Multiple-choice questions may continue on 2. −1.822 V the next column or page – find all choices before answering. 3. −0.911 V
001 10.0 points 4. −0.836 V
The equilibrium constant for the reaction 2 Hg(ℓ) + 2 Cl− (aq) + Ni2+ (aq) → 004 10.0 points Ni(s) + Hg2 Cl2 (s) What is the Ecell for is 5.6 × 10 −20 at 25 C. Calculate the value of ◦ Mg(s) | Mg2+ (aq)(0.15 M) || E for a cell utilizing this reaction. ◦ Au+ (aq)(0.3 M) | Au(s) ? Assume that the number of electrons trans- 1. − 1.14 V ferred in the reaction is n = 2. Mg2+ + 2 e− → Mg Ered ◦ = −2.36 V + 2. + 0.57 V Au + e → Au − Ered = +1.69 V ◦
3. + 1.14 V 1. 3.2 × 10−2 V
4. − 0.57 V 2. 4.01 V
5. − 0.25 V 3. 4.04 V
002 10.0 points 4. 4.08 V
The standard voltage of the cell 5. 4.03 V Ag(s) | AgBr(s) | Br−(aq) || Ag+(aq) | Ag(s) 005 10.0 points is +0.73 V at 25◦ C. Calculate the equilibrium Calculate the potential for the cell indicated: constant for the cell reaction. Fe | Fe2+ (10−3 M) || Pb2+ (10−5 M) | Pb Pb2+ + 2 e − → Pb E 0 = −0.126 V 1. 2.2 × 1012 Fe2+ + 2 e − → Fe E 0 = −0.440 V 2. 2.0 × 10−15 1. 0.284 V 3. 3.9 × 10−29 2. 0.373 V 4. 4.6 × 10−13 3. 0.255 V 5. 5.1 × 1014 4. 0.196 V 003 10.0 points 5. 0.432 V Calculate the reduction potential for the Zn2+ | Zn electrode if the Zn2+ concentra- 006 10.0 points tion is 3 × 10−3 M. The standard potential Consider the voltaic cell for Pt | H2 (1 atm) | H+ (? M) || Zn2+ + 2 e− → Zn Cl− (1 M) | AgCl(s) | Ag is −0.7628 V. + 2 H + 2 e → H2 − E 0 = 0.00 V AgCl + 1 e − → Ag + Cl− E 0 = 0.222 V 1. −1.672 V cotton (mac5246) – Homework #10 – holcombe – (51055) 2 If the measured cell potential for the cell is 4. 0.01 M 0.430 volts, what is the pH of the solution? 009 10.0 points 1. less than 1.00 Consider the voltaic cell In | In3+ || Ru3+ , Ru2+ | Pt 2. 4.00 In3+ + 3 e− → In E 0 = −0.340 V Ru3+ + 1 e− → Ru2+ E 0 = −0.080 V 3. 0.253 at 25 C. What is the equilibrium constant for ◦
the overall cell reaction?
4. 3.75 1. 7.1 × 1017 5. 3.52 2. 2.4 × 104 007 10.0 points Consider the cell 3. 2.0 × 1021 Pt | H2 (1 atm); H+ (? M) || Hg2 Cl2 (s); Cl− (1 M) | Hg 4. 1.5 × 1013 2 H+ + 2 e − → H2 E 0 = 0.00 V Hg2 Cl2 + 2 e → 2 Hg + 2 Cl E 0 = 0.268 V − − 5. 1.2 × 107 If the measured cell potential for the cell is 0.35 volts, what is the pH of the solution? 6. 1.3 × 101 1. 4.74 010 10.0 points The standard voltage of the cell 2. 2.77 Pt | H2(g) | H+(aq) || Cl− (aq) | AgCl(s) | Ag(s) 3. less than 1.00 is +0.22 V at 25◦ C. Calculate the equilibrium constant for the reaction 4. 1.39 2 AgCl(s) + H2 (g) → 2 Ag(s) + 2 H+ (aq) + 2 Cl− (aq) 5. 5.45 1. 2.7 × 107 008 10.0 points 2. 3.7 A battery formed from the two half re- actions below dies (reaches equilibrium). If 3. 5.2 × 103 [Fe2+ ] was 0.24 M in the dead battery, what would [Cd2+ ] be in the dead battery? 4. 7.4 ◦ Half reaction E Fe2+ −→ Fe −0.44 5. 1.7 × 103 Cd2+ −→ Cd −0.40 011 10.0 points 1. 120.3 M The principle of inhibiting the corrosion of iron by using a sacrificial anode is to allow 2. 0.0.0005 M 1. a metal that is more active than iron to 3. 5.4 M function as a cathode. cotton (mac5246) – Homework #10 – holcombe – (51055) 3 2. a metal with a higher reduction potential 5. Cu to be sacrificed.
3. a metal with a lower oxidation potential
to be sacrificed.
4. the iron to function as the anode.
5. a metal that is a better reducing agent to
be sacrificed.
012 10.0 points
A student was given a standard Fe(s) | Fe2+(aq) half-cell and another half- cell containing an unknown metal M im- mersed in 1 M MNO3 (aq). When these two half-cells were connected at 25 ◦ C, the com- plete cell functioned as a galvanic cell with E = 1.24 V. The reaction was allowed to con- tinue overnight and the two electrodes were weighted. The iron electrode was found to be lighter and the unknown metal electrode was heavier. What is the standard potential of the unknown M+ /M couple?
1. +1.68 V
2. +0.8 V
3. −0.8 V
4. −0.36 V
5. +2.04 V
013 10.0 points
If the standard potentials for the couples Cu2+ | Cu, Ag+ | Ag, and Fe2+ | Fe are +0.34, +0.80, and − 0.44 V, respectively, which is the strongest reducing agent?
Ten-Decimal Tables of the Logarithms of Complex Numbers and for the Transformation from Cartesian to Polar Coordinates: Volume 33 in Mathematical Tables Series