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Abstract
Joining steel with aluminum involving the fusion of one or both materials is possible by laser beam welding technique. This paper
describes a method, called laser braze welding, which is a suitable process to realize this structure. The main problem with thermal joining
of steel/aluminum assembly with processes such as TIG or MIG is the formation of fragile intermetallic phases, which are detrimental to
the mechanical performances of such joints. Braze welding permits a localized fusion of the materials resulting in a limitation on the
growth of fragile phases. This article presents the results of a statistical approach for an overlap assembly configuration using a filler wire
composed of 85% Zn and 15% Al. Tensile tests carried on these assemblies demonstrate a good performance of the joints. The fracture
mechanisms of the joints are analyzed by a detailed characterization of the seams.
r 2005 Elsevier Ltd. All rights reserved.
0030-3992/$ - see front matter r 2005 Elsevier Ltd. All rights reserved.
doi:10.1016/j.optlastec.2005.08.014
ARTICLE IN PRESS
A. Mathieu et al. / Optics & Laser Technology 39 (2007) 652–661 653
Table 1
Chemical composition of the materials (wt%)
Material Si Mg Fe Zn Mn Cu Ti Cd Pb Cr Al S P C
AA-6016 1.0–1.5 0.25–0.6 o0.5 o0.2 o0.2 o0.2 o0.15 — — o0.1 Bal. — — —
GXES steel 0.006 — Bal. — 0.105 — 0.068 — — — 0.034 0.006 0.009 0.002
Zn-based filler — — o0.02 Bal. — o0.003 — o0.003 o0.003 — 14–16 — — —
Table 2
Variables and levels (4 with 4 levels and 3 with 2 levels)
P (kW) Def. (mm) a (1) SBW (m/min) SFW (m/min) + (mm) Optic
mechanical strength. The other factors can be listed as speed of 2 M/min. Both the laser beam shapings have been
follows in the order of decreasing influence: laser power, tested. Fracture occurred at the steel/seam interface for
filler wire speed, braze welding speed, tilt angle, defocusing seam a and in the heat-affected zone (HAZ) of the base
length and laser beam shaping. Therefore, Table 3 lists the
optimal conditions found using this method.
Table 3
Optimized welding parameters
Fig. 3. Effects of different variables on the mechanical resistance (N/mm) of the joints.
Table 4
Relation Flin–fracture localization
Fig. 5. Fracture observed in the steel for a joint realized with optimal
parameters (sample width 30 mm).
aluminum for seam b (Fig. 4). It was found that the beam
shaping has the substantial impact on the occurrence of the
facture. The two-spot shaping seems to be quite good for
joints of this configuration. As shown in Fig. 4, when using
two spots beam shaping, weld are always more resistant
and fracture occurs in the HAZ. The impact of the two-
spots beam shaping is a different energy repartition from
single spot. The maximum energy density is lower and the
total surface irradiation is bigger. All that leads to a softer
and longer heating of the weld. For optimized process
parameters, fracture is observed in the steel as shown in
Fig. 5. Fig. 7. The three zones of the steel/seam interface.
4. Microstructure observations
4.1. Seam
variable composition: Al from 63% to 73%, Fe from 18% The interface zone situated near the seam foot is the
to 28% and Zn from 5% to 15% (at%). Their growth can most complex. One distinguishes a reaction layer of
be explained by a mechanism of Fe dissolution and thickness below 5 mm. This layer is located between the
precipitation into crystals of Fe–Al and Fe–Al–Zn steel and a light strip which is made almost of pure Zinc
composition. The compounds in this reaction layer are (Fig. 11). One also notes the presence of micro-shrinkage
mainly intermetallic phases like FeAl3 and Fe2Al5 [8]. The pores close to the interface between the reaction layer and
detected zinc is mainly in solid solution with Al. Fig. 10 the light strip. The liquid part of the seam that solidifies last
shows a micro-hardness profile across the steel/seam (Zn-rich zones) contracts and thus leads to the formation
interface in the intermediate part as defined earlier in of the defect. These defects can have more or less
Fig. 7. It can be seen that the micro-hardness values of the importance according to the cooling rate. In the case
reaction layer formed between the steel sheet and the seam shown in Fig. 11, these defects are very small and therefore
is around 400 Hv. This reaction layer is much harder than should not influence the monotonic mechanical strength.
the steel sheet and the seam (between 120 and 150 Hv). Their effect could however be different for fatigue tests.
The presence of the Zn-rich light strip can be explained by
a diffusion mechanism of Al in the solid or mushy state
towards the reaction layer from the Zn–Al rich seam. This
diffusion explains the Al depletion and therefore the Zn
enrichment of the zone located near the reaction layer. The
mechanism involving the creation of the intermetallic
compound layer (precipitation dissolution) is not the same
as in the case of the intermediate part, since the
intermetallic layer in the seam foot does not have the
similar microstructure. The microstructure near the inter-
mediate region has lesser defects and appears more intact.
It is possible that a diffusion mechanism of the Al through
the solid Fe competes with the previous mechanism
Fig. 9. Steel/seam interface near the intermediate part. because of the different cooling rate in the seam foot.
Fig. 12 presents the fracture surfaces of one sample,
shown on the seam side that breaks fractured at the steel/
seam interface. From Fig. 12, it can be observed that the
fracture surface composed of cracked and scaled slabs and
of small dendritic regions. These slabs come from the
reaction layer formed during the process. The brittleness of
the reaction layer is probably the origin of the fracture in
the joint interface with steel but the low cohesion between
the dendritic regions and the steel sheet can explain the low
values of the joint bonding strength.
Fig. 12. Fractograph of the seam side of the fracture, when fracture occurred at the HAZ of the aluminum base material.
Fig. 15. Fracture surface observed by SEM, side aluminum fractographs of the aluminum side of the fracture, when fracture occurred at the HAZ of the
aluminum base material.
Fig. 16. Relation between the length of the steel/seam interface and the mechanical resistance of the tensile specimen.
seam and the steel sheet. The literature [8] said that below a
thickness of 10 mm, the reaction layer seems to be not too
detrimental to the mechanical properties. In the present
observations, the reaction layer was measured to be less
than 15 mm. Moreover, this reaction layer thickness is not
constant along the steel/seam joint since it can vary from 0
to 15 mm.
Acknowledgements
Fig. 19. Relation between the geometrical criterion and the mechanical
strength (Flin).
This work has been carried out in the project ‘‘A3FL’’ of
the French Materials and Processes National Network
correlation between the wetting angle, brazed length and (RNMP: ‘‘Réseau National Matériaux et Procédés’’). The
mechanical strength a geometrical criterion based on the authors would like to thank the French ministry of
ratio between the brazed length (L) and the wetting angle research for the financial support, industrial partners
(y) as defined in Fig. 18 is proposed. (Renault, Alcan and ARES) for providing the materials
Fig. 19 presents the variation of the mechanical strength and facilities, and especially Dr. V. Sorel and Dr. I.
as a function of the ðL=yÞ ratio. It can be observed that Bordesoules for fruitful discussions. Academic partners of
increasing the ratio leads to an increase of the mechanical the project (GEMPPM, LMI and LTDS) are also thanked
strength of the joint. This criterion can be used to predict for fruitful discussions.
the strength of the joint without testing it but simply by
measuring the values of the two parameters L and y. References
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