Aits 1819 FT I Jeea Paper 2 Sol

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ALL INDIA TEST SERIES

FULL TEST – I
JEE (Advanced)-2018-19
PAPER –2
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. B
N
Sol.  Ndt  mv 1  e Cos 
0 (1)
  Ndt  m V  V sin   (2)
x 0 fr
Vx  V0 sin   V0 1  e  Cos 
eV0 cos  1 e
tan    q
Vx 1 e
2. AB
Sol. Graph must be hyperbolic.
3. BCD
Sol. N
N Fr
m
fr  
m
 mg fr mg N
N   mg  N cos   sin 
N sin   fr cos 
(for inclined plane to move over horizontal surface)
4. B
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AITS-FT-I (Paper-2)-PCM-JEE(Advanced)/19 2
Sol. Heat taken from water to freeze

 
mLf  mSi 0  10 c    
Heat taken by crushed ice = mi si 0  20 c 
5. AD
 hc hc 
Sol. f  n  cos60  cos 45 
 2 1 
f11  0
6. ABC
Sol.
1 2 3
3 1 3  2 2  1
  
V U R2 R1
7. ABCD
Sol. eVB  eE
ex B  eE
E  Bx
Ex
8. C
/ 2
20 m 20 m
Sol. E .m.f ()   m 3  Rd  4 R 3
0 4 R
 0 m sin 
q 4 R 3
m
o
9. A
Sol. Motion of insect will be S.H.M as Plank is always horizontal N1 N2
fr h  N x (1) h
fr  ma (2) fr
N1
mg
x
10. D
Sol. Motion of insect will be S.H.M as Plank is always horizontal N1 N2
fr h  N x (1) h
fr  ma (2) fr
N1
mg
x
11. C
Sol. R.C circuit
3 AITS-FT-I (Paper-2)-PCM-JEE(Advanced)/19
12. A
Sol. R.C circuit
SECTION – C
13. 9
 dx  1  dx 
Sol.       k x
dt
 in T1  dt out
 dx   dx   dx 
     
 dt net  dt in  dt out
14. 6
Sol.
O R/2
O
For pure Rolling  a  Rh

Vertical line equation Lo sphere
 Rh a 
N  mg  macmy acmy   
 2 2
ma
N  mg 
2
for not sliping
R  a
m2    mg  m 
2  2
15. 5
Sol. Process will turn from endothermic to exothermic at point where slope of P-V graph satisfy the
slope of adiabatic curve for same gas.
Y P P0 P
i.e.  and P   0  V  P0
V V0 V0
16. 3
Sol. Total  g  Electro  External    
{Final state is also in equilibrium}
17. 4
 v  v ob 
Sol. fab    fo
 v 
v f
1 ob  ob
v fo
f f 
v ob   ob o  v
 fo 
   o   ob fLo fLob
fob  fo
 
fo  fob
Difference in time interval of beep observed and produced is no. of oscillation multiplied by  .
t
t   
 ob
Hence beep produced for interval
t  t   4 sec
18. 2
Sol. Air 
Air Water Air
Air
2T
Po  Pw 
R
 2T 
Pw   Po  
 R 
 2T 
Fnet  Po A   Po  A
 R 
19. 3
Sol. BD  l 2
F
CD  l1
CDF and BB D are similar 2
BB  BD
 C
CF CD G
l h D
 2  1 1
l1 h
ACB and BDE are similar A B
E
AC DE

l1  l 2 l2
B'
20. 4
0  2
Sol.  Magnetic Pr essure
2
 2
Force  0  Pr o sec tion area
2
I

2R
Chemistry PART – II
SECTION – A
21. BC
3 4
Sol. Fe 2  Fe  CN6   Fe3   Fe  CN 6  

Fe 4 Fe  CN6  Blue precipitate
3
4
3
Fe  Fe  CN  6   Fe 4 Fe  CN 6  Blue precipitate

3
2 4
Fe  Fe  CN 6   Fe2 Fe  CN6  White precipitate
3
Fe3   Fe  CN6   Fe Fe  CN 6  Brown colour
4
Cu2   Fe  CN6   Cu2 Fe  CN6  Brown colour

1
Fe3   S 2 O32   Fe  S 2 O3   
 Fe2   S 4 O26 
violet colour
22. ABCD
Sol. (I) has higher dipole moment than (II).
H3C H
C C
H Br
23. ABC
Sol. H OH
O
O - H2O 3OH-
OH - CHCl 3 C OH
Ph C H + CCl 3 H
Ph CCl 3 HO
NaOH
(cannizaro reaction) -H2O
H C OH
PhCH2OH + PhCOONa
O
-
OH
HCOONa
24. B
Sol. (B) is major due to 6-membered cyclic transition state.
25. C
Sol. A 
 3B
a 0 initially
ax 3x time' t '
v 0  a and v t  a  5x
2.303  5v 0 
k log  
t  6v 0  v t 
Putting v t  2v 0 and at t  970 sec

2.303  5  2.303
k log     0.0971  2.303  104
970  4  970
0.693
 t1   3010 sec
2 2.303  10 4
26. ACD
Sol. Fact
27. ACD
Sol. (A) dx2  y2  dx2  y2 can do  or  overlap
(B) s + px can do  overlap
(C) dxy  dxy can do  or  overlap
(D) pz  p z can do  or  overlap
28. BD
Sol. Gas having higher critical temperature, shows higher extent of adsorption.
29. B
Sol. BF3 forms addition product with water
H2 O  
 H BF3 OH 
BF3  H2 O   H3 O  BF3 OH
30. A

Sol. H3BO3 is monobasic and B  OH4   is conjugate base of H3BO3. Also BF3 (electron deficient)
reacts with ether as:
R2 O  BF3  R2 O  BF3 
31. D
Sol. In the nearest neighbour of Mn2+(0), there are six oxides (x) at the adjacent six edge centre,
hence CN of
Mn2+ = 6.
The nearest neighbour points to the body centre is the 12 edge centres where oxide ions (x) are
present, hence CN of Ln4+ = 12.
In the nearest neighbour of O2-(x) there are only two Mn2+ on the adjacent corners, hence CN of x
= 2.
32. B
a
Sol.   
r O2   r Mn2    2
i 
a
  
r O2   r Ln4    2
ii 
From  i  and ii  ,
      
r O2   r Ln4   r O2   r mn2  
r  Ln   r  Mn 
4 2
SECTION – C
33. 7
Sol. K 2Cr2 O7 ,CuSO4 , H2 O2 ,Cl2 ,O3 ,FeCl3 ,HNO3
K 2Cr2 O7  7H2SO 4  6KI  4K 2 SO4  Cr2  SO4 3  3I2  7H2O
2CuSO 4  4KI  Cu2I2  I2  2K 2SO 4
H2 O2  2KI 
 I2  2KOH
Cl2  2KI  2KCl  I2
O3  2KI  H2 O 
 2KOH  I2  O2
2FeCl3  2KI  2FeCl2  I2  2KCl
8HNO3  6KI  6KNO3  2NO  4H2 O  3I2
2KMnO4  KI  H2O  KIO3  2MnO 2  2KOH
34. 7
Sol. I A
P
Q
or
O
I B
AB  OA  OB  2OA  2  OP  PA 
 2 PQ  PA   OP  PQ; OPQ is equilateral 
 2 PQ  covalent radius of C  covalet radius of I
0
 2 1.40  0.77  1.33   7.0 A
35. 9
Sol. x = 2, y = 0, z = 3, w = 8.
36. 7
Sol. w  3320  Pext V  nRt
3320
 T   200
2  8.3
 Q  14.94kJ  nCp T
14.94  1000
 Cp   37.35 Jk 1mol1
2  200
3 
Also, Cp    x  R where x  atomicity
2 
Cp 3 37.35
x    1.5  3
R 2 8.3
37. 3
Sol. k sp
AgCN 

 H  
 Ag  HCN; k eq 
ka
0.01  x x x
k sp x2
k eq   10 6 
ka 0.01  x
 keq is sufficiently small, 0.01 –x  0.01
 x  10 4 M
38. 4
Sol. Hydrocarbon is C4H8
rHC 1 MN2
 
rN2 2 MHC
MHC  28  2  56
24  2 8
DBE / DU  1
2
39. 4
Sol. O
Me O Me
Final product E is
x = 4 and y = 0 Me Me
O
O
40. 8
Sol. OH
O
H O
O H
HO OH
OH 5
pentasachharides derived from D - glucose
Each of the five monosachharides may be either  -D-glucose or  - D – glucose, thus total
pentasachharides possible = n = 25 = 32
32
Answer is 8
4
Mathematics PART – III
SECTION – A
41. AC
Sol. Use formula of 2 tan1 x
42. ABCD
z2 z2
Sol. (A)   zz  z  z  0 or z  z
z 1 z 1
(B) z  4 5 let   3  5z
  3  5  4 5  20
(C) z   2  a   i 3  a 2  x  iy
x  2  a & y  3  a2
2
  x  2  y2  3
(D) z 1  a   b  ic & a2  b2  c 2  1
1  iz a  ib
 
1  iz 1  c
43. ABC
  2 2 2 2 
Sol. a  b  c  a  b  c  2 a.b  0
  27
9  9  9  2 a.b  0   a.b  
2
2 
2 a  2 a.b  27 
 27
  a.b  2
44. ABCD
x2  1 1
Sol. f x  x ,x0
x x
45. ABD
Sol. Four odd  Four even   Three even  Three odd    Two even  Two odd
5 C4 .4! 4 C4 .4! 4 C3 .5 C1.4! 4 C2 .5 C2  4  4
 1584
46. CD
Sol. 3 cos A  coa  B  C   cos B  C   cos B  C   cos A
2cos A  cos B  C    cos  A  2C 
2   tan A.sin2C  cos2C 
47. ABCD
Sol. f  f  x    1  x   f  t   1  f 1  t 
f  t   f 1  t   1
 f  x   f 1  x   1
48. ABC
Sol. Facts
49. C
50. D
Sol. (for Q. 49-50)
1
L  lim

xe 2x 1  3x 2  2
C 1
x 

C xex  e x
 xe x 
51. B
52. D
Sol (for Q. 51-52)
1
bmax  2, r 
1  b2
SECTION – C
53. 8
Sol. 1st order linear DE
54. 5
Sol. f  x   x 2  2  a  1 x   a  3 
f  0   0 & f  2   0.
55. 8
4 4
r13 r23
Sol.  16
 32 2
3
 2
1r  r2 a
 
56. 7
Sol. 3iˆ  2ˆj  kˆ . a ˆi  bjˆ  ckˆ   a2  b 2  c 2 9  4  1
57. 7
2
Sol. F'  x    2x  3   f  x  dx
x
58. 5
Sol. Newton Leibnitz’s Rule
59. 4
Sol. Sum of AGP
60. 8
Sol. Facts

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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

Sol. Heat taken from water to freeze

For pure Rolling  a  Rh

Air Water Air

Putting v t  2v 0 and at t  970 sec

Mathematics PART – III

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