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Unit
18 Rate of reaction
Fig. 18.1 The burning of fireworks is a very fast Fig. 18.2 Rusting of iron is a very slow reaction
reaction
There are many reasons why chemists study reaction rates, for
example:
156
Unit 18 Rate of reaction
–3 –1
The rate of a reaction is usually expressed in mol dm s (i.e.
change in molar concentration per second). Other units such as
mol s–1, cm3 s–1 and g s–1 are also used.
0 0.0200 0 0
157
Topic 4 Acids and Bases
Fig. 18.3 shows three curves obtained by plotting the data of Table
18.1. Look at the triangle drawn on the curve for oxygen between
the time period 300 s to 400 s. Δ[O2(g)] represents the vertical side
of the triangle while Δt represents the horizontal side. The slope
Δ[O2(g)]
of the hypotenuse of the triangle is , i.e. the average rate
Δt
of formation of oxygen during that time period. The steeper the
hypotenuse, the higher the rate.
158
Unit 18 Rate of reaction
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159
Topic 4 Acids and Bases
Solution
0.242 g
Number of moles of CO2 formed =
44.0 g mol–1
= 0.00550 mol
0.00550 mol
Average rate of formation of CO2 =
60 s
–5
= 9.17 x 10 mol s–1
∴ the average rate of formation of carbon dioxide in the first minute is 9.17 x 10–5 mol s–1.
160
Unit 18 Rate of reaction
1 In a chemical reaction between magnesium and an acid, 0.0160 g of hydrogen gas is formed in
the first 40 seconds. What is the average rate of formation of hydrogen in mol s–1 for that time
interval?
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161
Topic 4 Acids and Bases
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Fig. 18.4 The concentration of nitrogen dioxide plotted against time when dinitrogen pentoxide decomposes at 55 °C
Notice that ‘d’ is used rather than Δ to show that the change is
taking place over a very small time interval.
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Fig. 18.5 Determining the instantaneous rate of formation of nitrogen dioxide at t = 350 s
163
Topic 4 Acids and Bases
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Fig. 18.6 Concentration of dinitrogen pentoxide plotted against time when it decomposes at 55 °C
AS 2007 Paper 2 Q2(a)(ii)
AL 2007 Paper 2 Q3(a)(ii)
164
Unit 18 Rate of reaction
A chloroethane sample with concentration of 0.100 mol dm–3 is maintained at 400 °C. The
way in which the concentration of chloroethane varies with time is shown in the graph below.
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i) t = 200 s;
ii) t = 400 s.
b) Suggest how the rate of decomposition of chloroethane varies with time by comparing the
two values calculated in (a).
165
Topic 4 Acids and Bases
Equal volumes of 0.200 mol dm–3 solutions of the two reactants are mixed together and
maintained at a constant temperature of 30 °C. The concentration of methylpropan-2-ol is
determined at different times. The results are shown in the table below.
0 0
120 0.0290
240 0.0480
360 0.0650
480 0.0760
600 0.0820
b) Calculate the average rate of formation of (CH3)3COH(aq) in the first 400 seconds.
A + B 2C
166
Unit 18 Rate of reaction
aA + bB cC + dD
1 d[A] 1 d[B] 1 d[C] 1 d[D]
Rate = – = – = =
a dt b dt c dt d dt
NH3(g) and O2(g) are allowed to react in a closed vessel of constant volume.
d[NO(g)]
The rate of formation of NO(g) =
dt
d[O2(g)]
The rate of consumption of O2(g) = –
dt
a) Express the rate of the reaction in terms of the above two expressions.
b) Find the rate of consumption of O2(g) if the rate of formation of NO(g) is 1.20 x 10–4 mol dm–3 s–1.
AS 2006 Q10(a)(i)
167
Topic 4 Acids and Bases
Solution
1 d[O2(g)] 1 d[NO(g)]
a) Rate = – =
5 dt 4 dt
d[O2(g)]
b) Rate of consumption of O2(g) = –
dt
5 d[NO(g)]
=
4 dt
5 –4 –3 –1
= (1.20 x 10 mol dm s )
4
= 1.50 x 10–4 mol dm–3 s–1
–4 –3 –1
∴ the rate of consumption of O2(g) is 1.50 x 10 mol dm s .
At a particular instant, the rate of formation of iodine was found to be 10–6 mol dm–3 s–1.
168
Unit 18 Rate of reaction
Fig. 18.7 shows the set-up of the experiment. Take the steps below
to follow the progress of the reaction:
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Fig. 18.7 Experimental set-up for collecting hydrogen gas produced in the reaction
between magnesium and dilute hydrochloric acid (showing the changes in the
first half minute only)
1 1 1 1 1 1 1
Time (min) 0 1 1 2 2 3 3 4 4 5 5 6 6
2 2 2 2 2 2 2
Volume of hydrogen
0 8 14 20 25 29 33 36 38 39 40 40 40 40
produced (cm3)
• The rate of the reaction is the highest at the start of the reaction
and the slope of the tangent to the curve at t = 0 min is the
steepest.
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Fig. 18.9 Experimental set-up for measuring the loss in mass of the reaction mixture in the reaction between
calcium carbonate and dilute hydrochloric acid (showing the changes in the first half minute only)
171
Topic 4 Acids and Bases
3 Record the mass of the flask plus its contents and start the stop
watch at the same time.
4 Record the mass of the flask plus its contents every 30 seconds
until the reaction stops.
The table below shows a set of sample results. Fig. 18.10 shows
the curve of loss in mass of the reaction mixture plotted against
time. The loss in mass of the reaction mixture equals the mass of
carbon dioxide formed. We may also plot the mass of the flask and
the reaction mixture against time (Fig. 18.11).
1 1 1 1
Time t (min) 0 1 1 2 2 3 3 4
2 2 2 2
Mass of flask and
110.00 108.50 107.50 106.95 106.60 106.41 106.33 106.30 106.30
reaction mixture (g)
Loss in mass of
0 1.50 2.50 3.05 3.40 3.59 3.67 3.70 3.70
reaction mixture (g)
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Fig. 18.10 A plot of loss in mass of the reaction Fig. 18.11 A plot of mass of the flask and the
mixture against time reaction mixture against time
172
Unit 18 Rate of reaction
2 Tilt the bottle containing the hydrochloric acid to mix the acid
with the magnesium ribbon.
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Fig. 18.12 Experimental set-up for measuring the pressure change in the reaction between magnesium and dilute
hydrochloric acid
The systematic name of oxalate For example, in the oxidation of oxalate ions (C2O42–)* by
ion is ethanedioate ion. permanganate ions (MnO4–), the intensity of the purple colour of
permanganate ions decreases as the reaction proceeds.
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N5 Examination questions may show the Fig. 18.13 The basic components of a colorimeter N5
basic components of a colorimeter
AS 2008 Paper 1 Q7(a),(b)
and ask students to give the name of
AL 2008 Paper 1 Q7(a)(i),(ii)
the instrument and the property of the
reaction mixture measured by it. In practice, we shine the light upon the sample and record the
fraction of light absorbed. This fraction is called the absorbance. The
absorbance is directly proportional to the colour intensity of the sample
and the concentration of the coloured species in the sample.
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Fig. 18.15 A plot of absorbance of the reaction mixture against time
N6 Examination questions often ask about • in the oxidation of methanoic acid by bromine, the intensity
the oxidation of methanoic acid by
bromine.
of the yellow-brown colour of bromine decreases as the reaction
proceeds. N6
4 Start the stop watch at the same time. The cross gets fainter as
the precipitate forms.
5 Stop the stop watch when the cross can no longer be seen from
176
above.
transmittance 透光度
Unit 18 Rate of reaction
(a) When the reactants are being (b) The cross gets fainter as more (c) The cross can no longer be seen
mixed, the cross can be clearly sulphur precipitate forms. as the solution becomes opaque.
seen.
Fig. 18.16 Following the progress of the reaction between sodium thiosulphate solution and dilute sulphuric acid
The cross disappears when enough sulphur forms and the solution
becomes opaque.
If the reaction is fast, the time to reach such a stage will be short.
If the reaction is slow, the time will be long. The length of time taken
to reach such a stage is thus inversely proportional to the average
rate of reaction from the start to the opaque stage.
The average rate of reaction from the start to the opaque stage
1
∝
time to reach the opaque stage
For each of the following reactions, suggest with reason(s) one method that can be used to follow
the progress of the reaction.
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(a) Withdraw a small sample from the reaction mixture (b) Titrate the alkali remaining in the sample of reaction
every 3 minutes and transfer the sample to an excess mixture against standard hydrochloric acid
of ice-cold water
Fig. 18.17 Steps to follow the progress of the alkaline hydrolysis of ethyl ethanoate
Step 1 Mix 100.0 cm3 of 0.0400 mol dm–3 ethyl ethanoate and 100.0 cm3 of 0.0400 mol dm–3
sodium hydroxide solution in a flask kept in a thermostat.
Step 2 Withdraw a 10.0 cm3 sample from the reaction mixture every 3 minutes and transfer it to
an excess of ice-cold water in a conical flask.
Step 3
–3
Titrate the sodium hydroxide remaining in each sample against 0.0100 mol dm
hydrochloric acid.
thermostat 恒温器
179
Topic 4 Acids and Bases
Time (min) 3 6 9 12 15 18
a) Suggest the purpose of transferring the withdrawn sample to ice-cold water in a conical flask in Step
2.
b) Calculate the concentration of hydroxide ions in the reaction mixture at the 3rd minute.
c) Calculate the concentrations of hydroxide ions in the reaction mixture at other time intervals and
plot the concentration against time.
Solution
a) This stops the hydrolysis in the withdrawn sample.
b) Hydrochloric acid and sodium hydroxide solution react according to the following equation:
–3 14.0
Number of moles of HCl used in titration = 0.0100 mol dm x dm3
1 000
= 1.40 x 10–4 mol
( 10.0
1 000 ) 3
dm
∴ the concentration of hydroxide ions in the reaction mixture at the 3rd minute is
0.0140 mol dm–3.
180
Unit 18 Rate of reaction
c)
Time 0 3 6 9 12 15 18
Concentration of
0.0200 0.0140 0.0109 0.00910 0.00775 0.00670 0.00595
hydroxide ions (mol dm–3)
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Advantages
Disadvantages
• Titrimetric analysis takes time and thus cannot be used for rapid
reactions.
181
Topic 4 Acids and Bases
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A worksheet on this activity is
available for download from Jing
Kung Chemistry Website.
Refer to page T62.
1 Compare the titrimetric analysis with methods using physical properties for following the progress
of a reaction. Identify the major differences between them.
2 Why is it better to select a method that does not involve sample withdrawal for following the
progress of a reaction?
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Effect of varying the concentration on the 18.13 Studying the effect of change in
rate of reaction
concentration of a reactant on
3FGFSFODF8FCTJUF the rate of a reaction
• Refer to the following website for a
simulation of the progress of the catalytic
decomposition of hydrogen peroxide
In each of the following activities, you are going to investigate the
solution: effect of varying the concentration of a reactant on the rate of a
http://www.chem.iastate.edu/group/ reaction. You will use different methods to follow the progress of
Greenbowe/sections/projectfolder/
flashfiles/kinetics2/rxnRate01.html the reactions.
• Refer to the following website for a "TTFTTNFOU'PSN
simulated experiment investigating An assessment form on this activity is available for download from Jing Kung
the effect of concentration change on Chemistry Website.
the rate of reaction between sodium
thiosulphate solution and hydrochloric
acid:
18.1
http://www.hkedcity.net/resources/ires/
ires_browse.phtml?res_cat_id=2840 Investigating the effect of varying the concentration of vinegar
solution on the rate of its reaction with baking soda (sodium
hydrogencarbonate).
182
Unit 18 Rate of reaction
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An assessment form on this activity is available for download from Jing Kung
Chemistry Website.
18.2
Investigating the effect of varying the concentration of a reactant
on the rate of the reaction between permanganate ions and
oxalate ions in an acidic solution.
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Fig. 18.18 Following the progress of a reaction using colorimeter and data-
logger system
cuvette 比色杯
183
Topic 4 Acids and Bases
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184
Unit 18 Rate of reaction
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The graph shows the variation of the mass of the conical flask and its contents against time.
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a) Write a balanced equation for the reaction between marble and dilute hydrochloric acid.
b) Find, from the graph, the mass of gas evolved from the reaction between marble and dilute
hydrochloric acid.
185
Topic 4 Acids and Bases
c) Keeping other conditions unchanged, the experiment was repeated using the same volume of
0.500 mol dm–3 hydrochloric acid.
ii) Sketch a curve on the same graph to show the variation of the mass of the conical flask and
its contents against time.
d) Suggest ONE advantage of using a data-logger in this experiment. CE 2005 Paper 1 Q10(b)(iii)
Solution
a) CaCO3(s) + 2HCl(aq) CaCl2(aq) + H2O(l) + CO2(g)
b) 1.10 g
c) i) The concentration of the hydrochloric acid is halved in the repeated experiment, but the same
volume is used. Therefore the number of moles of HCl in the acid is half that in the first
experiment. The amount of gas evolved is also half that in the first experiment.
1.10
∴ mass of gas evolved in the repeated experiment = g
2
= 0.550 g
ii)
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d) As the change in the mass is very small in this experiment, the use of a data-logger can give more
accurate results.
186
Unit 18 Rate of reaction
b) Would you expect the time required for the completion of Reaction II to be shorter or longer than
that for Reaction I? Explain your answer.
CE 2005 Paper 2 Q34
AS 2006 Q7(b)
Solution
a) When all the magnesium was used up and dissolved in the acid.
b) The time required for the completion of Reaction II would be longer. During the reaction between
magnesium and the acids, magnesium would react with hydrogen ions in the acids.
Hydrochloric acid is a strong acid that completely dissociates in water. On the other hand,
ethanoic acid is a weak acid that only partially dissociates in water. Therefore hydrochloric acid has
a higher concentration of hydrogen ions than ethanoic acid. The reaction rate between magnesium
and ethanoic acid is thus lower and the reaction takes a longer time to complete.
A colorimeter connected to a data-logger was used to follow the progress of the reaction.
Composition of sample
Reaction
Sample Volume of 0.1 mol dm –3
Volume of 1 mol dm–3
Volume of water (cm ) 3 time t (s)
Na2S2O3 (cm3) H2SO4 (cm3)
1 4.0 0.0 4.0 37
AS 2002 Q11(a)
187
Topic 4 Acids and Bases
b) Describe how the rate of the reaction can be obtained from the experimental results.
c) Explain why
d) Plot a suitable graph to show how change in the concentration of sodium thiosulphate in the sample
affects the rate of the reaction.
Solution
a) The time required for the sample to reach a certain level of absorbance could be taken as the reaction
time.
1
b) Rate of the reaction ∝
t
c) i) To keep the total volume of each sample constant. Thus, the concentration of sodium thiosulphate
in the sample is directly proportional to the volume of thiosulphate solution usd.
ii) To ensure that the only variable is the change in the concentration of sodium thiosulphate in
the sample.
d)
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It can be concluded that the rate of the reaction increases when the concentration of sodium
thiosulphate in the sample is increased.
188
Unit 18 Rate of reaction
1 To study the rate of reaction of zinc with excess hydrochloric acid, a student carried out the
following experiments at room temperature.
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b) Draw a labelled diagram of the experimental set-up for carrying out the experiment.
c) Copy the curve for Experiment 1 and draw the expected curve for Experiment 2 next to it.
d) In another experiment, the same mass of zinc was added to 50 cm3 of 2 mol dm–3 sulphuric
acid. The time required for the reaction to complete was shorter than that for Experiment 1.
Explain why.
2 Acidified propanone solution reacts with iodine according to the following equation:
The progress of the reaction can be followed by a colorimeter. Two samples are prepared as
listed below:
189
Topic 4 Acids and Bases
Volume of
Volume of Volume of Number of drops
1 mol dm–3
Sample 1 mol dm–3 distilled water of 0.02 mol dm–3
sulphuric acid
propanone (cm3) (cm3) I2
(cm3)
1 0.75 0.75 1.50 30
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a) Account for the change of absorbance of the sample 4BNQMF
as shown in the graph.
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Surface area of one side of the solid Surface area of 1 small cube
2 2
= 2 x 2 cm = 4 cm = 6 x 1 cm2 = 6 cm2
Total surface area (6 sides) Surface area of 8 small cube
= 6 x 4 cm2 = 24 cm2 cm2 2
= 8 x 6 = 48 cm
Fig. 18.21 If we break a piece of solid into 8 smaller pieces, its surface area
190 doubles
Unit 18 Rate of reaction
7JEFP
Investigating the effect of varying the surface area of marble chips on the rate of their reaction with dilute hydrochloric acid
In the following activity, you are going to investigate the effect
of varying the surface area of a solid reactant on the rate of a
reaction.
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An assessment form on this activity is available for download from Jing Kung
Chemistry Website.
18.3
Investigating the effect of varying the surface area of marble chips
on the rate of their reaction with dilute hydrochloric acid.
18.7 Studying how the particle size of calcium carbonate affects the
rate of its reaction with dilute hydrochloric acid
A flask containing excess 1 mol dm–3 hydrochloric acid was placed on an electronic balance. Some
calcium carbonate lumps were carefully added into the flask. The loss in mass of the reaction mixture
is plotted against time as shown.
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191
Topic 4 Acids and Bases
b) Why did the mass of the reaction mixture decrease during the experiment?
c) The dotted line represents the results from another experiment run under the same conditions except
using calcium carbonate of a different particle size. Would you expect the particle size to be larger
or smaller? Explain your answer.
Solution
a) CaCO3(s) + 2HCl(aq) CaCl2(aq) + CO2(g) + H2O(l)
c) The particle size of the calcium carbonate was smaller as the reaction represented by the dotted line
took less time to complete, i.e. the rate of this reaction was higher.
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• Effect of varying the temperature on the "TTFTTNFOU'PSN
rate of reaction An assessment form on this activity is available for
• Reaction rate and effective collisions download from Jing Kung Chemistry Website.
— Effect of concentration 18.5
• Reaction rate and effective collisions
— Effect of surface area Investigating the effect of varying the temperature on the rate
• Reaction rate and effective collisions
— Effect of temperature of acid hydrolysis of ethyl ethanoate.
192
Unit 18 Rate of reaction
a) Plot a graph of the time the milk keeps against the temperature.
c) Use your curve to predict how long the milk will keep at 20 °C.
Solution
a)
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193
Topic 4 Acids and Bases
b) The graph is a decreasing curve. As temperature increases, shelf life becomes shorter.
c) 1.4 days.
Some powdered calcium carbonate are allowed to react with excess 0.50 mol dm–3 hydrochloric acid
in a conical flask. The loss in mass of the reaction mixture is recorded at regular time intervals. The
results are represented by curve X.
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Sketch next to curve X the curve you expect for each of the following changes made:
There are two types of catalysts: positive catalysts and negative catalysts.
A positive catalyst is one that speeds up a reaction. A negative catalyst
is one that slows down a reaction.
18.7
Catalyzing the decomposition of hydrogen peroxide in solution.
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Two related worksheets with answers are available for download from Jing Kung Chemistry Website. Worksheet ➀ consists of
additional questions for promoting active reading. (Note: Questions in this worksheet also cover those in the textbook.)
Worksheet ➁, requiring students to indicate the relationship among various
terms by drawing, may help the less able readers improve their reading skills.
inflate 膨脹
195
Topic 4 Acids and Bases
Airbags are actually inflated by nitrogen gas produced from a rapid decomposition of sodium
azide (NaN3). This gas inflates the bag which bursts out. About a second later, the bag is already
deflating (it has holes in it) in order to get out of the way.
The process, from the initial impact of the crash to full inflation of the airbag, takes only about
40 milliseconds.
When the car decelerates very quickly, as in a head-on crash, the crash sensor would send an
electric spark to the inflator. This activates the decomposition of the sodium azide sealed inside
the inflator. The nitrogen gas produced inflates the airbag, cushioning the driver and reducing the
likelihood of injury.
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Fig. 18.25 In case of a collision, the crash sensor sends an electric spark to the inflator, setting off
a chemical reaction that produces nitrogen gas, which inflates the airbag
Questions
Airbags have been in the news in recent years because of deaths resulting from airbag deployments
in relatively minor low-speed crashes.
Refer to page T68.
1 Discuss how airbag deployments may lead to death.
2 Suggest how the airbag design may be improved so as to minimize such accidents.
196
Unit 18 Rate of reaction
2 The instantaneous rate at time t is equal to the slope of the tangent to a concentration-time
curve at that particular time t. The steeper the slope, the higher the rate.
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aA + bB cC + dD
197
Topic 4 Acids and Bases
f) titrimetric analysis.
5 In most cases, the rate of a reaction increases when the concentration of a reactant is
increased.
6 The rate of a reaction increases when the surface area of a solid reactant is increased.
7 In most cases, the rate of a reaction increases when the temperature is increased.
8 A catalyst is a substance which alters the rate of a reaction without itself undergoing any
permanent chemical changes.
198
Unit 18 Rate of reaction
reaction rate, measuring volume of gas, measuring loss in mass, measuring pressure, measuring colour
intensity, measuring light transmittance, titrimetric analysis, concentration of reactant, surface area of
solid reactant, temperature, presence of catalyst.
d[C2H5OH(aq)]
Rate of formation of ethanol =
2 Ethanol is produced by fermentation of glucose. The equation is: dt
d[C6H12O6(aq)]
Rate of consumption of glucose = –
C6H12O6(aq) 2C2H5OH(aq) + 2CO2(g) dt
d[C6H12O6(aq)] 1 d[C2H5OH(aq)]
glucose ethanol Rate = – =
dt 2 dt
How is the rate of formation of ethanol related to the rate of consumption of glucose?
–3
3 A flask containing excess 1 mol dm hydrochloric acid was placed on an electronic balance. Some zinc
powder was added into the flask. The mass of the flask and its contents was plotted against time as
shown in the graph below.
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199
Topic 4 Acids and Bases
Titrimetric analysis can be used to follow the progress of the reaction. Briefly describe the
procedure. Withdraw small samples of the reaction mixture at regular time intervals.
Quench the reaction by running each sample into an excess of ice-cold water.
Determine the concentration of dicarboxylic acid in each sample by titration with standard sodium hydroxide solution.
5 a) Draw a labelled diagram of a colorimeter and briefly describe how a colorimeter can be used to
follow the progress of a reaction. Refer to page T70.
b) Compare with titrimetric analysis, suggest ONE advantage of using physical methods to follow the
progress of a reaction.
6 Some experiments were conducted to measure the time taken for whole and crushed antacid tablet to
react with excess hydrochloric acid of different concentrations. The volume of acid used was the same
in each case. Conditions of the experiments are shown in the table below.
200
Unit 18 Rate of reaction
8 Excess marble chips (calcium carbonate) were added to 25 cm3 of 2 mol dm–3 hydrochloric acid. Which
measurement, taken at regular time intervals and plotted against time, will give the graph shown
below?
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A Temperature Calcium carbonate reacts with dilute hydrochloric acid to give carbon dioxide
B Volume of gas produced gas.
As carbon dioxide escapes, the reaction mixture gets lighter as the reaction
C pH of solution proceeds.
D Mass of the beaker and contents Hence the mass of the beaker and contents decreases as the reaction
proceeds.
9 The graph shows the variation of concentration of a reactant with time as a reaction proceeds.
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201
Topic 4 Acids and Bases
10 In an experiment to study the reaction between marble chips and dilute hydrochloric acid, the following
graph is obtained:
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Which of the following statements best explains why the slope of the graph rises gently at first and
then steeply beyond point X?
A The marble chips are covered by a layer of oxide which dissolves slowly in the acid.
B The carbon dioxide initially formed dissolves in the acid.
C The acid is cold at the start of the experiment.
D The acid dissociates completely as the reaction proceeds.
11 A student carried out an experiment to investigate the effect of particle size on reaction rate. The reaction
chosen was dilute hydrochloric acid with iron(II) sulphide, a reaction producing a poisonous soluble gas.
Which of the following experimental set-ups is suitable?
A B
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C D
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202
Unit 18 Rate of reaction
12 Two experiments were carried out separately to investigate the rate of reaction of powdered magnesium
with excess dilute sulphuric acid. The same mass of magnesium was used in both experiments. The
volume of hydrogen evolved was measured at regular time intervals.
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Which conditions were used in Experiment 2? Option A — The rate of reaction in Experiment
2 was lower when using a lower
temperature.
Temperature Concentration of acid Option B — The rate of reaction in Experiment
A Lower than Experiment 1 same as Experiment 1 2 would be higher when a higher
temperature and an acid of higher
B Higher than Experiment 1 higher than Experiment 1 concentration were used.
C Same as Experiment 1 same as Experiment 1 Option D — The rate of reaction in Experiment 2
D Same as Experiment 1 higher than Experiment 1 would be higher when an acid of higher
concentration was used.
13 Which of the following statements concerning 20 cm3 of 1 M CH3COOH and 10 cm3 of 1 M H2SO4 is
correct?
203
Topic 4 Acids and Bases
NH3(g) and O2(g) are allowed to react in a vessel of constant volume. Find the rate of consumption
of O2(g) if the rate of formation of NO(g) is 1.24 x 10–4 mol dm–3 s–1.
(HKASLE 2006)
16 The oxidation of iodide ion by arsenic acid, H3AsO4, is described by the following equation:
a) How is the rate of formation of I3–(aq) related to the rate of consumption of I (aq)?
–
Refer to page T70.
– –4 –3 –1
b) The rate of consumption of I (aq) is 4.80 x 10 mol dm s at a certain time interval.
17 For each of the following reactions, suggest with reason(s) one method that can be used to follow the
progress of the reaction.
colourless
O
–
H3C C O–(aq) + O NO2(aq) + H2O(l)
yellow
SO2Cl2(g) SO2(g) + Cl2(g) 1 mole of SO2Cl2 gas decomposes to give 2 moles of gas.
Follow the progress of the reaction by measuring the pressure of the reaction mixture.
d) The acid catalyzed hydrolysis of methyl ethanoate
Withdraw small samples of the reaction mixture at
CH3COOCH3(l) + H2O(l) CH3COOH(aq) + CH3OH(aq) regular time intervals.
Quench the reaction by running each sample into an excess of ice-cold water.
Determine the concentration of ethanoic acid in each sample by titration with standard sodium hydroxide solution.
When the hydrolysis is complete, carry out a final titration to find out the amount of alkali needed to neutralize the acid
catalyst present.
204
Unit 18 Rate of reaction
18 The decomposition of hydrogen peroxide solution into water and oxygen can be catalyzed by a catalyst
contained in potatoes.
The progress of the reaction can be followed by recording the mass over a period of time.
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The following graph was obtained from experiments to find the effect of pH on the efficiency of
the catalyst.
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205
Topic 4 Acids and Bases
a) Calculate the average rate of reaction over the first 20 minutes, in g min–1, for the experiment at
pH 10.
b) Suggest how the rate of reaction at a particular time can be determined, for the experiment at pH
7.
c) Suggest another way of following the progress of the reaction. Draw a labelled diagram of the
experimental set-up.
19 The effect of temperature changes on reaction rate can be studied using the reaction between ethanedioic
acid solution and acidified potassium permanganate solution.
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Describe how the rate of reaction can be obtained from the experimental results.
1
Rate of reaction α
time
(159.68 – 159.99) g
18 a) Average rate of reaction = –
20 min
–1
= 0.0155 g min
b) Draw a tangent to the curve at the particular time.
Determine the slope of the tangent.
c) Measure the volume of gas evolved.
0
gas syringe
potato discs
d) As the change in the mass is very small in this experiment, the use of a data-logger can give more accurate results.
206
Unit 18 Rate of reaction
The concentration of N2O5(g) at a temperature of 52 °C was measured at different times, and the
results are shown in the graph below:
Ym
$PODFOUSBUJPOPG/0 H
–2
(1.00 x 10 – 3.50 x 10–2) mol dm–3
Ym
NPMENm
Ym
Ym
(26.0 – 2.5) s
5JNF T
a) Calculate the average rate of decomposition of N2O5(g) during the time interval 20 – 30 s.
d) Copy the graph and sketch the variation of concentration of O 2(g) with time during the
experiment.
20 a) Average rate of decomposition of N2O5 d) 2 moles of N2O5 decompose to give 1 mole of O2. The
(1.20 x 10–2 – 1.80 x 10–2) mol dm–3 following table shows the concentrations of N2O5 and O2
= – as a function of time.
(30 – 20) s
= 6.00 x 10–4 mol dm–3 s–1
Concentration Change in concentration Concentration
b) Instantaneous rate of decomposition of N2O5(g) at 10 s Time(s) of N2O5(g) of N2O5(g) of O2(g)
(mol dm–3) (mol dm–3) (mol dm–3)
(1.00 x 10–2 – 3.50 x 10–2) mol dm–3
= – 0 4.00 x 10–2 0 0
(26.0 – 2.5) s
–3
= 1.06 x 10 mol dm s
–3 –1
–2 4.00 x 10–2 – 3.30 x 10–2 –2
5 3.30 x 10 0.35 x 10
= 0.70 x 10–2
–2 –2
c) Instantaneous rate of formation of NO2(g) 4.00 x 10 – 2.70 x 10
10 2.70 x 10–2 0.65 x 10–2
= 1.30 x 10–2
d[NO2(g)]
= 4.00 x 10–2 – 2.20 x 10–2
dt 15 2.20 x 10–2 –2 0.90 x 10–2
= 1.80 x 10
1 d[N2O5(g)] 1 d[NO2(g)]
Rate = – = 4.00 x 10–2 – 1.80 x 10–2
2 dt 4 dt 20 1.80 x 10–2 1.10 x 10–2
= 2.20 x 10–2
∴ instantaneous rate of formation of NO2(g) at 10 s 4.00 x 10–2 – 1.20 x 10–2
30 1.20 x 10–2 1.40 x 10–2
= 2 (1.06 x 10–3 mol dm–3 s–1) = 2.80 x 10–2
= 2.12 mol dm–3 s–1 4.00 x 10–2 – 0.80 x 10–2
40 0.80 x 10–2 1.60 x 10–2
= 3.20 x 10–2
207
Topic 4 Acids and Bases
21 An experiment was carried out to study the rate of the following reaction:
A sample of marble chips was allowed to react with 0.1 M hydrochloric acid, which had been
saturated with carbon dioxide. The graph below shows the experimental results obtained.
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DPMMFDUFE DN
5JNF NJO
ii) If the hydrochloric acid used has not been saturated with carbon dioxide, different experimental
results would be obtained. Copy the graph and sketch the results that would be obtained.
b) Suggest how the rate of the reaction at a particular time can be determined from the graph.
(HKASLE 2003)
208
Unit 18 Rate of reaction
X2(g) 2X(g)
In an experiment to study the decomposition of X2(g), 0.100 mol of X2(g) was charged into a closed
container of volume 1 dm3 kept at a constant temperature. The graph below shows the variation of the
concentration of X2(g) in the container with time.
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9 H
5JNF T
a) From the graph, calculate the average rate of decomposition of X2(g) in the time interval from the
start of the experiment to the 40th second.
b) Copy the graph and sketch the variation of the concentration of X(g) with time during the
experiment.
(HKASLE 2005)
209
Topic 4 Acids and Bases
23 Bromine and methanoic acid in aqueous solution react according to the following equation:
$PODFOUSBUJPOPG#S BR
NPMENm
5JNF T
a) Explain how the progress of the reaction could be followed by a colorimeter. Refer to page T71.
b) Give a reason why measuring the volume of CO2(g) is NOT a suitable method for following the
progress of the reaction.
c) How could you obtain the concentration of bromine from the colorimeter reading?
d) i) How was the rate of consumption of Br2(aq) related to the rate of formation of Br–(aq)?
ii) From the graph, determine the instantaneous rate of consumption of Br2(aq) at 150 s.
210
Unit 18 Rate of reaction
24 When an acid is added to bleach, chlorine gas is produced. The diagram below shows the experimental
set-up for carrying out this reaction.
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The reaction was carried out using an excess of acid (10 cm3) at 25 °C. The chlorine was collected
and its volume recorded every half minute. The graph below shows the results obtained.
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5JNF NJO
a) The reaction had not finished after 2.5 minutes. Explain how you know this is true.
The volume of chlorine was still increasing after 2.5 minutes.
b) The reaction finished within 5 minutes. Copy and continue the graph to show this. Use the graph
to estimate the total time for the reaction.
The total time for the reaction is about 4.5 minutes.
c) Keeping all other conditions unchanged, the experiment was repeated
25 A student performed an experiment to investigate the rate of reaction between zinc and an acid. 6 g
of zinc granules was added to a conical flask containing 100 cm3 of 2 M hydrochloric acid at 20 °C.
Afterwards the experiment was repeated with the following changes. In each case, state and explain
whether the expected reaction rate would increase or decrease.
211
Topic 4 Acids and Bases
26 A student investigated the effect of temperature on the rate of reaction. The reaction between sodium
thiosulphate solution and dilute sulphuric acid was used.
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Suggest THREE ways of improving the procedure for the investigation. Refer to page T72.
27 Magnesium reacts with dilute hydrochloric acid to produce hydrogen gas. Describe how you can carry
out a fair experiment to investigate how the concentration of the acid affects the rate of the reaction.
State the results you expect. Refer to page T73.
(For this question, you are required to give answers in paragraph form. Use equations, diagrams and
examples where appropriate.)
212