minutes (double the manufacturer’s all reinforcements were inserted in the For comparative purposes, the
recommended time) in the mold, same position for all specimens. The mean and standard deviations for
and an additional 10 minutes on the glass fiber bundles, with a 1.5-mm each test group were calculated. The
bench. BAC resin specimens were left diameter, were cut into 27-mm-long medians of the values were compared
to polymerize for 10 minutes (double pieces. The fibers were light polym- (pairwise and otherwise) by means
the manufacturer’s recommended erized by irradiating 3 different ar- of nonparametric analysis of vari-
time) in the mold, with an additional eas of the upper surface (center, left, ance (ANOVA) (Kruskal-Wallis test)
5 minutes for bench polymerization. and right) with a halogen light unit and summarized considering the
After polymerization, the blade was (Megalux CS; Megadenta, Radeberg, Bonferroni adjustment for multiple
carefully removed and the specimens Germany) for 40 seconds each. The comparisons (α=.05). The variability
were examined with a stereomicro- tip of the light unit was held within of the fracture toughness among the
scope (Zeiss, Oberkochen, Germany) 2 mm of the surface of the fiber. The different reinforcements within the 2
(x10 magnification) for the inclusion unit had the following specifications: groups was tested to see whether the
of voids or air bubbles. Specimens power, 82 W; tension, 220/110 VAC; assumptions of the Kruskal-Wallis
containing flaws were discarded and halogen lamp, 75 W; spectrum, 400 test were violated.
replaced. The edges of the specimens nm-500 nm. The polyethylene fiber
were finished with 1000-grit carbide braids, with a width of 3 mm, were RESULTS
paper (3M ESPE, St. Paul, Minn). cut into strips of 27 mm and impreg-
Specimen dimensions (width, height, nated with resin (according to the The descriptive statistics for the
and length) were measured 3 times manufacturer’s instructions). These fracture toughness values for the 8
using a bench digital micrometer fibers were polymerized and placed groups are summarized in Table I. All
(Model IDC-112; Mitutoyo Co, Hi- in the mold exactly as described for of the means were higher than the
Geerts et al
464 Volume 99 Issue 6
medians, indicating that there was fracture toughness of the glass fiber cantly higher fracture toughness than
positive skew. However, this skew was group displayed the largest standard the polyethylene group (P<.001). Al-
small and did not warrant data trans- deviation and interquartile range. The though the polyethylene fiber group
formation. Reasons for using non- differences among the standard de- demonstrated a lower fracture tough-
parametric ANOVA were the small viations of the 4 PMMA groups were ness compared to the control group,
specimen groups and the presence of not significant. The wire group exhib- this difference was not significant.
3 outlier values. Although the mean ited the highest median and the poly- For the BAC material, the fracture
was higher than the median for all ethylene fiber group the lowest. This toughness of the polyethylene fiber
groups, the difference was small, ex- difference was significant (P<.001). displayed the largest standard devia-
cept for the glass fiber reinforcement Compared to the control, the wire tion of all 4 groups. The differences
of PMMA. This was due to 1 high out- group had significantly higher fracture among the standard deviations of the
lier value. The side-by-side box plot toughness (P<.001), as did the glass 4 groups were not significant. The
for PMMA demonstrates this (Fig. 3). fiber (P<.01). The difference between control group displayed the smallest
Figure 4 presents the side-by-side box glass fiber and wire reinforcement was standard deviation and interquar-
plot for the 4 BAC groups. not significant (P>.10). Both the glass tile range. The wire group exhibited
For the PMMA resin material, the fiber and the wire group had signifi- the highest median, and the glass fi-

Table I. Descriptive statistics for fracture toughness (KIC in MNm-1.5) for 8 groups (n=13)
PMMA Resin BAC Resin

Control Wire PE Glass Control Wire PE Glass

Minimum 25.89 32.47 24.59 33.27 30.86 40.93 22.60 40.43

Median 27.89 39.00 25.82 34.44 31.17 44.02 33.10 42.31

Mean 29.07 42.74 29.79 40.01 35.32 45.97 35.77 46.75

SD 2.63 5.02 3.87 8.85 2.38 3.21 4.46 3.88

IQR 5.25 5.85 2.75 5.94 1.91 3.74 3.56 3.31

Maximum 33.79 50.79 38.22 62.76 40.72 53.11 41.41 52.41

PMMA = polymethyl methacrylate resin, BAC = bis-acryl composite resin, IQR = interquartile range,
wire = stainless steel wire, PE = polyethylene fiber, glass = glass fiber

55.00
60

46.25
50

37.50
40

28.75
30

20.00
20 BAC Glass PE Wire
PMMA Glass PE Wire

3 Side-by-side box plot of fracture toughness (KIC in 4 Side-by-side box plot of fracture toughness (KIC in
MNm-1.5) for 4 PMMA groups. Dots represent outliers. MNm-1.5) for 4 BAC groups. Dot represents 1 outlier. BAC
PMMA = polymethyl methacrylate resin, glass = glass = bis-acryl composite resin, glass = glass fiber, PE = poly-
fiber, PE = polyethylene fiber, wire = stainless steel wire. ethylene fiber, wire = stainless steel wire.

The Journal of Prosthetic Dentistry Geerts et al


June 2008 465
ber group demonstrated the highest PMMA resin reinforced with polyeth- er standard deviations for the bisac-
mean. Compared to the control, the ylene fiber resulted in the lowest me- rylate cartridge products compared
wire group had a significantly higher dian fracture toughness (25.82) and is to hand-mixed PMMA resin prod-
fracture toughness (P<.001), as did even weaker than the control PMMA ucts. The present study confirms that
the glass fiber (P<.001). The fracture resin (27.89; the second smallest). All the standard deviations between the
toughness of the wire group was sig- reinforced groups demonstrated sig- BAC and the PMMA resin do not dif-
nificantly higher than the fracture nificantly higher fracture toughness fer significantly. After filling the mold,
toughness of the polyethylene fiber for BAC resin than for PMMA resin hand pressure was applied for 30 sec-
group (P<.001), but not significant- (glass fiber, P<.005; polyethylene fi- onds until contact was established
ly higher than that of the glass fiber ber, P<.005; wire, P<.005). between the glass plate and the top
group. The fracture toughness of the surface of the mold. The pressure was
glass fiber group was significantly DISCUSSION not standardized and this is a study
higher than that of the polyethylene limitation.
fiber (P<.005). Polyethylene fibers did The null hypothesis was that the 3 In contrast with the PMMA, BAC
provide reinforcement, but the frac- reinforcements would not significant- resins are capable of cross-linking
ture toughness of the polyethylene-re- ly alter the fracture toughness of the 2 with other monomer chains, result-
inforced BAC material was not signifi- resins. The data support rejection of ing in higher strength and toughness.3
cantly higher than the unreinforced the hypothesis for the glass fiber and The present study confirms the higher
control BAC material (P>.10). the stainless steel wire, but not for the fracture toughness of the control BAC
Comparing the BAC and PMMA polyethylene fiber. resin over the control PMMA resin.
materials, the fracture toughness me- No interim material meets the However, it has been found that flex-
dian for the control BAC resin was ideal requirements for each situation. ural strength among different brands
higher than for the control PMMA res- Strength is only 1 factor to consider of the BAC resins varies greatly, with
in, and this was confirmed by a Krus- when selecting a material for interim some brands having even lower values
kal-Wallis test (P<.01). The 2 standard FPDs. Other important factors in- than the simpler and less expensive
deviations were approximately equal, clude ease of use, esthetics, marginal PMMA resin products.3,6 Significant
but the interquartile range of the BAC adaptation, shrinkage, biocompatibil- differences in strength were also re-
resin (1.91) was smaller than that of ity, and cost.6 A strong material may ported among different brands of
the PMMA resin (5.25). For the wire- lack other required characteristics, PMMA resin materials used for inter-
reinforced groups, the standard de- such as good color stability or ease of im FPDs.4 Therefore, comparisons of
viation of the PMMA resin group was manipulation. A single anterior tooth studies using different brands should
somewhat larger than the standard restoration will have different require- be made with caution.
deviation of the BAC resin group, but ments than a posterior long-span in- In the present study, the pow-
the difference was not significant. terim FPD. The clinician must choose der-liquid ratio of the PMMA resin
For the polyethylene reinforcement, the material and reinforcement meth- was changed for ease of manipula-
the fracture toughness median of the od appropriate for each application. tion. This might have influenced the
PMMA group was significantly lower In vitro static load tests differ from strength of the material. In practice,
than the median of the BAC resin the dynamic intraoral conditions. Cy- clinicians do not always adhere to
group (P<.001). For the glass fiber re- clic loading can be incorporated in manufacturers’ recommendations
inforcement, the standard deviation the testing method to simulate the and change powder-liquid ratios to
and interquartile range of the PMMA clinical environment. Microcracks modify handling properties of materi-
group was larger than that of the BAC and defects that grow inherently dur- als. The influence of the powder-liq-
resin group, but not significantly dif- ing thermal and mechanical processes uid ratio on the strength of fiber-re-
ferent. can significantly reduce strength mea- inforced polymers is a potential topic
BAC resin reinforced with wire ex- surements.27 No cyclic loading in a for future research.
hibited the highest median (44.02), moist environment was performed in PMMA resin, a brittle material,
BAC resin with glass fiber the second the present study, and this is a study has a higher compressive than ten-
highest (42.31), and PMMA resin with limitation. sile strength.5 Therefore, restorations
wire (39.00) the third highest. The BAC resins are supplied in a car- fracture on the tension side away
same 3 material combinations make tridge delivery system, presumably from the occlusal load. When the ten-
up the 3 highest means, namely BAC providing a more consistent mix than sile strength of the polymer is lower
resin with glass fiber (46.75; high- can be achieved by hand mixing the than the tensile strength of the fiber,
est), BAC resin reinforced with wire PMMA monomer and polymer. How- the specimen will gain strength when
(45.97; second highest), and PMMA ever, this could not be substantiated the fiber is placed in the area of higher
resin with wire (42.74; third highest). by Haselton et al,2 who found no low- tension, away from the load. This was
Geerts et al
466 Volume 99 Issue 6
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Noteworthy Abstracts of the Current Literature


Accuracy of impressions and casts using different implant impression techniques in a
multi-implant system with an internal hex connection

Wenz HJ, Reuter HU, Hertrampf K.


Int J Oral Maxillofac Implants 2008;23:39-47.

Purpose. The aim of this study was to investigate the deviations of the implant positions of both impressions and
casts using different impression materials and techniques. Furthermore, the existence of a correlation between the
deviations of the impression and those of the cast was investigated.

Materials and Methods. A reference model was fabricated with 5 Frialit-2 implants parallel to each other. In a stan-
dardized experimental setting, 5 stone casts were produced with 5 different techniques using polyether (A) or polyvi-
nyl siloxane (B through E). In 3 groups, a direct technique was used with a medium-viscosity material or a putty-tray
material in combination with a light-viscosity syringe material (A to C). In 2 groups, an indirect technique (either
1-step [group D] or 2-step [group E]) was used with a putty-tray material in combination with a light-viscosity syringe
material. The center-to-center distances were measured for impressions and casts in the horizontal plane using a com-
puter-aided microscope, and the relative and absolute deviations compared to the reference model were calculated.
Analysis of variance followed by the post-hoc Scheffe test (parametric data) or the Kruskal-Wallis test followed by
pair-wise Mann-Whitney tests (nonparametric data) were used for statistical analyses. Deviations of impressions were
compared with their respective casts using paired t tests and the Pearson correlation coefficient.

Results. No significant differences for the relative deviations were found for impressions (–5 to –8 µm) or casts (+7 to
+16 µm). Group E produced significantly higher absolute deviations for impressions (38 µm) and casts (39 µm) com-
pared to the other groups (11 to 18 µm and 17 to 23 µm, respectively). A significant correlation between deviation of
the impression and its respective cast was found for every group (r = 0.40 to 0.80) except group D.

Conclusion. The distortions in the horizontal plane of the casts obtained from the impression techniques of groups
A to D would probably not affect the clinical fit of implant-retained superstructures. Because of the high variation of
deviations (–113 to +124 µm), the 2-step technique cannot be recommended. The method to measure both impres-
sion and cast provided a better understanding of how inaccuracies are caused.

Reprinted with permission of Quintessence Publishing.

Geerts et al

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