Fuel cell

From Wikipedia, the free encyclopedia

Jump to: navigation, search

For other uses, see Fuel cell (disambiguation).

Direct-methanol fuel cell. The actual fuel cell stack is the layered cube shape in the center of
the image

A fuel cell is an electrochemical cell that converts a source fuel into an electrical current. It
generates electricity inside a cell through reactions between a fuel and an oxidant, triggered
in the presence of an electrolyte. The reactants flow into the cell, and the reaction products
flow out of it, while the electrolyte remains within it. Fuel cells can operate virtually
continuously as long as the necessary flows are maintained.

Fuel cells are different from conventional electrochemical cell batteries in that they consume
reactant from an external source, which must be replenished[1] – a thermodynamically open
system. By contrast, batteries store electrical energy chemically and hence represent a
thermodynamically closed system.

Many combinations of fuels and oxidants are possible. A hydrogen fuel cell uses hydrogen as
its fuel and oxygen (usually from air) as its oxidant. Other fuels include hydrocarbons and
alcohols. Other oxidants include chlorine and chlorine dioxide.[2]

Contents
[hide]

 1 Design
o 1.1 Proton exchange fuel cells
  1.1.1 Proton exchange membrane fuel cell design issues
o 1.2 High temperature fuel cells
 1.2.1 SOFC
 1.2.2 MCFC
 2 History
 3 Types of fuel cell
 4 Efficiency
o 4.1 Fuel cell efficiency
o 4.2 In practice
 5 Fuel cell applications
o 5.1 Power
o 5.2 Cogeneration
o 5.3 Hydrogen transportation and refueling
o 5.4 Other applications
o 5.5 Market structure
 6 Fuel cell economics
 7 Research and development
 8 See also
 9 References
 10 Further reading
 11 External links

[edit] Design
Fuel cells come in many varieties; however, they all work in the same general manner. They
are made up of three segments which are sandwiched together: the anode, the electrolyte, and
the cathode. Two chemical reactions occur at the interfaces of the three different segments.
The net result of the two reactions is that fuel is consumed, water or carbon dioxide is
created, and an electrical current is created, which can be used to power electrical devices,
normally referred to as the load.

At the anode a catalyst oxidizes the fuel, usually hydrogen, turning the fuel into a positively
charged ion and a negatively charged electron. The electrolyte is a substance specifically
designed so ions can pass through it, but the electrons cannot. The freed electrons travel
through a wire creating the electrical current. The ions travel through the electrolyte to the
cathode. Once reaching the cathode, the ions are reunited with the electrons and the two react
with a third chemical, usually oxygen, to create water or carbon dioxide.
A block diagram of a fuel cell

The most important design features in a fuel cell are:

 The electrolyte substance. The electrolyte substance usually defines the type of fuel
cell.
 The fuel that is used. The most common fuel is hydrogen.
 The anode catalyst, which breaks down the fuel into electrons and ions. The anode
catalyst is usually made up of very fine platinum powder.
 The cathode catalyst, which turns the ions into the waste chemicals like water or
carbon dioxide. The cathode catalyst is often made up of nickel.

A typical fuel cell produces a voltage from 0.6 V to 0.7 V at full rated load. Voltage
decreases as current increases, due to several factors:

 Activation loss
 Ohmic loss (voltage drop due to resistance of the cell components and interconnects)
 Mass transport loss (depletion of reactants at catalyst sites under high loads, causing
rapid loss of voltage).[3]

To deliver the desired amount of energy, the fuel cells can be combined in series and parallel
circuits, where series yields higher voltage, and parallel allows a higher current to be
supplied. Such a design is called a fuel cell stack. Further, the cell surface area can be
increased, to allow stronger current from each cell.

[edit] Proton exchange fuel cells

In the archetypal hydrogen–oxygen proton exchange membrane fuel cell (PEMFC) design, a
proton-conducting polymer membrane, (the electrolyte), separates the anode and cathode
sides. This was called a "solid polymer electrolyte fuel cell" (SPEFC) in the early 1970s,
before the proton exchange mechanism was well-understood. (Notice that "polymer
electrolyte membrane" and "proton exchange mechanism" result in the same acronym.)
On the anode side, hydrogen diffuses to the anode catalyst where it later dissociates into
protons and electrons. These protons often react with oxidants causing them to become what
is commonly referred to as multi-facilitated proton membranes. The protons are conducted
through the membrane to the cathode, but the electrons are forced to travel in an external
circuit (supplying power) because the membrane is electrically insulating. On the cathode
catalyst, oxygen molecules react with the electrons (which have traveled through the external
circuit) and protons to form water — in this example, the only waste product, either liquid or
vapor.

In addition to this pure hydrogen type, there are hydrocarbon fuels for fuel cells, including
diesel, methanol (see: direct-methanol fuel cells and indirect methanol fuel cells) and
chemical hydrides. The waste products with these types of fuel are carbon dioxide and water.

Construction of a high temperature PEMFC: Bipolar plate as electrode with in-milled gas
channel structure, fabricated from conductive plastics (enhanced with carbon nanotubes for
more conductivity); Porous carbon papers; reactive layer, usually on the polymer membrane
applied; polymer membrane.

Condensation of water produced by a PEMFC on the air channel wall. The gold wire around
the cell ensures the collection of electric current.[4]

The materials used in fuel cells differ by type. In a typical membrane electrode assembly
(MEA), the electrode–bipolar plates are usually made of metal, nickel or carbon nanotubes,
and are coated with a catalyst (like platinum, nano iron powders or palladium) for higher
efficiency. Carbon paper separates them from the electrolyte. The electrolyte could be
ceramic or a membrane.

[edit] Proton exchange membrane fuel cell design issues

 Costs. In 2002, typical fuel cell systems cost US$1000 per kilowatt of electric power
output. In 2009, the Department of Energy reported that 80-kW automotive fuel cell
system costs in volume production (projected to 500,000 units per year) are $61 per
kilowatt[5] . The goal is $35 per kilowatt. In 2008 UTC Power has 400 kW stationary
fuel cells for $1,000,000 per 400 kW installed costs. The goal is to reduce the cost in
order to compete with current market technologies including gasoline internal
combustion engines. Many companies are working on techniques to reduce cost in a
variety of ways including reducing the amount of platinum needed in each individual
cell. Ballard Power Systems have experiments with a catalyst enhanced with carbon
silk which allows a 30% reduction (1 mg/cm² to 0.7 mg/cm²) in platinum usage
without reduction in performance.[6] Monash University, Melbourne uses PEDOT as a
cathode.[7]
 The production costs of the PEM (proton exchange membrane). The Nafion
membrane currently costs $566/m². In 2005 Ballard Power Systems announced that
its fuel cells will use Solupor, a porous polyethylene film patented by DSM.[8][9]
 Water and air management[10] (in PEMFCs). In this type of fuel cell, the membrane
must be hydrated, requiring water to be evaporated at precisely the same rate that it is
produced. If water is evaporated too quickly, the membrane dries, resistance across it
increases, and eventually it will crack, creating a gas "short circuit" where hydrogen
and oxygen combine directly, generating heat that will damage the fuel cell. If the
water is evaporated too slowly, the electrodes will flood, preventing the reactants
from reaching the catalyst and stopping the reaction. Methods to manage water in
cells are being developed like electroosmotic pumps focusing on flow control. Just as
in a combustion engine, a steady ratio between the reactant and oxygen is necessary to
keep the fuel cell operating efficiently.
 Temperature management. The same temperature must be maintained throughout the
cell in order to prevent destruction of the cell through thermal loading. This is
particularly challenging as the 2H2 + O2 -> 2H2O reaction is highly exothermic, so a
large quantity of heat is generated within the fuel cell.
 Durability, service life, and special requirements for some type of cells. Stationary
fuel cell applications typically require more than 40,000 hours of reliable operation at
a temperature of -35 °C to 40 °C (-31 °F to 104 °F), while automotive fuel cells
require a 5,000 hour lifespan (the equivalent of 150,000 miles) under extreme
temperatures. Current service life is 7,300 hours under cycling conditions.[11]
Automotive engines must also be able to start reliably at -30 °C (-22 °F) and have a
high power to volume ratio (typically 2.5 kW per liter).
 Limited carbon monoxide tolerance of the cathode.

[edit] High temperature fuel cells

[edit] SOFC

Main article: Solid oxide fuel cell

A solid oxide fuel cell (SOFC) is extremely advantageous “because of a possibility of using a
wide variety of fuel” [12]. Unlike most other fuel cells which only use hydrogen, SOFCs can
run on hydrogen, butane, methanol, and other petroleum products. The different fuels each
have their own chemistry.

For methanol fuel cells, on the anode side, a catalyst breaks methanol and water down to
form carbon dioxide, hydrogen ions, and free electrons. The hydrogen ions move across the
electrolyte to the cathode side, where they react with oxygen to create water. A load
connected externally between the anode and cathode completes the electrical circuit. Below
are the chemical equations for the reaction:

Anode Reaction: CH3OH + H2O → CO2 + 6H+ + 6e-

Cathode Reaction: 3/2 O2 + 6H+ + 6e- → 3H2O

Overall Reaction: CH3OH + 3/2 O2 → CO2 + 2H2O + electrical energy

At the anode SOFCs can use nickel or other catalysts to break apart the methanol and create
hydrogen ions and CO2. A solid called yttria stabilized zirconia (YSZ) is used as the
electrolyte. Like all fuel cell electrolytes YSZ is conductive to ions, allowing them to pass
from the anode to cathode, but is non-conductive to electrons. YSZ is a durable solid and is
advantageous in large industrial systems. Although YSZ is a good ion conductor, it only
works at very high temperatures. The standard operating temperature is about 950oC [13].
Running the fuel cell at such a high temperature easily breaks down the methane and oxygen
into ions. A major disadvantage of the SOFC, as a result of the high heat, is that it “places
considerable constraints on the materials which can be used for interconnections” [13]. Another
disadvantage of running the cell at such a high temperature is that other unwanted reactions
may occur inside the fuel cell. It is common for carbon dust, graphite, to build up on the
anode, preventing the fuel from reaching the catalyst. Much research is currently being done
to find alternatives to YSZ that will carry ions at a lower temperature.

[edit] MCFC

Main article: Molten carbonate fuel cell

Molten carbonate fuel cells (MCFCs) operate in a similar manner, except the electrolyte
consists of liquid (molten) carbonate, which is a negative ion and an oxidizing agent. Because
the electrolyte loses carbonate in the oxidation reaction, the carbonate must be replenished
through some means. This is often performed by recirculating the carbon dioxide from the
oxidation products into the cathode where it reacts with the incoming air and reforms
carbonate.

Unlike proton exchange fuel cells, the catalysts in SOFCs and MCFCs are not poisoned by
carbon monoxide, due to much higher operating temperatures. Because the oxidation reaction
occurs in the anode, direct utilization of the carbon monoxide is possible. Also, steam
produced by the oxidation reaction can shift carbon monoxide and steam reform hydrocarbon
fuels inside the anode. These reactions can use the same catalysts used for the
electrochemical reaction, eliminating the need for an external fuel reformer.
MCFC can be used for reducing the CO2 emission from coal fired power plants[14] as well as
gas turbine power plants.[15]

[edit] History
Main article: Timeline of hydrogen technologies

Sketch of William Grove's 1839 fuel cell

The principle of the fuel cell was discovered by German scientist Christian Friedrich
Schönbein in 1838 and published in one of the scientific magazines of the time.[16] Based on
this work, the first fuel cell was demonstrated by Welsh scientist and barrister Sir William
Robert Grove in the February 1839 edition of the Philosophical Magazine and Journal of
Science[17] and later sketched, in 1842, in the same journal.[18] The fuel cell he made used
similar materials to today's phosphoric-acid fuel cell.

In 1955, W. Thomas Grubb, a chemist working for the General Electric Company (GE),
further modified the original fuel cell design by using a sulphonated polystyrene ion-
exchange membrane as the electrolyte. Three years later another GE chemist, Leonard
Niedrach, devised a way of depositing platinum onto the membrane, which served as catalyst
for the necessary hydrogen oxidation and oxygen reduction reactions. This became known as
the 'Grubb-Niedrach fuel cell'. GE went on to develop this technology with NASA and
McDonnell Aircraft, leading to its use during Project Gemini. This was the first commercial
use of a fuel cell. It wasn't until 1959 that British engineer Francis Thomas Bacon
successfully developed a 5 kW stationary fuel cell. In 1959, a team led by Harry Ihrig built a
15 kW fuel cell tractor for Allis-Chalmers which was demonstrated across the US at state
fairs. This system used potassium hydroxide as the electrolyte and compressed hydrogen and
oxygen as the reactants. Later in 1959, Bacon and his colleagues demonstrated a practical
five-kilowatt unit capable of powering a welding machine. In the 1960s, Pratt and Whitney
licensed Bacon's U.S. patents for use in the U.S. space program to supply electricity and
drinking water (hydrogen and oxygen being readily available from the spacecraft tanks).

United Technologies Corporation's UTC Power subsidiary was the first company to
manufacture and commercialize a large, stationary fuel cell system for use as a co-generation
power plant in hospitals, universities and large office buildings. UTC Power continues to
market this fuel cell as the PureCell 200, a 200 kW system (although soon to be replaced by a
400 kW version, expected for sale in late 2009).[19] UTC Power continues to be the sole
supplier of fuel cells to NASA for use in space vehicles, having supplied the Apollo missions,
[20]
and currently the Space Shuttle program, and is developing fuel cells for automobiles,
buses, and cell phone towers; the company has demonstrated the first fuel cell capable of
starting under freezing conditions with its proton exchange membrane automotive fuel cell.

[edit] Types of fuel cell

Efficienc
Qualifie Working Cost
Fuel cell Electrolyt Efficienc y
d power temperatur Status (USD/W)
name e y (cell) (system)
(W) e (°C)
Metal Aqueous > -20
Commercia
hydride fuel alkaline (50% Ppeak @
l / Research
cell solution 0°C)
Electro- Aqueous
Commercia
galvanic fuel alkaline < 40
l / Research
cell solution
Direct
Polymer
formic acid Commercia
membrane < 50 W < 40
fuel cell l / Research
(ionomer)
(DFAFC)
Aqueous
Zinc-air Mass
alkaline < 40
battery production
solution
Polymer
Microbial membrane
< 40 Research
fuel cell or humic
acid
Upflow
microbial
< 40 Research
fuel cell
(UMFC)
Polymer
Regenerative Commercia
membrane < 50
fuel cell l / Research
(ionomer)
Direct Aqueous
Commercia
borohydride alkaline 70
l
fuel cell solution
Aqueous
Alkaline fuel 10 – 100 Commercia
alkaline < 80 60–70% 62%
cell kW l / Research
solution
Direct Polymer
100 mW Commercia
methanol membrane 90–120 20–30% 10–20%
– 1 kW l / Research
fuel cell (ionomer)
Reformed Polymer 5W– 250–300 50–60% 25–40% Commercia
methanol membrane 100 kW (Reformer) l / Research
fuel cell (ionomer) 125–200
 (PBI)
Direct- Polymer
< 140 > 25
ethanol fuel membrane Research
mW/cm² ? 90–120
cell (ionomer)
Proton 50–120
Polymer
exchange 100 W – (Nafion) Commercia
membrane 50–70% 30–50% 30–35
membrane 500 kW 125–220 l / Research
(ionomer)
fuel cell (PBI)
Liquid
electrolytes
with redox
1 kW –
RFC - Redox shuttle and Research
10 MW
polymer
membrane
(Ionomer)
Molten
40%
Phosphoric phosphoric < 10 Commercia
150-200 55% Co-Gen: 4–4.50
acid fuel cell acid MW l / Research
90%
(H3PO4)
Molten Molten
Commercia
carbonate alkaline 100 MW 600-650 55% 47%
l / Research
fuel cell carbonate
Tubular O2--
solid oxide conducting < 100 Commercia
850-1100 60–65% 55–60%
fuel cell ceramic MW l / Research
(TSOFC) oxide
H+-
Protonic
conducting
ceramic fuel 700 Research
ceramic
cell
oxide
Direct
Several Commercia
carbon fuel 700-850 80% 70%
different l / Research
cell
O2--
Planar Solid
conducting < 100 Commercia
oxide fuel 850-1100 60–65% 55–60%
ceramic MW l / Research
cell
oxide
Any that
Enzymatic will not
< 40 Research
Biofuel Cells denature
the enzyme
Magnesium- Commercia
salt water -20 - 55 90%
Air Fuel Cell l / Research

[edit] Efficiency
[edit] Fuel cell efficiency
The efficiency of a fuel cell is dependent on the amount of power drawn from it. Drawing
more power means drawing more current, which increases the losses in the fuel cell. As a
general rule, the more power (current) drawn, the lower the efficiency. Most losses manifest
themselves as a voltage drop in the cell, so the efficiency of a cell is almost proportional to its
voltage. For this reason, it is common to show graphs of voltage versus current (so-called
polarization curves) for fuel cells. A typical cell running at 0.7 V has an efficiency of about
50%, meaning that 50% of the energy content of the hydrogen is converted into electrical
energy; the remaining 50% will be converted into heat. (Depending on the fuel cell system
design, some fuel might leave the system unreacted, constituting an additional loss.)

For a hydrogen cell operating at standard conditions with no reactant leaks, the efficiency is
equal to the cell voltage divided by 1.48 V, based on the enthalpy, or heating value, of the
reaction. For the same cell, the second law efficiency is equal to cell voltage divided by 1.23
V. (This voltage varies with fuel used, and quality and temperature of the cell.) The
difference between these numbers represents the difference between the reaction's enthalpy
and Gibbs free energy. This difference always appears as heat, along with any losses in
electrical conversion efficiency.

Fuel cells do not operate on a thermal cycle. As such, they are not constrained, as combustion
engines are, in the same way by thermodynamic limits, such as Carnot cycle efficiency.[21] At
times this is misrepresented by saying that fuel cells are exempt from the laws of
thermodynamics, because most people think of thermodynamics in terms of combustion
processes (enthalpy of formation). The laws of thermodynamics also hold for chemical
processes (Gibbs free energy) like fuel cells, but the maximum theoretical efficiency is higher
(83% efficient at 298K [22] in the case of hydrogen/oxygen reaction) than the Otto cycle
thermal efficiency (60% for compression ratio of 10 and specific heat ratio of 1.4).
Comparing limits imposed by thermodynamics is not a good predictor of practically
achievable efficiencies. Also, if propulsion is the goal, electrical output of the fuel cell has to
still be converted into mechanical power with another efficiency drop. In reference to the
exemption claim, the correct claim is that the "limitations imposed by the second law of
thermodynamics on the operation of fuel cells are much less severe than the limitations
imposed on conventional energy conversion systems".[23] Consequently, they can have very
high efficiencies in converting chemical energy to electrical energy, especially when they are
operated at low power density, and using pure hydrogen and oxygen as reactants.

It should be underlined that fuel cell (especially high temperature) can be used as a heat
source in conventional heat engine (gas turbine system). In this case the ultra high efficiency
is predicted (above 70%).[24][25]

[edit] In practice

For a fuel cell operating on air, losses due to the air supply system must also be taken into
account. This refers to the pressurization of the air and dehumidifying it. This reduces the
efficiency significantly and brings it near to that of a compression ignition engine.
Furthermore fuel cell efficiency decreases as load increases.

The tank-to-wheel efficiency of a fuel cell vehicle is about 45% at low loads and shows
average values of about 36% when a driving cycle like the NEDC (New European Driving
Cycle) is used as test procedure.[26] The comparable NEDC value for a Diesel vehicle is 22%.
In 2008 Honda released a fuel cell electric vehicle (the Honda FCX Clarity) with fuel stack
claiming a 60% tank-to-wheel efficiency.[27]

It is also important to take losses due to fuel production, transportation, and storage into
account. Fuel cell vehicles running on compressed hydrogen may have a power-plant-to-
wheel efficiency of 22% if the hydrogen is stored as high-pressure gas, and 17% if it is stored
as liquid hydrogen.[28] In addition to the production losses, over 70% of US' electricity used
for hydrogen production comes from thermal power, which only has an efficiency of 33% to
48%, resulting in a net increase in carbon dioxide production by using hydrogen in
vehicles[citation needed].

Fuel cells cannot store energy like a battery, but in some applications, such as stand-alone
power plants based on discontinuous sources such as solar or wind power, they are combined
with electrolyzers and storage systems to form an energy storage system. The overall
efficiency (electricity to hydrogen and back to electricity) of such plants (known as round-
trip efficiency) is between 30 and 50%, depending on conditions.[29] While a much cheaper
lead-acid battery might return about 90%, the electrolyzer/fuel cell system can store
indefinite quantities of hydrogen, and is therefore better suited for long-term storage.

Solid-oxide fuel cells produce exothermic heat from the recombination of the oxygen and
hydrogen. The ceramic can run as hot as 800 degrees Celsius. This heat can be captured and
used to heat water in a micro combined heat and power (m-CHP) application. When the heat
is captured, total efficiency can reach 80-90% at the unit, but does not consider production
and distribution losses. CHP units are being developed today for the European home market.

[edit] Fuel cell applications

Type 212 submarine with fuel cell propulsion of the German Navy in dry dock

[edit] Power

Fuel cells are very useful as power sources in remote locations, such as spacecraft, remote
weather stations, large parks, rural locations, and in certain military applications. A fuel cell
system running on hydrogen can be compact and lightweight, and have no major moving
parts. Because fuel cells have no moving parts and do not involve combustion, in ideal
conditions they can achieve up to 99.9999% reliability.[30] This equates to around one minute
of down time in a two year period.

Since electrolyzer systems do not store fuel in themselves, but rather rely on external storage
units, they can be successfully applied in large-scale energy storage, rural areas being one
example. In this application, batteries would have to be largely oversized to meet the storage
demand, but fuel cells only need a larger storage unit (typically cheaper than an
electrochemical device).
One such pilot program is operating on Stuart Island in Washington State. There the Stuart
Island Energy Initiative[31] has built a complete, closed-loop system: Solar panels power an
electrolyzer which makes hydrogen. The hydrogen is stored in a 500 gallon tank at 200 PSI,
and runs a ReliOn fuel cell to provide full electric back-up to the off-the-grid residence.

[edit] Cogeneration

Configuration of components in a fuel cell car.

Micro combined heat and power (MicroCHP) systems such as home fuel cells and
cogeneration for office buildings and factories are in mass production phase. The system
generates constant electric power (selling excess power back to the grid when it is not
consumed), and at the same time produces hot air and water from the waste heat. MicroCHP
is usually less than 5 kWe for a home fuel cell or small business.[32] A lower fuel-to-electricity
conversion efficiency is tolerated (typically 15-20%), because most of the energy not
converted into electricity is utilized as heat. Some heat is lost with the exhaust gas just as in a
normal furnace, so the combined heat and power efficiency is still lower than 100%, typically
around 80%. In terms of exergy however, the process is inefficient, and one could do better
by maximizing the electricity generated and then using the electricity to drive a heat pump.
Phosphoric-acid fuel cells (PAFC) comprise the largest segment of existing CHP products
worldwide and can provide combined efficiencies close to 90%[33] (35-50% electric +
remainder as thermal) Molten-carbonate fuel cells have also been installed in these
applications, and solid-oxide fuel cell prototypes exist.

[edit] Hydrogen transportation and refueling

Main articles: Fuel cell vehicle, Hydrogen vehicle, Hydrogen station, and Hydrogen highway

The world's first certified Fuel Cell Boat (HYDRA), in Leipzig/Germany

Toyota FCHV PEM FC fuel cell vehicle.

Mercedes-Benz (Daimler AG) Citaro fuel cell bus on Aldwych, London.

Element One fuel cell vehicle.

Hydrogen fueling station.

Toyota's FCHV-BUS at the Expo 2005.

 Land vehicles

In 2003 President George Bush proposed the Hydrogen Fuel Initiative (HFI), which was later
implemented by legislation through the 2005 Energy Policy Act and the 2006 Advanced
Energy Initiative. These aimed at further developing hydrogen fuel cells and its infrastructure
technologies with the ultimate goal to produce commercial fuel cell vehicles by 2020. By
2008, the U.S. had contributed 1 billion dollars to this project.[34]

In May 2009, however, the Obama Administration announced that it will "cut off funds" for
the development of fuel cell hydrogen vehicles, since other vehicle technologies will lead to
quicker reduction in emissions in a shorter time. The US Secretary of Energy explained that
hydrogen vehicles "will not be practical over the next 10 to 20 years", and also mentioned the
challenges involved in the development of the required infrastructure to distribute hydrogen
fuel. Nevertheless, the U.S. government will continue to fund research related to stationary
fuel cells.[35] The National Hydrogen Association and the U.S. Fuel Cell Council criticized
this decision arguing that "...the cuts proposed in the DOE hydrogen and fuel cell program
threaten to disrupt commercialization of a family of technologies that are showing
exceptional promise and beginning to gain market traction."[36]

There are numerous prototype or production cars and buses based on fuel cell technology
being researched or manufactured by motor car manufacturers.

The GM 1966 Electrovan was the automotive industry's first attempt at an automobile
powered by a hydrogen fuel cell. The Electrovan, which weighed more than twice as much as
a normal van, could travel up to 70 mph for 30 seconds.[26][37]

The 2001 Chrysler Natrium used its own on-board hydrogen processor. It produces hydrogen
for the fuel cell by reacting sodium borohydride fuel with Borax, both of which Chrysler
claimed were naturally occurring in great quantity in the United States.[38] The hydrogen
produces electric power in the fuel cell for near-silent operation and a range of 300 miles
without impinging on passenger space. Chrysler also developed vehicles which separated
hydrogen from gasoline in the vehicle, the purpose being to reduce emissions without relying
on a nonexistent hydrogen infrastructure and to avoid large storage tanks.[39]
In 2005 the British firm Intelligent Energy produced the first ever working hydrogen run
motorcycle called the ENV (Emission Neutral Vehicle). The motorcycle holds enough fuel to
run for four hours, and to travel 100 miles in an urban area, at a top speed of 50 miles per
hour.[40] In 2004 Honda developed a fuel-cell motorcycle which utilized the Honda FC Stack.
[41][42]

In 2007, the Revolve Eco-Rally (launched by HRH Prince of Wales) demonstrated several
fuel cell vehicles on British roads for the first time, driven by celebrities and dignitaries from
Brighton to London's Trafalgar Square.[citation needed] Fuel cell powered race vehicles, designed
and built by university students from around the world, competed in the world's first
hydrogen race series called the 2008 Formula Zero Championship, which began on August
22, 2008 in Rotterdam, the Netherlands. More races are planned for 2009 and 2010. After this
first race, Greenchoice Forze from the university of Delft (The Netherlands) became leader in
the competition. Other competing teams are Element One (Detroit), HerUCLAs (LA),
EUPLAtecH2 (Spain), Imperial Racing Green (London) and Zero Emission Racing Team
(Leuven).

In 2008, Honda released a hydrogen vehicle, the FCX Clarity. Meanwhile there exist also
other examples of bikes[43] and bicycles[44] with a hydrogen fuel cell engine.

A few companies are conducting hydrogen fuel cell research and practical fuel cell bus trials.
Daimler AG, with thirty-six experimental units powered by Ballard Power Systems fuel cells
completing a successful three-year trial, in eleven cities, in January 2007. [45][46] There are also
fuel cell powered buses currently active or in production, such as a fleet of Thor buses with
UTC Power fuel cells in California, operated by SunLine Transit Agency.[47] The Fuel Cell
Bus Club is a global cooperative effort in trial fuel cell buses.

The first Brazilian hydrogen fuel cell bus prototype will begin operation in São Paulo during
the first semester of 2009. The hydrogen bus was manufactured in Caxias do Sul and the
hydrogen fuel will be produced in São Bernardo do Campo from water through electrolysis.
The program, called "Ônibus Brasileiro a Hidrogênio" (Brazilian Hydrogen Autobus),
includes three additional buses.[48][49]

 Airplanes

Boeing researchers and industry partners throughout Europe conducted experimental flight
tests in February 2008 of a manned airplane powered only by a fuel cell and lightweight
batteries. The Fuel Cell Demonstrator Airplane, as it was called, used a Proton Exchange
Membrane (PEM) fuel cell/lithium-ion battery hybrid system to power an electric motor,
which was coupled to a conventional propeller.[50] In 2003, the world's first propeller driven
airplane to be powered entirely by a fuel cell was flown (the first fuel cell powered aircraft
was the Space Shuttle). The fuel cell was a unique FlatStackTM stack design which allowed
the fuel cell to be integrated with the aerodynamic surfaces of the plane.[51]

 Boats

The world's first Fuel Cell Boat HYDRA used an AFC system with 6.5 kW net output.

 Submarines
The Type 212 submarines of the German and Italian navies use fuel cells to remain
submerged for weeks without the need to surface.

 Fueling stations

The first public hydrogen refueling station was opened in Reykjavík, Iceland in April 2003.
This station serves three buses built by DaimlerChrysler that are in service in the public
transport net of Reykjavík. The station produces the hydrogen it needs by itself, with an
electrolyzing unit (produced by Norsk Hydro), and does not need refilling: all that enters is
electricity and water. Royal Dutch Shell is also a partner in the project. The station has no
roof, in order to allow any leaked hydrogen to escape to the atmosphere.

The California Hydrogen Highway is an initiative by the California Governor to implement a

series of hydrogen refueling stations along that state. These stations are used to refuel
hydrogen vehicles such as fuel cell vehicles and hydrogen combustion vehicles. As of July
2007 California had 179 fuel cell vehicles and twenty five stations were in operation,[52] and
ten more stations have been planned for assembly in California. However, there have already
been three hydrogen fueling stations decommissioned.[53]

South Carolina also has a hydrogen freeway in the works. There are currently two hydrogen
fueling stations, both in Aiken and Columbia, SC. Additional stations are expected in places
around South Carolina such as Charleston, Myrtle Beach, Greenville, and Florence.
According to the South Carolina Hydrogen & Fuel Cell Alliance, the Columbia station has a
current capacity of 120 kg a day, with future plans to develop on-site hydrogen production
from electrolysis and reformation. The Aiken station has a current capacity of 80 kg. There is
extensive funding for Hydrogen fuel cell research and infrastructure in South Carolina. The
University of South Carolina, a founding member of the South Carolina Hydrogen & Fuel
Cell Alliance, received 12.5 million dollars from the Department of Energy for its Future
Fuels Program. [54]

Japan also has a hydrogen highway, as part of the Japan hydrogen fuel cell project. Twelve
hydrogen fueling stations have been built in 11 cities in Japan. Canada, Sweden and Norway
also have hydrogen highways implemented.

[edit] Other applications

 Providing power for base stations or cell sites[55][56]

 Off-grid power supply
 Distributed generation
 Fork Lifts
 Emergency power systems are a type of fuel cell system, which may include lighting,
generators and other apparatus, to provide backup resources in a crisis or when
regular systems fail. They find uses in a wide variety of settings from residential
homes to hospitals, scientific laboratories, data centers[57], telecommunication[58]
equipment and modern naval ships.
 An uninterrupted power supply (UPS) provides emergency power and, depending on
the topology, provide line regulation as well to connected equipment by supplying
power from a separate source when utility power is not available. Unlike a standby
generator, it can provide instant protection from a momentary power interruption.
  Base load power plants
 Electric and hybrid vehicles.
 Notebook computers for applications where AC charging may not be available for
weeks at a time.
 Portable charging docks for small electronics (e.g. a belt clip that charges your cell
phone or PDA).
 Smartphones with high power consumption due to large displays and additional
features like GPS might be equipped with micro fuel cells.
 Small heating appliances [59]

[edit] Market structure

Not all geographic markets are ready for SOFC powered m-CHP appliances. Currently, the
regions that lead the race in Distributed Generation and deployment of fuel cell m-CHP units
are the EU and Japan.[60]

[edit] Fuel cell economics

Use of hydrogen to fuel vehicles would be a critical feature of a hydrogen economy. A fuel
cell and electric motor combination is not directly limited by the Carnot efficiency of an
internal combustion engine.

Low temperature fuel cell stacks proton exchange membrane fuel cell (PEMFC), direct
methanol fuel cell (DMFC) and phosphoric acid fuel cell (PAFC) use a platinum catalyst.
Impurities create catalyst poisoning (reducing activity and efficiency) in these low-
temperature fuel cells, thus high hydrogen purity or higher catalyst densities are required.[61]
Although there are sufficient platinum resources for future demand[62], most predictions of
platinum running out and/or platinum prices soaring do not take into account effects of
reduction in catalyst loading and recycling. Recent research at Brookhaven National
Laboratory could lead to the replacement of platinum by a gold-palladium coating which may
be less susceptible to poisoning and thereby improve fuel cell lifetime considerably.[63]
Another method would use iron and sulphur instead of platinum. This is possible through an
intermediate conversion by bacteria. This would lower the cost of a fuel cell substantially (as
the platinum in a regular fuel cell costs around $1500, and the same amount of iron costs only
around $1.50). The concept is being developed by a coalition of the John Innes Centre and
the University of Milan-Bicocca.[64]

Current targets for a transport PEM fuel cells are 0.2 g/kW Pt – which is a factor of 5
decrease over current loadings – and recent comments from major original equipment
manufacturers (OEMs) indicate that this is possible. Recycling of fuel cells components,
including platinum, will conserve supplies. High-temperature fuel cells, including molten
carbonate fuel cells (MCFC's) and solid oxide fuel cells (SOFC's), do not use platinum as
catalysts, but instead use cheaper materials such as nickel and nickel oxide. They also do not
experience catalyst poisoning by carbon monoxide, and so they do not require high-purity
hydrogen to operate. They can use fuels with an existing and extensive infrastructure, such as
natural gas, directly, without having to first reform it externally to hydrogen and CO followed
by CO removal.