Professional Documents
Culture Documents
A1. You should know what proper fractions, improper fractions and mixed numbers are.
x
A fraction is one natural number x divided by another y. x is called the numerator and y is called the
y
denominator.
For example,
1 3 5 11
2 4 6 8
are all fractions.
A proper fraction is one in which the numerator is less than the denominator.
For example,
1 5 7 1
2 7 8 11
are all proper fractions.
An improper fraction is one in which the numerator is greater than the denominator. For example,
3 7 121 14
2 4 55 3
are all improper fractions.
A mixed number consists of a whole number and a proper fraction.
For example,
7 1 3 11
6 1 2 5
8 2 4 12
are all mixed numbers.
Any mixed number can be written as an improper fraction and any improper fraction can be written
as a mixed number.
b
For any mixed number a we have
c
b ac + b b
a = =a+
c c c
For example
3 (5 × 4) + 3 23
5 = =
4 4 4
Another example.
7 (8 × 6) + 7 48 + 7 55
6 = = =
8 8 8 8
An improper fraction can be expressed as a mixed number by using long division.
11
For example, to write as a mixed number, we divide 5 into 11. We get 2 plus remainder 1. So,
5
(5 × 2) + 1 = 11
and
11 1
=2
5 5
A2. You should know the definitions of common denominator, greatest common divisor and least
common multiple and be able to add and subtract fractions.
The greatest common divisor of two numbers a, b, written gcd(a, b) is the greatest divisor of both.
For example, gcd(7, 14) = 7 , gcd(24, 16) = 8 and gcd(23, 7) = 1
The least common multiple of two numbers a, b, written lcm(a, b) is the least multiple of each of the
numbers which is common to both. In fact, for positive integers a and b,
ab
lcm(a, b) =
gcd(a, b)
For example,
7 × 14 98
lcm(7, 14) = = = 14
gcd(7, 14) 7
More example.
16 × 24 384
lcm(16, 24) = = = 48
gcd(16, 24) 8
2×5 10
lcm(2, 5) = = = 10
gcd(2, 5) 1
To add or subtract fractions, we express each fraction with the same denominator as the others to form
a common denominator. Then the numerators are added to obtain the answer. The best choice for the
denominator is the least common multiple of all of the denominators.
1 1
Example Add + . The least common multiple of the denominators is 6, since lcm(2, 3) = 6.
2 3
1 3 1 2
= =
2 6 3 6
So
1 1 3 2 5
+ = + =
2 3 6 6 6
1 1
Example Find − .
8 7
The least common multiple of the denominators is 56, since lcm(8, 7) = 56.
1 7 1 8
= =
8 56 7 56
So
1 1 7 8 1
− = − =−
8 7 56 56 56
1 1
Example Find +
3 9
Solution. Since the least common multiple of the denominators is 9, we have
1 1 3 1 4
+ = + =
3 9 9 9 9
A3. Recall the laws of addition, multiplication and division for fractions :
x z x·z
· =
y w y·w
x z x w x·w
÷ = · =
y w y z y·z
x z x±z
± =
y y y
x z xw yz xw ± yz
± = ± =
y w yw yw yw
You can use these rules to simplify algebraic expressions and solve problems.
Also note:
x
y x x 1 x
= ÷z= × = (∗∗)
z y y z yz
BUT
x y z xz
y
= x ÷ = x × = (∗ ∗ ∗)
z
z y y
Also note how we use common denominators to simplify fractions. For all real numbers x, y, z, w with
x 6= 0, y 6= 0, we have:
x z xw ± yz
± = (∗ ∗ ∗∗)
y w yw
Examples.
4 2 4×2 8
× = =
9 3 9 × 3 27
4 2 4 3 4 × 3 12 2
÷ = × = = =
9 3 9 2 9 × 2 18 3
Note, as in this last example, we should always factor out common factors from both numerator and de-
nominator , then cancel them out so to put the fraction in is simplest form.
12 2
Since 12 is 2 × 6 and 18 is 3 × 6, becomes .
18 3
1. B Brackets.
2. O Order (Powers).
3. D Division.
4. M Multiplication.
5. A Addition.
6. S Subtraction.
Work from left to right, doing the operations in the order above.
Example. Find
1 1 5 2 5 3
+ ÷ − ×( ÷ )
2 3 6 7 8 5
Division is next
1 5 1 6 6 2
÷ = × = =
3 6 3 5 15 5
So we now have
1 2 2 25
+ − ×
2 5 7 24
Multiplication is next.
2 25 1 25 25
× = × =
7 24 7 12 84
So we now have
1 2 25
+ −
2 5 84
16 − 32 = 16 − 9 = 7
Using BODMAS again, Order is followed by Division and then we do Multiplication. (Note that we
usually go from left to right when two operations are identical, so we’ll do the two Order operations from
left to right.) We get
74 × 5 ÷ 22 = 2401 × 5 ÷ 22
5
= 2401 × 5 ÷ 4 = 2401 ×
4
2401 × 5 12005
= = = 3001.25
4 4
A5.You should know the properties of the real numbers.
The real numbers, denoted by R, can be represented as the set of points on an infinite line called the real
line. The point 0 is called the origin and the numbers can be scaled up and down that line. The points to
the right of 0 are positive and to the left of 0 are negative. We can add, subtract, multiply and divide real
numbers.
The rational numbers are those which, when written in decimal form, have the decimals eventually
repeat in some way.
1 1 61
For example, = 0.333..., written 0.3̇ is rational, = 0.5000... = 0.5 is rational. But also, = 5.545454...is
3 2 11
rational.
Those real
√ numbers whose decimals do not repeat in any way are called irrational numbers. For ex-
ample, 2, π and e are all irrational numbers.
Properties of the real numbers
For all real numbers a, b and c,
a+b=b+a
(commutative law addition)
ab = ba
(commutative law multiplication)
a + (b + c) = (a + b) + c
(associative law addition)
a(bc) = (ab)c
(associative law multiplication)
For every real number a there exists a real number 0 such that
a+0=0+a=a
(additive identity)
For every real number a there exists a real number −a such that
a + (−a) = (−a) + a = 0
(additive inverse)
For every real number a there exists a real number 1 such that
a×1=1×a=a
(multiplicative identity)
1
For every real number a, except for 0, there exists a real number such that
a
1 1
a× = ×a=1
a a
(multiplicative inverse)
Now using the above laws, for all real numbers a, b, c, d we have
(a + b)(c + d) = ac + ad + bc + bd (∗)
A6. You should now be able to expand and simplify algebraic expressions.
we multiply out, removing the brackets, and then collect like terms.
First of all, let’s look at each part of the expression separately. Using (*),
Remember, (−) × (−) = (+) (−) × (+) = (−) (+) × (−) = (−) (+) × (+) = (+)
Also, if you are unsure of the order of the operations, see A4 where BODMAS is explained - anything in
B Brackets first, then O Order, D Division, M Multiplication, A Addition and S Subtraction. Lastly,
again using (*) and the distributive law,
Therefore, putting this all together and then adding like terms, we get
Another example. You should be able to make r the subject of the equation in the formula
L(1 − rt)
t=
(h − rt)
Solution. Here we multiply both sides by (h − rt) to get
L(1 − rt)
t(h − rt) = × (h − rt) = L(1 − rt)
(h − rt)
and so, using the distributive law,
th − rt2 = L − Lrt
Then, by adding Lrt to both sides, we get
th − rt2 + Lrt − th = L − th
and by using the commutative law twice, we can say this is equivalent to the equation
Lrt − rt2 + th − th = L − th
which means
Lrt − rt2 = L − th
because th − th = 0.
We then take rt out as a common factor
1 1 2 − (x + 2) 2 − x − 2 −x
− = = =
x+2 2 2(x + 2) 2(x + 2) 2(x + 2)
Putting this together and using (**) we get
1 1 −x
x+2 − 2 2(x+2) −x −1
= = =
x x 2x(x + 2) 2(x + 2)
as the x’s cancel out.
A8. You should be able to solve simultaneous equations with two variables, and interpret problems
where they are used.
Simultaneous Equations
Simultaneous equations are sets of algebraic equations which contain multiple variables. A solution to
such a set of simultaneous equations is a particular set of specified values for the variables which satisfies
the equations. For example,
x+y =0
x − y = 10
is a set of two simultaneous equations with two variables x and y. It has solution x = 5, y = −5 which is
easily obtained by adding the first and second equations to get 2x = 10. So x = 5 and y = −5. (Also note,
in some cases there may be no solution and sometimes there an infinite number of solutions.)
Another example, solve the following equations for x and y.
x − 2y = 7 (1)
7x − 6y = −15 (2)
First of all, we can multiply both sides of equation (1) by 7 to get 7x − 14y = 49. We do this so that we
can eliminate x as we now have
7x − 14y = 49 (3)
7x − 6y = −15 (2)
7x − 14y = 49 (3)
7x − 6y = −15 (2)
− − − − − − − − −−
0 − 8y = 64 (∗)
4x − y + z = 5
x+y−z =0
− − − − − − −−
5x + 0 + 0 = 5
and so x = 1. Putting x = 1 back into equations (1), (2) and (3), we get
−y + z = 1 (4)
−2y + 7z = 17 (5)
y − z = −1 (6)
Equations (4) and (6) are the same since −y + z = 1 is equivalent to y − z = −1. So we need only consider
two equations in two variables now to find y and z. So let’s consider (4) and (5).
To eliminate y we can multiply (4) by -2 and add it to (5) (or multiply (4) by 2 and subtract it from (2)).
Let’s do the former. Then,
2y − 2z = −2 (7)
−2y + 7z = 17 (5)
Adding we get 5z = 15 and therefore z = 3. Putting z = 3 back into equation (4) we get y = 2. So, for the
set above, x = 1, y = 2, z = 3 satisfies the three equations and is therefore a solution.
A9. You should be able to factorize polynomials. Note the following factors:
ax + ay = a(x + y)
x2 − y 2 = (x − y)(x + y)
x2 + 2xy + y 2 = (x + y)2
x3 − y 3 = (x − y)(x2 + xy + y 2 )
x3 + y 3 = (x + y)(x2 − xy + y 2 )
There are different methods used to factorize polynomials. Sometimes the factors are clear and can be
found easily. For example, consider x2 − 8x + 15. Note that 15 = 5 × 3 and 8 = 5 + 3. So you can write
x2 −8x+15 as (x−3)(x−5). Solving x2 −8x+15 = 0 we get (x−3)(x−5) = 0, so x = 3, x = 5 are the solutions.
Another example. Consider 4x2 − 8x − 21. If we want to factor this into (ax + b)(cx + d) for inte-
gers a, b, c, d, then
ax2 + bx + c = 0
It is: √
−b ± b2 − 4ac
x=
2a
Note that
(1) when b2 − 4ac > 0 there are two distinct real solutions;
(3) when b2 − 4ac < 0 there are no real solutions (but two complex conjugate solutions).
Geometrically speaking, f (x) = ax2 +bx+c is a parabola, and the values (x, 0) where f (x) = 0 are the points
in the xy-plane where this parabola intersects the x-axis. So when ∆ > 0, the parabola f (x) = ax2 + bx + c
intersects the x-axis at two places, when ∆ = 0 it intersects the x-axis at one place only, and when ∆ < 0
it does not intersect the x-axis at all.
Example. Solve the following quadratic equations for real x and y using the quadratic formula above. If
there are no real solutions, state why.
(a) x2 + 2x − 2 = 0
(b) x2 + 2x + 2 = 0
Solution. (a) x2 + 2x − 2 = 0 is in the form ax2 + bx + c = 0. Here a = 1, b = 2, c = −2. We use the
quadratic formula to get the solution. That is,
√ p √
−b ± b2 − 4ac −2 ± 22 − (4 × 1 × −2) −2 ± 4 + 8
x= = =
2a 2×1 2
√ √
−2 ± 12 −2 ± 2 3 √
= = = −1 ± 3
2 2
√ √
So there are two solutions, and they are: x = −1 + 3 and x = −1 − 3.
Chemistry Example.
Example. In Chemistry, the molecular weight or molar mass of a compound is found by adding
the atomic weights of all of the atoms in the compound. It is given in grams per mole (written g/mol or
gmol−1 ).
(a) Find the molar mass = molecular weight of H2 O (water).
(b) Find the molar mass = molecular weight of NaCl (sodium chloride).
(c) Find the molar mass = molecular weight of NH4 Br (ammonium bromide).
Note: Hydrogen (H) has atomic weight 1.008, Oxygen (O) has atomic weight 16.00, Sodium (Na)
has atomic weight 22.99, Chlorine (Cl) has atomic weight 35.85, Nitrogen (N) has atomic weight
14.01 and Bromine has atomic weight 79.90.
Solution.
(a) Water, H2 O, consists of two Hydrogen atoms and one Oxygen atom. Hydrogen has atomic weight
1.008 and Oxygen has atomic weight 16.00. So the molar mass, or molecular weight, of water is:
(b) Sodium (Na) has atomic weight 22.99 and Chlorine (Cl) has atomic weight 35.85. So the molar mass,
or molecular weight, of sodium chloride is:
(c) Nitrogen (N) has atomic weight 14.01, Hydrogen has atomic weight 1.008, and Bromine has atomic
weight 79.90. So the molar mass, or molecular weight, of ammonium bromide is:
Statistics Example.
Example. In Statistics, the mean or average of a set of data is the sum of the each of the data values
divided by the number of data values. The following data set is the retail value of 10 new luxury cars chosen
from a car sales outlet. Find the mean of the following set of data.
$75, 000 $84, 000 $84, 000 $90, 000 $90, 000 $90, 000 $90, 500 $90, 500 $90, 700 $100, 000
75, 000 + (2 × 84, 000) + (3 × 90, 000) + (2 × 90, 500) + 90, 700 + 100, 000 = 884, 700
If an athlete runs from 85m to 1105m in 210 seconds, what is the athlete’s average velocity?
Biology Example.
Example.In Biology, the final concentration of a substance is found by dividing the initial volume by the
final volume and multiplying by the initial concentration. That is,
initial volume
final concentration = × initial concentration
final volume
(a) A solution of coloured liquid contains 3 grams of stain per litre. If 1 mL of stain is diluted by adding
7 mL of distilled water to it, what is the final concentration?
(b) The final concentration of a coloured liquid is 0.75 grams of stain per litre. The initial volume was 1
mL and the final volume was 10mL. What was the initial concentration?
Solution.
(a) The initial volume is 1 mL and the final volume is (1 + 7) = 8 mL. Since the liquid contains 3 gams
of stain per litre, then
initial volume
final concentration = × initial concentration
final volume
1mL
= × 3 grams per litre = 0.375 grams per litre = 0.375 g/L
8mL
(b) Since
initial volume
final concentration = × initial concentration
final volume
we have
final volume
initial concentration = final concentration ×
initial volume
That is,
10 mL
initial concentration = 0.75 grams per litre × = 7.5 g/L
1 mL
Biology Example.
In population genetics, there are two main measures of genetic variation - the allele frequency and the
genotype frequency.
The allele frequency is the proportion of the total that is represented by a single, specific allele (out of all
alleles at that locus in that population).
The genotype frequency is the proportion of the total that is represented by a single, specific genotype
(out of all possible genotypes at that locus in that population).
Consider a population of 100 pea plants. 64 tall plants have genotype T T , 32 tall plants have genotype T t
and 4 dwarf plants have genotype tt.
Solution. (a)
Chemistry Example.
The ideal gas equation is
P V = nRT
where
How many moles of nitrogen gas occupy 2.5 L at 1 atm pressure and 27◦ C?
Solution. The gas equation is P V = nRT . We are told that V = 1L, P = 1atm, R = 0.08216 L
atm mol−1 K−1 and T = 27 + 273 = 300◦ K (as the temperature has to be converted from Celsius to Kelvin.)
We wish to find n. So rearranging, we get
PV 1atm × 2.5L
n= = = 0.1014mol
RT 0.08216L atm mol−1 K−1 × 300K
Physics/Engineering Example.
Kinematics is the branch of mechanics which describes the motion of bodies independently of external forces.
It deals with the relation between distance, time, velocity and acceleration, and the mathematical principles
which are applied to them.
Galileo hypothesized that at a given location on earth in the absence of air resistance, all objects fall with
the same constant acceleration. This is due to gravity, written g, which is (nearly) constant near the surface
of the earth. Acceleration due to gravity on the earth is g = 9.8 m/s2 . Vertical displacement is represented
by y, so that as y increases with height, g acts in the negative y direction.
The kinematics equations describing the motion are:
v = v0 − gt
1
y − y0 = (v + v0 )t
2
1
y − y0 = v0 t − gt2
2
v 2 = v02 − 2g(y − y0 )
where v = velocity, v0 = initial velocity, t = time, a = −g = constant acceleration, y = vertical displacement
and y0 = initial vertical displacement.
(a) If an object is projected vertically upward from the ground with a speed of 15 m/s, how long does it
take to reach its highest point?
(b) How high does the object rise?
Solution.
(a) At its highest point, the velocity is zero, so we set v = 0. Using the equation v = v0 − gt we have
0 = v0 − gt. Rearrange this to make t the subject of the equation.
v0
0 = v0 − gt ⇔ v0 = gt ⇔ t=
g
So
15m/s
t= = 1.53s
9.8m/s2
and it takes 1.53 seconds to reach its highest point.
Note: the symbol ⇔ is used in mathematics to denote ”if and only if” and can be used when Equation A is
equivalent to Equation B. What this means logically is:
Be careful when using these symbols. Sometimes ⇐ or ⇒ are all you can use as one equation may imply
the other equation, but they may not be equivalent.
(b) We use the kinematics equation
v 2 = v02 − 2g(y − y0 )
At the highest point v = 0 and also y0 = 0 as the initial vertical displacement is 0. So the equation above
becomes
0 = v02 − 2gy
We now rearrange the equation to make y the subject, as we require the vertical displacement (height).
v02
0 = v02 − 2gy ⇔ 2gy = v02 ⇔ y=
2g
We now use the values given
v02 (15m/s)2
y= = = 11.48m
2g (2 × 9.8)m/s2
So the object rises 11.48 m.
Biology Example.
The increase in a rate caused by a 10◦ C increase in temperature is called the Q10 . If the rate doubles,
Q10 is 2; if the rate triples, Q10 is 3. In fact, when rates R1 and R2 have been observed at two different
temperatures T1 and T2 respectively, then
10
R2 T2 −T1
Q10 =
R1
If R1 = 135 at T1 = 33◦ and R2 = 170 at T2 = 39◦ , what is Q10 ? (Give your answer as a fraction or correct
to 4 decimal places.)
Solution.
Simply plug in the values into the equation and solve. We get
10 10 2
R2 T2 −T1 170 38−33 170 1156
Q10 = = = = = 1.5857
R1 135 135 729
Chemistry Example.
Given the acid dissociation equilibrium HA + H2 O ↔ A− + H3 O+ , the percentage ionization is given by
[H3 O+ ]
% ionization = × 100%
[HA] initial
where square brackets denotes the ”molar concentration of”.
(a) Given the molar concentration of H3 O+ is [H3 O+ ] = 0.007M and the initial molar concentration of
the acid is [HA]initial = 0.3M , what is the percentage ionization?
(Give your answer correct to 2 decimal places.)
(b) For a different acid, suppose the percent ionization is 5% and [HA]initial = 1.8M . Find the concen-
tration of H3 O+ . (Give your answer correct to 2 decimal places.)
Solution.
(a) Plug in the values given into the equation to get
[H3 O+ ]
% ionization = × 100% = 0.233%
[HA] initial
(b)
[H3 O+ ]
% ionization = × 100%
[HA] initial
so plugging in the values we get
[H3 O+ ]
5% = × 100% and therefore [H3 O+ ] = 0.09M
1.8
Physics/Engineering Example.
The average velocity of an object is defined as its displacement divided by the time elapsed. That is,
displacement final position - initial position
average velocity = =
time elapsed time elapsed
This is written as
∆x x2 − x1
v̄ = = in units m/s
∆t t2 − t1
(a) A bicycle travels from 85m to 1105m in 210 seconds. What is the velocity of the bicycle?
(b) Another bicycle travels from 60m to a finishing point at a velocity of 3.3m/s in 180 seconds. What
is the finishing point?
Solution.
(a)Using the equations above,
∆x x2 − x1 1105m − 85m
v̄ = = = = 4.857m/s
∆t t2 − t1 210m
(b)
∆x x2 − x1 x2 − 60
v̄ = = =
∆t t2 − t1 180
So we solve for x2 .
x2 = v̄ × 180 + 60 = 3.3 × 180 + 60 = 654m
Chemistry Example.
A useful equation used in Chemistry and Biology is n = cv, where n is the amount of a substance (in mol)
(moles of solute), v is the volume (in litres)(litres of solution) and c is the amount of substance per unit
volume (mol per litre)(molarity).
Use this equations to find out how many grams of solid Mg(NO3 )2 are required to make 5.5L of a 2.5M
Mg(NO3 )2 solution.
Note: Magnesium (Mg) has molar mass 24.31, Nitrogen (N) has molar mass 14.01 and Oxygen (O) has
molar mass 16.00.
Solution.
n = c × V where n is the amount of a substance (in mol) (moles of solute),
mass
n=
molar mass
Since the molar mass of Magnesium (Mg) is 24.31, the molar mass of Nitrogen (N) is 14.01 and the molar
mass of Oxygen (O) is 16.00, then the molar mass of Mg(NO3 )2 is
Hence,
mass = 148.33 × 2.5 × 5.5 = 2039.5g
Therefore, the required mass of Mg(NO3 )2 is 2039.5 g.
EXERCISES
6. Use the rules of arithmetic operations of fractions and the order of arithmetic operations to find the
solutions to the following.
1 6 5 3 7 7 5 8 3 5 8 3 3 2 3
(a) − + (b) ÷ + (c) × ÷ (d) × − × ÷( + )
2 5 2 4 5 2 6 9 4 6 9 4 2 5 2
7. In Chemistry, the molecular weight or molar mass of a compound is found by adding the atomic
weights of all of the atoms in the compound. It is given in grams per mole (written g/mol or gmol−1 ).
(a) Find the molar mass = molecular weight of MgO (magnesium oxide).
(b) Find the molar mass = molecular weight of Na2 SO3 (sodium sulphite).
(c) Find the molar mass = molecular weight of Na2 SO4 (sodium sulphate).
(d) Find the molar mass = molecular weight of Fe2 O3 (iron oxide).
Note: Magnesium (Mg) has atomic weight 24.31, Oxygen (O) has atomic weight 16.00, Sodium
(Na) has atomic weight 22.99, Sulfur has atomic weight 32.07 and Iron (Fe) has atomic weight
55.85.
8. The following data set is the retail value of 15 display homes at a particular display village. Find the
mean of this set of data.
$375, 000 $375, 000 $284, 000 $284, 000 $190, 000 $190, 000 $190, 000 $250, 500
$290, 500 $290, 700 $300, 000 $375, 000 $190, 000 $284, 000 $284, 000
9. In Physics, the average velocity of an object is defined as its displacement divided by the time elapsed.
This is written as
∆x x2 − x1
v̄ = = in units m/s
∆t t2 − t1
where x1 is the initial position, x2 is the final position, t1 is the initial time, t2 is the final time and
t2 − t1 is the time taken.
If an athlete runs from 12m to 147m in 20 seconds, what is the athlete’s average velocity?
10. In Biology, the final concentration of a substance is found by dividing the initial volume by the final
volume and multiplying by the initial concentration. That is,
initial volume
final concentration = × initial concentration
final volume
(a) A solution of coloured liquid contains 7 grams of stain per litre. If 1 mL of stain is diluted by
adding 9 mL of distilled water to it, what is the final concentration?
(b) The final concentration of a coloured liquid is 0.55 grams of stain per litre. The initial volume
was 1 mL and the final volume was 11mL. What was the initial concentration?
11. Expand and then simplify 4bc(ad + 3d) − 2bcd + 15bc(d − ad).
12. Expand and simplify 7(x + 2y)(2x − y)and then state the coefficient of x2 .
14. Perform the following operations, stating your answer in its simplest form.
7 42
(i) ×
14 6
6 19
(ii) ÷
15 4
15. Recall the ideal gas equation P V = nRT .
16. A useful equation used in Biology and Chemistry is n = cv, where n is the amount of a substance (in
mol) (moles of solute), v is the volume (in litres)(litres of solution) and c is the amount of substance
per unit volume (mol per litre)(molarity).
17. The increase in a rate caused by a 10◦ C increase in temperature is called the Q10 . If the rate doubles,
Q10 is 2; if the rate triples, Q10 is 3. In fact, when rates R1 and R2 have been observed at two different
temperatures T1 and T2 respectively, then
10
R2 T2 −T1
Q10 =
R1
If R1 = 120 at T1 = 20◦ and R2 = 140 at T2 = 25◦ , what is Q10 ?(Give your answer as a fraction or
correct to 4 decimal places.)
18. Given the acid dissociation equilibrium HA + H2 O ↔ A− + H3 O+ , the percentage ionization is given
by
[H3 O+ ]
% ionization = × 100%
[HA] initial
(a) Given [H3 O+ ] = 0.003M and [HA]initial = 0.1M, what is the percentage ionization? (Give your
answer correct to 2 decimal places.)
(b) For a different acid, suppose the percent ionization is 4% and [HA]initial = 1.9M. Find the
concentration of H3 O+ . (Give your answer correct to 3 decimal places.)
(a) If she wants the same amount of units S1 and S2 dissolved, how many units of each substance
does she dissolve if it takes her 3 hours to complete the task.
(b) If, at another time, she wants 3 times as much of substance S2 than Substance S1 dissolved in
the solution, how many units of each substance does she dissolve if it takes her 2 hours?
21. Pharmacist Bob sold two brands of headache tablets, Brand A and Brand B. In total, had 200 packets.
Brand A cost 7 dollars and Brand B cost 9 dollars. He sold them all and collected 1500 dollars. How
many packets of each brand did he sell?
22. Consider the first order equilibrium reaction A+B ↔ X +Y and let a, b, x and y represent the number
of moles of the respective products and reactants. The equilibrium constant is given by
xy x2
k= =
(a − x)(b − x) (a − x)(b − x)
Use algebraic techniques to rewrite this equation (*) in the quadratic form ax2 + bx + c = 0. Given
k = 8, a = 2 moles and b = 4 moles, solve for x using the quadratic formula and hence find the number
x of moles of each product. (Give your answer correct to 2 decimal places. You will get two solutions
- give the smallest positive number as your answer.)
23. The volume of a cone is given by the formula V = 13 πr2 h, where r is the radius of the circle at the
top of the cone and h is its height. If V = 37 cm3 and r = 5cm, what is the height of the cone?
24. The surface area of a sphere of radius r is given by A = 4πr2 The radius of the Jupiter is approxi-
mately 71, 492 = 7.1492 × 104 km. What is its surface area approximately?
25. Let C denote degrees Celsius, F denote degrees Fahrenheit, and K denote Kelvin temperatures. To
convert temperature from one scale to another, we use:
5 9
K = C + 273 C = (F − 32) F = C + 32
9 5
(a) If the maximum temperature one day is 34.3◦ C, what is this in Fahrenheit?
(b) If a temperature in Kelvin is measured as 232◦ K, what is this in Fahrenheit?
26. In population genetics, there are two main measures of genetic variation - the allele frequency and the
genotype frequency.
The allele frequency is the proportion of the total that is represented by a single, specific allele (out
of all alleles at that locus in that population).
The genotype frequency is the proportion of the total that is represented by a single, specific
genotype (out of all possible genotypes at that locus in that population).
Consider a population of 250 pea plants. 155 tall plants have genotype T T , 83 tall plants have
genotype T t and 12 dwarf plants have genotype tt.
(a) An athlete runs from 12m to 147m in 20 seconds. What is the athlete’s average velocity?
(b) Another athlete runs from 12m to a finishing point at a velocity of 5.1m/s in 25 seconds. What
is the finishing point?
(a)
5x − 3y = 1
5x + 4y = 22
(b)
x − 3y = 2
2x + 2y = 20
(c)
x + 3y + z = 3
x+y+z =1
−x + y + 2z = −2
30. Use the equation n = c × V to find out how many grams of solid Mg(NO3 )2 are required to make 3.5L
of a 1.5M Mg(NO3 )2 solution.
Note: Magnesium (Mg) has molar mass 24.31, Nitrogen (N) has molar mass 14.01 and Oxygen (O)
has molar mass 16.00.
ANSWERS
1. (i) proper (ii) improper (iii) improper (iv) mixed number (v) proper (vi) improper (vii) improper (viii)
mixed number
29 7 20
2. (a) (b) (c)
6 4 3
1 1 9
3. (a) 8 (b) 4 (c) 12
3 4 11
4. (a) 7 (b) 3 (c) 2 (d) 1
8.$276,847
9. 6.75 m/s
nRT
15. (a) V = P (b) 43.328
n
16. (a) c = (b) 0.34
v
49
17. = 1.3611
36
18. (a) 3% (b) 0.076M
√ √
−7 + 13 −7 − 13
19. (i) x = −2 (ii) x = 3 (iii) x = 5 or x = 9 (iv) x = or x =
2 2
3
(v) x = 1 or x = −
2
20. (a) 18 units of S1 and 18 units of S2 . (b) 5 units of S1 and 15 units of S2 .
30. 778.73 g