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Calculations

1. Molarity of the standard HCl solution and report it as M ± ΔM

%𝑝𝑢𝑟𝑖𝑡𝑦 1
2(𝑚𝑎𝑠𝑠𝑁𝑎2𝐶𝑂3 )( )( )
100 𝐹𝑊𝑁𝑎2𝐶𝑂3
𝑀𝐻𝐶𝑙 = 𝑉𝐻𝐶𝑙

Trial 1
1
2(0.0918±0.0002)(0.999)( )
= 105.99
0.033±0.10
0.0002 0.10 2
= 0.0524395955 ± 0.0524395955√( )2 + ( )
1.979×10−3 0.033
= 0.05 ± 0.1𝑀

Trial 2
1
2(0.0534±0.0002)(0.999)(105.99)
=
0.019±0.10
0.0002 2 0.10 2
= 0.0529807678 ± 0.0529807678√( ) +( )
0.0534 0.019
= 0.05 ± 0.3𝑀

Trial 2
1
2(0.1181±0.0002)(0.999)(105.99)
=
0.0228±0.10
0.0002 2 0.10
= 0.09764401806 ± 0.09764401806√( ) +( )2
0.1181 0.0228
= 0.10 ± 0.4𝑀

𝑀𝐻𝐶𝑙,1 +𝑀𝐻𝐶𝑙,2 +𝑀𝐻𝐶𝑙,3 (0.05±0.1𝑀)+(0.05±0.3𝑀)+(0.10±0.4𝑀)


𝑀𝐻𝐶𝑙,𝑎𝑣𝑒 = = = 0.06 ± 0.50 M
3 3

2. Percentage composition of the sample and report it as %A ± Δ%

Trial 1
(0.06±0.5𝑀)(0.01090±0.07−0.00510±0.07)
% NaHCO3 = [(0.06±0.5𝑀)(0.00510±0.07)]+[(0.06±0.5𝑀)(0.01090±0.07−0.00510±0.07)] × 100%
0.7 0.7
3.48×10−4 ±3.48×10−4 √(0.01090)2+(0.0051)2 ×100%
= 0.5 2 0.7 2 0.7 0.7 2
(3.06×10−4 ±3.06×10−4 √( ) +( ) )+(3.48×10−4 ±3.48×10−4 √( )2 +( ) )
0.06 0.0051 0.01090 0.0051

= 0.5321100917 ± 90%
= 53% ± 90% NaHCO3
Trial 3

(0.06±0.5𝑀)(0.0087±0.01−0.0044±0.01)
% NaOH = [(0.06±0.5𝑀)(0.0044±0.01)]+[(0.06±0.5𝑀)(0.0087±0.01−0.0044±0.01)] × 100%
0.5 0.1
2.58×10−4 ±2.58×10−4 √(0.06)2 +(0.0043)2
= 0.5 2 0.1 2 0.5 2 0.1 2
× 100%
(2.64×10−4 ±2.64×10−4 √( ) +( ) )+(2.58×10−4 ±2.58×10−4 √( ) +( ) )
0.06 0.0044 0.06 0.0043

= 0.4942528736 ± 14%
= 49% ± 14% NaOH

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