TUTORIAL SHEETS

THERMODYNAMICS
1. Calculate the entropy change when 2 moles of an ideal gas are
allowed to expand isothermally & reversibly at 20̊ C from a
pressure of 15atm to 3atm.
2. Calculate the change in entropy that occurs when 600Joules of heat
flows from a body at 400K to a body at 273K, assuming that the
temp. Of both bodies does not change due to flow of heat.
3. Calculate the change in free energy at 25̊ C for the reaction:
CO (g) + ½ O2 (g) ―› CO2 (g) ΔH = -67.37 kcal/mol
ΔS = - 20.7 cal/deg/mol
4. Calculate the enthalpy of vaporisation for organic solvent having
b.pt 325K. The vapour pressure for solvent is 0.3222atm at 305K.
5. At what temp. Should water boil at a space station where the
atmospheric pressure is 528mmHg? Latent heat of vaporisation of
water is 545.5cal/g.
6. Melting point of phenol is 314K & its latent heat of fusion is
24.9cal/g. The value of dp/dT is 231atm/deg. Calculate the change
in volume when 1gm of phenol is melt at its m.pt.
7. The free energy change (ΔG) for a given process is ̶ 85.77 kJ at
25°C & ̶ 83.68 kJ at 35°C. Calculate the change in enthalpy &
entropy at 30°C.
8. Calculate ΔA & ΔG for a reversible compression of 5 moles of
ideal gas from 5atm to 100atm at 27°C.
9. Compute the change in chemical potential of a substance if the
partial pressure of an ideal gas falls from 1atm to 0.5atm at 298K.
10. Calculate vapour pressure of water at 80°C if its value at 100°C is
760cm. The mean heat of vaporisation of water is 540cal/g.
11. The heat of vaporisation of water is 40.82kJ/mol. The molar
volume of liquid water is 0.019dm3/mol, & molar volume of steam
is 30.199dm3/mol, at 100°C & 1atm. What would be the change in
boiling point of water at 100°C, if atmospheric pressure is changed
by 1mmHg?

WATER TREATMENT
1. 50 ml of standard hard water containing 1mg of pure CaCO3 per
ml consumed 20 ml of EDTA. 50 ml of water sample consumed
25 ml of same EDTA using EBT indicator. Calculate the total
hardness of water sample in ppm.
2. 100 ml of water sample required 25 ml of N/50 H2SO4 for
neutralization to phenolphthalein end point. After this, methyl
 orange was added to this & further acid required was 5.5 ml.
Calculate the type & magnitude of water alkalinity.
3. 0.28g of CaCO3 was dissolved in HCl & solution was made up
to 1litre with distilled water. 100ml of above solution required
28ml of EDTA solution in titration. 100ml of hard water sample
required 33ml of same EDTA in titration. After boiling 100ml
of hard water, titration required 10ml of EDTA. Calculate
temporary & permanent hardness.
4. 100ml of hard water sample when titrated with phenolphthalein
required 20ml of N/50 HCl for neutralization. Another 100ml of
water sample required 22.5ml of same acid using methyl
orange. Calculate the alkalinity.
5. 50ml of water sample required 20ml of N/ 50 HCl for
neutralisation using phenolphthalein. After this methyl orange
was added & further acid required was again 20ml. Calculate
the alkalinity of water.
6. While titrating a sample of hard water, 50ml of sample
consumed 10ml of 0.01N EDTA to attain the end point.
Calculate the total hardness of the sample in terms of mg/lit.
7. 100ml of hard water neutralizes exactly 12ml of 0.12N HCl
using methyl orange indicator. What kind of hardness is
present? Express the same in terms of mg/lit.

PHASE RULE
1. Calculate P, C, F for the following system:
a) Rhombic sulphur ↔ monoclinic sulphur
b) Two partially miscible liquids in the absence of its vapours.
c) An emulsion of oil in water.
d) Finally ground mixture of graphite, sulphur, NaCl.
e) MgCO3(s) ↔ MgO(s) + CO2 (g)
f) H2O (l) ↔ H2 (g) + ½ O2 (g)
g) 2H2O (s) ↔ H2O (g) + H2O (l)
h) NH4Cl (s) ↔ x NH3 (g) + y HCl (g)
i) N2O4 (g) ↔ 2NO2 (g)
j) 2KClO3 (s) ↔ 2KCl (s) + 3O2 (g)

2. How thermal analysis done on Eutectic mixture?

3. Explain the effect of change in temp. on phases of water system if
pressure is kept constant at 1atm.with phase diagram.