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Time Institute
Day Group name by CC
Groups
1
Monday 3:00 to 5:00 pm 1
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Recap
• Materials Tetrahedron
Structure-Processing-Properties-Performance
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Examples of Each Material Family
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1
3
System automatically
attains the stable state
Otherwise Unstable
Pressure
Temperature
Internal energy
Enthalpy
Thermodynamic Properties
U = internal energy
ΔU = q-w
dU = dq – dw
at constant P, dw = PdV
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Thermodynamic Properties
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Thermodynamic Properties
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Demonstration of PV term in solid
U = 6 x 56.4 KJ/mole
= 338.4 KJ
1)Oscillatory
2)Rotational
3)Translational
Thermal Energy
Atoms in solid oscillate about mean position
with varying amplitude and directions
T , frequency
n E *
exp
N kT
S k lnW
W is the number of
configurations having the
same energy
N!
W Cn
N
n!( N n)!
Stirling’s Approximation
ln n! n ln n n
S k ln W
N!
k ln
n!( N n)!
k[ N ln N n ln n ( N n) ln( N n)]
Free Energy
Gibbs Free Energy
G H TS
G = 0 reversible change
G < 0 irreversible or
spontaneous change
G > 0 impossible
Kinetics
Kinetics
Arrhenius plot
Q
rate A exp
RT
ln (rate)
Q
slope
R
1
T
Consider a reaction between different
atomic species A, B and C:
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Q
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