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Abstract
The gas dispersion properties that are the subjects of this communication include three measured parameters, gas superficial velocity
(gas rate), gas holdup and bubble size, plus the derived parameter, bubble surface area flux. Over the past 10 years sensors to measure
these parameters have been introduced and those originating from McGill University are briefly described.
The sensors have seen extensive use in plant campaigns and experiences on four cell types at three sites are discussed. The impact of
frother in controlling bubble size by retarding coalescence is illustrated, indicating the need to understand chemistry/machine interac-
tions in interpreting gas dispersion results. An increase in Sauter mean bubble size (D32) with superficial gas velocity (gas rate, Jg)
was found, which was fitted empirically by D32 = D0 + C, J ng where D0 0.5–0.6 mm and C and n are fitted parameters dependent
on the system (machine and chemistry). Following this, a consistent trend in bubble surface area flux (Sb) vs. Jg was also observed.
The relationship between Sauter mean and number mean (D10) is suggested to interpret the nature of the distribution. Analysing gas
holdup vs. gas rate shows both a dependence on location in the cell as well as cell position in a bank, factors which must be considered
when comparing data from different plants and circuits.
The instrumentation and methodologies being developed are presenting new opportunities for incorporating cell hydrodynamics into
metallurgical diagnostics. A case study at one plant serves as illustration.
Ó 2005 Elsevier Ltd. All rights reserved.
0892-6875/$ - see front matter Ó 2005 Elsevier Ltd. All rights reserved.
doi:10.1016/j.mineng.2005.09.045
ARTICLE IN PRESS
characterization data from three concentrators: North (radial and depth variations in gas distribution in a cell
American Palladium Ltd.Õs Lac des Iles (LDI) (Ontario, can be expected).
Canada); Impala PlatinumÕs UG2 (Impala) (S. Africa);
and Noranda/FalconbridgeÕs Raglan (Raglan) (Quebec, 2. Instrumentation
Canada). The paper focuses on forced air mechanical
machines: at Raglan, (nominal) 28-m3 Outokumpu OK- The basic measurement is the gas superficial velocity
28 U-bottom cells; at LDI, 130-m3 Outokumpu OK-130 (Jg), namely the volumetric flow rate of gas (air) (Qg) per
tank cells; and at Impala, 50-m3 Bateman 50 and 30-m3 cross-sectional area of the cell (A). i.e., Jg = Qg/A with
Metso RCS 30 tank cells. Common gas dispersion fea- units typically cm/s. This is often termed simply Ôgas rateÕ.
tures are identified, for example the dependence of bubble The data reported here were measured using the so-called
size on gas rate. There is no intent to compare cell on/off Jg sensor (Fig. 1a) (Torrealba-Vargas et al., 2004).
designs as this would require a more complete under- It comprises a tube to collect bubbles by natural buoyancy
standing of the role of at least the following: pulp prop- and infers Jg from the rate of increase in pressure once a
erties (density, viscosity), mechanical factors (energy valve is closed (specimen Ôpressure-variationÕ curves are
input, mixing), solution chemistry (notably frother dosage included, Fig. 1b). The estimation of Jg requires the bulk
and sometimes salt concentration) and sampling location density (qbulk) and this is usually taken at the same time
Fig. 1a. Schematic of McGill on/off gas rate sensor (Note, level in tube descends as air accumulates).
Fig. 1b. Example pressure variation curves for the on/off sensor.
ARTICLE IN PRESS
0.4
0.3
Fraction
0.4
0.2 Volume
Surface 0.3
Number
0.1
Fraction
0.2 Volume 0.4
0.0 Surface
0.1 1.0 10.0 0.1 Number 0.3
Db (mm)
Fraction
0.0 0.2 Volume
0.1 1.0 10.0 Surface
Number
Db (mm) 0.1
0.0
3.0 0.1 1.0 10.0
Db (mm)
2.5
0.4
D10 or D32 (mm)
2.0
1.5 0.3
D10
Fraction
1.0 D32 0.2 Volume
Surface
0.5
Number
0.1
0.0
0 20 40 60
0.0
Frother Addition (pm) 0.1 1.0 10.0
Db (mm)
Fig. 4. Impact of frother dosage on mean bubble size (D32 and D10) and on frequency distributions (number, surface area, volume) at selected frother
dosages.
3
40
Outokumpu TC 130 LDI
2.5 Jg=0.11
Jg=0.11
30
Frequency (%)
Jg=0.48
Jg=0.48
2
D32 (mm)
0.5 0
0.1 1.0 10.0
0
0 0.5 1 1.5 2 2.5 3 Db (mm)
25
diminishes in frequency with a second mode becoming evi- Jg =0.43
Jg=0.43
dent (ca. 2.5 mm), suggestive of an effect on the secondary 20
Frequency (%)
Jg =1.0
Jg=1.0
process. The top gas rate may be too high for the frother Jg =2.4
15 Jg=2.4
dosage to fully retard coalescence.
The availability of bubble size distribution data invites 10
exploration of the properties. Plotting D32 against D10 pro-
vides some insight into the effect of gas rate on the distribu- 5
tion. Fig. 7 shows the result for two of the cases in Fig. 6. 0
The LDI (Outokumpu) data closely follow the identity, 0.1 1.0 10.0
which means the distribution remains narrow over the Db (mm)
gas rate range, compared with the Impala (Bateman) data
which indicates a widening distribution with increasing gas Fig. 6b. Impact of gas rate on number frequency (LDI—Outokumpu).
ARTICLE IN PRESS
rate. The different response may be related to the degree of 100 Impala Bateman
coalescence but more experience is required to pursue this
2
D32 (mm)
LDI
the high end of the range in the literature (Gorain et al.,
1.5 Outokumpu 1997; Powell et al., 2000). Xu et al. (1991) suggest a maxi-
1 mum Sb in water–air systems of ca. 160 s1.
Impala
Bateman
Following from Fig. 5, the trends could be fitted by
0.5
6J g
0 Sb ¼ . ð2Þ
0 0.5 1 1.5 2 2.5 3 ðD0 þ CJ g Þ
D10 (mm) After calibration (to provide estimates of D0, C and n), Eq.
Fig. 7. Sauter mean (D32) versus number mean (D10). (2) could be integrated into flotation simulators.
80
March
gas injection point. This is seen here: reading across, the
(% passing)
location.
0
0 1 2 3 4 5 6
3.5. Linking to metallurgy: an example Db (mm)
By way of an industrial case study, the investigation into Fig. 12. A comparison of bubble size distributions at the Matagami
seasonal variation in zinc concentrate grade at Matagami is concentrator for March and August at the same gas rate setting.
20
Concentrate Grade (%Zn)
55
Located at center Aug/02
Located at launder 53
16
Aug/02 Repeat
51
εg @ 2.5m (%)
12 March/02
49
March/02
8 OK28
OK28 47 Repeat
45
4 0 1 2 3 4 5
August March
0 Jg (cm/s)
0.0 0.4 0.8 1.2 1.6 2.0
Jg @ 2.5 m (cm/s) Fig. 13a. Zinc concentrate grade versus gas rate for winter (March) and
summer (August) zinc rougher surveys at Matagami. Note, arrows
Fig. 11. Gas holdup versus gas rate with Jg sensor at two locations. indicate plant operating settings.
ARTICLE IN PRESS
August
R2 = 0.9166 the influence of sampling location.
52 7. Gas dispersion measurement offers unique new insights
March
50
into metallurgical behaviour with opportunities for pro-
Linear fit cess improvements, as illustrated by a case study.
48
46 Acknowledgements
0 10 20 30 40 50 60
Bubble Surface Area in Fraction <1 mm (%)
The authors wish to thank the site personnel for their
Fig. 14. The concentrate grade data for March and August correlate when enthusiastic assistance during the campaigns, and SGS
plotted against the proportion of the surface area flux within the minus Lakefield Research for facilitating two of these initiatives
1 mm bubble fraction.
(Impala and LDI). The authors represent the various teams
assembled to conduct the work and wish to acknowledge
Various relationships were investigated to try to explain the significant contribution of the following: M. Bailey, J.
this dependency and, ultimately, the one demonstrated in Torrealba-Vargas, L. Calzado and R. Dahlke. Funding
Fig. 14, showing the concentrate grade is inversely-linearly was from two NSERC (Natural Sciences and Engineering
related to the proportion of bubble surface area flux con- Research Council of Canada) CRD grants, one sponsored
tained in the minus 1 mm bubbles proved the most con- by INCO, Noranda, Falconbridge, Teck-Cominco, COR-
vincing (R2 = 0.92). At this juncture it is not known if EM and SGS Lakefield Research, and the other by
the role of the fine bubbles is to enhance collection of gan- AMIRA International under the P9 project.
gue particles by true flotation or entrainment mechanisms
(For further discussion see Nesset et al. (2005)). While References
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